CN107721164A - A kind of quartz glass of absorbable ultraviolet - Google Patents

A kind of quartz glass of absorbable ultraviolet Download PDF

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Publication number
CN107721164A
CN107721164A CN201711109571.9A CN201711109571A CN107721164A CN 107721164 A CN107721164 A CN 107721164A CN 201711109571 A CN201711109571 A CN 201711109571A CN 107721164 A CN107721164 A CN 107721164A
Authority
CN
China
Prior art keywords
sericite
powder
quartz glass
ultraviolet
hours
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711109571.9A
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Chinese (zh)
Inventor
顾承永
介强
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bengbu Yong Cheng Glass Products Co Ltd
Original Assignee
Bengbu Yong Cheng Glass Products Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bengbu Yong Cheng Glass Products Co Ltd filed Critical Bengbu Yong Cheng Glass Products Co Ltd
Priority to CN201711109571.9A priority Critical patent/CN107721164A/en
Publication of CN107721164A publication Critical patent/CN107721164A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B20/00Processes specially adapted for the production of quartz or fused silica articles, not otherwise provided for
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • C03C1/02Pretreated ingredients
    • C03C1/026Pelletisation or prereacting of powdered raw materials
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C4/00Compositions for glass with special properties
    • C03C4/08Compositions for glass with special properties for glass selectively absorbing radiation of specified wave lengths
    • C03C4/085Compositions for glass with special properties for glass selectively absorbing radiation of specified wave lengths for ultraviolet absorbing glass

Abstract

The invention discloses a kind of quartz glass of absorbable ultraviolet, it is related to glass working arts field, is made up of following component:Quartz sand, activation sericite in powder, attapulgite, calcium oxide, carbide slag, perlite, magnesia, barium phosphate 46, fluorite, borax, titanium dioxide, calcium phosphate;The present invention to sericite by carrying out activation process, pass through the sericite and the synergy of perlite after activation, the ability of the absorption ultraviolet of quartz glass prepared by the present invention can greatly be improved, 94.5% can be reached to the absorptivity of long wave ultraviolet (UVA) wavelength (320~400mm), 90.2% can be reached to the absorptivity of ultraviolet B radiation (UVB) wavelength (280~320nm), and also there is infrared external reflection characteristic, the glass that simultaneously prepared by the present invention, its heat-proof quality is preferable, sunshine can effectively be stopped, so as to ensure the cool place of interior, and with unique color and tint, durability is high, more than 30% is improved compared to the common commercially available quartz glass life-span.

