CN107674709A - Broken coal gasification uses device and handling process of the partial CO 2 as gasifying agent - Google Patents

Broken coal gasification uses device and handling process of the partial CO 2 as gasifying agent Download PDF

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Publication number
CN107674709A
CN107674709A CN201711044355.0A CN201711044355A CN107674709A CN 107674709 A CN107674709 A CN 107674709A CN 201711044355 A CN201711044355 A CN 201711044355A CN 107674709 A CN107674709 A CN 107674709A
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CN
China
Prior art keywords
pressure
gasifying agent
regulating valve
carbon dioxide
mixing arrangement
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711044355.0A
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Chinese (zh)
Inventor
李斌
毛中浩
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Bo Huayongli Chemical Inc Tianjin
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Bo Huayongli Chemical Inc Tianjin
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Application filed by Bo Huayongli Chemical Inc Tianjin filed Critical Bo Huayongli Chemical Inc Tianjin
Priority to CN201711044355.0A priority Critical patent/CN107674709A/en
Publication of CN107674709A publication Critical patent/CN107674709A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02Fixed-bed gasification of lump fuel
    • C10J3/20Apparatus; Plants
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02Fixed-bed gasification of lump fuel
    • C10J3/20Apparatus; Plants
    • C10J3/30Fuel charging devices
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72Other features
    • C10J3/723Controlling or regulating the gasification process
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72Other features
    • C10J3/78High-pressure apparatus
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2200/00Details of gasification apparatus
    • C10J2200/15Details of feeding means
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913Carbonaceous raw material
    • C10J2300/093Coal
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/18Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1807Recycle loops, e.g. gas, solids, heating medium, water

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Industrial Gases (AREA)

Abstract

The invention discloses a kind of gasification of broken coal to use device of the partial CO 2 as gasifying agent, gasification furnace grate distributor chamber connects gasifying agent mixing arrangement, gasifying agent mixing arrangement connects steam pipe line, oxygen pipeline, carbon dioxide pipeline, pressure-regulating valve one is set along gas conveying direction on carbon dioxide pipeline, switch valve one, surge tank, pressure-regulating valve two, pressure controller one and switch valve two, pressure controller two with the interlocked control of pressure-regulating valve one is set at the top of surge tank, pressure-regulating valve two is parallel with pressure-regulating valve three, pressure-regulating valve two and pressure-regulating valve three with the Staged cotrol of pressure controller one.The carbon dioxide gas that the present invention can be vented to downstream unit recycles, part vapor is substituted by carbon dioxide and not only adjusts gas composition, also reduce vapor consumption, reduce the device capability of coal gas unit for treating water and phenol ammonia recovery unit in lower procedure, organic wastewater discharge is reduced, suitable for fixed bed pressured gasification stove etc..

