CN107699972A - The toughener preparation method added in the main kernmantle stretching preparation process of culturing net - Google Patents

The toughener preparation method added in the main kernmantle stretching preparation process of culturing net Download PDF

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Publication number
CN107699972A
CN107699972A CN201710948849.5A CN201710948849A CN107699972A CN 107699972 A CN107699972 A CN 107699972A CN 201710948849 A CN201710948849 A CN 201710948849A CN 107699972 A CN107699972 A CN 107699972A
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parts
nylon
toughener
kernmantle
added
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CN201710948849.5A
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Inventor
刘大忠
施列强
许正贵
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Bengbu Tian Wangyuxu Articles For Use Co Ltd
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Bengbu Tian Wangyuxu Articles For Use Co Ltd
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    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01KANIMAL HUSBANDRY; CARE OF BIRDS, FISHES, INSECTS; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
    • A01K61/00Culture of aquatic animals
    • A01K61/60Floating cultivation devices, e.g. rafts or floating fish-farms
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/73Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
    • D06M11/76Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224Esters of carboxylic acids; Esters of carbonic acid
    • D06M13/2246Esters of unsaturated carboxylic acids
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/325Amines
    • D06M13/335Amines having an amino group bound to a carbon atom of a six-membered aromatic ring
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/227Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/227Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
    • D06M15/233Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated aromatic, e.g. styrene
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/59Polyamides; Polyimides
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/80Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in fisheries management
    • Y02A40/81Aquaculture, e.g. of fish

Abstract

The toughener added in the main kernmantle stretching preparation process of culturing net, including following components are prepared:30 50 parts of acrylic polymer, 50 70 parts of acrylic ester grafted styrenic elastomer, 10 30 parts of antioxidant, 25 100 parts of p-aminobenzoic acid, 4 16 parts of sodium hydroxide, 250 260 parts of water, 10 12 parts of zinc oxide, 69 parts of surfactant, 36 parts of sodium metasilicate, 12 parts of sodium carbonate, 10 12 parts of ammoniacal liquor, 16 24 parts of corn oil, 58 parts of thermoplastic polyolefin elastomer graft, 45 parts of polyolefin, 1 10 parts of nylon.Beneficial effect is:It with the addition of a small amount of nylon, nylon is grafted on nylon toughener, so that the nylon toughener prepared not only possesses the Toughening Properties of toughener, also so that toughener possesses the characteristic of compatilizer, the mixed effect of toughener and nylon can be greatly improved using this kind of toughener, the perfect structure of fabric of island-in-sea type tenacity increased nylon, the microstructural flaws of fabric of island-in-sea type tenacity increased nylon are reduced, be advantageous to further improve the mechanical property of tenacity increased nylon.

