CN107686737A - Gu softening temperature section is the coke making and coal blending method of more than 90 DEG C 1/3 coking coal - Google Patents
Gu softening temperature section is the coke making and coal blending method of more than 90 DEG C 1/3 coking coal Download PDFInfo
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- CN107686737A CN107686737A CN201710868809.XA CN201710868809A CN107686737A CN 107686737 A CN107686737 A CN 107686737A CN 201710868809 A CN201710868809 A CN 201710868809A CN 107686737 A CN107686737 A CN 107686737A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B57/00—Other carbonising or coking processes; Features of destructive distillation processes in general
- C10B57/04—Other carbonising or coking processes; Features of destructive distillation processes in general using charges of special composition
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Abstract
The invention discloses the coke making and coal blending method that a kind of solid softening temperature section is more than 90 DEG C 1/3 coking coal, belong to coal-blending coking technical field.This method comprises the following steps:1) Giseeler fluidity measure is carried out to 1/3 coking coal:1/3 coking coal for choosing solid softening temperature section >=90 DEG C is designated as the coking coal of A classes 1/3, Gu 90 DEG C of softening temperature section < 1/3 coking coal is designated as the coking coal of B classes 1/3;2) coking coal of A classes 1/3 is subjected to coal blending by following mass percent:Bottle coal:5%, rich coal:The coking coal of 0~30%, A class 1/3:The coking coal of 0~30%, B class 1/3:25%, coking coal:40%, lean coal:10%.Subdivision collocation is optimized by the solid softening temperature section being introduced into Giseeler fluidity index 1/3 coking coal partially fertile to ature of coal to use, and is partly substituted high-quality rich coal, on the premise of coke quality is stablized, is reached the purpose for reducing coal blending cost.
Description
Technical field
The present invention relates to the coke making and coal blending method of 1/3 coking coal, belongs to coal-blending coking technical field, is specifically related to one kind
Gu-softening temperature section is the coke making and coal blending method of more than 90 DEG C 1/3 coking coal.
Background technology
China's coal resource enriches, but coking coal resource is in short supply, and skewness weighs in limited coking coal resource.
In the coal reserves verified, coking coal reserves only accounts for the 26% of coal gross reserves, and coking coal only accounts for coking coal reserves
17.57%, wherein, rich coal accounts for the 10% of coking coal reserves.And in coal-blending coking, burnt rich coal should typically account for 50%-60%, because
This, contradiction is serious between coking coal resource and the demand of coke making and coal blending.
In order to improve coke quality and reduce production cost, coking worker in various countries' gradually starts to pay attention to non-master
Come in the application study of coking coal, and the coal that 1/3 coking coal is higher as content in China's coal resource deposit, how to use 1/3 Jiao
Coal has turned into the required problems faced of coking worker.1/3 coking coal is as a kind of degree of metamorphism between coking coal and rich coal
Coal, its complexity are higher than burnt rich coal, and use of the China to 1/3 coking coal depend on traditional coal index and
Certain lack be present in the combined index of the vitrinite reflectance of coal petrography index and its distribution, both indexs and both indexs
Fall into, it is impossible to reasonable employment comprehensively is accomplished to 1/3 coking coal.
Chinese invention patent application (application publication number:CN104804755A, data of publication of application:2015-07-29) disclose
Gu-soft silicon carbide is the coke making and coal blending method of less than 85 DEG C 1/3 coking coal, Coal Blending Schemes disclosed in the application for a patent for invention are:
1) Giseeler fluidity measure is carried out to 1/3 coking coal, selection wherein consolidates 1/3 coking coal that softening temperature section is 70~85 DEG C and is designated as I class
1/3 coking coal, 85 DEG C of temperature range > 1/3 coking coal are designated as other 1/3 coking coal;2) coking coal of I class 1/3 is pressed into following mass percent
Carry out coal blending:Gas rich coal:1~10%, rich coal:1~10%, the coking coal of I class 1/3:1~15%, other 1/3 coking coal:10~20%,
Coking coal:40~45%, lean coal:10~15%;Solid-softening temperature the section is divided into 34% for the volatilization of less than 85 DEG C 1/3 coking coal
More than and.
