CN107687574A - A kind of tenebrescent rod - Google Patents
A kind of tenebrescent rod Download PDFInfo
- Publication number
- CN107687574A CN107687574A CN201710695644.0A CN201710695644A CN107687574A CN 107687574 A CN107687574 A CN 107687574A CN 201710695644 A CN201710695644 A CN 201710695644A CN 107687574 A CN107687574 A CN 107687574A
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- China
- Prior art keywords
- parts
- double
- solution
- tenebrescent
- rod
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F21—LIGHTING
- F21K—NON-ELECTRIC LIGHT SOURCES USING LUMINESCENCE; LIGHT SOURCES USING ELECTROCHEMILUMINESCENCE; LIGHT SOURCES USING CHARGES OF COMBUSTIBLE MATERIAL; LIGHT SOURCES USING SEMICONDUCTOR DEVICES AS LIGHT-GENERATING ELEMENTS; LIGHT SOURCES NOT OTHERWISE PROVIDED FOR
- F21K2/00—Non-electric light sources using luminescence; Light sources using electrochemiluminescence
- F21K2/06—Non-electric light sources using luminescence; Light sources using electrochemiluminescence using chemiluminescence
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K9/00—Tenebrescent materials, i.e. materials for which the range of wavelengths for energy absorption is changed as a result of excitation by some form of energy
- C09K9/02—Organic tenebrescent materials
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- General Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Luminescent Compositions (AREA)
Abstract
A kind of tenebrescent rod, including sealing and bent plastic tube, plastic tube be built-in with glass tube, plastic tube is made up of built with activator solution, glass tube built with oxalate ester solution, oxalate ester solution the composition of following masses fraction：20 30 parts of dibutyl phthalate, double (2, the alcoxyl carbonyl phenyl of 4 dinitro 6) 15 25 parts of oxalate, 5,12 0.2 0.7 parts of (phenylacetylene base) naphthacene, 5,6,11,12 0.1 0.3 parts of tetraphenyl naphthonaphthalenes, 1 2.5 3.5 parts of (phenylacetylene base) anthracene of chlorine 9,10 pairs；Activator solution is made up of the composition of following masses fraction：40 45 parts of triethyl citrate, 5 10 parts of hydrogen peroxide, 0.1 0.6 parts of sodium salicylate, 38 parts of water.The glo-stick of the present invention can change colour in luminescence process, and change is obvious, total fluorescent lifetime length.
Description
Technical field
The present invention relates to a kind of chemiluminescence glo-stick, and in particular to one kind can be changed into green in luminescence process from yellow
Glo-stick.
Background technology
In entertainment place or celebration commonly use glo-stick come increase live atmosphere with stage interactive, existingization
It is all solid color to learn luminous fluorescent rod, is all same color from starting shinny to terminating, relatively simple.At present, do not send out also
The chemiluminescence rod that a kind of existing color in luminescence process can change.
The content of the invention
It is an object of the invention to provide it is a kind of can be in luminescence process from the tenebrescent rod of yellow virescence.
To achieve the above object, the technical solution adopted by the present invention is：
A kind of tenebrescent rod, including sealing and bent plastic tube, plastic tube be built-in with glass tube, plastic tube is built with work
Agent solution, glass tube are made up of built with oxalate ester solution, wherein oxalate ester solution the composition of following masses fraction：It is adjacent
Dibatyl phithalate 20-30 parts, double (2,4- dinitro -6- alcoxyls carbonyl phenyl) oxalate 15-25 parts, 5,12- (phenylacetylenes
Base)-naphthacene 0.2-0.7 parts, 5,6,11,12- tetraphenyl naphthonaphthalene 0.1-0.3 parts, double (phenylacetylene base) anthracenes of chloro- 9, the 10- of 1-
2.5-3.5 part；Activator solution is made up of the composition of following masses fraction：Triethyl citrate 40-45 parts, hydrogen peroxide 5-10
Part, sodium salicylate 0.1-0.6 parts, water 3-8 parts.
The compound method of oxalate ester solution is：By dibutyl phthalate（DBP）With double (2,4- dinitro -6- alkane
Oxygen carbonyl phenyl) oxalate（CPPO）, 5,12- (phenylacetylene base)-naphthacene, 5,6,11,12- tetraphenyls naphthonaphthalene, the chloro- 9,10- of 1-
Double (phenylacetylene base) anthracene mixing, are heated with stirring to 70-80 DEG C, obtain mixing liquid after being completely dissolved, naturally cool to room temperature system
Into oxalate ester solution.