Description

The toughener preparation method added in the main kernmantle stretching preparation process of culturing net
Technical field:
The present invention relates to a kind of fish to need articles for use, and in particular to the toughness reinforcing added in the main kernmantle stretching preparation process of culturing net Agent preparation method.
Background technology:
Culturing net, more than 99% is process with synthetic fibers, mainly have the monofilament of nylon 6 or modification of nylon, multifilament or Multiple monofilament, the fibers such as polyethylene, polyester, Vingon can also be used, generally use the La Sheer warp knits equipped with 4~8 sley bar Warp thread lopping is connected networking by machine, claims warp knit knotless net.Because tricot machine speed is higher (600 revs/min), the net door width of woollen yarn knitting It is wealthy, angry eyes number up to 800 mesh more than, conversion specification is convenient, and production efficiency is higher than first two method several times.Warp knit knotless net is put down Whole, in light weight, Stability Analysis of Structures, knot strength are high, indeformable, not loose after etting breakage, but not wear-resisting, and physical life is short.
The content of the invention:
The technical problems to be solved by the invention are the defects of part takes prior art, there is provided the main kernmantle stretching of culturing net The toughener preparation method added in preparation process.
The technical problems to be solved by the invention are realized using following technical scheme.
The toughener preparation method added in the main kernmantle stretching preparation process of culturing net, it is characterised in that:Including following Step:
Acrylic polymer, acrylic ester grafted styrenic elastomer, antioxidant, water are added into reactor In, stirred 4 hours with 90 DEG C, be cooled to 75 DEG C, be hydrogenated with sodium oxide molybdena, p-aminobenzoic acid, high-speed stirred, 60 DEG C of insulation reactions 1 Hour, diethylene glycol ether acetate is then added, continues heating stirring 1 hour, zinc oxide stirring is added, 50 is dropped to temperature Below DEG C, press filtration, liquid is obtained;
Sodium metasilicate stirs 2 minutes with antioxidant, stands volatilization, is mixed after 3 days with by sodium carbonate, heats, and collects water and steams Gas;
Thermoplastic polyolefin elastomer graft, polyolefin, nylon and ammoniacal liquor are sequentially added in agitator, is stirred Stand, filter after dissolving, collect solids;
Solids is mixed with liquid and vapor and is stirred continuously at 80 DEG C, is completed to overall prepared in grume.
Above-mentioned component used is specially:Acrylic polymer 30-50 parts, acrylic ester grafted phenylethylene elasticity Body 50-70 parts, antioxidant 10-30 parts, p-aminobenzoic acid 25-100 parts, sodium hydroxide 4-16 parts, water 250-260 parts, oxidation Zinc 10-12 parts, surfactant 6-9 parts, sodium metasilicate 3-6 parts, sodium carbonate 1-2 parts, ammoniacal liquor 10-12 parts, corn oil 16-24 Part, thermoplastic polyolefin elastomer graft 5-8 parts, polyolefin 4-5 parts, nylon 1-10 parts.
Above-mentioned component used is specially:30 parts of acrylic polymer, acrylic ester grafted styrenic elastomer 50 parts, 10 parts of antioxidant, 25 parts of p-aminobenzoic acid, 4 parts of sodium hydroxide, 250 parts of water, 10 parts of zinc oxide, surfactant 6 Part, 3 parts of sodium metasilicate, 1 part of sodium carbonate, 10 parts of ammoniacal liquor, 16 parts of corn oil, 5 parts of thermoplastic polyolefin elastomer graft, polyene 4 parts of hydrocarbon, 1 part of nylon.
Above-mentioned component used is specially:50 parts of acrylic polymer, acrylic ester grafted styrenic elastomer 70 parts, 30 parts of antioxidant, 100 parts of p-aminobenzoic acid, 16 parts of sodium hydroxide, 260 parts of water, 12 parts of zinc oxide, surfactant 9 Part, 6 parts of sodium metasilicate, 2 parts of sodium carbonate, 12 parts of ammoniacal liquor, 24 parts of corn oil, 8 parts of thermoplastic polyolefin elastomer graft, polyene 5 parts of hydrocarbon, 10 parts of nylon.
Described part is parts by weight.
The surfactant is stearic acid or neopelex or fatty glyceride.
Chief editor's knitmesh after drawing and forming is used on culturing net, and the appearance profile of the cross section of culturing net is circle, directly Footpath is 1~30 millimeter, is woven formed in the shape of a spiral by three strands of main kernmantles and six strands of secondary kernmantles, is wound outside per share main kernmantle Two strands of secondary kernmantles.
Per share secondary kernmantle includes at least two nylon wires and some filaments, filament are wrapped on nylon wire.
The two secondary kernmantle direction windings wound on main kernmantle, every 20 centimetres of knottings, and put rubber sleeve.
Nylon wire has two in the per share secondary kernmantle, and filament has 8~16 in the per share secondary kernmantle Root.
A diameter of 0.35mm~0.8mm of nylon wire, described filametntary a diameter of in the per share secondary kernmantle 0.25mm~0.3mm.
Beneficial effect is:A small amount of nylon is with the addition of, nylon is grafted on nylon toughener so that the nylon of preparation Toughener not only possesses the Toughening Properties of toughener, also causes toughener to possess the characteristic of compatilizer, using this kind of toughener energy Enough greatly improve the mixed effect of toughener and nylon, the perfect structure of fabric of island-in-sea type tenacity increased nylon, reduce fabric of island-in-sea type toughness reinforcing The microstructural flaws of nylon, be advantageous to further improve the mechanical property of tenacity increased nylon;
Toughener is added in drawing process, toughener is penetrated into fiber, combined together before kernmantle shaping, stretches Tenacity of fibre afterwards gets a promotion, and possesses more preferable abrasion resistant effect and service life.
Brief description of the drawings:
