CN107715663A - A kind of system and method for adsorption type low temperature plasma advanced treating foul gas - Google Patents
A kind of system and method for adsorption type low temperature plasma advanced treating foul gas Download PDFInfo
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- CN107715663A CN107715663A CN201711202052.7A CN201711202052A CN107715663A CN 107715663 A CN107715663 A CN 107715663A CN 201711202052 A CN201711202052 A CN 201711202052A CN 107715663 A CN107715663 A CN 107715663A
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- low temperature
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/32—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by electrical effects other than those provided for in group B01D61/00
- B01D53/323—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by electrical effects other than those provided for in group B01D61/00 by electrostatic effects or by high-voltage electric fields
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/102—Carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/104—Alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/112—Metals or metal compounds not provided for in B01D2253/104 or B01D2253/106
- B01D2253/1122—Metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/116—Molecular sieves other than zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/30—Sulfur compounds
- B01D2257/306—Organic sulfur compounds, e.g. mercaptans
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/702—Hydrocarbons
- B01D2257/7027—Aromatic hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/80—Employing electric, magnetic, electromagnetic or wave energy, or particle radiation
- B01D2259/818—Employing electrical discharges or the generation of a plasma
Abstract
The present invention relates to a kind of system and method for adsorption type low temperature plasma advanced treating foul gas;The system of adsorption type low temperature plasma advanced treating foul gas is sequentially connected composition including vavuum pump, flowmeter, gas cushion, adsorption type low temperature plasma reactor, high-frequency and high-voltage power supply and return-flow system by pipeline;Adsorption type low temperature plasma reactor includes air inlet, gas outlet, lucite shell, separation net, discharge plate, dielectric impedance plate and adsorbent.Present invention incorporates the advantage of lower temperature plasma technology and adsorption technology to handle foul gas, reduces intermediate product, O3The problem of, it is more suitable for being effectively treated various mixed gases, gas below standard after processing is flowed back using return-flow system, reduces the equipment and cost of after-treatment, reduces the expense of whole reaction system.
Description
Technical field
The present invention relates to environmental protection application field, relates generally to a kind of adsorption type low temperature plasma advanced treating stench
The system and method for gas, processing system and method are handled more particularly to the deep purifying to foul gas.
Background technology
The processes such as industrial production, sewage disposal and garbage loading embeading can produce odorant, and these pollutants spill into air
In pollute the environment, be detrimental to health, and regional effect is brought everywhere as the flowing of air is spilt into, therefore arranging
Need to take appropriate technological means to be handled before putting.Wherein endanger larger odorant have inorganic and organic sulfur compound,
Ammonia and organic amine, aromatic hydrocarbons etc..
What on January 15th, 1994 implemented《Emission standard for odor pollutants》(GB14554-93)Define odorant pollutant
(Odor pollutants)Referring to all stimulates olfactory organ to cause people unhappy and damages the gaseous matter of living environment.It is smelly
Gas concentration(Odor concentration)Refer to foul gas(Including peculiar smell)It is diluted, is diluted to just with odorless air
When odorless, required dilution is counted, so without guiding principle amount.For a certain material《Standard》Define methyl mercaptan, methyl sulfide and benzene
The concentration of emission of the organic matters such as ethene, but《Emission standard for odor pollutants》(GB14554-93)With《Air Pollutant Emission mark
It is accurate》(GB16297-96)Promulgate and have 20 years as long as, if industry continues according to this effluent standard, the surrounding air matter of various regions
It is increasingly strict that amount would become hard to satisfaction《Ambient air quality》(GB3095-2012).Therefore the stench of different industries discharge
The discharge standard of different industries is should refer to, such as《Urban wastewater treatment firm pollutant emission standard》(GB18918-2002)、《Medical treatment
Mechanism water pollution discharge standard》(GB18466-2005)Deng all defining specific emission standard.With people to environmental protection and
The consciousness of health gradually steps up, and starts to administer the pollutant of the processing system of full-scale plant waste gas and waste water release gas,
To solve the phenomenon and problem that foul gas disturbs residents.
