CN107720985A - A kind of compound oil field water process antisludging agent - Google Patents
A kind of compound oil field water process antisludging agent Download PDFInfo
- Publication number
- CN107720985A CN107720985A CN201711006853.6A CN201711006853A CN107720985A CN 107720985 A CN107720985 A CN 107720985A CN 201711006853 A CN201711006853 A CN 201711006853A CN 107720985 A CN107720985 A CN 107720985A
- Authority
- CN
- China
- Prior art keywords
- antisludging agent
- oil field
- water process
- present
- field water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
- C02F5/08—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
- C02F5/10—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
- C02F5/14—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
- C02F5/08—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
- C02F5/10—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
- C02F5/08—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
- C02F5/10—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
- C02F5/12—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/10—Nature of the water, waste water, sewage or sludge to be treated from quarries or from mining activities
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Abstract
The invention discloses a kind of compound oil field water process antisludging agent, oil field water process can not be effectively applicable to by solving existing antisludging agent, due to the problem of influence of crude oil causes treatment effect bad during processing.The present invention according to percent by weight, including:The methoxy amphetamine 5 20% of 4 hydroxyl 3;Polyacrylic acid 10 30%;Aromatic thiazole 10 30%;Carboxyl ethylene phosphoric acid 20 50%;Remaining is deionized water.The present invention can effectively avoid crude oil from preventing antisludging agent the influence of fouling, improve the effect of scale inhibition, and effectively reduce the dosage of antisludging agent, and effect is very notable.
Description
Technical field
The present invention relates to antisludging agent, and in particular to a kind of compound oil field water process antisludging agent.
Background technology
At present, in oilfield produced water system, one of the problem of fouling is the most serious run into Water-quality control.Fouling can be sent out
Life is in each position on stratum, pit shaft or ground, some wells and oil reservoir because dirt is too early in the production layer deposition of pit shaft borehole
Ground is discarded;Fouling can also occur to set in gravel packing zone, down-hole pump, oil pipe column, oil nozzle and oil-stocking equipment, gathering line etc.
Standby and water treatment system any position.Fouling can produce to oil field and bring serious harm;Led because incrustation scale belongs to the bad of heat
Body, the formation of incrustation scale greatly reduce heat-transfer effect;Oil reservoir and near wellbore zone fouling, gas channel can be blocked, reduce oil reservoir and ooze
Saturating rate, declines oil well output.The deposition of incrustation scale can cause equipment and the local corrosion of pipeline, perforate and destroy in a short time;
Incrustation scale can also reduce water flow section product, increase resistance to water-flow and conveying energy, rolled up cleaning charge and repair time.
Flood pattern fouling, rises water injection pressure, and energy consumption increases and production capacity reduces.
Oilfield scaling mainly has two big reasons:First, stratum water contains the easy fouling salt ion of high concentration, in oil recovery process
Pressure, temperature or water constituent change change original chemical balance and produce dirt, and main dirty composition is calcium carbonate, can be mixed with carbon
Sour magnesium, calcium sulfate etc..Second, two or more incompatible water mixing, scale-forming ion interact and generate dirt, the most
It common are barium sulfate and strontium sulfate scale.Particularly in offshore oilfield seawater injection recovery process, stratum water often contains barium strontium ion,
And seawater contains substantial amounts of sulfate ion, both mix the barium and strontium sulfate for producing indissoluble.
Also, oil extraction in oil field factory recovered water is to be come out with crude oil from reservoir exploitation, and generation is not only carried in waste water
Various salts and gas ion in the stratum such as the calcium of crude oil, magnesium, barium, strontium, carbonate, sulfate radical, also carry crude oil.Adopting
During oil, thus oil field extracted water be present not only COD and oil content are high, and the problem of temperature is high, salinity is high.
Existing antisludging agent can not be effectively applicable to oil field water process, because the influence of crude oil causes treatment effect during processing
It is bad.
The content of the invention
The technical problems to be solved by the invention are:Existing antisludging agent can not be effectively applicable to oil field water process, processing
When due to the problem of influence of crude oil causes treatment effect bad, and it is an object of the present invention to provide it is a kind of solve the above problems it is compound
Oil field water process antisludging agent.
The present invention is achieved through the following technical solutions:
A kind of compound oil field water process antisludging agent, according to percent by weight, including:
Remaining is deionized water.
It by the optimization of said components and proportioning, can effectively avoid crude oil from preventing antisludging agent the influence of fouling, improve resistance
The effect of dirt, and the dosage of antisludging agent is effectively reduced, effect is very notable.
Further, include according to percent by weight, the present invention:
Remaining is deionized water.
Preferably, the present invention is made up of according to percent by weight following components:
Remaining is deionized water.
As optimal set-up mode, according to percent by weight, the present invention is made up of following components:
Remaining is deionized water.
The present invention compared with prior art, has the following advantages and advantages:
1st, by the optimization of component and proportioning of the invention, crude oil can be effectively avoided to prevent antisludging agent the influence of fouling,
The effect of scale inhibition is improved, and effectively reduces the dosage of antisludging agent, effect is very notable;
2nd, instant component is few, dosage is few, cost is low, and the equipment such as pipe container will not be caused to corrode, to environment
It is pollution-free, environmentally friendly.