The compound method of activator solution is：Triethyl citrate, hydrogen peroxide, sodium salicylate, water are mixed, stirring is equal
It is even that activator solution is made.
The mass ratio of oxalate ester solution and activator solution is 1:1.5.
Beneficial effects of the present invention：
Glass tube of the present invention takes the formula of composite fluorescent dye and activator to adjust built with the fluorescent dye of different fluorescence efficiencies
It is whole, obtain the chemiluminescence glo-stick with color changeable effect.
Embodiment
For a further understanding of the present invention, this breaking-out is further illustrated with reference to embodiment：
Fluorescent dye of the invention by selecting different fluorescence efficiencies, the formula of composite fluorescent dye and activator is taken to adjust,
Obtain the chemiluminescence glo-stick with color changeable effect.
Selective plasticization agent dibutyl phthalate, tributyl 2-acetylcitrate, n-butylbenzoate, triacetin
Deng being used as oxalate ester solvent.
Select the solvent as activator such as repefral, triethyl citrate, tert-butyl alcohol.
Double (2,4,6- trichlorophenyls) oxalates of selection, double (the chloro- 6- alcoxyls carbonyl phenyls of 2,4,5- tri-) oxalates, it is double (2,
4- dinitro -6- alcoxyls carbonyl phenyl) oxalate, double (the chloro- 6- alcoxyls carbonyl phenyls of 2,4- bis-) oxalates are as reducing agent.
Selection fusion linear conjugate aromatic hydrocarbons, double (styryl) anthracenes of such as 9,10-, double (4- the methoxyphenyls) -2- chlorine of 9,10-
Double (phenylacetylene base) anthracenes of the chloro- 9,10- of anthraquinone, 1-, bis- chloro- 9,10- of 1,8- double (phenylacetylene base) anthracene, N, N- dibutyl -5,6,12,
13- tetra- (4- tert-butyl benzenes epoxide) -3,4,9,10- imidodicarbonic diamide, 5,12- (phenylacetylene base)-naphthacene, the benzene of 5,6,11,12- tetra-
Base naphthonaphthalene, as fluorescer.
Hydrogen peroxide, urea peroxide are selected as oxidant.
Sodium salicylate, sodium perborate are selected as catalyst.
The reaction equation of peroxyoxalate luminescence system is as follows：
Oxalate+H2O2+ fluorescerCatalyst→2CO2+ 2ArOH+ fluorescers+light
（Ar=substitution virtue machine base）
The fluorescer of the appropriate different luminous efficiencies of selection, chloro- 9, the 10- of 1- double (phenylacetylene base) anthracene, 1 grown by the timeliness that lights,
8- bis- chloro- 9,10- double (phenylacetylene base) anthracene, N, N- dibutyl -5,6,12,13- four (4- tert-butyl benzenes epoxide) -3,4,9,10-
Imidodicarbonic diamide) and luminous efficiency superelevation 5,12- (phenylacetylene base)-naphthacene, 5,6,11,12- tetraphenyl naphthalene short with luminous timeliness
And naphthalene press 3：1 ratio mixing, with appropriate oxalate ester（14 ~ 25% mass ratioes）, it is (adjacent to be dissolved in appropriate organic solvent
Dibatyl phithalate, tributyl 2-acetylcitrate, n-butylbenzoate etc.) in, it is configured to oxalate ester solution and (is commonly called as lighting
Liquid).
Embodiment 1：
The present invention a preferred embodiment be：
1st, the oxalate ester solution in tenebrescent rod is prepared：
Oxalate ester solution is made up of the composition of following masses fraction：25 parts of dibutyl phthalate, it is double (2,4- dinitros-
6- alcoxyls carbonyl phenyl) 20 parts of oxalate, 5,12- (phenylacetylene base) -0.4 part of naphthacene, 5,6,11,12- tetraphenyl naphthonaphthalenes 0.2
Part, double 3.0 parts of (phenylacetylene base) anthracenes of chloro- 9, the 10- of 1-.
Oxalate ester solution manufacturing method：
By above-mentioned dibutyl phthalate（DBP）With double (2,4- dinitro -6- alcoxyls carbonyl phenyl) oxalates（CPPO）、5,
Double (phenylacetylene base) anthracene mixing of 12- (phenylacetylene base)-naphthacene, 5,6,11,12- tetraphenyl naphthonaphthalenes, chloro- 9, the 10- of 1-, stirring add
Heat obtains mixing liquid after being completely dissolved, naturally cools to room temperature and oxalate ester solution is made to 70-80 DEG C.
2nd, the activator solution in tenebrescent rod is prepared：
Activator solution is made up of the composition of following mass fraction：40 parts of triethyl citrate, 7 parts of hydrogen peroxide, sodium salicylate
0.3 part, 5 parts of water.