At present, domestic and international common processing foul gas device mainly has following several:Combustion method, oxidizing process, absorption process,
Absorption method, biological process and low temperature plasma method.Wherein, combustion oxidation method is degraded suitable for high concentration foul gas, is inhaled
Attached method is mainly used to handle the foul gas of low concentration.Absorption process purification gaseous contaminant is to remove gaseous contaminant to eliminate
Pollution, the method are applied to the foul gas of middle and high concentration.Absorption process and absorption method are not removed pollutant thoroughly, but
Foul gas is transferred in solid phase or liquid phase, and then reduces the bad smell of air.And bioanalysis is in processing low concentration, Yi Sheng
Effect consumption and more economy during the stench of thing degraded, requirement of the microorganism to living environment is more harsh, works as treatment conditions
When growth to microorganism has limited, the decrease with the obvious advantage of microorganism process.However, low temperature plasma method generally exists
Under normal temperature and pressure, the method can reach the effect of preferable degradation of contaminant.
Due to foul gas composition and the complexity of property, traditional monotechnics is generally unattainable processing in many cases
It is required that;Absorption and sorption method can not thoroughly remove odorant pollutant under normal circumstances;Combustion method, oxidizing process and biological process
There are many limitations, and it is economical unreasonable;And lower temperature plasma technology has simple technique, high treating effect and secondary pollution
The advantages that few, progressively show its advantage technically and economically, the particularly application in processing low content VOCs and stench
In.In recent years, because the superiority that lower temperature plasma technology processing foul gas has, many researchers have carried out correlation
Explore, using different types of plasma-generating source, design different reactors, and achieve certain achievement.At present, it is single
Solely the problems such as treatment effect is low, and accessory substance is difficult to control is still suffered from using a kind of technique device processing foul gas, and absorbent-type
Lower temperature plasma technology can effectively improve clearance, reduce energy consumption, reduce secondary pollution, be provided for the removal of foul gas
One new technological development direction.
The content of the invention
Goal of the invention:
The present invention is for above-mentioned various problems present in existing processing foul gas technology, it is proposed that a kind of adsorption type low temperature etc.
The system and method for gas ions advanced treating foul gas, adsorbent is filled in discharge plasma space, can not increased
On the premise of reactor size, extend residence time of the foul gas in reactor;Increase simultaneously at original reaction unit rear portion
Add-back streaming system, by controlling capacity of returns, by reaction product and the O of generation3Isoreactivity material is passed into adsorption type low temperature again
Further deeply handled in plasma reactor, reduce the investment using low temperature plasma processes and operating cost merely.
Technical scheme:
The present invention is achieved through the following technical solutions:
A kind of system of adsorption type low temperature plasma advanced treating foul gas, it is characterised in that:Its system include vavuum pump,
Flowmeter, gas cushion, adsorption type low temperature plasma reactor, high-frequency and high-voltage power supply and return-flow system;
Vavuum pump, flowmeter, gas cushion and adsorption type low temperature plasma reactor are sequentially connected with one by one;Return-flow system
It is connected side by side with vavuum pump, flowmeter, gas cushion and adsorption type low temperature plasma reactor.
The system of adsorption type low temperature plasma advanced treating foul gas, after adsorption type low temperature plasma reactor
Three-way pipe one end connection return-flow system one end, the other end connection flow gauge of return-flow system, return-flow system include gas transport pump,
Mass flowmenter, controlled valve and online gas tester,
Online gas tester, controlled valve, mass flowmenter and gas transport pump are sequentially connected with one by one.
The system of adsorption type low temperature plasma advanced treating foul gas, have adsorption type low temperature etc. of cavity body structure from
Daughter reactor, front end are air inlets, and rear end is gas outlet, and centre is lucite shell, be provided with lucite shell every
Off-network, discharge plate and dielectric-slab, discharge plate are fixed on the outside of dielectric-slab, and adsorbent is provided with cavity.
The system of adsorption type low temperature plasma advanced treating foul gas, adsorption type low temperature plasma reactor is low
Addition adsorbent in isothermal plasma region of discharge.
The system of adsorption type low temperature plasma advanced treating foul gas, adsorbent are silica gel, and activated alumina is active
Charcoal, molecular sieve, the mixing of any one or more in iron carbon filler.
Respectively there is an isolation system of adsorption type low temperature plasma advanced treating foul gas, the left and right ends between dielectric-slab
Net, isolation screen distance are less than adsorbent diameter.
The system of adsorption type low temperature plasma advanced treating foul gas, the height of adsorption type low temperature plasma reactor
Press bond high-frequency and high-voltage power supply, adsorption type low temperature plasma reactor low-pressure end ground connection.
