CN107720842A - A kind of new restoration of the ecosystem agent - Google Patents

A kind of new restoration of the ecosystem agent Download PDF

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Publication number
CN107720842A
CN107720842A CN201711033087.2A CN201711033087A CN107720842A CN 107720842 A CN107720842 A CN 107720842A CN 201711033087 A CN201711033087 A CN 201711033087A CN 107720842 A CN107720842 A CN 107720842A
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China
Prior art keywords
kaolin
starch
derivative
remodeling
citric acid
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711033087.2A
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Chinese (zh)
Inventor
秋晓东
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhejiang Qiu's Environment Protection Technology Development Co Ltd
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Zhejiang Qiu's Environment Protection Technology Development Co Ltd
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Priority to CN201711033087.2A priority Critical patent/CN107720842A/en
Publication of CN107720842A publication Critical patent/CN107720842A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/281Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/58Treatment of water, waste water, or sewage by removing specified dissolved compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/58Treatment of water, waste water, or sewage by removing specified dissolved compounds
    • C02F1/62Heavy metal compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/722Oxidation by peroxides
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/008Sludge treatment by fixation or solidification
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/101Sulfur compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/105Phosphorus compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/007Contaminated open waterways, rivers, lakes or ponds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/04Oxidation reduction potential [ORP]
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/06Controlling or monitoring parameters in water treatment pH
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/14NH3-N

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Water Treatment By Sorption (AREA)

Abstract

The invention discloses a kind of new restoration of the ecosystem agent, including following composition:10 30wt% nanoscale ferroso-ferric oxide;50 60wt% calper calcium peroxide;10 15wt% kaolin;25 50wt% diatomite;3 5wt% citric acid;5 8wt% chitin and its derivative;30 40wt% remodeling starch.The present invention can solve the problem that the shortcomings of the prior art, with reference to different pollution of river characteristics, adjust its component, by condensing, adsorbing, redox, chelating fix, the physical and chemical process such as separation and precipitation, restoration of the ecosystem in situ is carried out to bed mud, meets the needs of existing market.

