CN107698875A - A kind of polymer fiber material - Google Patents
A kind of polymer fiber material Download PDFInfo
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- CN107698875A CN107698875A CN201711152457.4A CN201711152457A CN107698875A CN 107698875 A CN107698875 A CN 107698875A CN 201711152457 A CN201711152457 A CN 201711152457A CN 107698875 A CN107698875 A CN 107698875A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/047—Reinforcing macromolecular compounds with loose or coherent fibrous material with mixed fibrous material
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/10—Homopolymers or copolymers of propene
- C08J2323/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Reinforced Plastic Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of polymer fiber material, its formula are as follows：20 50 parts of steel fibre, 10 22 parts of glass fibre, 8 28 parts of polypropylene, 0.1 0.6 parts of lubricant, 0.9 1.2 parts of antioxidant, 26 parts of inorganic assistant, 0.3 0.6 parts of initiator, 16 parts of thickener.Various fibers give full play to respective performance in the present invention, form a kind of complementary composite reinforced body, substantially improve volume waterproofing and anti-leakage performance, shock resistance, add toughness.
Description
Technical field
The invention belongs to fibrous filtration technology field, and in particular to a kind of polymer fiber material.
Background technology
Fiber-reinforced resin matrix compound material is due to its specific strength, specific stiffness is higher, designability is strong, anti-fatigue performance
Well, the features such as environmental resistance is superior and can realize global formation, has been widely used for the modern high-tech such as Aero-Space
Skill field.Wherein, shaping of the preform composite liquid condition shaping technology as a kind of inexpensive composite product
Technology, it is an important directions of Advanced Resin-based Composites research.
Fiber-reinforced resin matrix compound material is used in terms of filtering or relatively fewer at present, itself main reason is that its
Toughness is bad, the easy cracking under etching condition.
The content of the invention
It is an object of the invention to provide a kind of polymer fiber material, various fibers give full play to respective property in the present invention
Can, a kind of complementary composite reinforced body is formed, volume waterproofing and anti-leakage performance, shock resistance is substantially improved, adds toughness.
A kind of polymer fiber material, its formula are as follows：：Steel fibre 20-50 parts, glass fibre 10-22 parts, polypropylene 8-
28 parts, lubricant 0.1-0.6 parts, antioxidant 0.9-1.2 parts, inorganic assistant 2-6 parts, initiator 0.3-0.6 parts, thickener 1-
6 parts.
The lubricant is using one kind in wax, polypropylene wax, Tissuemat E, amide waxe.
The antioxidant is using one kind in antioxidant 1010, antioxidant 1098, irgasfos 168.
The inorganic assistant uses nano titanium oxide or nano zine oxide.
The initiator is using isopropyl benzene hydroperoxide, TBHP, methyl ethyl ketone peroxide, cyclohexanone peroxide
In one kind.
The thickener is using one kind in carbomer, polyacrylic acid, polyurethane thickener, Sodium Polyacrylate.
The preparation method of the composite strengthening toughness reinforcing anti-crack fiber material, its step are as follows：
Step 1, polypropylene, inorganic assistant, antioxidant and initiator are put into autoclave, isothermal reaction；
Step 2, glass fibre and lubricant are added in autoclave, constant temperature and pressure reaction；
Step 3, thickener is added in autoclave, stirs, obtain hybrid resin；
Step 4, steel fibre is dipped in hybrid resin, heating water bath, naturally dry mixes steel fibre after aerated reaction；
Step 5, mixing steel fibre is placed in reaction under high pressure thing, carries out critical reaction, obtain composite strengthening toughness reinforcing anti-crack fiber
Material.
Isothermal reaction in the step 1 is 100-110 DEG C, reaction time 20-30min.
Thermostat temperature in the step 2 is 150-155 DEG C, constant-pressure pressure 13-55kPa, reaction time 15-
25min。
Water bath heating temperature in the step 4 is 80-90 DEG C, and aerating gas is nitrogen, and aeration flow velocity is 1.0-
3.5mL/min。
Critical reaction pressure in the step 5 is 15-25MPa, and temperature is 120-150 DEG C.
Compared with prior art, the invention has the advantages that：
1st, various fibers give full play to respective performance in the present invention, form a kind of complementary composite reinforced body, substantially improve volume
Waterproofing and anti-leakage performance, shock resistance, add toughness.
2nd, the present invention solves the defects of resin corrosion-resistant, easy to aging and service life is short, corrosion-resistant, no to realize
The advantages of easy to aging and service life is long.
3rd, the present invention possesses good shock resistance, and impact strength is up to 52KJ/m2, and intensity and rigidity are also maintained at
Higher level, combination property are superior.
