CN107686591A - A kind of antibacterial fresh-keeping packaging bag and preparation method thereof - Google Patents

A kind of antibacterial fresh-keeping packaging bag and preparation method thereof Download PDF

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Publication number
CN107686591A
CN107686591A CN201710949990.7A CN201710949990A CN107686591A CN 107686591 A CN107686591 A CN 107686591A CN 201710949990 A CN201710949990 A CN 201710949990A CN 107686591 A CN107686591 A CN 107686591A
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CN
China
Prior art keywords
parts
packaging bag
keeping packaging
resin
fresh
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710949990.7A
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Chinese (zh)
Inventor
张泽成
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Province Taihu Ze Hong Plastic Co Ltd
Original Assignee
Anhui Province Taihu Ze Hong Plastic Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Province Taihu Ze Hong Plastic Co Ltd filed Critical Anhui Province Taihu Ze Hong Plastic Co Ltd
Priority to CN201710949990.7A priority Critical patent/CN107686591A/en
Publication of CN107686591A publication Critical patent/CN107686591A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/16Applications used for films
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/066LDPE (radical process)

Abstract

The invention discloses a kind of antibacterial fresh-keeping packaging bag, in parts by weight, it is made up of 90 100 parts of ldpe resin, 7 15 parts of type low density polyethylene resin, 14 parts of nano titanium oxide, 25 parts of citric acid, 26 parts of zeins, 8 15 parts of methyl methacrylate, 0.1 0.5 parts of antioxidant, 37 parts of polyethylene glycol, 4 10 parts of glass fibre, 14 parts of rosin resin.Invention additionally discloses the preparation method of above-mentioned antibacterial fresh-keeping packaging bag.Because present invention uses ldpe resin, good with other materials compatibilities, the antibacterial fresh-keeping packaging bag of gained has intensity height, while has the performance of insect prevention and antibacterial, without worrying the infringement of bacterium and insect to material inside antibacterial fresh-keeping packaging bag, closer to the life of people.