A kind of method of adsorption type low temperature plasma advanced treating foul gas, its method and step are as follows:
Step 1:The system for installing adsorption type low temperature plasma advanced treating foul gas, first turns on high-frequency and high-voltage power supply
And regulating power source voltage, after type reaction of low temperature plasma device Uniform Discharge to be adsorbed, open vavuum pump and input foul gas
Into the system of adsorption type low temperature plasma advanced treating foul gas, by flowmeter control enter adsorption type low temperature etc. from
The gas flow of daughter advanced treating foul gas system;
Step 2:When foul gas concentration is higher than limit value, return-flow system is opened;
Step 3:Controlled valve is opened, mass flowmenter is opened, gas backstreaming is delayed by flowmeter with air in gas
Rush in device and be well mixed, subsequently into adsorption type low temperature plasma reactor;
Step 4:Increase gas backstreaming ratio by adjusting mass flowmenter;Online gas tester detection adsorption type low temperature etc. from
The situation up to standard of the gas of daughter reactor discharge, if foul gas content is up to standard in tail gas, closing volume system;Processing is disliked
The system of odour continues to run with.
Advantage and effect:
The invention has the advantages that and beneficial effect:
(1)Adsorbent can make foul gas is relative to be enriched with, and on the premise of reactor size is not increased, increase foul gas exists
The residence time of reaction zone, so as to improve degradation rate.
(2)Return-flow system can be reprocessed the product not reacted completely.
(3)By controlling reflux ratio to make the increase of import air quantity, improve due to adsorption type low temperature plasma caused by electric discharge
Reactor fever phenomenon.
(4)O in product after the system processing foul gas of the adsorption type low temperature plasma advanced treating foul gas3Contain
Measure low.
(5)Intermediate product kind after the system processing foul gas of the adsorption type low temperature plasma advanced treating foul gas
Class is few, content is low.
Brief description of the drawings
Fig. 1 is the system schematic of adsorption type low temperature plasma advanced treating foul gas of the present invention;
Fig. 2 is adsorption type low temperature plasma reactor configurations figure in the present invention;
Fig. 3 is profile of the adsorption type low temperature plasma reactor configurations figure along dotted line A in the present invention;
Fig. 4 is return-flow system schematic diagram.
Description of reference numerals:
1st, vavuum pump;2nd, flowmeter;3rd, gas buffer tank;4th, adsorption type low temperature plasma reactor;5th, high-frequency and high-voltage power supply;
6th, return-flow system;7th, air inlet;8th, gas outlet;9th, lucite shell;10th, separation net;11st, discharge plate;12nd, dielectric-slab;
13rd, adsorbent;14th, online gas tester;15th, gas transport pump;16th, mass flowmenter;17th, controlled valve.
Embodiment
The present invention provides system and the side of a kind of adsorption type low temperature plasma advanced treating foul gas with backflow
Method, foul gas are thoroughly removed under low temperature plasma, adsorbent and return-flow system collective effect.
The present invention is described further below in conjunction with the accompanying drawings:
As shown in figure 1, a kind of system of adsorption type low temperature plasma advanced treating foul gas, its system include vavuum pump 1,
Flowmeter 2, gas cushion 3, adsorption type low temperature plasma reactor 4, high-frequency and high-voltage power supply 5 and return-flow system 6;
Vavuum pump 1, flowmeter 2, gas cushion 3 and adsorption type low temperature plasma reactor 4 are sequentially connected with one by one;Backflow
System 6 is connected side by side with vavuum pump 1, flowmeter 2, gas cushion 3 and adsorption type low temperature plasma reactor 4.
As shown in figure 4, the system of adsorption type low temperature plasma advanced treating foul gas, adsorption type low temperature plasma
Three-way pipe one end connection return-flow system 6 one end after reactor 4, the other end connection flow gauge 2 of return-flow system 6, return-flow system 6
Including gas transport pump 15, mass flowmenter 16, controlled valve 17 and online gas tester 14, online gas tester 14,
Controlled valve 17, mass flowmenter 16 and gas transport pump 15 are sequentially connected with one by one.Gas treatment is up to standard, be expelled directly out without
Cross circuit system 6.Gas monitors whether gas meets discharging standards in real time by online gas tester 14, if met
Then it is expelled directly out;If do not met, the controlled valve 17 of unlatching return-flow system 6 introduces a gas into return-flow system 6 and carried out at circulation
Reason, until the styrene in gas, methyl mercaptan, methyl sulfide isoconcentration meet discharging standards.Online gas tester is selected
Model SNC4000_EFF Shanghai richness looks forward or upwards the online gas detecting instrument of environmental protection company, including display screen, test software etc..