Description

A kind of new restoration of the ecosystem agent
Technical field
The present invention relates to a kind of new restoration of the ecosystem agent.
Background technology
As industrial or agricultural is fast-developing, a large amount of sanitary wastewaters and part industrial wastewater rich in organic matter are discharged into river, lake Pool, causes to decline to a great extent to oxygen content of water, causes river and lake that organic with serious pollution phenomenon is generally presented.It is a large amount of dirty Dye thing deposits to river, lake-bottom, causes bed mud to be chronically at anaerobic environment, is progressively degenerated in the case where anaerobe acts on, Cause river course blackening, smelly.At present, the river improvement method to municipal pollution has a desilting, microorganism aeration, water plant and In-situ immobilization etc..Conventional desilting construction investment is big, cumbersome, and mud moisture content is high, and transport and disposal are difficult;Microorganism is aerated Maintenance cost is big, and thinks little of bed mud and aquosity in-situ immobilization;Water plant is decomposed such as maintenance in time, easily corruption, is ruined Water body, later stage plant treatment cost is high, easily causes secondary pollution, so causes Bian Zhibianhei in urban river regulation.It is and former Position restoration of the ecosystem method adds restoration of the ecosystem agent at normal temperatures and pressures can condense heavy metal and organic pollution in sewage quickly, lead to Peroxidating bed mud sulfide eliminates black smelly, activation bed mud indigenous microorganism, reparation water body activity and biosystem, fundamentally changes Kind water quality of river and raising water body self-purification ability;The applicant prepares a kind of new restoration of the ecosystem agent on this basis, with reference to Different pollution of river characteristics, adjust its component, by condensing, adsorbing, redox, chelating fix, the physics such as separation and precipitation Chemical process, restoration of the ecosystem in situ is carried out to bed mud, to meet the needs of existing market.
The content of the invention
The technical problem to be solved in the present invention is to overcome the defects of existing, there is provided a kind of new restoration of the ecosystem agent, with reference to Different pollution of river characteristics, adjust its component, by condensing, adsorbing, redox, chelating fix, the physics such as separation and precipitation Chemical process, restoration of the ecosystem in situ is carried out to bed mud, meets the needs of existing market.
In order to solve the above-mentioned technical problem, the invention provides following technical scheme:
A kind of new restoration of the ecosystem agent, it is characterised in that:Including following composition:
10-30wt% nanoscale ferroso-ferric oxide;
50-60wt% calper calcium peroxide;
10-15wt% kaolin;
25-50wt% diatomite;
3-5wt% citric acid;
5-8wt% chitin and its derivative;
30-40wt% remodeling starch.
The present invention is done further preferably, including following composition:15-30wt% nanoscale ferroso-ferric oxide; 55-60wt% calper calcium peroxide;15-15wt% kaolin;35-50wt% diatomite;3-5wt% citric acid;6- 8wt% chitin and its derivative;35-40wt% remodeling starch.
The present invention is done further preferably, including following composition:10wt% nanoscale ferroso-ferric oxide; 60wt% calper calcium peroxide;15wt% kaolin;25wt% diatomite;3wt% citric acid;8wt% chitin and Its derivative;40wt% remodeling starch.
The present invention is done further preferably, including following composition:30wt% nanoscale ferroso-ferric oxide; 50wt% calper calcium peroxide;10wt% kaolin;50wt% diatomite;5wt% citric acid;5wt% chitin and Its derivative;30wt% remodeling starch.
The present invention is done further preferably, including following composition:20wt% nanoscale ferroso-ferric oxide; 55wt% calper calcium peroxide;13wt% kaolin;38wt% diatomite;4wt% citric acid;6wt% chitin and Its derivative;35wt% remodeling starch.
The present invention is done further preferably, including following composition:28wt% nanoscale ferroso-ferric oxide; 52wt% calper calcium peroxide;14wt% kaolin;40wt% diatomite;3.5wt% citric acid;7wt% chitin And its derivative;38wt% remodeling starch.
The present invention is done further preferably, including following composition:18wt% nanoscale ferroso-ferric oxide; 52wt% calper calcium peroxide;12wt% kaolin;45wt% diatomite;4.5wt% citric acid;6wt% chitin And its derivative;32wt% remodeling starch.
The beneficial effect that is reached of the present invention is compared with prior art:
In this natural inorganic complex ecological renovation agent component, nanoscale ferroso-ferric oxide and calper calcium peroxide absorption and oxygen Change sulfide in bed mud, calper calcium peroxide can also improve bed mud oxidation reduction potential value, and kaolin and diatomite can adsorb, and sink Most of organic or inorganic pollutant in shallow lake and solidification river bottom mud;Citric acid is reacted to neutrality for adjusting pH storerooms;First Shell element and its derivative can chelate heavy metal and sulfide as natural chelate, prevent sulfide from regenerating, and stablize a low mud huge sum of money Category and phosphorus;Starch of retrofiting provides carbon source material and keeps bed mud high-carbon, low nitrogen balance, activate and recover indigenous microorganism in bed mud, Water body activity and biosystem, the ammonia nitrogen in water body is effectively controlled, so as to recover the self-purification capacity in river, is converted into sewage The excellent clean water of water quality, it is limpid bright, reach the class water index of earth's surface four to five, water environment ecological self-purification function is recovered completely After reach the class water quality of earth's surface two to three.The restoration of the ecosystem agent is pure natural mineral matter, sewage can quickly be condensed, raw material are low It is honest and clean, non-secondary pollution, application easy to spread.