Description

Broken coal gasification uses device and handling process of the partial CO 2 as gasifying agent
Technical field
The present invention relates to crushed coal pressure gasifying field, is to be related to a kind of broken coal gasification to use part dioxy in particular Change device and handling process of the carbon as gasifying agent.
Background technology
Gasifying agent is generally oxygen+vapor in crushed coal pressure gasifying technology, and steam oxygen ratio is typically in 5~8Kg/NM3.Due to Low (the gasification temperature of fixed bed gasification reaction temperature<1100 DEG C), the resolution ratio of vapor is relatively low in gasifying agent, typically in 30%- 40%, most of undecomposed steam is cooled into the waste water containing organic matter in downstream with raw gas.Coal gas waste has COD High, the characteristics of oil content is high, colourity is high and intractability is big, corresponding water-oil separating and phenol ammonia recovery unit not only invest it is high, Floor space is big, and fluctuation of service.
Because carbon dioxide and thermodynamics, the dynamics of carbon reaction, vapor and carbon reaction are essentially identical, two anti- Should all be strong endothermic reaction, in high temperature, the equilibrium constant of two reactions is close, and some vapor is substituted as gas using carbon dioxide Agent has feasibility in technique, and has operability.
The content of the invention
The invention aims to overcome deficiency of the prior art, there is provided a kind of broken coal gasification uses part titanium dioxide Device and handling process of the carbon as gasifying agent, while meeting that the gasification of fixed bed broken coal requires, downstream unit can be put Empty carbon dioxide gas is recycled, and reaches resource minimizing and the recycling purpose of carbon dioxide, while passes through dioxy Gas composition can not only be adjusted by changing carbon replacement part vapor, and reduce vapor consumption, reduce coal gas in lower procedure The device capability of unit for treating water and phenol ammonia recovery unit, reduce organic wastewater discharge.
The purpose of the present invention can be achieved through the following technical solutions.
The broken coal gasification of the present invention uses device of the partial CO 2 as gasifying agent, including gasification furnace, the gasification Furnace roof portion is provided with coal lock, and bottom is provided with grey lock, and the gasification furnace grate distributor chamber is connected with gasifying agent mixing arrangement, described The steam inlet of gasifying agent mixing arrangement is connected with steam pipe line, and the oxygen intake of the gasifying agent mixing arrangement is connected with oxygen Pipeline, the carbon dioxide entrance of the gasifying agent mixing arrangement are connected with carbon dioxide pipeline, edge on the carbon dioxide pipeline Gas conveying direction is disposed with pressure-regulating valve one, switch valve one, surge tank, pressure-regulating valve two, pressure controller one With switch valve two, the surge tank top is provided with the pressure controller two with the interlocked control of pressure-regulating valve one, the pressure Pressure-regulating valve three, the pressure-regulating valve two and pressure-regulating valve three are parallel between the air inlet of regulating valve two and gas outlet With the Staged cotrol of pressure controller one.
The gasifying agent mixing arrangement is made up of mixing tube, nozzle and mixed cell.
The purpose of the present invention can be also achieved through the following technical solutions.
Being gasified based on above-mentioned broken coal for the present invention uses handling process of the partial CO 2 as gasifying agent, including with Lower step:
Step 1, gasification furnace normally drive to run, and steam pipe line and oxygen pipeline are defeated into gasifying agent mixing arrangement respectively Steam and oxygen are sent, gasifying agent is used as after mixing, gasification reaction is participated in into gasification furnace;
Step 2, in downstream unit after carbon-dioxide gas compressor normal operation, open pressure-regulating valve one and switch valve One, the carbon dioxide after compressor pressure-raising is introduced into surge tank;
