CN107697968A - A kind of method and apparatus that bittern mineral is extracted using solar energy - Google Patents

A kind of method and apparatus that bittern mineral is extracted using solar energy Download PDF

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Publication number
CN107697968A
CN107697968A CN201711171474.2A CN201711171474A CN107697968A CN 107697968 A CN107697968 A CN 107697968A CN 201711171474 A CN201711171474 A CN 201711171474A CN 107697968 A CN107697968 A CN 107697968A
Authority
CN
China
Prior art keywords
bittern
heat carrier
pump
mineral
extracted
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711171474.2A
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Chinese (zh)
Inventor
雷政军
翟腾飞
高超
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Xian Westpeace Fire Technology Co Ltd
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Xian Westpeace Fire Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Xian Westpeace Fire Technology Co Ltd filed Critical Xian Westpeace Fire Technology Co Ltd
Priority to CN201711171474.2A priority Critical patent/CN107697968A/en
Publication of CN107697968A publication Critical patent/CN107697968A/en
Priority to PCT/CN2018/114991 priority patent/WO2019100959A1/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/04Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • C02F1/14Treatment of water, waste water, or sewage by heating by distillation or evaporation using solar energy
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/20Controlling water pollution; Waste water treatment
    • Y02A20/208Off-grid powered water treatment
    • Y02A20/212Solar-powered wastewater sewage treatment, e.g. spray evaporation

Abstract

The present invention relates to a kind of method and apparatus that bittern mineral is extracted using solar energy, it is characterised in that comprises the following steps:A) organic heat carrier is heated using solar thermal collector;B the organic heat carrier after heating) is heated into bittern by heat exchanger;C the bittern after heating) is made to carry out mineral matter separation by evaporation crystallization equipment.The present invention is sparsely populated for China Salt Lake Area, and infrastructure is not perfect, the insufficient situation of energy supply, there is provided a kind of method and apparatus that bittern mineral is extracted using solar energy, economical and efficient and energy-conserving and environment-protective, suitable for large-scale promotion.