From the foregoing, it will be observed that the present invention can solve the problem that the shortcomings of the prior art, it is special with reference to the different pollutions of river Property, adjust its component, by condensing, adsorbing, redox, chelating fix, the physical and chemical process such as separation and precipitation, the bottom of to Mud carries out restoration of the ecosystem in situ, meets the needs of existing market.
Embodiment
The preferred embodiments of the present invention are illustrated below, it will be appreciated that preferred embodiment described herein is only used In the description and interpretation present invention, it is not intended to limit the present invention.
The present invention relates to a kind of new restoration of the ecosystem agent, it is characterised in that:Including following composition:10-30wt%'s receives Meter level ferroso-ferric oxide;50-60wt% calper calcium peroxide;10-15wt% kaolin;25-50wt% diatomite;3- 5wt% citric acid;5-8wt% chitin and its derivative;30-40wt% remodeling starch.Further can preferably one The new restoration of the ecosystem agent of kind, including following composition:15-30wt% nanoscale ferroso-ferric oxide;55-60wt% peroxide Change calcium;15-15wt% kaolin;35-50wt% diatomite;3-5wt% citric acid;6-8wt% chitin and its Derivative;35-40wt% remodeling starch.
Embodiment 1:
A kind of new restoration of the ecosystem agent of the present invention, including following composition:The 10wt% oxidation of nanoscale four three Iron;60wt% calper calcium peroxide;15wt% kaolin;25wt% diatomite;3wt% citric acid;8wt% crust Element and its derivative;40wt% remodeling starch.
In actual use, the PH of sewage is 7.9 to the present invention before improvement, and high violent hydrochlorate index is 12.01mg/L, Ammonia nitrogen index is 4.06mg/L, and total phosphorus index is 0.2mg/L, is bad V classes water quality;But it is for PH using after administering in the present invention 7.1, ammonia nitrogen index is 0.77mg/L, and total phosphorus index is 0.14mg/L, is III class water quality.
Embodiment 2
A kind of new restoration of the ecosystem agent of the present invention, including following composition:30wt% nanoscale ferroso-ferric oxide; 50wt% calper calcium peroxide;10wt% kaolin;50wt% diatomite;5wt% citric acid;5wt% chitin and Its derivative;30wt% remodeling starch.
In actual use, the PH of sewage is 8.16 to the present invention before improvement, and high violent hydrochlorate index is 11.71mg/L, Ammonia nitrogen index is 3.56mg/L, and total phosphorus index is 0.8mg/L, is bad V classes water quality;But it is for PH using after administering in the present invention 7.0, ammonia nitrogen index is 1.87mg/L, and total phosphorus index is 0.07mg/L, is IV class water quality.
Embodiment 3
A kind of new restoration of the ecosystem agent of the present invention, including following composition:20wt% nanoscale ferroso-ferric oxide; 55wt% calper calcium peroxide;13wt% kaolin;38wt% diatomite;4wt% citric acid;6wt% chitin and Its derivative;35wt% remodeling starch.
In actual use, the PH of sewage is 7.5 to the present invention before improvement, and high violent hydrochlorate index is 12.88mg/L, Ammonia nitrogen index is 5.46mg/L, and total phosphorus index is 0.52mg/L, is bad V classes water quality;But it is for PH using after administering in the present invention 7.1, ammonia nitrogen index is 1.57mg/L, and total phosphorus index is 0.24mg/L, is III class water quality.
Embodiment 4
A kind of new restoration of the ecosystem agent of the present invention, including following composition:28wt% nanoscale ferroso-ferric oxide; 52wt% calper calcium peroxide;14wt% kaolin;40wt% diatomite;3.5wt% citric acid;7wt% chitin And its derivative;38wt% remodeling starch.
In actual use, the PH of sewage is 8.12 to the present invention before improvement, and high violent hydrochlorate index is 9.94mg/L, Ammonia nitrogen index is 10.3mg/L, and total phosphorus index is 0.98mg/L, is bad V classes water quality;But it is for PH using after administering in the present invention 7.2, ammonia nitrogen index is 1.45mg/L, and total phosphorus index is 0.22mg/L, is IV class water quality.
Embodiment 5
A kind of new restoration of the ecosystem agent of the present invention, including following composition:18wt% nanoscale ferroso-ferric oxide; 52wt% calper calcium peroxide;12wt% kaolin;45wt% diatomite;4.5wt% citric acid;6wt% chitin And its derivative;32wt% remodeling starch.
In actual use, the PH of sewage is 7.66 to the present invention before improvement, and high violent hydrochlorate index is 11.01mg/L, Ammonia nitrogen index is 3.06mg/L, and total phosphorus index is 0.2mg/L, is bad V classes water quality;But it is for PH using after administering in the present invention 7.35, ammonia nitrogen index is 0.87mg/L, and total phosphorus index is 0.04mg/L, is III class water quality.
Finally it should be noted that:The preferred embodiments of the present invention are the foregoing is only, are not limited to this hair It is bright, although the present invention is described in detail with reference to the foregoing embodiments, for those skilled in the art, its according to The technical scheme described in foregoing embodiments can so be modified, or which part technical characteristic is equal Replace.Within the spirit and principles of the invention, any modification, equivalent substitution and improvements made etc., it should be included in this Within the protection domain of invention.