Fig. 1 is that the chief editor of the embodiment of the present invention 3 knits rope structure schematic diagram;
Fig. 2 is the cross-sectional structure schematic diagram of the embodiment of the present invention 3.
Embodiment:
In order that the technical means, the inventive features, the objects and the advantages of the present invention are easy to understand, tie below Specific embodiment is closed, the present invention is expanded on further.
Specific embodiment 1:
The toughener preparation method added in the main kernmantle stretching preparation process of culturing net, comprises the following steps:
Acrylic polymer, acrylic ester grafted styrenic elastomer, antioxidant, water are added into reactor In, stirred 4 hours with 90 DEG C, be cooled to 75 DEG C, be hydrogenated with sodium oxide molybdena, p-aminobenzoic acid, high-speed stirred, 60 DEG C of insulation reactions 1 Hour, diethylene glycol ether acetate is then added, continues heating stirring 1 hour, zinc oxide stirring is added, 50 is dropped to temperature Below DEG C, press filtration, liquid is obtained;
Sodium metasilicate stirs 2 minutes with antioxidant, stands volatilization, is mixed after 3 days with by sodium carbonate, heats, and collects water and steams Gas;
Thermoplastic polyolefin elastomer graft, polyolefin, nylon and ammoniacal liquor are sequentially added in agitator, is stirred Stand, filter after dissolving, collect solids;
Solids is mixed with liquid and vapor and is stirred continuously at 80 DEG C, is completed to overall prepared in grume.
Above-mentioned component used is specially:30 parts of acrylic polymer, acrylic ester grafted styrenic elastomer 50 parts, 10 parts of antioxidant, 25 parts of p-aminobenzoic acid, 4 parts of sodium hydroxide, 250 parts of water, 10 parts of zinc oxide, surfactant 6 Part, 3 parts of sodium metasilicate, 1 part of sodium carbonate, 10 parts of ammoniacal liquor, 16 parts of corn oil, 5 parts of thermoplastic polyolefin elastomer graft, polyene 4 parts of hydrocarbon, 1 part of nylon.
Part is parts by weight.
Surfactant is stearic acid or neopelex or fatty glyceride.
Compare the net of uniaxial direct tensile:
Net prepared by this law stretching, it is not easy to break;It is placed in roller, rotation roller, in the case of 1000 turns, rotates 1 Hour, there is different degrees of damage in the net of common nylon braiding, and unrepairable, line is broken, and the intact nothing of the net of this law Damage, every square of load-bearing 600kg are bigger 20-40% than common net load-bearing;
By adding toughener in drawing process, the mechanical property of net is improved, the bulk strength of net, net greatly improved Service life significantly improves.
Embodiment 2:The toughener preparation method added in the main kernmantle stretching preparation process of culturing net, including following step Suddenly:
Acrylic polymer, acrylic ester grafted styrenic elastomer, antioxidant, water are added into reactor In, stirred 4 hours with 90 DEG C, be cooled to 75 DEG C, be hydrogenated with sodium oxide molybdena, p-aminobenzoic acid, high-speed stirred, 60 DEG C of insulation reactions 1 Hour, diethylene glycol ether acetate is then added, continues heating stirring 1 hour, zinc oxide stirring is added, 50 is dropped to temperature Below DEG C, press filtration, liquid is obtained;
Sodium metasilicate stirs 2 minutes with antioxidant, stands volatilization, is mixed after 3 days with by sodium carbonate, heats, and collects water and steams Gas;
Thermoplastic polyolefin elastomer graft, polyolefin, nylon and ammoniacal liquor are sequentially added in agitator, is stirred Stand, filter after dissolving, collect solids;
Solids is mixed with liquid and vapor and is stirred continuously at 80 DEG C, is completed to overall prepared in grume.
Above-mentioned component used is specially:50 parts of acrylic polymer, acrylic ester grafted styrenic elastomer 70 parts, 30 parts of antioxidant, 100 parts of p-aminobenzoic acid, 16 parts of sodium hydroxide, 260 parts of water, 12 parts of zinc oxide, surfactant 9 Part, 6 parts of sodium metasilicate, 2 parts of sodium carbonate, 12 parts of ammoniacal liquor, 24 parts of corn oil, 8 parts of thermoplastic polyolefin elastomer graft, polyene 5 parts of hydrocarbon, 10 parts of nylon.
Part is parts by weight.
Surfactant is stearic acid or neopelex or fatty glyceride.
Compare the net of uniaxial direct tensile:
Net prepared by this law stretching, it is not easy to break;It is placed in roller, rotation roller, in the case of 1000 turns, rotates 1 Hour, there is different degrees of damage in the net of common nylon braiding, and unrepairable, line is broken, and the intact nothing of the net of this law Damage, every square of load-bearing 630kg are bigger 20-40% than common net load-bearing;
By adding toughener in drawing process, the mechanical property of net is improved, the bulk strength of net, net greatly improved Service life significantly improves.
Embodiment 3:Chief editor's knitmesh after drawing and forming is used on culturing net, and the appearance profile of the cross section of culturing net is Circle, a diameter of 1~30 millimeter, woven formed in the shape of a spiral by three strands of main kernmantles 1 and six strands of secondary kernmantles 2, per share chief editor Knit rope two strands of secondary kernmantles of outer winding.
Per share secondary kernmantle includes two nylon wires 21 and 8 filaments 22, and filament is wrapped on nylon wire.
The two secondary kernmantle direction windings wound on main kernmantle, every 20 centimetres of knottings, and put rubber sleeve 3.
A diameter of 0.35mm~0.8mm of nylon wire, described filametntary a diameter of in the per share secondary kernmantle 0.25mm~0.3mm.
General principle, principal character and the advantages of the present invention of the present invention has been shown and described above.The technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the simply explanation described in above-described embodiment and specification is originally The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its Equivalent thereof.

