CN107722658A - A kind of preparation method of the sheet material of enhanced water resistance energy - Google Patents

A kind of preparation method of the sheet material of enhanced water resistance energy Download PDF

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Publication number
CN107722658A
CN107722658A CN201710918349.7A CN201710918349A CN107722658A CN 107722658 A CN107722658 A CN 107722658A CN 201710918349 A CN201710918349 A CN 201710918349A CN 107722658 A CN107722658 A CN 107722658A
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China
Prior art keywords
parts
flaggy
sheet material
water resistance
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201710918349.7A
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Chinese (zh)
Inventor
姜剑波
辛世花
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Zhenjiang City Star Yao Intelligent Equipment Co Ltd
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Zhenjiang City Star Yao Intelligent Equipment Co Ltd
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Priority to CN201710918349.7A priority Critical patent/CN107722658A/en
Publication of CN107722658A publication Critical patent/CN107722658A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00Compositions of lignin-containing materials
    • C08L97/02Lignocellulosic material, e.g. wood, straw or bagasse
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1284Application of adhesive
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/726Permeability to liquids, absorption
    • B32B2307/7265Non-permeable
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Dry Formation Of Fiberboard And The Like (AREA)

Abstract

The present invention proposes a kind of preparation method of the sheet material of enhanced water resistance energy, and its step is as follows:(1)Count to mix modified Lauxite, sodium hydroxide, emulsifying agent, cyclohexanone, polypropylene fibre, polyethyleneglycol diglycidylether, silica, isocyanates, coalescents at a temperature of 50 60 DEG C in parts by weight and obtain adhesive;(2)Count extruding obtains the first flaggy, the second flaggy and the 3rd flaggy respectively after 38 50 parts of 35 45 parts of wood powder, 25 30 parts of bamboo powder, 10 18 parts of PVC powder and adhesive mixing in parts by weight;(3)The epoxide-resin glue that a layer thickness is 0.1 0.3mm is respectively coated between the first flaggy, the second flaggy and the 3rd flaggy;(4)The first flaggy after coating epoxide-resin glue, the second flaggy and the 3rd flaggy is hot-forming, and the sheet material being prepared has suitable intensity, while and can reaches good water resistance.