Description

A kind of quartz glass of absorbable ultraviolet
Technical field
The invention belongs to glass working arts field, and in particular to a kind of quartz glass of absorbable ultraviolet.
Background technology
Glass is a kind of transparent semisolid, semiliquid material, the formation contiguous network structure in melting, in cooling procedure Viscosity gradually increases and hardened and non crystallized silicates nonmetallic materials.The main component of simple glass is silica, It has very high chemical stability, heat endurance and good transparency, therefore is widely used in every field.People at present Widely used glass be mostly individual layer plate glass, it has good translucency, but heat insulating effect is poor, no It can effectively stop that the heat of outdoor sunshine is got in, so as to cause indoor temperature higher, and can not effectively obstruct ultraviolet Line, excessive ultraviolet easily cause to damage to human body.
The content of the invention
The purpose of the present invention is to be directed to the problem of existing, there is provided a kind of quartz glass of absorbable ultraviolet.
The present invention is achieved by the following technical solutions:
A kind of quartz glass of absorbable ultraviolet, is made up of following component by weight:Quartz sand 120-180, activation thin,tough silk Mica powder 18-25, attapulgite 10-15, calcium oxide 6-10, carbide slag 0.1-0.3, perlite 12-16, magnesia 13-15, phosphorus Sour barium 4-6, fluorite 8-10, borax 0.1-0.5, titanium dioxide 2-4, calcium phosphate 3-6.
Further, the activation sericite in powder preparation method is:By sericite in powder use mass fraction for 2% secondary chlorine Acid sodium solution soaks 35min at 80 DEG C, is then filtered, and is dried to constant weight, then sericite in powder is calcined at 420 DEG C 20min, room temperature is then naturally cooled to, then the glycerine of its quality 10% is added into sericite in powder, after stirring, ground Mill 2 hours, then it is dried to constant weight, crosses 300 mesh, then by sericite in powder ultrasonic disperse into deionized water, with 1500r/ Min rotating speeds stir 30 hours, stand 15min, and mass fraction is made and is 15% sericite in powder suspension slurry, then adds sericite The benzene sulfonic acid sodium salt of silty amount 0.35%, is heated to 55 DEG C, stirs 1.5 hours, is then filtered, adopt be washed with deionized to Neutrality, then it is dried under vacuum to constant weight, produces.
Further, dried under the vacuum to be dried in the case where vacuum is 0.05MPa, temperature is 120 DEG C.
Further, the carbide slag is handled for 2 hours by 800 DEG C of calcinings.
Further, the quartz glass preparation method of the absorbable ultraviolet is:
(1)Raw material is prepared:The above-mentioned each raw material of precise, each raw material is uniformly mixed;
(2)High temperature melting:By mixed raw material at 1650 DEG C high temperature melting, be incubated 2 hours, obtain fused materials;
(3)Processing and forming:Fused materials are clarified, cooled down 3 hours, is 1250 DEG C to temperature, removes smelting furnace, be added to mould In tool, cooling and shaping is carried out, cooldown rate is 10 DEG C/min, until being cooled to room temperature;
(4)Examine:It is ground polishing, deburring, inspection, packaging.
The present invention has advantages below compared with prior art:The present invention passes through work by carrying out activation process to sericite The synergy of sericite and perlite after change, the absorption ultraviolet of quartz glass prepared by the present invention can greatly be improved Ability, 94.5% can be reached to the absorptivity of long wave ultraviolet (UVA) wavelength (320~400mm), to ultraviolet B radiation (UVB) absorptivity of wavelength (280~320nm) can reach 90.2%, and also have infrared external reflection characteristic, to wavelength Infrared reflectivity beyond 800nm is up to more than 88%, while glass prepared by the present invention, and its heat-proof quality is preferable, Neng Gouyou Effect stops sunshine, and so as to ensure the cool place of interior, and with unique color and tint, durability is high, compared to common The commercially available quartz glass life-span improves more than 30%.
Embodiment
Embodiment 1
A kind of quartz glass of absorbable ultraviolet, is made up of following component by weight:Quartz sand 120, activation sericite Powder 18, attapulgite 10, calcium oxide 6, carbide slag 0.1, perlite 12, magnesia 13, barium phosphate 4, fluorite 8, borax 0.1, titanium White powder 2, calcium phosphate 3.
Further, the activation sericite in powder preparation method is:By sericite in powder use mass fraction for 2% secondary chlorine Acid sodium solution soaks 35min at 80 DEG C, is then filtered, and is dried to constant weight, then sericite in powder is calcined at 420 DEG C 20min, room temperature is then naturally cooled to, then the glycerine of its quality 10% is added into sericite in powder, after stirring, ground Mill 2 hours, then it is dried to constant weight, crosses 300 mesh, then by sericite in powder ultrasonic disperse into deionized water, with 1500r/ Min rotating speeds stir 30 hours, stand 15min, and mass fraction is made and is 15% sericite in powder suspension slurry, then adds sericite The benzene sulfonic acid sodium salt of silty amount 0.35%, is heated to 55 DEG C, stirs 1.5 hours, is then filtered, adopt be washed with deionized to Neutrality, then it is dried under vacuum to constant weight, produces.