Claims (2)

1. the toughener preparation method added in the main kernmantle stretching preparation process of culturing net, it is characterised in that:Including following step Suddenly:
Acrylic polymer, acrylic ester grafted styrenic elastomer, antioxidant, water are added in reactor, with 90 DEG C are stirred 4 hours, are cooled to 75 DEG C, are hydrogenated with sodium oxide molybdena, p-aminobenzoic acid, high-speed stirred, 60 DEG C of insulation reactions 1 hour, Then add diethylene glycol ether acetate, continue heating stirring 1 hour, add zinc oxide stirring, to temperature drop to 50 DEG C with Under, press filtration, obtain liquid;
Sodium metasilicate stirs 2 minutes with antioxidant, stands volatilization, is mixed after 3 days with by sodium carbonate, heats, and collects vapor;
Thermoplastic polyolefin elastomer graft, polyolefin, nylon and ammoniacal liquor are sequentially added in agitator, is stirred dissolving Stand, filter afterwards, collect solids;
Solids is mixed with liquid and vapor and is stirred continuously at 80 DEG C, is completed to overall prepared in grume.
2. the toughener preparation method added in the main kernmantle stretching preparation process of culturing net according to claim 1, its It is characterised by, the surfactant is stearic acid or neopelex or fatty glyceride.
CN201710948849.5A 2017-10-12 2017-10-12 The toughener preparation method added in the main kernmantle stretching preparation process of culturing net Pending CN107699972A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111657197A (en) * 2020-05-09 2020-09-15 中国水产科学研究院东海水产研究所 Preparation method of cylindrical box body for deep and open sea net cage with antifouling performance

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102391605A (en) * 2011-09-02 2012-03-28 沈阳科通塑胶有限公司 Preparation method of polyformaldehyde toughening agent, toughening polyformaldehyde and toughening agent
CN102532855A (en) * 2012-02-15 2012-07-04 沈阳科通塑胶有限公司 Polycarbonate injection molding grade toughening agent, toughened polycarbonate and preparation method of polycarbonate injection molding grade toughening agent
CN106800620A (en) * 2016-12-29 2017-06-06 宁波能之光新材料科技有限公司 A kind of cloth angle regeneration nylon toughener and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102391605A (en) * 2011-09-02 2012-03-28 沈阳科通塑胶有限公司 Preparation method of polyformaldehyde toughening agent, toughening polyformaldehyde and toughening agent
CN102532855A (en) * 2012-02-15 2012-07-04 沈阳科通塑胶有限公司 Polycarbonate injection molding grade toughening agent, toughened polycarbonate and preparation method of polycarbonate injection molding grade toughening agent
CN106800620A (en) * 2016-12-29 2017-06-06 宁波能之光新材料科技有限公司 A kind of cloth angle regeneration nylon toughener and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111657197A (en) * 2020-05-09 2020-09-15 中国水产科学研究院东海水产研究所 Preparation method of cylindrical box body for deep and open sea net cage with antifouling performance

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