Chinese invention patent application (application publication number:CN104804755A, data of publication of application:2015-07-29) disclose
Volatilization is divided into the coke making and coal blending method of 1/3 coking coal of 34% and the above, and the Coal Blending Schemes of this method are:1) 1/3 coking coal is carried out
Giseeler fluidity determines, and 1/3 coking coal for choosing wherein solid -70 DEG C of softening temperature section < is designated as the coking coal of II class 1/3, Gu Ruanwenduqu
Between 85 DEG C of ﹥ 1/3 coking coal be designated as other 1/3 coking coal.2) coking coal of II class 1/3 is subjected to coal blending by following mass percent:Gas fertilizer
Coal:1~10%, rich coal:1~15%, the coking coal of II class 1/3:5~10%, other 1/3 coking coal:10~20%, coking coal:40~
45%, lean coal:10~15%.
But solid-softening temperature the section for 1/3 coking coal that above-mentioned two pieces application for a patent for invention uses is respectively less than 70 DEG C with 70
Between~85 DEG C, its maximum fluidity can not reach the standard of substituting fat.
The content of the invention
In order to solve the above technical problems, the invention discloses the refining that a kind of solid-softening temperature section is more than 90 DEG C 1/3 coking coal
Burnt blending method, the coke making and coal blending method are by the solid-softening temperature section being introduced into Giseeler fluidity index partially fertile to ature of coal
1/3 coking coal optimizes subdivision collocation and used, and partly substitutes high-quality rich coal, on the premise of coke quality is stablized, reaches reduction
The purpose of coal blending cost.
To achieve the above object, match somebody with somebody the invention provides a kind of solid-softening temperature section for the coking of more than 90 DEG C 1/3 coking coal
Coal method, comprises the following steps:
1) Giseeler fluidity measure is carried out to 1/3 coking coal:1/3 coking coal for choosing solid-softening temperature section >=90 DEG C is designated as A classes
1/3 coking coal, Gu -90 DEG C of softening temperature section < 1/3 coking coal is designated as the coking coal of B classes 1/3;
2) coking coal of A classes 1/3 is subjected to coal blending by following mass percent:
Bottle coal:5%, rich coal:The coking coal of 0~30%, A class 1/3:The coking coal of 0~30%, B class 1/3:25%, coking coal:40%, it is thin
Coal:10%.
Further, the coking coal of A classes 1/3 is subjected to coal blending by following mass percent:
Bottle coal:5%, rich coal:The coking coal of 0~20%, A class 1/3:The coking coal of 0~20%, B class 1/3:25%, coking coal:40%, it is thin
Coal:10%, the mass percent of the coking coal of A classes 1/3 does not include zero.
Preferably, the coking coal of A classes 1/3 is subjected to coal blending by following mass percent:
Bottle coal:5%, rich coal:The coking coal of 18%, A class 1/3:The coking coal of 2%, B class 1/3:25%, coking coal:40%, lean coal:
10%.
Preferably, the coking coal of A classes 1/3 is subjected to coal blending by following mass percent:
Bottle coal:5%, rich coal:The coking coal of 15%, A class 1/3:The coking coal of 5%, B class 1/3:25%, coking coal:40%, lean coal:
10%.
Preferably, the coking coal of A classes 1/3 is subjected to coal blending by following mass percent:
Bottle coal:5%, rich coal:The coking coal of 13%, A class 1/3:The coking coal of 7%, B class 1/3:25%, coking coal:40%, lean coal:
10%.
Preferably, the coking coal of A classes 1/3 is subjected to coal blending by following mass percent:
Bottle coal:5%, rich coal:The coking coal of 10%, A class 1/3:The coking coal of 10%, B class 1/3:25%, coking coal:40%, lean coal:
10%.
Preferably, the coking coal of A classes 1/3 is subjected to coal blending by following mass percent:
Bottle coal:5%, rich coal:The coking coal of 8%, A class 1/3:The coking coal of 12%, B class 1/3:25%, coking coal:40%, lean coal:
10%.
Preferably, the coking coal of A classes 1/3 is subjected to coal blending by following mass percent:
Bottle coal:5%, rich coal:The coking coal of 5%, A class 1/3:The coking coal of 15%, B class 1/3:25%, coking coal:40%, lean coal:
10%.
Preferably, the coking coal of A classes 1/3 is subjected to coal blending by following mass percent:
Bottle coal:5%, rich coal:The coking coal of 3%, A class 1/3:The coking coal of 17%, B class 1/3:25%, coking coal:40%, lean coal:
10%.
Bottle coal:5%, rich coal:The coking coal of 0%, A class 1/3:The coking coal of 20%, B class 1/3:25%, coking coal:40%, lean coal:
10%.
Preferably, the coking coal of A classes 1/3 is subjected to coal blending by following mass percent:
Bottle coal:5%, rich coal:The coking coal of 15%, A class 1/3:The coking coal of 10%, B class 1/3:20%, coking coal:40%, lean coal:
10%.