Description

A kind of method and apparatus that bittern mineral is extracted using solar energy
Technical field
It is more specifically a kind of to utilize solar energy extraction bittern chats the present invention relates to bittern technical field of comprehensive utilization The method and apparatus of material.
Background technology
Contain the mineral resources such as abundant magnesium, lithium, calcium, potassium in salt lake bittern.China's salt lake resources are mainly distributed on green grass or young crops The provinces such as sea, Tibet, Xinjiang, but because the Salt Lake Area of these provinces is often sparsely populated, infrastructure is not perfect, and the energy supplies Should be inadequate, therefore bring serious restriction to these resources are developed.The method master of mineral matter is extracted in bittern at present There are evaporative crystallization method, the precipitation method, salting out method, carbonizatin method, floatation, extraction, ion exchange adsorption, calcination method, film point From a variety of methods such as method.Existing production technology, in order to save the requirement of the energy, reduction to infrastructure, use nature beach more The methods of solarization, evaporative crystallization, but shine to take due to sunshine beach and often reach 3~6 months, seriously limit carrying for production efficiency Rise, and industrial evaporative crystallization method is also unsuitable for directly applying in Yanhu District because energy consumption is huge, bittern extraction and comprehensive utilization Therefore the popularization of technology is also restricted.Therefore a kind of simple, efficient and energy-conserving and environment-protective extractive technique is sought, it appears outstanding To be important.
The content of the invention
The characteristics of the defects of for prior art, particularly China's salt lake resources distribution ground, the invention provides a kind of profit With the method and apparatus of solar energy extraction bittern mineral, economical and efficient and energy-conserving and environment-protective, pushed away suitable for Yanhu District scale Extensively.
The technical solution adopted by the present invention is:
A kind of method that bittern mineral is extracted using solar energy, it is characterised in that comprise the following steps:A) using too Positive energy heat collector heats to organic heat carrier;B bittern) is heated by heat exchanger using the organic heat carrier after heating;C) make Bittern after heating carries out mineral matter separation by evaporation crystallization equipment.
Further, described solar thermal collector is vacuum tube solar heating element, metal absorber vacuum tube heat collection function Device, heat pipe vacuum tube hot collector.
The metal absorber vacuum tube collector includes:Concentric locking collar tubular type vacuum tube collector, U-tube formula vacuum tube collection Hot device, thermal storage type vacuum tube heat collector, internal focusing vacuum pipe heat collector, straight-through vacuum tube heat collector.
Further, the organic heat carrier temperature after heating described in step A is more than 120 DEG C,
It is further preferred that described organic heat carrier temperature after heating is more than 180 DEG C.
Further, described organic heat carrier is mineral oil origin organic heat carrier and synthesis type organic heat carrier.
Further, the mineral oil origin organic heat carrier is the mixture of paraffinic base hydrocarbon, and cycloalkyl is hydrocarbon The mixture of compound, the one or more in the mixture of including aromatic hydrocarbons.
The synthesis type organic heat carrier includes:Alkylbenzene, alkyl biphenyl, benzyl group and two benzyl group toluene, biphenyl and biphenyl Ether azeotropic mixture, terphenyl and partially hydrogenated terphenyl, alkyl biphenyl ether, aliphatic hydrocarbon, poly- α alkane, silicone oil, fluorine nytron One or more in thing.
Another object of the present invention is to provide the device that bittern mineral is extracted using solar energy, its feature exists In:Including solar thermal collector, heat exchanger, evaporative crystallization unit;
The evaporative crystallization unit includes crystallizing evaporator, condenser, condensate drum and pump;
The pump includes heat exchanger pump, circulating pump, magma pump, bittern feed pump, vavuum pump;
The heat exchanger is provided with heat carrier import, heating medium outlet, bittern charging aperture and bittern discharging opening;
The heat carrier import of the heat exchanger is connected by heat exchanger pump with solar thermal collector, and the heating medium outlet leads to Cross circulation line and be connected to solar thermal collector;The bittern charging aperture is connected by changing circulating pump with feed reservoir, the bittern Discharging opening is connected with crystallizing evaporator;
The steam (vapor) outlet of the crystallizing evaporator is connected with condenser, and the condenser rear end is provided with condensate drum;It is described Condensate drum is connected with vavuum pump.
Further, the steam (vapor) outlet of the crystallizing evaporator can also connect the heat carrier progress after MVR equipment heat exchangings Reheat, improve the utilization rate of heat.
Circulation line is formed by pipeline and magma pump in the crystallizing evaporator bottom, in the magma pump and return duct Magma discharging opening is provided between road.
It is provided with organic heat carrier holding vessel between the solar thermal collector and heat exchanger, the solar thermal collector and has Holding vessel pump is provided between machine heat carrier holding vessel.