Further, dried under the vacuum to be dried in the case where vacuum is 0.05MPa, temperature is 120 DEG C.
Further, the carbide slag is handled for 2 hours by 800 DEG C of calcinings.
Further, the quartz glass preparation method of the absorbable ultraviolet is:
(1)Raw material is prepared:The above-mentioned each raw material of precise, each raw material is uniformly mixed;
(2)High temperature melting:By mixed raw material at 1650 DEG C high temperature melting, be incubated 2 hours, obtain fused materials;
(3)Processing and forming:Fused materials are clarified, cooled down 3 hours, is 1250 DEG C to temperature, removes smelting furnace, be added to mould In tool, cooling and shaping is carried out, cooldown rate is 10 DEG C/min, until being cooled to room temperature;
(4)Examine:It is ground polishing, deburring, inspection, packaging.
Embodiment 2
A kind of quartz glass of absorbable ultraviolet, is made up of following component by weight:Quartz sand 180, activation sericite Powder 25, attapulgite 15, calcium oxide 10, carbide slag 0.3, perlite 16, magnesia 15, barium phosphate 6, fluorite 10, borax 0.5, Titanium dioxide 4, calcium phosphate 6.
Further, the activation sericite in powder preparation method is:By sericite in powder use mass fraction for 2% secondary chlorine Acid sodium solution soaks 35min at 80 DEG C, is then filtered, and is dried to constant weight, then sericite in powder is calcined at 420 DEG C 20min, room temperature is then naturally cooled to, then the glycerine of its quality 10% is added into sericite in powder, after stirring, ground Mill 2 hours, then it is dried to constant weight, crosses 300 mesh, then by sericite in powder ultrasonic disperse into deionized water, with 1500r/ Min rotating speeds stir 30 hours, stand 15min, and mass fraction is made and is 15% sericite in powder suspension slurry, then adds sericite The benzene sulfonic acid sodium salt of silty amount 0.35%, is heated to 55 DEG C, stirs 1.5 hours, is then filtered, adopt be washed with deionized to Neutrality, then it is dried under vacuum to constant weight, produces.
Further, dried under the vacuum to be dried in the case where vacuum is 0.05MPa, temperature is 120 DEG C.
Further, the carbide slag is handled for 2 hours by 800 DEG C of calcinings.
Further, the quartz glass preparation method of the absorbable ultraviolet is:
(1)Raw material is prepared:The above-mentioned each raw material of precise, each raw material is uniformly mixed;
(2)High temperature melting:By mixed raw material at 1650 DEG C high temperature melting, be incubated 2 hours, obtain fused materials;
(3)Processing and forming:Fused materials are clarified, cooled down 3 hours, is 1250 DEG C to temperature, removes smelting furnace, be added to mould In tool, cooling and shaping is carried out, cooldown rate is 10 DEG C/min, until being cooled to room temperature;
(4)Examine:It is ground polishing, deburring, inspection, packaging.
Embodiment 3
A kind of quartz glass of absorbable ultraviolet, is made up of following component by weight:Quartz sand 150, activation sericite Powder 20, attapulgite 12, calcium oxide 8, carbide slag 0.2, perlite 15, magnesia 14, barium phosphate 5, fluorite 9, borax 0.3, titanium White powder 3, calcium phosphate 4.
Further, the activation sericite in powder preparation method is:By sericite in powder use mass fraction for 2% secondary chlorine Acid sodium solution soaks 35min at 80 DEG C, is then filtered, and is dried to constant weight, then sericite in powder is calcined at 420 DEG C 20min, room temperature is then naturally cooled to, then the glycerine of its quality 10% is added into sericite in powder, after stirring, ground Mill 2 hours, then it is dried to constant weight, crosses 300 mesh, then by sericite in powder ultrasonic disperse into deionized water, with 1500r/ Min rotating speeds stir 30 hours, stand 15min, and mass fraction is made and is 15% sericite in powder suspension slurry, then adds sericite The benzene sulfonic acid sodium salt of silty amount 0.35%, is heated to 55 DEG C, stirs 1.5 hours, is then filtered, adopt be washed with deionized to Neutrality, then it is dried under vacuum to constant weight, produces.
Further, dried under the vacuum to be dried in the case where vacuum is 0.05MPa, temperature is 120 DEG C.
Further, the carbide slag is handled for 2 hours by 800 DEG C of calcinings.
Further, the quartz glass preparation method of the absorbable ultraviolet is:
(1)Raw material is prepared:The above-mentioned each raw material of precise, each raw material is uniformly mixed;
(2)High temperature melting:By mixed raw material at 1650 DEG C high temperature melting, be incubated 2 hours, obtain fused materials;
(3)Processing and forming:Fused materials are clarified, cooled down 3 hours, is 1250 DEG C to temperature, removes smelting furnace, be added to mould In tool, cooling and shaping is carried out, cooldown rate is 10 DEG C/min, until being cooled to room temperature;
(4)Examine:It is ground polishing, deburring, inspection, packaging.
After tested, using quartz glass prepared by common unmodified sericite to long wave ultraviolet (UVA) wavelength (320~ Absorptivity 400mm) only up to reach 50.5%, to the absorptivity highest of ultraviolet B radiation (UVB) wavelength (280~320nm) Reach 62.2%;And glass prepared by the present invention can reach to the absorptivity of long wave ultraviolet (UVA) wavelength (320~400mm) To 94.5%, 90.2% is up to the absorptivity of ultraviolet B radiation (UVB) wavelength (280~320nm).