Description

A kind of antibacterial fresh-keeping packaging bag and preparation method thereof
Technical field
The present invention relates to plastic packaging bag manufacture field, and in particular to a kind of antibacterial fresh-keeping packaging bag and preparation method thereof.
Background technology
Fresh-keeping packaging bag is the plastic packing product for a kind of fresh-keeping foodstuff that people commonly use, now with many families all from not Open them.Food in microwave oven heating can use, and food is deposited in refrigerator can equally use, and people are mainly using freshness protection package Prevent the erosion of dust and bacterium to food.The most fresh-keeping packaging bags and conventional polybag sold in the market Equally, all it is using ethene masterbatch as raw material, according to the variety classes of ethene masterbatch, fresh-keeping packaging bag can be divided into three major types:The One kind is polyethylene, abbreviation PE, and this material is mainly used in the packaging of food, the water fruits and vegetables bought usually this Fresh-keeping packaging bag, be included in supermarket buying return semi-finished product all be this material;Second is polyvinyl chloride, referred to as PVC, this material can be used for packaging for foodstuff, but its security to human body has a certain impact;The third is poly- inclined two Vinyl chloride, abbreviation PVDC, it is mainly used in the packagings of the products such as some prepared food, ham.In these three freshness protection packages, PE and PVDC this two The fresh-keeping packaging bag of kind of material be to human body it is safe, can be with safe to use, and PVC fresh-keeping packaging bags contain carcinogen, it is right Human body harm is larger.From physical angle, fresh-keeping packaging bag has appropriate oxygen permeability and moisture permeability, adjusts by fresh-keeping product week The oxygen recipe ingredient and moisture recipe ingredient enclosed, the dust in air is obstructed, so as to extend the freshness date of food.Prior art Some defects be present in middle antibacterial fresh-keeping packaging bag:1st, some antibacterial fresh-keeping packaging bag insufficient strengths, easily cause tearing for packaging bag Split, just do not have the effect of packaging;2nd, the antibacterial fresh-keeping packaging bag also having can not meet the requirement of antibacterial.
The content of the invention
It is an object of the invention to provide a kind of high, the of good preservation effect antibacterial fresh-keeping packaging bag of intensity and its preparation side Method.
Above-mentioned purpose is achieved through the following technical solutions:
A kind of antibacterial fresh-keeping packaging bag of the present invention, in parts by weight, is made up of following raw materials according:Ldpe resin 90-100 parts, type low density polyethylene resin 7-15 parts, nano titanium oxide 1-4 parts, citric acid 2-5 parts, the molten egg of corn alcohol White 2-6 parts, methyl methacrylate 8-15 parts, antioxidant 0.1-0.5 parts, polyethylene glycol 3-7 parts, glass fibre 4-10 parts, pine Botany bar gum 1-4 parts.
The preparation method of above-mentioned antibacterial fresh-keeping packaging bag, its preparation method are:Low density polyethylene (LDPE) is taken using said ratio It is resin, type low density polyethylene resin, nano titanium oxide, citric acid, zeins, methyl methacrylate, anti- Oxygen agent, polyethylene glycol, glass fibre, rosin resin, melted, be kneaded by extrusion or extrusion blow moulding technique, being extruded, be cold But, dry, after pelletizing, blown film, bag produce antibacterial fresh-keeping packaging bag.
Take after above-mentioned technical proposal due to present invention uses ldpe resin, with other materials compatibilities Good, the antibacterial fresh-keeping packaging bag of gained has intensity height, while has the performance of insect prevention and antibacterial, without worrying bacterium and insect Infringement to material inside antibacterial fresh-keeping packaging bag, closer to the life of people.
The embodiment of form by the following examples, the above of the present invention is remake further specifically It is bright, but the scope that should not be construed as the above-mentioned theme of the present invention is only limitted to following embodiment, it is all to be based on the above institute of the present invention The technology of realization belongs to the scope of the present invention.
Embodiment
A kind of antibacterial fresh-keeping packaging bag of the present invention and preparation method thereof is made to say into a line with reference to specific embodiment It is bright:
Embodiment 1:
A kind of antibacterial fresh-keeping packaging bag of the present invention, in parts by weight, is made up of following raw materials according:Ldpe resin 90 parts, 7 parts of type low density polyethylene resin, 1 part of nano titanium oxide, 2 parts of citric acid, 2 parts of zeins, methyl-prop 8 parts of e pioic acid methyl ester, 0.1 part of antioxidant, 3 parts of polyethylene glycol, 4 parts of glass fibre, 1 part of rosin resin.
The preparation method of above-mentioned antibacterial fresh-keeping packaging bag, comprises the following steps:
Using said ratio take ldpe resin, type low density polyethylene resin, nano titanium oxide, citric acid, Zeins, methyl methacrylate, antioxidant, polyethylene glycol, glass fibre, rosin resin, by extruding or extruding Blow molding process is melted, is kneaded, being extruded, being cooled down, being dried, after pelletizing, and blown film, bag produce antibacterial fresh-keeping packaging bag.
Embodiment 2:
A kind of antibacterial fresh-keeping packaging bag of the present invention, in parts by weight, is made up of following raw materials according:Ldpe resin 95 parts, 10 parts of type low density polyethylene resin, 3 parts of nano titanium oxide, 3 parts of citric acid, 3 parts of zeins, methyl 10 parts of methyl acrylate, 0.3 part of antioxidant, 4 parts of polyethylene glycol, 6 parts of glass fibre, 2 parts of rosin resin.
The preparation method of above-mentioned antibacterial fresh-keeping packaging bag, comprises the following steps:
Using said ratio take ldpe resin, type low density polyethylene resin, nano titanium oxide, citric acid, Zeins, methyl methacrylate, antioxidant, polyethylene glycol, glass fibre, rosin resin, by extruding or extruding Blow molding process is melted, is kneaded, being extruded, being cooled down, being dried, after pelletizing, and blown film, bag produce antibacterial fresh-keeping packaging bag.
Embodiment 3:
A kind of antibacterial fresh-keeping packaging bag of the present invention, in parts by weight, is made up of following raw materials according:Ldpe resin 100 parts, 15 parts of type low density polyethylene resin, 4 parts of nano titanium oxide, 5 parts of citric acid, 6 parts of zeins, methyl 15 parts of methyl acrylate, 0.5 part of antioxidant, 7 parts of polyethylene glycol, 10 parts of glass fibre, 4 parts of rosin resin.
The preparation method of above-mentioned antibacterial fresh-keeping packaging bag, comprises the following steps:
Using said ratio take ldpe resin, type low density polyethylene resin, nano titanium oxide, citric acid, Zeins, methyl methacrylate, antioxidant, polyethylene glycol, glass fibre, rosin resin, by extruding or extruding Blow molding process is melted, is kneaded, being extruded, being cooled down, being dried, after pelletizing, and blown film, bag produce antibacterial fresh-keeping packaging bag.
In the various embodiments described above, because present invention uses ldpe resin, institute good with other materials compatibilities The antibacterial fresh-keeping packaging bag obtained has intensity height, while has the performance of insect prevention and antibacterial, without worrying that bacterium and insect are resisted The infringement of material inside bacterium fresh-keeping packaging bag, closer to the life of people.