Preferably, the coking coal of A classes 1/3 is subjected to coal blending by following mass percent:
Bottle coal:5%, rich coal:The coking coal of 15%, A class 1/3:The coking coal of 8%, B class 1/3:22%, coking coal:40%, lean coal:
10%.
Preferably, the coking coal of A classes 1/3 is subjected to coal blending by following mass percent:
Bottle coal:5%, rich coal:The coking coal of 15%, A class 1/3:The coking coal of 2%, B class 1/3:28%, coking coal:40%, lean coal:
10%.
Yet further, the adhesive index value of the coking coal of A classes 1/3:90, maximum thick ness of plastic layer Y value:19, max-flow
Dynamic degree:12543ddpm, Gu-softening temperature section:99℃.
Further, the adhesive index value of the coking coal of B classes 1/3:88, maximum thick ness of plastic layer Y value:17, max-flow
Dynamic degree:1578ddpm, Gu-softening temperature section:83℃.
Further, the adhesive index value of the rich coal:95, maximum thick ness of plastic layer Y value:27, fugitive constituent Vdaf:
31%, maximum fluidity:50000ddpm, Gu-softening temperature section:105℃.
Beneficial effect:
The method of the present invention is using Giseeler fluidity index is introduced, and to ature of coal, 1/3 partially fertile coking coal optimizes fine distribution
With when solid-softening temperature section reaches 90 DEG C and the above, its maximum fluidity basically reaches or more than 10000ddpm, this explanation
The gel activity of 1/3 coking coal is big, and rich content, to be in close proximity to rich coal, and its price is significantly lower than rich coal, wherein often
The price difference of ton reduces the production cost of coal blending, therefore can be used by Optimized Coal Blending to a certain extent more than 26 yuan
Such 1/3 coking coal part substituting fat, so as to reach stable coke quality, reduce the purpose of coal blending cost.
Embodiment
In order to preferably explain the present invention, below in conjunction with the specific embodiment main contents that the present invention is furture elucidated, but
Present disclosure is not limited solely to following examples.
The invention discloses the coke making and coal blending method that a kind of solid-softening temperature section is more than 90 DEG C 1/3 coking coal, the coking is matched somebody with somebody
Gu coal method is finely divided by using Giseeler fluidity index-- softening temperature section of coal to 1/3 coking coal, solid-soft temperature is chosen
1/3 coking coal of degree section >=90 DEG C is designated as the coking coal of A classes 1/3, Gu -90 DEG C of softening temperature section < 1/3 coking coal is designated as Jiao of B classes 1/3
Coal;Wherein, the coking coal of A classes 1/3, the performance parameter of the high-quality rich coal of the coking coal of B classes 1/3 and Shanxi are as shown in table 1;
The performance parameter list of the part coal of table 1
The fugitive constituent V of the above-mentioned high-quality rich coal in ShanxidafFor 31%.
In addition, partly substituting high-quality rich coal from the coking coal of A classes 1/3, table 2 has been obtained.
The mass percentage content (%) of 2 various coking coals of table
Scheme | Bottle coal | Rich coal | The coking coal of A classes 1/3 | The coking coal of B classes 1/3 | Coking coal | Lean coal |
Contrast | 5 | 20 | 0 | 25 | 40 | 10 |
1 | 5 | 18 | 2 | 25 | 40 | 10 |
2 | 5 | 15 | 5 | 25 | 40 | 10 |
3 | 5 | 13 | 7 | 25 | 40 | 10 |
4 | 5 | 10 | 10 | 25 | 40 | 10 |
5 | 5 | 8 | 12 | 25 | 40 | 10 |
6 | 5 | 5 | 15 | 25 | 40 | 10 |
7 | 5 | 3 | 17 | 25 | 40 | 10 |
8 | 5 | 0 | 20 | 25 | 40 | 10 |
9 | 5 | 15 | 10 | 20 | 40 | 10 |
10 | 5 | 15 | 8 | 22 | 40 | 10 |
11 | 5 | 15 | 2 | 28 | 40 | 10 |
The coking coal configured to above-mentioned contrast scheme and 1~embodiment of embodiment 11 carries out heat property test point respectively
Analysis, has obtained table 3;
The heat property test analysis list of 3 various coking coals of table
As shown in Table 3, using the coking coal part substituting fat of A classes 1/3, when the mass percentage content of the coking coal of A classes 1/3 is 2
When between~17%, the post reaction strength CSR of coke is 69.95~62.89%, when the complete substituting fat of the coking coal of A classes 1/3,
The post reaction strength CSR of coke is 62.00%, and 70.50% compared with rich coal is small, therefore, is substituted when using the coking coal part of A classes 1/3
During rich coal, there is no too much influence for the combination property of mixed coal.