Claims (7)

  1. A kind of 1. new restoration of the ecosystem agent, it is characterised in that:Including following composition:
    10-30wt% nanoscale ferroso-ferric oxide;
    50-60wt% calper calcium peroxide;
    10-15wt% kaolin;
    25-50wt% diatomite;
    3-5wt% citric acid;
    5-8wt% chitin and its derivative;
    30-40wt% remodeling starch.
  2. A kind of 2. new restoration of the ecosystem agent according to claim 1, it is characterised in that:Including following composition:15- 30wt% nanoscale ferroso-ferric oxide;55-60wt% calper calcium peroxide;15-15wt% kaolin;35-50wt% silicon Diatomaceous earth;3-5wt% citric acid;6-8wt% chitin and its derivative;35-40wt% remodeling starch.
  3. A kind of 3. new restoration of the ecosystem agent according to claim 1, it is characterised in that:Including following composition: 10wt% nanoscale ferroso-ferric oxide;60wt% calper calcium peroxide;15wt% kaolin;25wt% diatomite;3wt% Citric acid;8wt% chitin and its derivative;40wt% remodeling starch.
  4. A kind of 4. new restoration of the ecosystem agent according to claim 1, it is characterised in that:Including following composition: 30wt% nanoscale ferroso-ferric oxide;50wt% calper calcium peroxide;10wt% kaolin;50wt% diatomite;5wt% Citric acid;5wt% chitin and its derivative;30wt% remodeling starch.
  5. A kind of 5. new restoration of the ecosystem agent according to claim 1, it is characterised in that:Including following composition: 20wt% nanoscale ferroso-ferric oxide;55wt% calper calcium peroxide;13wt% kaolin;38wt% diatomite;4wt% Citric acid;6wt% chitin and its derivative;35wt% remodeling starch.
  6. A kind of 6. new restoration of the ecosystem agent according to claim 1, it is characterised in that:Including following composition: 28wt% nanoscale ferroso-ferric oxide;52wt% calper calcium peroxide;14wt% kaolin;40wt% diatomite; 3.5wt% citric acid;7wt% chitin and its derivative;38wt% remodeling starch.
  7. A kind of 7. new restoration of the ecosystem agent according to claim 1, it is characterised in that:Including following composition: 18wt% nanoscale ferroso-ferric oxide;52wt% calper calcium peroxide;12wt% kaolin;45wt% diatomite; 4.5wt% citric acid;6wt% chitin and its derivative;32wt% remodeling starch.
CN201711033087.2A 2017-10-30 2017-10-30 A kind of new restoration of the ecosystem agent Pending CN107720842A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108314271A (en) * 2018-04-08 2018-07-24 安徽美自然环境科技有限公司 One kind being used for landscape water eutrophication deep treatment method
CN108439524A (en) * 2018-04-08 2018-08-24 安徽美自然环境科技有限公司 One kind is for eutrophication water dephosphorization composite drug and preparation method thereof
CN112321102A (en) * 2020-10-26 2021-02-05 安徽省通源环境节能股份有限公司 Black and odorous water body sediment repairing agent and preparation and use methods thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6427686A (en) * 1987-07-23 1989-01-30 Hodogaya Chemical Co Ltd Viscous substance removing agent
CN104671426A (en) * 2013-11-29 2015-06-03 大连三科生物工程有限公司 Culture water body cleaning agent
CN106995220A (en) * 2017-04-25 2017-08-01 四川蓉泰环保技术有限公司 A kind of composition of efficient water treatment agent and preparation method thereof and application method
CN107089718A (en) * 2017-06-02 2017-08-25 常州大学 A kind of nanometer Fe3O4/CaO2The method for repairing PAEs polluted underground waters
CN107200451A (en) * 2017-07-21 2017-09-26 曹恩惠 A kind of NEW TYPE OF COMPOSITE materialization agglutinant and river course, lake desilting in situ and ecological reestablishment

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6427686A (en) * 1987-07-23 1989-01-30 Hodogaya Chemical Co Ltd Viscous substance removing agent
CN104671426A (en) * 2013-11-29 2015-06-03 大连三科生物工程有限公司 Culture water body cleaning agent
CN106995220A (en) * 2017-04-25 2017-08-01 四川蓉泰环保技术有限公司 A kind of composition of efficient water treatment agent and preparation method thereof and application method
CN107089718A (en) * 2017-06-02 2017-08-25 常州大学 A kind of nanometer Fe3O4/CaO2The method for repairing PAEs polluted underground waters
CN107200451A (en) * 2017-07-21 2017-09-26 曹恩惠 A kind of NEW TYPE OF COMPOSITE materialization agglutinant and river course, lake desilting in situ and ecological reestablishment

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108314271A (en) * 2018-04-08 2018-07-24 安徽美自然环境科技有限公司 One kind being used for landscape water eutrophication deep treatment method
CN108439524A (en) * 2018-04-08 2018-08-24 安徽美自然环境科技有限公司 One kind is for eutrophication water dephosphorization composite drug and preparation method thereof
CN112321102A (en) * 2020-10-26 2021-02-05 安徽省通源环境节能股份有限公司 Black and odorous water body sediment repairing agent and preparation and use methods thereof

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Application publication date: 20180223