Organic heat carrier is heated to 180 DEG C by the solar thermal collector, is stored into organic heat carrier storage tank, from raw material Pond adds bittern through bittern charging aperture, and cycle heat exchange, the organic heat carrier after heat exchange are carried out with organic heat carrier in heat exchanger Solar thermal collector is recycled to through circulation line to reuse, the bittern after being heated is evaporated crystallization in evaporator, steams Vapour is discharged from upper outlet and recycled, and mineral matter magma is exported from magma and discharged, and required mineral matter is obtained by centrifuge.
Evaporative crystallization unit of the present invention can also utilize the side for strengthening air velocity and increase evaporation surface The evaporation and crystallization system equipment that method is realized.
Relative to prior art, advantage of the invention is that:
1) present invention combine Salt Lake Area actual conditions, using local illumination it is strong the characteristics of, suit measures to local conditions, propose utilization too The method that positive energy heat collector replaces traditional vapours, crystallization treatment is evaporated to bittern, mineral matter needed for extraction is effectively save The requirement of the energy, reduction to infrastructure, is widely applied suitable for Salt Lake Area.
2) organic heat carrier heat-conducting medium proposed by the present invention, the aqueous medium heat conduction of abandoning tradition, using heat conduction temperature more Bittern can be directly heated to more than boiling point as heat-conducting medium, substantially increase bittern evaporation crystallization by high organic heat carrier Efficiency.
Brief description of the drawings
Fig. 1 is the structural representation of the embodiment of the present invention 1
In figure:1- solar thermal collectors, 2- organic heat carrier holding vessels, 3- heat exchangers, 5- crystallizing evaporators, 6- condensations Device, 7- condensate drums, 8- holding vessel pumps, 9- heat exchanger pumps, 10- circulating pumps, 11- magmas pump, 12- bittern feed pump, vavuum pump 13rd, the import of 21- heat carriers, 22- heating medium outlets, 23- bittern discharging openings, 24- bittern charging apertures
Embodiment
It is the specific embodiment of present invention below, is solved the skill of technical problem in present specification for illustrating Art scheme, contribute to skilled artisan understands that present invention, but the realization of technical solution of the present invention is not limited to these Embodiment.
Embodiment 1
A kind of device that bittern mineral is extracted using solar energy, including solar thermal collector 1, heat exchanger 3, evaporation knot Brilliant unit;The evaporative crystallization unit includes crystallizing evaporator 5, condenser 6, condensate drum 7 and pump;The pump includes heat exchanger Pump 9, circulating pump 10, magma pump 11, bittern feed pump 12, vavuum pump 13;The heat exchanger 3 is provided with heat carrier import 21, heat carries Body outlet 22, bittern charging aperture 24 and bittern discharging opening 23;The heat carrier import 21 of the heat exchanger 3 by heat exchanger pump 9 with Solar thermal collector 1 is connected, and the heating medium outlet 22 is connected to solar thermal collector 1 by circulation line;The bittern enters Material mouth 24 is connected by changing circulating pump 10 with feed reservoir, and the bittern discharging opening 23 is connected with crystallizing evaporator 5;The evaporation knot The steam (vapor) outlet of brilliant device 5 is connected with condenser 6, and the rear end of condenser 6 is provided with condensate drum 7;The condensate drum is connected with Vavuum pump 13.Circulation line is formed by pipeline and magma pump 11 in the bottom of crystallizing evaporator 5, the magma pump 11 with Magma discharging opening is provided between return line.Organic heat carrier holding vessel 2 is provided between the solar thermal collector 1 and heat exchanger 3, Holding vessel pump 8 is provided between the solar thermal collector 1 and organic heat carrier holding vessel 2.
Organic heat carrier is heated to 180 DEG C by the solar thermal collector, is stored into organic heat carrier storage tank, from raw material Pond adds bittern through bittern charging aperture 24, and cycle heat exchange is carried out with organic heat carrier in heat exchanger 3, and organic heat after heat exchange carries Body is recycled to solar thermal collector 1 through circulation line and reused, and the bittern after being heated is evaporated knot in evaporator 5 Crystalline substance, steam are discharged from upper outlet, and the condensed condensation of device 6 is recycled, and mineral matter magma is exported from magma and discharged, and passes through centrifuge Centrifugation obtains required mineral matter.The steam (vapor) outlet of the crystallizing evaporator can also connect the heat carrier after MVR equipment heat exchangings and enter Row reheats, and improves the utilization rate of heat.
The apparatus of the present invention of embodiment 2 are compared with the prior art
As can be seen from the table, in terms of extraction efficiency, DNA purity and process cycle, apparatus of the present invention are evaporated with vapour source Crystallization apparatus can reach higher level, but apparatus of the present invention directly utilize solar energy, energy-conserving and environment-protective, to base material facility dependency degree It is small.Although method is shone on natural beach directly utilizes solar energy, floor space is huge, and process cycle and extraction efficiency are far below this hair It is bright.
Above-described embodiment is only the explanation to preferred scheme of the present invention, is not intended to limit the present invention.As long as the present invention's Change, modification in spirit to above-described embodiment should all fall into the claimed scope of following claims It is interior.