Step 3, pass through Staged cotrol pressure-regulating valve two and the aperture of pressure regulation three so that carbon dioxide pipeline pressure Power is higher 0.7~0.8MPa than oxygen line pressure;
Step 4, switch valve two is opened, carbon dioxide is introduced into gasifying agent mixing arrangement, carbon dioxide, steam and oxygen Gas is used as gasifying agent after being mixed in gasifying agent mixing arrangement, and gasification reaction is participated in into gasification furnace;
Step 5, after carbon dioxide line pressure fluctuates increasing or compressor jumps car, closing switch valve two, by titanium dioxide Carbon is cut out, and keeps gasifier operation stable.
Compared with prior art, beneficial effect caused by technical scheme is:
(1) in the present invention, gasification furnace grate distributor chamber is connected with gasifying agent mixing arrangement, using mixing tube, nozzle and mixes Unit composition is closed, steam and carbon dioxide entrance use aperture mode, increase premixing effect, make steam, carbon dioxide in oxygen It is well mixed in gas scattered;
(2) present invention utilizes the dioxy of the de- system emptying of downstream unit acid on the basis of original gasification furnace flow is retained Change carbon and pass through the pressure of surge tank and Staged cotrol regulation of carbon dioxide pipeline, high-pressure carbon dioxide gas after compressor boosts After being mixed by gasifying agent blender with oxygen, steam, part vapor is substituted, mixed gasifying agent enters gasification furnace grate Distributor chamber, into gasification furnace in participate in gasification reaction;
(3) carbon dioxide gas that the present invention can be vented to downstream unit recycles, and reaches the money of carbon dioxide Source reduction and recycling purpose, while gas composition can not only be adjusted by carbon dioxide replacement part vapor, and Vapor consumption is reduced, reduces the device capability of coal gas unit for treating water and phenol ammonia recovery unit in lower procedure, is reduced organic Discharge of wastewater.
Brief description of the drawings
Fig. 1 is the structural representation of the present invention;
Reference:1 gasification furnace;2 coals are locked;3 ash locks;4 gasifying agent mixing arrangements;5 steam pipe lines;6 oxygen pipelines;7 two Carbonoxide pipeline;8 pressure-regulating valves one;9 pressure-regulating valves two;10 pressure-regulating valves three;11 switch valves one;12 switch valves two; 13 pressure controllers one;14 pressure controllers two;15 surge tanks.
Embodiment
The invention will be further described below in conjunction with the accompanying drawings.
As shown in figure 1, a kind of broken coal gasification of the present invention uses device of the partial CO 2 as gasifying agent, including gas Change stove 1, the top of gasification furnace 1 is provided with coal lock 2, and bottom is provided with ash lock 3, and the gasification furnace 1 is using broken coal pressurization adverse current Contact continuous gasification dry ash extraction technique.The grate distributor chamber of gasification furnace 1 is connected with gasifying agent mixing arrangement 4, the gasification Agent mixing arrangement 4 exports to be connected with the inside of gasification furnace 1.The gasifying agent mixing arrangement 4 is by mixing tube, nozzle and mixed cell group Into steam inlet and carbon dioxide entrance use aperture mode, increase premixing effect, make steam, carbon dioxide in oxygen In be well mixed scattered, mixed steam, carbon dioxide and oxygen are used as gasifying agent, into gasification furnace 1 in participation gasified reverse Should.
The steam inlet of the gasifying agent mixing arrangement 4 is connected with steam pipe line 5, and the steam pipe line 5 is settable two, One is used for the conveying into gasifying agent mixing arrangement 4 and vapours is pressed through in battery limit (BL), and another is used to mix to gasifying agent The middle pressure self-produced steam from gas bag is conveyed in device 4.The oxygen intake of the gasifying agent mixing arrangement 4 is connected with oxygen pipeline 6, for conveying the oxygen from battery limit (BL) into gasifying agent mixing arrangement 4.