Description

A kind of preparation method of the sheet material of enhanced water resistance energy
Technical field
The present invention relates to a kind of sheet material, specifically a kind of preparation method of the sheet material of enhanced water resistance energy.
Background technology
In water resistance bamboo and wood sheet material, such as:Building template, container bottom board, automobile-used sheet material, reinforced composite wooden floor etc. Production and processing is technical, uses the high adhesive of some water resistances always both at home and abroad, such as:Phenolic resin, polyurethane, melamine Amine-formaldehyde resins etc..These adhesive can crosslink reaction in the process of sheet material with lumber fibre, be formed netted Structure, so as to improve the water resistance of sheet material.But it is high using these adhesive generally existing costs, expend bulk petroleum The problems such as wage source.Use the toxicity such as substantial amounts of phenol, isocyanates, melamine larger in adhesive synthesis simultaneously Industrial chemicals, environment is not only polluted, and producers are endangered larger.Therefore, there is an urgent need to develop, cost is low, pollutes It is small, intensity is high, the novel adhesive of water-tolerant and sheet fabrication technology.
The content of the invention
The present invention proposes a kind of preparation method of the sheet material of enhanced water resistance energy, the sheet material being prepared regarding to the issue above With suitable intensity, while and can reaches good water resistance.
Specific technical scheme is as follows:
A kind of preparation method of the sheet material of enhanced water resistance energy, its step are as follows:
(1)Count modified Lauxite 35-48 parts, sodium hydroxide 5-8 parts, emulsifying agent 3-8 parts, cyclohexanone in parts by weight 40-55 parts, polypropylene fibre 10-15 parts, polyethyleneglycol diglycidylether 12-15 parts, silica 3-5 parts, isocyanates 1-3 parts, coalescents 2-4 parts mix at a temperature of 50-60 DEG C and obtain adhesive;
(2)Count in parts by weight and mix wood powder 35-45 parts, bamboo powder 25-30 parts, PVC powder 10-18 parts and adhesive 38-50 parts Extruding obtains the first flaggy, the second flaggy and the 3rd flaggy respectively afterwards;
(3)The epoxy resin that a layer thickness is 0.1-0.3mm is respectively coated between the first flaggy, the second flaggy and the 3rd flaggy Glue;
(4)The first flaggy after coating epoxide-resin glue, the second flaggy and the 3rd flaggy is hot-forming.
Further, the thickness of the first flaggy is 1-2mm, and the thickness of the second flaggy is 0.2-0.5mm, the thickness of the 3rd flaggy Spend for 1-2mm.
Further, the Lauxite of the modification presses 2 by polyethylene glycol, Lauxite and water:6:3 are mixed with Arrive.
Further, the emulsifying agent is APES.
Further, the coalescents are propandiol butyl ether.
Beneficial effects of the present invention are:The present invention has suitable intensity, while and can reaches good water resistance.
Embodiment
To make technical scheme become apparent from clearly, below the present invention is described further, it is any to this The scheme that the technical characteristic progress equivalencing of inventive technique scheme and conventional reasoning are drawn each falls within the scope of the present invention.
Embodiment one
A kind of preparation method of the sheet material of enhanced water resistance energy, its step are as follows:
(1)Count 40 parts modified of Lauxite, 7 parts of sodium hydroxide, 5 parts of emulsifying agent, 48 parts of cyclohexanone, poly- third in parts by weight 12 parts of alkene fiber, 13 parts of polyethyleneglycol diglycidylether, 4 parts of silica, 2 parts of isocyanates, 3 parts of coalescents are in 50- Mixed at a temperature of 60 DEG C and obtain adhesive;
(2)Counting in parts by weight will extrude respectively after 42 parts of 40 parts of wood powder, 28 parts of bamboo powder, 15 parts of PVC powder and adhesive mixing To the first flaggy, the second flaggy and the 3rd flaggy;
(3)The epoxy resin that a layer thickness is 0.1-0.3mm is respectively coated between the first flaggy, the second flaggy and the 3rd flaggy Glue;
(4)The first flaggy after coating epoxide-resin glue, the second flaggy and the 3rd flaggy is hot-forming.
Further, the thickness of the first flaggy is 1.5mm, and the thickness of the second flaggy is 0.4mm, and the thickness of the 3rd flaggy is 1.5mm。
Further, the Lauxite of the modification presses 2 by polyethylene glycol, Lauxite and water:6:3 are mixed with Arrive.
Further, the emulsifying agent is APES.
Further, the coalescents are propandiol butyl ether.
Embodiment two
A kind of preparation method of the sheet material of enhanced water resistance energy, its step are as follows:
(1)Count 35 parts modified of Lauxite, 5 parts of sodium hydroxide, 3 parts of emulsifying agent, 40 parts of cyclohexanone, poly- third in parts by weight 10 parts of alkene fiber, 12 parts of polyethyleneglycol diglycidylether, 3 parts of silica, 1 part of isocyanates, 2 parts of coalescents are in 50- Mixed at a temperature of 60 DEG C and obtain adhesive;
(2)Counting in parts by weight will extrude respectively after 38 parts of 35 parts of wood powder, 25 parts of bamboo powder, 10 parts of PVC powder and adhesive mixing To the first flaggy, the second flaggy and the 3rd flaggy;
(3)The epoxy resin that a layer thickness is 0.1-0.3mm is respectively coated between the first flaggy, the second flaggy and the 3rd flaggy Glue;
(4)The first flaggy after coating epoxide-resin glue, the second flaggy and the 3rd flaggy is hot-forming.
Further, the thickness of the first flaggy is 1mm, and the thickness of the second flaggy is 0.2mm, and the thickness of the 3rd flaggy is 1mm。
Further, the Lauxite of the modification presses 2 by polyethylene glycol, Lauxite and water:6:3 are mixed with Arrive.
Further, the emulsifying agent is APES.
Further, the coalescents are propandiol butyl ether.
Embodiment three
A kind of preparation method of the sheet material of enhanced water resistance energy, its step are as follows:
(1)Count 48 parts modified of Lauxite, 8 parts of sodium hydroxide, 8 parts of emulsifying agent, 55 parts of cyclohexanone, poly- third in parts by weight 15 parts of alkene fiber, 15 parts of polyethyleneglycol diglycidylether, 5 parts of silica, 3 parts of isocyanates, 4 parts of coalescents are in 50- Mixed at a temperature of 60 DEG C and obtain adhesive;
(2)Counting in parts by weight will extrude respectively after 50 parts of 45 parts of wood powder, 30 parts of bamboo powder, 18 parts of PVC powder and adhesive mixing To the first flaggy, the second flaggy and the 3rd flaggy;
(3)The epoxy resin that a layer thickness is 0.1-0.3mm is respectively coated between the first flaggy, the second flaggy and the 3rd flaggy Glue;
(4)The first flaggy after coating epoxide-resin glue, the second flaggy and the 3rd flaggy is hot-forming.
Further, the thickness of the first flaggy is 2mm, and the thickness of the second flaggy is 0.5mm, and the thickness of the 3rd flaggy is 2mm。
Further, the Lauxite of the modification presses 2 by polyethylene glycol, Lauxite and water:6:3 are mixed with Arrive.
Further, the emulsifying agent is APES.
Further, the coalescents are propandiol butyl ether.