Claims (5)

1. a kind of quartz glass of absorbable ultraviolet, it is characterised in that be made up by weight of following component:Quartz sand 120-180, activation sericite in powder 18-25, attapulgite 10-15, calcium oxide 6-10, carbide slag 0.1-0.3, perlite 12-16, Magnesia 13-15, barium phosphate 4-6, fluorite 8-10, borax 0.1-0.5, titanium dioxide 2-4, calcium phosphate 3-6.
A kind of 2. quartz glass of absorbable ultraviolet as claimed in claim 1, it is characterised in that the activation sericite in powder Preparation method is:Use mass fraction to soak 35min at 80 DEG C for 2% liquor natrii hypochloritis sericite in powder, then carry out Filtering, is dried to constant weight, then sericite in powder is calcined into 20min at 420 DEG C, then naturally cools to room temperature, then to sericite The glycerine of its quality 10% is added in powder, after stirring, is ground 2 hours, is then dried to constant weight, crosses 300 mesh, Again by sericite in powder ultrasonic disperse into deionized water, stirred 30 hours with 1500r/min rotating speeds, stand 15min, quality is made Fraction is 15% sericite in powder suspension slurry, then adds the benzene sulfonic acid sodium salt of sericite in powder quality 0.35%, is heated to 55 DEG C, stirring 1.5 hours, then filtered, adopt and be washed with deionized to neutrality, be then dried under vacuum to constant weight, produce.
A kind of 3. quartz glass of absorbable ultraviolet as claimed in claim 2, it is characterised in that under the vacuum drying be It is dried in the case where vacuum is 0.05MPa, temperature is 120 DEG C.
4. a kind of quartz glass of absorbable ultraviolet as claimed in claim 1, it is characterised in that the carbide slag passes through 800 DEG C of calcinings are handled for 2 hours.
A kind of 5. quartz glass of absorbable ultraviolet as claimed in claim 1, it is characterised in that the absorbable ultraviolet Quartz glass preparation method be:
(1)Raw material is prepared:The above-mentioned each raw material of precise, each raw material is uniformly mixed;
(2)High temperature melting:By mixed raw material at 1650 DEG C high temperature melting, be incubated 2 hours, obtain fused materials;
(3)Processing and forming:Fused materials are clarified, cooled down 3 hours, is 1250 DEG C to temperature, removes smelting furnace, be added to mould In tool, cooling and shaping is carried out, cooldown rate is 10 DEG C/min, until being cooled to room temperature;
(4)Examine:It is ground polishing, deburring, inspection, packaging.
CN201711109571.9A 2017-11-11 2017-11-11 A kind of quartz glass of absorbable ultraviolet Pending CN107721164A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711109571.9A CN107721164A (en) 2017-11-11 2017-11-11 A kind of quartz glass of absorbable ultraviolet

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Application Number Priority Date Filing Date Title
CN201711109571.9A CN107721164A (en) 2017-11-11 2017-11-11 A kind of quartz glass of absorbable ultraviolet

Publications (1)

Publication Number Publication Date
CN107721164A true CN107721164A (en) 2018-02-23

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Country Status (1)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112876065A (en) * 2021-02-05 2021-06-01 北京国信同创科技有限责任公司 Lead-containing glass capable of transmitting medium-wave ultraviolet rays and preparation method and application thereof
CN116715436A (en) * 2023-08-07 2023-09-08 山东天旭特种玻璃有限公司 Super white glass for solar energy and preparation method thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103641309A (en) * 2013-11-01 2014-03-19 何开生 Glass composition for absorbing ultraviolet ray and infrared ray and its application

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103641309A (en) * 2013-11-01 2014-03-19 何开生 Glass composition for absorbing ultraviolet ray and infrared ray and its application

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112876065A (en) * 2021-02-05 2021-06-01 北京国信同创科技有限责任公司 Lead-containing glass capable of transmitting medium-wave ultraviolet rays and preparation method and application thereof
CN112876065B (en) * 2021-02-05 2022-10-11 北京国信同创科技有限责任公司 Lead-containing glass capable of transmitting medium-wave ultraviolet rays and preparation method and application thereof
CN116715436A (en) * 2023-08-07 2023-09-08 山东天旭特种玻璃有限公司 Super white glass for solar energy and preparation method thereof
CN116715436B (en) * 2023-08-07 2023-11-24 山东天旭特种玻璃有限公司 Super white glass for solar energy and preparation method thereof

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Application publication date: 20180223

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