The carbon dioxide entrance of the gasifying agent mixing arrangement 4 is connected with carbon dioxide pipeline 7, the carbon dioxide pipeline 7 are connected to the high-pressure carbon dioxide gas house steward of downstream unit, are set gradually on the carbon dioxide pipeline 7 along gas conveying direction There are pressure-regulating valve 1, switch valve 1, surge tank 15, pressure-regulating valve 29, pressure controller 1 and switch valve 2 12. The surge tank 15 is used to enter the high-pressure carbon dioxide after compressor pressure-raising row buffering, and the top of surge tank 15 is set There is pressure controller 2 14, the pressure controller 2 14 is used to monitor and control buffer tank pressure, with pressure-regulating valve 1 Lock control.Pressure-regulating valve 3 10, the pressure regulation are parallel between the air inlet of the pressure-regulating valve 29 and gas outlet Valve 29 and pressure-regulating valve 3 10 with the Staged cotrol of pressure controller 1.
Coal is periodically added in gasification furnaces 1 by coal lock 2, in press through vapours/middle pressure self-produced steam, oxygen and carbon dioxide Gas is used as gasifying agent after the mixing of gasifying agent mixing arrangement 4, enters gasification furnace by the qi-emitting hole for being distributed in revolving grate surface 1, gasifying agent with from coal lock 2 coal counter current contacting, generate raw gas.Coal and caused ash after gasifying agent reaction, by fire grate Rotation be continually drained ash lock 3, by ash lock 3 pressure releases after periodically purge out.
Broken coal gasification based on said apparatus uses handling process of the partial CO 2 as gasifying agent, can be to downstream The carbon dioxide gas of device emptying is recycled, and is reached resource minimizing and the recycling purpose of carbon dioxide, is led to simultaneously Gas composition can not only be adjusted by crossing carbon dioxide replacement part vapor, and reduce vapor consumption, reduce lower procedure The device capability of middle coal gas unit for treating water and phenol ammonia recovery unit, reduce organic wastewater discharge.Specifically include following steps:
Step 1, gasification furnace 1 normally drive to run, and steam pipe line 5 and oxygen pipeline 6 are respectively to gasifying agent mixing arrangement 4 Middle conveying steam and oxygen, gasifying agent is used as after well mixed, gasifying agent, which enters, participates in gasification reaction in gasification furnace 1;
Step 2, in downstream unit after carbon-dioxide gas compressor normal operation, switch valve 1 is opened, according to surge tank The aperture of 15 internal pressure interlocked control pressure-regulating valve 1, the high-pressure carbon dioxide after compressor pressure-raising is drawn through entrance Into surge tank 15;
Step 3, the buffered outlet of tank 15 of high-pressure carbon dioxide continues to convey to the direction of gasifying agent mixing arrangement 4, by dividing Process control adjusts the aperture of pressure-regulating valve 29 and pressure-regulating valve 3 10 so that the pressure ratio oxygen pipeline of carbon dioxide pipeline 7 High 0.7~the 0.8MPa of 6 pressure;
Step 4, open switch valve 2 12, high-pressure carbon dioxide is introduced into gasifying agent mixing arrangement 4, make carbon dioxide, Steam and oxygen are well mixed in gasifying agent mixing arrangement 4 is used as gasifying agent, and gasifying agent, which enters, participates in gasified reverse in gasification furnace 1 Should;
Step 5, after the pressure oscillation increasing of carbon dioxide pipeline 7 or compressor jump car, closing switch valve 2 12 immediately, High-pressure carbon dioxide is cut out, keeps gasification furnace 1 stable.
Although the function and the course of work of the present invention are described above in conjunction with accompanying drawing, the invention is not limited in Above-mentioned concrete function and the course of work, above-mentioned embodiment is only schematical, rather than restricted, ability The those of ordinary skill in domain is not departing from present inventive concept and scope of the claimed protection situation under the enlightenment of the present invention Under, many forms can also be made, these are belonged within the protection of the present invention.