Claims (5)

1. a kind of preparation method of the sheet material of enhanced water resistance energy, it is characterized in that, its step is as follows:
(1)Count modified Lauxite 35-48 parts, sodium hydroxide 5-8 parts, emulsifying agent 3-8 parts, cyclohexanone in parts by weight 40-55 parts, polypropylene fibre 10-15 parts, polyethyleneglycol diglycidylether 12-15 parts, silica 3-5 parts, isocyanates 1-3 parts, coalescents 2-4 parts mix at a temperature of 50-60 DEG C and obtain adhesive;
(2)Count in parts by weight and mix wood powder 35-45 parts, bamboo powder 25-30 parts, PVC powder 10-18 parts and adhesive 38-50 parts Extruding obtains the first flaggy, the second flaggy and the 3rd flaggy respectively afterwards;
(3)The epoxy resin that a layer thickness is 0.1-0.3mm is respectively coated between the first flaggy, the second flaggy and the 3rd flaggy Glue;
(4)The first flaggy after coating epoxide-resin glue, the second flaggy and the 3rd flaggy is hot-forming.
2. a kind of preparation method of the sheet material of enhanced water resistance energy as claimed in claim 1, it is characterized in that, the thickness of the first flaggy For 1-2mm, the thickness of the second flaggy is 0.2-0.5mm, and the thickness of the 3rd flaggy is 1-2mm.
3. a kind of preparation method of the sheet material of enhanced water resistance energy as claimed in claim 1, it is characterized in that, the ureaformaldehyde of the modification Resin presses 2 by polyethylene glycol, Lauxite and water:6:3 are mixed with to obtain.
4. a kind of preparation method of the sheet material of enhanced water resistance energy as claimed in claim 1, it is characterized in that, the emulsifying agent is alkane Base phenol polyethenoxy ether.
5. a kind of preparation method of the sheet material of enhanced water resistance energy as claimed in claim 1, it is characterized in that, the coalescents are Propandiol butyl ether.
CN201710918349.7A 2017-09-30 2017-09-30 A kind of preparation method of the sheet material of enhanced water resistance energy Withdrawn CN107722658A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107603258A (en) * 2017-10-04 2018-01-19 镇江市星耀智能装备有限公司 A kind of sheet material of enhanced water resistance energy
CN107619650A (en) * 2017-10-04 2018-01-23 镇江市星耀智能装备有限公司 A kind of adhesive for water resistant sheet material

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1069509A (en) * 1991-08-15 1993-03-03 鞠纯衡 Lignin modified uric-aldehyde resin and production method thereof
CN101899277A (en) * 2010-04-30 2010-12-01 华烁科技股份有限公司 Waterborne polyurethane adhesive for RFID antenna substrate
CN202130082U (en) * 2011-05-13 2012-02-01 上海杰事杰新材料(集团)股份有限公司 PVC (polyvinyl chloride) wood-plastic foaming cupboard board
CN102585131A (en) * 2012-02-21 2012-07-18 北京化工大学 Glycidyl ether modified urea formaldehyde resin and preparation method thereof
CN103540282A (en) * 2013-09-16 2014-01-29 浙江农林大学 Urea-formaldehyde resin wood adhesive modifier and applications thereof
CN104277742A (en) * 2014-10-23 2015-01-14 泸州市诚实人钢性防水工程有限公司 Waterproof adhesive

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1069509A (en) * 1991-08-15 1993-03-03 鞠纯衡 Lignin modified uric-aldehyde resin and production method thereof
CN101899277A (en) * 2010-04-30 2010-12-01 华烁科技股份有限公司 Waterborne polyurethane adhesive for RFID antenna substrate
CN202130082U (en) * 2011-05-13 2012-02-01 上海杰事杰新材料(集团)股份有限公司 PVC (polyvinyl chloride) wood-plastic foaming cupboard board
CN102585131A (en) * 2012-02-21 2012-07-18 北京化工大学 Glycidyl ether modified urea formaldehyde resin and preparation method thereof
CN103540282A (en) * 2013-09-16 2014-01-29 浙江农林大学 Urea-formaldehyde resin wood adhesive modifier and applications thereof
CN104277742A (en) * 2014-10-23 2015-01-14 泸州市诚实人钢性防水工程有限公司 Waterproof adhesive

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107603258A (en) * 2017-10-04 2018-01-19 镇江市星耀智能装备有限公司 A kind of sheet material of enhanced water resistance energy
CN107619650A (en) * 2017-10-04 2018-01-23 镇江市星耀智能装备有限公司 A kind of adhesive for water resistant sheet material

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