The present invention behind adsorption type low temperature plasma reactor 4 increase return-flow system 6, can make adsorption type low temperature etc. from
Reaction product and the O of generation in daughter reactor 43Isoreactivity Material recirculation is further handled.
As shown in Figures 2 and 3, the system of adsorption type low temperature plasma advanced treating foul gas, there is cavity body structure
Adsorption type low temperature plasma reactor 4, front end is air inlet 7, and rear end is gas outlet 8, and centre is lucite shell 9,
Separation net 10, discharge plate 11 and dielectric-slab 12 are provided with lucite shell 9, discharge plate 11 is fixed on outside dielectric-slab 12
Side, cavity is interior to be provided with adsorbent 13.Foul gas enters from air inlet 7, successively by separation net 10, discharge of plasma in low temperature
Area, adsorbent 13 and opposite side separation net 10, finally discharged from gas outlet;Discharge plate 11 is fixed on the outside of dielectric-slab 12.
Adsorption type low temperature plasma reactor 4 is cuboid, and external dimensions is 500 × 380 × 200mm, horizontal placement,
Plasma occurring mode is board-like dielectric barrier discharge, and electrode board size is 300 × 280 × 2mm, and electric discharge spacing is 8mm.
The system of adsorption type low temperature plasma advanced treating foul gas, adsorption type low temperature plasma reactor 4 exist
Adsorbent 13 is added with discharge of plasma in low temperature area, by two kinds of reactive mode combination depth foul gas.
The system of adsorption type low temperature plasma advanced treating foul gas, adsorbent 13 are silica gel, and activated alumina is living
Property charcoal, molecular sieve, the mixing of any one or more in iron carbon filler.Internal filling adsorbent is now selected to be lived for self-control sintering
Property carbon filling material, sintering temperature be 800 DEG C, the filler porosity after high temperature sintering is 40-60%, chooses a diameter of 4-6mm fillers
It is standby.
The system of adsorption type low temperature plasma advanced treating foul gas, the left and right ends between dielectric impedance plate 12 respectively have
One separation net 10, the aperture of separation net 10 are less than adsorbent diameter, prevent adsorbent with gas diffusion.Sintered and lived according to above-mentioned self-control
The diameter of property carbon filling material, is now limited in 2 ~ 4mm by separation net diameter.
The system of adsorption type low temperature plasma advanced treating foul gas, adsorption type low temperature plasma reactor 4
High-pressure side connects high-frequency and high-voltage power supply, the low-pressure end of adsorption type low temperature plasma reactor 4 ground connection, it is ensured that experiment is normally carried out.
A kind of method of adsorption type low temperature plasma advanced treating foul gas, its method and step are as follows:
Step 1:The system for installing above-mentioned adsorption type low temperature plasma advanced treating foul gas, first turns on high-frequency and high-voltage
Power supply 5 and to adjust input power be 70W, after the Uniform Discharge of type reaction of low temperature plasma device 4 to be adsorbed, opening vavuum pump 1 will
Foul gas is input in the system of adsorption type low temperature plasma advanced treating foul gas, is controlled and entered by flowmeter 2
The gas flow of adsorption type low temperature plasma advanced treating foul gas system, gas flow are controlled in 0.5L/min or so;
Step 2:The content of foul gas in discharge gas is tested using online gas tester 14, for example, styrene, first sulphur
Alcohol, methyl sulfide etc.;When foul gas concentration is higher than limit value, return-flow system 6 is opened;
Step 3:Controlled valve 17 is opened, mass flowmenter 16 is opened, gas backstreaming is passed through flowmeter 2, recycle ratio control
In the range of 20% ~ 60%, it is well mixed with air in gas cushion 3, subsequently into adsorption type low temperature plasma reaction
In device 4;
Step 4:Increase gas backstreaming ratio by adjusting mass flowmenter 16;Online gas tester 14 detects adsorption type low temperature
The situation up to standard for the gas that plasma reactor 4 discharges, if foul gas content is up to standard in tail gas, closing volume system;
The system of processing foul gas continues to run with.
Claims (8)
- A kind of 1. system of adsorption type low temperature plasma advanced treating foul gas, it is characterised in that:Its system includes vacuum Pump(1), flowmeter(2), gas cushion(3), adsorption type low temperature plasma reactor(4), high-frequency and high-voltage power supply(5)With return Streaming system(6);By vavuum pump(1), flowmeter(2), gas cushion(3)With adsorption type low temperature plasma reactor(4)One by one sequentially Connection;Return-flow system(6)With vavuum pump(1), flowmeter(2), gas cushion(3)With adsorption type low temperature plasma reactor (4)Connection side by side.