Meanwhile in rich coal used in our factory in 2017, high-quality middle volatile matter, high fluidity rich coal cost price are
1236 yuan/ton (prices in June), 1/3 high-quality coking coal cost price are 1211 yuan/ton (prices in June), and price differential reaches 26 yuan/ton, on
Half a year high-quality middle volatile matter, high fluidity rich coal dosage reach 84000 tons, the 2.1% of total dosage are accounted for, if according to this patent side
Method can be implemented, and substitute high-quality rich coal with 1/3 high-quality coking coal part, replacement amount is 1% or so, according to coking coal yearly consumption
8000000 tons of calculating, it is contemplated that 2,080,000 yuan of coal blending cost can be saved.
Above example is only optimal citing, and is not the restriction to embodiments of the present invention.Except above-described embodiment
Outside, the present invention also has other embodiment.All technical schemes formed using equivalent substitution or equivalent transformation, all fall within the present invention
It is required that protection domain.
Claims (6)
1. a kind of solid-softening temperature section is the coke making and coal blending method of more than 90 DEG C 1/3 coking coal, it is characterised in that:Including following step
Suddenly:
1) Giseeler fluidity measure is carried out to 1/3 coking coal:1/3 coking coal for choosing solid-softening temperature section >=90 DEG C is designated as A classes 1/3
Coking coal, Gu -90 DEG C of softening temperature section < 1/3 coking coal is designated as the coking coal of B classes 1/3;
2) coking coal of A classes 1/3 is subjected to coal blending by following mass percent:
Bottle coal:5%, rich coal:The coking coal of 0~30%, A class 1/3:The coking coal of 0~30%, B class 1/3:20~30%, coking coal:40%, it is thin
Coal:10%.
2. solid-soft silicon carbide according to claim 1 is the coke making and coal blending method of more than 90 DEG C 1/3 coking coal, its feature
It is:The coking coal of A classes 1/3 is subjected to coal blending by following mass percent:
Bottle coal:5%, rich coal:The coking coal of 0~20%, A class 1/3:The coking coal of 0~20%, B class 1/3:25%, coking coal:40%, lean coal:
10%, the mass percent of the coking coal of A classes 1/3 does not include zero.
3. solid-soft silicon carbide according to claim 2 is the coke making and coal blending method of more than 90 DEG C 1/3 coking coal, its feature
It is:The coking coal of A classes 1/3 is subjected to coal blending by following mass percent:
Bottle coal:5%, rich coal:The coking coal of 15%, A class 1/3:The coking coal of 5%, B class 1/3:25%, coking coal:40%, lean coal:10%.
4. solid-soft silicon carbide according to claim 1 or 2 is the coke making and coal blending method of more than 90 DEG C 1/3 coking coal, it is special
Sign is:The adhesive index value of the coking coal of A classes 1/3:90, maximum thick ness of plastic layer Y value:19, maximum fluidity:
12543ddpm, Gu-softening temperature section:99℃.
5. solid-soft silicon carbide according to claim 1 or 2 is the coke making and coal blending method of more than 90 DEG C 1/3 coking coal, it is special
Sign is:The adhesive index value of the coking coal of B classes 1/3:88, maximum thick ness of plastic layer Y value:17, maximum fluidity:
1578ddpm, Gu-softening temperature section:83℃.
6. solid-soft silicon carbide according to claim 1 or 2 is the coke making and coal blending method of more than 90 DEG C 1/3 coking coal, it is special
Sign is:The adhesive index value of the rich coal:95, maximum thick ness of plastic layer Y value:27, fugitive constituent Vdaf:31%, maximum fluidity
Degree:50000ddpm, Gu-softening temperature section:105℃.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108641739A (en) * | 2018-04-28 | 2018-10-12 | 重庆大学 | A method of improving coke quality coal blending |
Citations (1)
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CN104804755A (en) * | 2015-05-14 | 2015-07-29 | 武汉钢铁(集团)公司 | Coal blending method for coking 1/3 coking coal having solid softening temperature interval below 85 DEG C |
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CN104804755A (en) * | 2015-05-14 | 2015-07-29 | 武汉钢铁(集团)公司 | Coal blending method for coking 1/3 coking coal having solid softening temperature interval below 85 DEG C |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108641739A (en) * | 2018-04-28 | 2018-10-12 | 重庆大学 | A method of improving coke quality coal blending |
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