Embodiment
For the object, technical solutions and advantages of the present invention are more clearly understood, with reference to embodiment, the present invention is made
Further to describe in detail, exemplary embodiment of the invention and its explanation are only used for explaining the present invention, are not intended as to this
The restriction of invention.
Embodiment 1
A kind of compound oil field water process antisludging agent, including the component of following percetage by weight are formed:
Remaining is deionized water.
Wherein, 4- hydroxy-3-methoxies crystal methamphetamine is 10%;Polyacrylic acid is 23%;Aromatic thiazole is 17%;Carboxylic
Base ethylene phosphoric acid is 24%;Remaining is deionized water.
A kind of above-mentioned preparation technology of compound oil field water process antisludging agent is as follows in the present embodiment:
Step 1: by 4- hydroxy-3-methoxies crystal methamphetamine, polyacrylic acid, aromatic thiazole, carboxyl ethylene phosphoric acid
It is added in deionized water, mixes;
Step 2: heating, makes temperature bring up to 60-80 DEG C, 30-60min is mixed, mixture is made;
Step 3: mixture is added in the sand of 1-2 times of quality, mix, finished product is made after drying.
The particle diameter of the sand is 1 preferably by mass ratio in the present embodiment:1:1 rough sand, middle husky and fine sand are formed, wherein
The particle diameter of rough sand is 3~5mm, and middle husky particle diameter is 0.5~1mm, and the particle diameter of fine sand is 0.01~0.2mm.
Embodiment 2
The preparation technology of heat and salinity tolerance foam discharging agent, it is made up of the component of following percetage by weight:
Remaining is deionized water.
Embodiment 3
The present embodiment and the difference of embodiment 1 are, are made up of the component of following percetage by weight:
Remaining is deionized water.
Embodiment 4
The present embodiment is comparative example, and the present embodiment is made up of the component of following percetage by weight:
Remaining is deionized water.
Embodiment 5
The present embodiment is comparative example, and the present embodiment is made up of the component of following percetage by weight:
Remaining is deionized water.
To finished product made of above-described embodiment in the oil field that saline formation water thereby coexists with oil (containing oil quality 0.5, containing salt quality
0.12) detected in, detect scale inhibition performance, the addition of antisludging agent is respectively 1mg/L, 3mg/L and 5mg/L, and testing result is such as
Shown in table 1.
Table 1
Compounding by the present invention is understood by above table, scale inhibition effect can be effectively improved, and use can also be reduced
Amount.
Above-described embodiment, the purpose of the present invention, technical scheme and beneficial effect are carried out further
Describe in detail, should be understood that the embodiment that the foregoing is only the present invention, be not intended to limit the present invention
Protection domain, within the spirit and principles of the invention, any modification, equivalent substitution and improvements done etc., all should include
Within protection scope of the present invention.
Claims (4)
- A kind of 1. compound oil field water process antisludging agent, it is characterised in that according to percent by weight, including:
- 2. a kind of compound oil field water process antisludging agent according to claim 1, it is characterised in that according to weight percent Number meter, including:
- 3. a kind of compound oil field water process antisludging agent according to claim 2, it is characterised in that according to weight percent Number meter, is made up of following components:
- 4. a kind of compound oil field water process antisludging agent according to claim 3, it is characterised in that according to weight percent Number meter, is made up of following components:
Priority Applications (1)
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CN201711006853.6A CN107720985A (en) | 2017-10-25 | 2017-10-25 | A kind of compound oil field water process antisludging agent |
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CN201711006853.6A CN107720985A (en) | 2017-10-25 | 2017-10-25 | A kind of compound oil field water process antisludging agent |
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CN201711006853.6A Withdrawn CN107720985A (en) | 2017-10-25 | 2017-10-25 | A kind of compound oil field water process antisludging agent |
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6379612B1 (en) * | 1998-07-27 | 2002-04-30 | Champion Technologies, Inc. | Scale inhibitors |
CN101838057A (en) * | 2009-03-16 | 2010-09-22 | 董兆祥 | Multifunctional anti-incrustation corrosion inhibitor and preparation method thereof |
CN103420512A (en) * | 2012-05-25 | 2013-12-04 | 鲍宜仿 | Preparation method of (1-hydroxyethylene) diphosphonic acid compound scale inhibitor |
CN104445651A (en) * | 2014-12-10 | 2015-03-25 | 苏州路路顺机电设备有限公司 | Sewage water treatment agent |
-
2017
- 2017-10-25 CN CN201711006853.6A patent/CN107720985A/en not_active Withdrawn
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6379612B1 (en) * | 1998-07-27 | 2002-04-30 | Champion Technologies, Inc. | Scale inhibitors |
CN101838057A (en) * | 2009-03-16 | 2010-09-22 | 董兆祥 | Multifunctional anti-incrustation corrosion inhibitor and preparation method thereof |
CN103420512A (en) * | 2012-05-25 | 2013-12-04 | 鲍宜仿 | Preparation method of (1-hydroxyethylene) diphosphonic acid compound scale inhibitor |
CN104445651A (en) * | 2014-12-10 | 2015-03-25 | 苏州路路顺机电设备有限公司 | Sewage water treatment agent |
Non-Patent Citations (2)
Title |
---|
严莲荷等: "《水处理药剂及配方手册》", 31 January 2004 * |
吴玉红等: "《禁毒化学技术》", 31 March 2015, 中国人民公安大学出版社 * |
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Application publication date: 20180223 |