Claims (3)

1. a kind of broken coal gasification uses device of the partial CO 2 as gasifying agent, including gasification furnace (1), the gasification furnace (1) top is provided with coal lock (2), and bottom is provided with ash lock (3), it is characterised in that gasification furnace (1) the grate distributor chamber connection There is gasifying agent mixing arrangement (4), the steam inlet of the gasifying agent mixing arrangement (4) is connected with steam pipe line (5), the gasification The oxygen intake of agent mixing arrangement (4) is connected with oxygen pipeline (6), the carbon dioxide entrance of the gasifying agent mixing arrangement (4) It is connected with carbon dioxide pipeline (7), pressure-regulating valve is disposed with along gas conveying direction on the carbon dioxide pipeline (7) One (8), switch valve one (11), surge tank (15), pressure-regulating valve two (9), pressure controller one (13) and switch valve two (12), The pressure controller two (14) with pressure-regulating valve one (8) interlocked control, the pressure are provided with the top of the surge tank (15) Pressure-regulating valve three (10), the pressure-regulating valve two (9) and pressure are parallel between the air inlet of regulating valve two (9) and gas outlet Force regulating valve three (10) with pressure controller one (13) Staged cotrol.
2. broken coal gasification according to claim 1 uses device of the partial CO 2 as gasifying agent, it is characterised in that The gasifying agent mixing arrangement (4) is made up of mixing tube, nozzle and mixed cell.
3. a kind of broken coal gasification based on the claims 1 and 2 uses handling process of the partial CO 2 as gasifying agent, It is characterised in that it includes following steps:
Step 1, gasification furnace (1) normally drive to run, and steam pipe line (5) and oxygen pipeline (6) are respectively to gasifying agent mixing arrangement (4) conveying steam and oxygen, are used as gasifying agent in after mixing, and gasification reaction is participated in into gasification furnace (1);
Step 2, in downstream unit after carbon-dioxide gas compressor normal operation, open pressure-regulating valve one (8) and switch valve one (11), the carbon dioxide after compressor pressure-raising is introduced into surge tank (15);
Step 3, the aperture of three (10) is adjusted by Staged cotrol pressure-regulating valve two (9) and pressure so that carbon dioxide pipeline (7) pressure ratio oxygen pipeline (6) high 0.7~0.8MPa of pressure;
Step 4, open switch valve two (12), carbon dioxide is introduced into gasifying agent mixing arrangement (4), carbon dioxide, steam and Oxygen is used as gasifying agent after being mixed in gasifying agent mixing arrangement (4), and gasification reaction is participated in into gasification furnace (1);
Step 5, after car is jumped in carbon dioxide pipeline (7) pressure oscillation increasing or compressor, closing switch valve two (12), by two Carbonoxide is cut out, and keeps gasification furnace (1) stable.
CN201711044355.0A 2017-10-31 2017-10-31 Broken coal gasification uses device and handling process of the partial CO 2 as gasifying agent Pending CN107674709A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110055109A (en) * 2018-04-08 2019-07-26 新能能源有限公司 Fluidized-bed gasification furnace gasifying agent conveyance control method and system

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102071062A (en) * 2010-07-02 2011-05-25 陕西神木化学工业有限公司 Method for Texaco gasification process oven
CN202369558U (en) * 2011-12-22 2012-08-08 衡水鑫德化工防腐设备科技有限公司 Oxygen-enriched blowing continuous gasification double-cylinder gas generating furnace
US20140305784A1 (en) * 2011-12-29 2014-10-16 Wuhan Kaidi General Research Institute Of Engineering & Technology Co., Ltd. Gasifier and method of using the same for gasification of biomass and solid waste
CN106635168A (en) * 2016-11-28 2017-05-10 伊犁出入境检验检疫局综合技术服务中心 Method and system for preparing gas by fixed bed gasifier
CN207452036U (en) * 2017-10-31 2018-06-05 天津渤化永利化工股份有限公司 Broken coal gasification is using device of the partial CO 2 as gasifying agent

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102071062A (en) * 2010-07-02 2011-05-25 陕西神木化学工业有限公司 Method for Texaco gasification process oven
CN202369558U (en) * 2011-12-22 2012-08-08 衡水鑫德化工防腐设备科技有限公司 Oxygen-enriched blowing continuous gasification double-cylinder gas generating furnace
US20140305784A1 (en) * 2011-12-29 2014-10-16 Wuhan Kaidi General Research Institute Of Engineering & Technology Co., Ltd. Gasifier and method of using the same for gasification of biomass and solid waste
CN106635168A (en) * 2016-11-28 2017-05-10 伊犁出入境检验检疫局综合技术服务中心 Method and system for preparing gas by fixed bed gasifier
CN207452036U (en) * 2017-10-31 2018-06-05 天津渤化永利化工股份有限公司 Broken coal gasification is using device of the partial CO 2 as gasifying agent

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110055109A (en) * 2018-04-08 2019-07-26 新能能源有限公司 Fluidized-bed gasification furnace gasifying agent conveyance control method and system
CN110055109B (en) * 2018-04-08 2024-05-03 新能能源有限公司 Gasifying agent conveying control method and system for fluidized bed gasifier

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Application publication date: 20180209