Claims (9)

  1. A kind of 1. method that bittern mineral is extracted using solar energy, it is characterised in that comprise the following steps:A the sun) is utilized Energy heat collector heats to organic heat carrier;B the organic heat carrier after heating) is heated into bittern by heat exchanger;C heating) is made Bittern afterwards carries out mineral matter separation by evaporation crystallization equipment.
  2. 2. the method according to claim 1 that bittern mineral is extracted using solar energy, it is characterised in that:In step A Described solar thermal collector is vacuum tube solar heating element, metal absorber vacuum tube collector, heat pipe type vacuum pipe collection Hot device.
  3. 3. the method according to claim 1 that bittern mineral is extracted using solar energy, it is characterised in that:In step A Described organic heat carrier temperature after heating is more than 120 DEG C.
  4. 4. the method according to claim 3 that bittern mineral is extracted using solar energy, it is characterised in that:In step A Described organic heat carrier temperature after heating is more than 180 DEG C.
  5. 5. the method according to claim 1 that bittern mineral is extracted using solar energy, it is characterised in that:Described has Machine heat carrier is mineral oil origin organic heat carrier and/or synthesis type organic heat carrier.
  6. 6. the method according to claim 5 that bittern mineral is extracted using solar energy, it is characterised in that:The mineral Oil type organic heat carrier is the mixture of paraffinic base hydrocarbon, and the mixture of cycloalkyl hydrocarbon, aromatic hydrocarbon is hydrocarbon One or more in the mixture of compound.
  7. 7. the method according to claim 5 that bittern mineral is extracted using solar energy, it is characterised in that:The synthesis Type organic heat carrier includes:Alkylbenzene, alkyl biphenyl, benzyl group and two benzyl group toluene, biphenyl and Biphenyl Ether azeotropic mixture, three Benzene and partially hydrogenated terphenyl, alkyl biphenyl ether, aliphatic hydrocarbon, poly- α alkane, silicone oil, the one or more in fluorine hydrocarbon.
  8. A kind of 8. device for realizing method as claimed in claim 1, it is characterised in that:Including solar thermal collector (1), heat exchanger (3), evaporative crystallization unit;
    The evaporative crystallization unit includes crystallizing evaporator (5), condenser (6), condensate drum (7) and pump;The pump includes changing Hot device pump (9), circulating pump (10), magma pump (11), bittern feed pump (12), vavuum pump (13);
    The heat exchanger (3) is provided with heat carrier import (21), heating medium outlet (22), bittern charging aperture (24) and bittern discharging opening (23);The heat carrier import (21) of the heat exchanger (3) is connected by heat exchanger pump (9) with solar thermal collector (1), the heat Carrier outlet (22) is connected to solar thermal collector (1) by circulation line;The bittern charging aperture (24) is by changing circulating pump (10) it is connected with feed reservoir, the bittern discharging opening (23) is connected with crystallizing evaporator (5);
    Circulation line is formed by pipeline and magma pump (11) in the crystallizing evaporator (5) bottom, in the magma pump (11) Magma discharging opening is provided between return line.
  9. 9. device according to claim 8, it is characterised in that:Set between the solar thermal collector (1) and heat exchanger (3) There is organic heat carrier holding vessel (2), holding vessel is provided between the solar thermal collector (1) and organic heat carrier holding vessel (2) Pump (8).
CN201711171474.2A 2017-11-22 2017-11-22 A kind of method and apparatus that bittern mineral is extracted using solar energy Pending CN107697968A (en)

Priority Applications (2)

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CN201711171474.2A CN107697968A (en) 2017-11-22 2017-11-22 A kind of method and apparatus that bittern mineral is extracted using solar energy
PCT/CN2018/114991 WO2019100959A1 (en) 2017-11-22 2018-11-12 Method and device for extracting minerals in salt lake water by using solar energy

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Application Number Priority Date Filing Date Title
CN201711171474.2A CN107697968A (en) 2017-11-22 2017-11-22 A kind of method and apparatus that bittern mineral is extracted using solar energy

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Cited By (3)

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CN109443065A (en) * 2018-12-01 2019-03-08 中节能城市节能研究院有限公司 A kind of absorption energy storage equipment of big concentration difference based on active crystallization technique
WO2019100957A1 (en) * 2017-11-22 2019-05-31 西安威西特消防科技有限责任公司 Device for extracting minerals from brine by using solar energy
WO2019100959A1 (en) * 2017-11-22 2019-05-31 西安威西特消防科技有限责任公司 Method and device for extracting minerals in salt lake water by using solar energy

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CN107308662A (en) * 2017-04-13 2017-11-03 北京浦仁美华环保科技股份有限公司 The MVR evaporating, concentrating and crystallizing techniques of lithium are extracted from salt lake bittern

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CN107697968A (en) * 2017-11-22 2018-02-16 西安威西特消防科技有限责任公司 A kind of method and apparatus that bittern mineral is extracted using solar energy
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CN101928023A (en) * 2010-09-03 2010-12-29 山西大学 Device and method for preparing lithium carbonate from brine by utilizing solar energy
CN102336448A (en) * 2011-08-29 2012-02-01 陶欣 Saline treatment system and method
CN107308662A (en) * 2017-04-13 2017-11-03 北京浦仁美华环保科技股份有限公司 The MVR evaporating, concentrating and crystallizing techniques of lithium are extracted from salt lake bittern

Cited By (4)

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WO2019100957A1 (en) * 2017-11-22 2019-05-31 西安威西特消防科技有限责任公司 Device for extracting minerals from brine by using solar energy
WO2019100959A1 (en) * 2017-11-22 2019-05-31 西安威西特消防科技有限责任公司 Method and device for extracting minerals in salt lake water by using solar energy
CN109443065A (en) * 2018-12-01 2019-03-08 中节能城市节能研究院有限公司 A kind of absorption energy storage equipment of big concentration difference based on active crystallization technique
CN109443065B (en) * 2018-12-01 2023-12-26 中节能城市节能研究院有限公司 Large concentration difference absorption type energy storage device based on active crystallization technology

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