Embodiment
The present invention is described further with reference to embodiment：
Embodiment 1
A kind of polymer fiber material, its formula are as follows：40 parts of steel fibre, 11 parts of glass fibre, 11 parts of polypropylene, lubricant
0.1 part, 0.8 part of antioxidant, 3 parts of inorganic assistant, 0.3 part of initiator, 1 part of thickener.
The lubricant uses wax.
The antioxidant uses antioxidant 1010.
The inorganic assistant uses nano titanium oxide.
The initiator uses isopropyl benzene hydroperoxide.
The thickener uses carbomer.
The preparation method of the composite strengthening toughness reinforcing anti-crack fiber material, its step are as follows：
Step 1, polypropylene, inorganic assistant, antioxidant and initiator are put into autoclave, isothermal reaction；
Step 2, glass fibre and lubricant are added in autoclave, constant temperature and pressure reaction；
Step 3, thickener is added in autoclave, stirs, obtain hybrid resin；
Step 4, steel fibre is dipped in hybrid resin, heating water bath, naturally dry mixes steel fibre after aerated reaction；
Step 5, mixing steel fibre is placed in reaction under high pressure thing, carries out critical reaction, obtain composite strengthening toughness reinforcing anti-crack fiber
Material.
Isothermal reaction in the step 1 is 100 DEG C, reaction time 20min.
Thermostat temperature in the step 2 is 150 DEG C, constant-pressure pressure 13kPa, reaction time 15min.
Water bath heating temperature in the step 4 is 80 DEG C, and aerating gas is nitrogen, and aeration flow velocity is 1.0mL/min.
Critical reaction pressure in the step 5 is 15MPa, and temperature is 120 DEG C.
Embodiment 2
A kind of polymer fiber material, its formula are as follows：40 parts of steel fibre, 19 parts of glass fibre, 18 parts of polypropylene, lubricant
0.3 part, 1.3 parts of antioxidant, 5 parts of inorganic assistant, 0.9 part of initiator, 5 parts of thickener.
The lubricant uses polypropylene wax.
The antioxidant uses antioxidant 1098.
The inorganic assistant uses nano zine oxide.
The initiator uses TBHP.
The thickener uses polyacrylic acid.
The preparation method of the composite strengthening toughness reinforcing anti-crack fiber material, its step are as follows：
Step 1, polypropylene, inorganic assistant, antioxidant and initiator are put into autoclave, isothermal reaction；
Step 2, glass fibre and lubricant are added in autoclave, constant temperature and pressure reaction；
Step 3, thickener is added in autoclave, stirs, obtain hybrid resin；
Step 4, steel fibre is dipped in hybrid resin, heating water bath, naturally dry mixes steel fibre after aerated reaction；
Step 5, mixing steel fibre is placed in reaction under high pressure thing, carries out critical reaction, obtain composite strengthening toughness reinforcing anti-crack fiber
Material.
Isothermal reaction in the step 1 is 110 DEG C, reaction time 30min.
Thermostat temperature in the step 2 is 155 DEG C, constant-pressure pressure 55kPa, reaction time 25min.
Water bath heating temperature in the step 4 is 90 DEG C, and aerating gas is nitrogen, and aeration flow velocity is 3.5mL/min.
Critical reaction pressure in the step 5 is 25MPa, and temperature is 150 DEG C.
Embodiment 3
A kind of polymer fiber material, its formula are as follows：50 parts of steel fibre, 15 parts of glass fibre, 18 parts of polypropylene, lubricant
0.2 part, 0.9 part of antioxidant, 4 parts of inorganic assistant, 0.7 part of initiator, 3 parts of thickener.
The lubricant uses amide waxe.
The antioxidant uses irgasfos 168.
The inorganic assistant uses nano titanium oxide.
The initiator uses methyl ethyl ketone peroxide.
The thickener uses Sodium Polyacrylate.
The preparation method of the composite strengthening toughness reinforcing anti-crack fiber material, its step are as follows：
Step 1, polypropylene, inorganic assistant, antioxidant and initiator are put into autoclave, isothermal reaction；
Step 2, glass fibre and lubricant are added in autoclave, constant temperature and pressure reaction；
Step 3, thickener is added in autoclave, stirs, obtain hybrid resin；
Step 4, steel fibre is dipped in hybrid resin, heating water bath, naturally dry mixes steel fibre after aerated reaction；
Step 5, mixing steel fibre is placed in reaction under high pressure thing, carries out critical reaction, obtain composite strengthening toughness reinforcing anti-crack fiber
Material.
Isothermal reaction in the step 1 is 105 DEG C, reaction time 25min.
Thermostat temperature in the step 2 is 153 DEG C, constant-pressure pressure 36kPa, reaction time 19min.