Activator solution preparation method：
Above-mentioned triethyl citrate, hydrogen peroxide, sodium salicylate, water are mixed, stirs and activator solution is made.
3rd, the manufacture of tenebrescent rod：
By above-mentioned configuration good oxalate ester solution and activator solution, by 1:1.5 mass ratio is respectively by oxalate ester solution
It is filled in glass tube, activator solution is filled in plastic tube, and glass tube is put into plastic tube, is sealed opening, is become
Color glo-stick finished product.
4th, the detection of tenebrescent rod：
At room temperature, bending plastic pipe, crush glass tube, two kinds of liquid mixing, priming color is yellow（Brightness reaches
More than 1000lux）, it is changed into yellow green during 3-10 minutes, becomes green after 10 minutes, total fluorescent lifetime is 100 ~ 240 minutes.
The tenebrescent rod color change of the present invention is obvious, interesting stronger than original fluorescent product.
Claims (5)
1. a kind of tenebrescent rod, including sealing and bent plastic tube, plastic tube is built-in with glass tube, plastic tube built with
Activator solution, glass tube is built with oxalate ester solution, it is characterised in that the oxalate ester solution is by following masses fraction
Composition composition：Dibutyl phthalate 20-30 parts, double (2,4- dinitro -6- alcoxyls carbonyl phenyl) oxalate 15-25 parts,
5,12- (phenylacetylene base)-naphthacene 0.2-0.7 parts, 5,6,11,12- tetraphenyl naphthonaphthalene 0.1-0.3 parts, the double (benzene of chloro- 9, the 10- of 1-
Acetenyl) anthracene 2.5-3.5 parts；The activator solution is made up of the composition of following masses fraction：Triethyl citrate 40-45
Part, hydrogen peroxide 5-10 parts, sodium salicylate 0.1-0.6 parts, water 3-8 parts.
2. tenebrescent rod as claimed in claim 1, it is characterised in that the oxalate ester solution is by following masses fraction
Composition forms：25 parts of dibutyl phthalate, double (2,4- dinitro -6- alcoxyls carbonyl phenyl) 20 parts of oxalates, 5,12- (benzene
Acetenyl) 0.4 part of-naphthacene, 5,6,11,12- 0.2 part of tetraphenyl naphthonaphthalenes, double 3.0 parts of (phenylacetylene base) anthracenes of chloro- 9, the 10- of 1-；
The activator solution is made up of the composition of following masses fraction：40 parts of triethyl citrate, 7 parts of hydrogen peroxide, sodium salicylate
0.3 part, 5 parts of water.
3. any tenebrescent rod as claimed in claim 1 or 2, it is characterised in that the preparation side of the oxalate ester solution
Method is：By dibutyl phthalate and double (2,4- dinitro -6- alcoxyls carbonyl phenyl) oxalate, 5,12- (phenylacetylene base)-fourth
Province, 5,6,11,12- tetraphenyl naphthonaphthalenes, double (phenylacetylene base) anthracene mixing of chloro- 9, the 10- of 1-, are heated with stirring to 70-80 DEG C, completely
Mixing liquid is obtained after dissolving, room temperature is naturally cooled to and oxalate ester solution is made.
4. any tenebrescent rod as claimed in claim 1 or 2, it is characterised in that the compound method of the activator solution
For：Triethyl citrate, hydrogen peroxide, sodium salicylate, water are mixed, stirs and activator solution is made.
5. any tenebrescent rod as claimed in claim 1 or 2, it is characterised in that the oxalate ester solution and the work
The mass ratio of agent solution is 1:1.5.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710695644.0A CN107687574A (en) | 2017-08-15 | 2017-08-15 | A kind of tenebrescent rod |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710695644.0A CN107687574A (en) | 2017-08-15 | 2017-08-15 | A kind of tenebrescent rod |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107687574A true CN107687574A (en) | 2018-02-13 |
Family
ID=61153363
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710695644.0A Pending CN107687574A (en) | 2017-08-15 | 2017-08-15 | A kind of tenebrescent rod |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107687574A (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1069051A (en) * | 1991-07-30 | 1993-02-17 | 中国科学院大连化学物理研究所 | The cold light pipe of a kind of chemical luminous system and system thereof |
-
2017
- 2017-08-15 CN CN201710695644.0A patent/CN107687574A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1069051A (en) * | 1991-07-30 | 1993-02-17 | 中国科学院大连化学物理研究所 | The cold light pipe of a kind of chemical luminous system and system thereof |
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