CN107694322A - A kind of furnace sulfur fixation coal-saving agent - Google Patents

A kind of furnace sulfur fixation coal-saving agent Download PDF

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Publication number
CN107694322A
CN107694322A CN201711074720.2A CN201711074720A CN107694322A CN 107694322 A CN107694322 A CN 107694322A CN 201711074720 A CN201711074720 A CN 201711074720A CN 107694322 A CN107694322 A CN 107694322A
Authority
CN
China
Prior art keywords
coal
lime stone
nano
furnace
saving agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711074720.2A
Other languages
Chinese (zh)
Inventor
周宇红
王祥西
陈康康
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
State Power Investment Group Yuanda Environmental Protection Catalyst Co Ltd
JIAXING ZHONGTAI ENERGY-SAVING TECHNOLOGY Co Ltd
Original Assignee
State Power Investment Group Yuanda Environmental Protection Catalyst Co Ltd
JIAXING ZHONGTAI ENERGY-SAVING TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by State Power Investment Group Yuanda Environmental Protection Catalyst Co Ltd, JIAXING ZHONGTAI ENERGY-SAVING TECHNOLOGY Co Ltd filed Critical State Power Investment Group Yuanda Environmental Protection Catalyst Co Ltd
Priority to CN201711074720.2A priority Critical patent/CN107694322A/en
Publication of CN107694322A publication Critical patent/CN107694322A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/81Solid phase processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/50Sulfur oxides

Abstract

Sulfur-fixing coal saving agent in a kind of Boiler Furnace.The present invention replaces common lime stone using nano-calcium carbonate in stove, so as to greatly reduce dosage.Not only desulfurized effect is better than common lime stone, and reduce due to using large quantities of lime stone and caused by thermal losses, saved coal consumption, reached the double effectses of sulfur-immobilizing coal-saving.

Description

A kind of furnace sulfur fixation coal-saving agent
The invention belongs to coal combustion and sulfur fixation coal-saving additive, for boiler furnace sulfur fixation and the additive economized on coal.
Boiler fired coal desulfurization is divided into three kinds of methods:By coal washing desulfurization before combustion, although coal washing can reduce sulfur content, very Difficulty reaches discharge standard;Although flue gas desulfurization desulfurized effect is preferable, investment is larger, and desulphurization cost is also higher;Add lime Stone desulfuration in furnace can reach preferable effect, while again without big investment.
Although it is simplest method to add lime stone desulfuration in furnace, the efficiency comparison of its desulfurization is low.Due to lime Stone is graininess, and specific surface area is still smaller after decomposition, after CaO and SO2 or the SO3 reaction on surface, it is prevented that in particle CaO further participate in reaction.Therefore, more lime stone need to be used in desulfuration in furnace, typically in Kg more than 100, in addition it is useful Arrive 200Kg's.So, substantial amounts of heat energy is just consumed, hence it is evident that reduce steam coal rates.
In view of true above, it is an object of the invention to provide a kind of effect that can reach solid sulphur, and can greatly reduce by In the sulfur-fixing coal saving agent for adding large quantities of lime stone and consumption of calorie.The present invention is to use nano-calcium carbonate desulfuration in furnace.Nano-sized carbon Sour calcium has big surface area, can reach 40-50 square metres/g, and this can greatly reduce the dosage of nano-calcium carbonate, both reach The effect of solid sulphur has reached the effect economized on coal again, therefore is called sulfur-fixing coal saving agent.
The present invention is realized by the following method.
Embodiment 1)
8 parts of nano-calcium carbonate is taken, 6 parts of nano magnesia, adds in 86 parts of water, by high-speed shearing machine, suspension is made, Obtain finished product.
Embodiment 2)
10 parts of nano-calcium carbonate is taken, 4 parts of nano magnesia, adds in 86 parts of water, by high-speed shearing machine, suspension is made Liquid, obtain finished product.
This product is uniformly sprayed on coal using sprayer unit during use, fountain height 0.1-0.3%.

Claims (1)

1. a kind of furnace sulfur fixation coal-saving agent, economized on coal using nano-calcium carbonate replacement common lime stone for desulfuration in furnace, its composition For (w/w):Nano-calcium carbonate (accounting for 8-12%), nano magnesia (accounting for 4-6%), water (accounting for 82-88%).It is configured to suspension, Uniformly it is sprayed on coal, usage amount 0.1-0.3%.
CN201711074720.2A 2017-11-06 2017-11-06 A kind of furnace sulfur fixation coal-saving agent Pending CN107694322A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711074720.2A CN107694322A (en) 2017-11-06 2017-11-06 A kind of furnace sulfur fixation coal-saving agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711074720.2A CN107694322A (en) 2017-11-06 2017-11-06 A kind of furnace sulfur fixation coal-saving agent

Publications (1)

Publication Number Publication Date
CN107694322A true CN107694322A (en) 2018-02-16

Family

ID=61178212

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711074720.2A Pending CN107694322A (en) 2017-11-06 2017-11-06 A kind of furnace sulfur fixation coal-saving agent

Country Status (1)

Country Link
CN (1) CN107694322A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114558441A (en) * 2022-03-02 2022-05-31 通化鑫鸿新材料有限公司 Preparation method and application of solid high-fluidity, high-efficiency and low-byproduct nano calcium carbonate denitration agent

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1492031A (en) * 2003-07-30 2004-04-28 辽河石油勘探局 Additive for raw coal burning suporting and desulfurizing
CN105733724A (en) * 2016-01-12 2016-07-06 韩秀峰 Sulfur-fixation efficiently combusted clean coal with desulfuration effect and preparation method

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1492031A (en) * 2003-07-30 2004-04-28 辽河石油勘探局 Additive for raw coal burning suporting and desulfurizing
CN105733724A (en) * 2016-01-12 2016-07-06 韩秀峰 Sulfur-fixation efficiently combusted clean coal with desulfuration effect and preparation method

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
刘建忠等: "纳米碳酸钙微观特征及其促进燃煤脱硫特性研究", 《燃料化学学报》 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114558441A (en) * 2022-03-02 2022-05-31 通化鑫鸿新材料有限公司 Preparation method and application of solid high-fluidity, high-efficiency and low-byproduct nano calcium carbonate denitration agent

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Application publication date: 20180216