Claims (2)

1. a kind of antibacterial fresh-keeping packaging bag, in parts by weight, it is made up of following raw materials according:
Ldpe resin 90-100 parts,
Type low density polyethylene resin 7-15 parts,
Nano titanium oxide 1-4 parts,
Citric acid 2-5 parts,
Zeins 2-6 parts,
Methyl methacrylate 8-15 parts,
Antioxidant 0.1-0.5 parts,
Polyethylene glycol 3-7 parts,
Glass fibre 4-10 parts,
Rosin resin 1-4 parts.
2. a kind of preparation method of antibacterial fresh-keeping packaging bag according to claim 1, its preparation method are:Matched somebody with somebody using above-mentioned Than taking ldpe resin, type low density polyethylene resin, nano titanium oxide, citric acid, zeins, first Base methyl acrylate, antioxidant, polyethylene glycol, glass fibre, rosin resin, melted by extrusion or extrusion blow moulding technique Melt, be kneaded, extruding, cooling down, drying, after pelletizing, blown film, bag produce antibacterial fresh-keeping packaging bag.
CN201710949990.7A 2017-10-13 2017-10-13 A kind of antibacterial fresh-keeping packaging bag and preparation method thereof Pending CN107686591A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710949990.7A CN107686591A (en) 2017-10-13 2017-10-13 A kind of antibacterial fresh-keeping packaging bag and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710949990.7A CN107686591A (en) 2017-10-13 2017-10-13 A kind of antibacterial fresh-keeping packaging bag and preparation method thereof

Publications (1)

Publication Number Publication Date
CN107686591A true CN107686591A (en) 2018-02-13

Family

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Family Applications (1)

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Country Status (1)

Country Link
CN (1) CN107686591A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108892851A (en) * 2018-08-17 2018-11-27 苏州煜水生物科技有限公司 A kind of low density polyethylene (LDPE) antibiotic plastic and preparation method
CN109370011A (en) * 2018-10-23 2019-02-22 安徽洋龙塑业有限公司 A kind of food antimicrobial plastic bag material and preparation method thereof
CN112280153A (en) * 2020-11-16 2021-01-29 丽的包装(广东)有限公司 Traditional Chinese medicine granule packaging bag and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103819782A (en) * 2012-11-16 2014-05-28 无锡市黄盛包装制品有限公司 Preparation method for fruit and vegetable moisture-permeable antifogging packaging film
CN103819792A (en) * 2012-11-16 2014-05-28 无锡市黄盛包装制品有限公司 Fruit and vegetable antibacterial fresh-keeping packaging material
CN103819781A (en) * 2012-11-16 2014-05-28 无锡市黄盛包装制品有限公司 Preparation method for fruit and vegetable antibacterial fresh-keeping packaging material

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103819782A (en) * 2012-11-16 2014-05-28 无锡市黄盛包装制品有限公司 Preparation method for fruit and vegetable moisture-permeable antifogging packaging film
CN103819792A (en) * 2012-11-16 2014-05-28 无锡市黄盛包装制品有限公司 Fruit and vegetable antibacterial fresh-keeping packaging material
CN103819781A (en) * 2012-11-16 2014-05-28 无锡市黄盛包装制品有限公司 Preparation method for fruit and vegetable antibacterial fresh-keeping packaging material

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108892851A (en) * 2018-08-17 2018-11-27 苏州煜水生物科技有限公司 A kind of low density polyethylene (LDPE) antibiotic plastic and preparation method
CN109370011A (en) * 2018-10-23 2019-02-22 安徽洋龙塑业有限公司 A kind of food antimicrobial plastic bag material and preparation method thereof
CN112280153A (en) * 2020-11-16 2021-01-29 丽的包装(广东)有限公司 Traditional Chinese medicine granule packaging bag and preparation method thereof

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Application publication date: 20180213