- 2. the system of adsorption type low temperature plasma advanced treating foul gas according to claim 1, it is characterised in that: Adsorption type low temperature plasma reactor(4)Three-way pipe one end connection return-flow system afterwards(6)One end, return-flow system(6)It is another One end connection flow gauge(2), return-flow system(6)Including gas transport pump(15), mass flowmenter(16), controlled valve(17)With Online gas tester(14);Online gas tester(14), controlled valve(17), mass flowmenter(16)With gas transport pump(15)Sequentially connect one by one Connect.
- 3. the system of adsorption type low temperature plasma advanced treating foul gas according to claim 1, it is characterised in that Adsorption type low temperature plasma reactor with cavity body structure(4), front end is air inlet(7), rear end is gas outlet(8), in Between be lucite shell(9), lucite shell(9)It is interior to be provided with separation net(10), discharge plate(11)And dielectric-slab(12), Discharge plate(11)It is fixed on dielectric-slab(12)Outside, cavity is interior to be provided with adsorbent(13).
- 4. the system of the adsorption type low temperature plasma advanced treating foul gas according to claim 1 or 3, its feature exist In:Adsorption type low temperature plasma reactor(4)Adsorbent is added with discharge of plasma in low temperature area(13).
- 5. the system of adsorption type low temperature plasma advanced treating foul gas according to claim 3, it is characterised in that: Adsorbent(13)It is silica gel, activated alumina, activated carbon, molecular sieve, the mixing of any one or more in iron carbon filler.
- 6. the system of adsorption type low temperature plasma advanced treating foul gas according to claim 3, it is characterised in that: Dielectric-slab(12)Between left and right ends respectively have a separation net(10), separation net(10)Aperture is less than adsorbent(13)Diameter.
- 7. the system of adsorption type low temperature plasma advanced treating foul gas according to claim 1, it is characterised in that: Adsorption type low temperature plasma reactor(4)High-pressure side connection high-frequency and high-voltage power supply, adsorption type low temperature plasma reactor (4)Low-pressure end is grounded.
- A kind of 8. method of adsorption type low temperature plasma advanced treating foul gas, it is characterised in that its method and step is as follows:Step 1:The system for installing adsorption type low temperature plasma advanced treating foul gas, first turns on high-frequency and high-voltage power supply (5)And regulating power source voltage, type reaction of low temperature plasma device to be adsorbed(4)After Uniform Discharge, vavuum pump is opened(1)By stench Gas is input in the system of adsorption type low temperature plasma advanced treating foul gas, passes through flowmeter(2)Control, which enters, inhales The gas flow of attached type low temperature plasma advanced treating foul gas system;Step 2:When foul gas concentration is higher than limit value, return-flow system is opened(6);Step 3:Open controlled valve(17), by mass flowmenter(16)Open, gas backstreaming is passed through flowmeter(2), with sky Gas is in gas cushion(3)It is interior well mixed, subsequently into adsorption type low temperature plasma reactor(4)In;Step 4:By adjusting mass flowmenter(16)Increase gas backstreaming ratio;Online gas tester(14)Detect absorbent-type Reaction of low temperature plasma device(4)The situation up to standard of the gas of discharge, if foul gas content is up to standard in tail gas, closing volume System;The system of processing foul gas continues to run with.
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Cited By (1)
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CN110374669A (en) * | 2019-08-29 | 2019-10-25 | 贵州大学 | A kind of high sealing gas dilution discharge device |
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CN105664679A (en) * | 2016-01-13 | 2016-06-15 | 长沙上意电子科技有限公司 | DBD plasma exhaust-gas treatment equipment |
CN106621759A (en) * | 2015-10-30 | 2017-05-10 | 杭州科瑞特环境技术有限公司 | Automobile 4S store spraying waste gas treatment device and technology thereof |
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CN102091514A (en) * | 2010-12-28 | 2011-06-15 | 浙江大学 | Device and method for treating obnoxious gas and industrial VOCs |
CN106621759A (en) * | 2015-10-30 | 2017-05-10 | 杭州科瑞特环境技术有限公司 | Automobile 4S store spraying waste gas treatment device and technology thereof |
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