Water bath heating temperature in the step 4 is 85 DEG C, and aerating gas is nitrogen, and aeration flow velocity is 2.6mL/min.
Critical reaction pressure in the step 5 is 15-25MPa, and temperature is 120-150 DEG C.
Embodiment 1-3 embodiment catalytic effect is as follows：
| Embodiment 1 | Embodiment 2 | Embodiment 3 | |
| Impact strength | 58KJ/m2 | 53KJ/m2 | 56KJ/m2 |
One embodiment of the invention is the foregoing is only, is not intended to limit the present invention, it is all using equivalent substitution or the side of equivalent transformation
The technical scheme that formula is obtained, all falls within protection scope of the present invention.
Claims (10)
1. a kind of polymer fiber material, its formula is as follows：Steel fibre 20-50 parts, glass fibre 10-22 parts, polypropylene 8-28
Part, lubricant 0.1-0.6 parts, antioxidant 0.9-1.2 parts, inorganic assistant 2-6 parts, initiator 0.3-0.6 parts, thickener 1-6
Part.
2. a kind of polymer fiber material according to claims 1, it is characterised in that the lubricant uses wax, gathered
One kind in propylene wax, Tissuemat E, amide waxe.
3. a kind of polymer fiber material according to claims 1, it is characterised in that the antioxidant uses antioxygen
One kind in agent 1010, antioxidant 1098, irgasfos 168.
4. a kind of polymer fiber material according to claims 1, it is characterised in that the inorganic assistant uses nanometer
Titanium dioxide or nano zine oxide.
5. a kind of polymer fiber material according to claims 1, it is characterised in that the initiator uses isopropylbenzene
One kind in hydrogen peroxide, TBHP, methyl ethyl ketone peroxide, cyclohexanone peroxide.
6. a kind of polymer fiber material according to claims 1, it is characterised in that the thickener uses Ka Boshu
One kind in fat, polyacrylic acid, polyurethane thickener, Sodium Polyacrylate.
A kind of 7. polymer fiber material according to claims 1, it is characterised in that the composite strengthening toughness reinforcing cracking resistance
The preparation method of fibrous material, its step are as follows：
Step 1, polypropylene, inorganic assistant, antioxidant and initiator are put into autoclave, isothermal reaction；
Step 2, glass fibre and lubricant are added in autoclave, constant temperature and pressure reaction；
Step 3, thickener is added in autoclave, stirs, obtain hybrid resin；
Step 4, steel fibre is dipped in hybrid resin, heating water bath, naturally dry mixes steel fibre after aerated reaction；
Step 5, mixing steel fibre is placed in reaction under high pressure thing, carries out critical reaction, obtain composite strengthening toughness reinforcing anti-crack fiber
Material.
8. a kind of polymer fiber material according to claims 7, it is characterised in that the constant temperature in the step 1 is anti-
100-110 DEG C is should be, reaction time 20-30min.
A kind of 9. polymer fiber material according to claims 7, it is characterised in that the constant temperature temperature in the step 2
Spend for 150-155 DEG C, constant-pressure pressure 13-55kPa, reaction time 15-25min.
10. a kind of polymer fiber material according to claims 7, it is characterised in that the water-bath in the step 4 adds
Hot temperature is 80-90 DEG C, and aerating gas is nitrogen, and aeration flow velocity is 1.0-3.5mL/min；Critical reaction in the step 5
Pressure is 15-25MPa, and temperature is 120-150 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711152457.4A CN107698875A (en) | 2017-11-19 | 2017-11-19 | A kind of polymer fiber material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711152457.4A CN107698875A (en) | 2017-11-19 | 2017-11-19 | A kind of polymer fiber material |
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| Publication Number | Publication Date |
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| CN107698875A true CN107698875A (en) | 2018-02-16 |
Family
ID=61180326
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711152457.4A Pending CN107698875A (en) | 2017-11-19 | 2017-11-19 | A kind of polymer fiber material |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112592527A (en) * | 2020-12-24 | 2021-04-02 | 四川兰晨管业有限公司 | Polyethylene double-wall corrugated pipe and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106243509A (en) * | 2016-08-31 | 2016-12-21 | 何县香 | A kind of composite strengthening toughness reinforcing anti-crack fiber material |
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2017
- 2017-11-19 CN CN201711152457.4A patent/CN107698875A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106243509A (en) * | 2016-08-31 | 2016-12-21 | 何县香 | A kind of composite strengthening toughness reinforcing anti-crack fiber material |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112592527A (en) * | 2020-12-24 | 2021-04-02 | 四川兰晨管业有限公司 | Polyethylene double-wall corrugated pipe and preparation method thereof |
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Application publication date: 20180216 |