CN107674604A - A kind of self-adhesive paper containing environmentally friendly air purifying type water-base cement - Google Patents

A kind of self-adhesive paper containing environmentally friendly air purifying type water-base cement Download PDF

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Publication number
CN107674604A
CN107674604A CN201710643835.2A CN201710643835A CN107674604A CN 107674604 A CN107674604 A CN 107674604A CN 201710643835 A CN201710643835 A CN 201710643835A CN 107674604 A CN107674604 A CN 107674604A
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parts
self
air purifying
environmentally friendly
type water
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陈飘
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Suzhou Floating Composite Mstar Technology Ltd
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Suzhou Floating Composite Mstar Technology Ltd
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Priority to CN201710643835.2A priority Critical patent/CN107674604A/en
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J189/00—Adhesives based on proteins; Adhesives based on derivatives thereof
    • C09J189/04—Products derived from waste materials, e.g. horn, hoof or hair
    • C09J189/06—Products derived from waste materials, e.g. horn, hoof or hair derived from leather or skin
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/04—Non-macromolecular additives inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/06—Non-macromolecular additives organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08—Macromolecular additives
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21B—FIBROUS RAW MATERIALS OR THEIR MECHANICAL TREATMENT
    • D21B1/00—Fibrous raw materials or their mechanical treatment
    • D21B1/04—Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres
    • D21B1/12—Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres by wet methods, by the use of steam
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H15/00—Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution
    • D21H15/02—Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution characterised by configuration
    • D21H15/10—Composite fibres
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24—Polysaccharides
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/36—Polyalkenyalcohols; Polyalkenylethers; Polyalkenylesters
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/675—Oxides, hydroxides or carbonates
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/16—Sizing or water-repelling agents
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/18—Reinforcing agents
    • D21H21/20—Wet strength agents
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/001—Release paper
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/12—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
    • C09J2301/122—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/306—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being water-activatable
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
    • C09J2301/408—Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the adhesive layer
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2497/00—Presence of lignin
    • C09J2497/005—Presence of lignin in the release coating

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

The invention belongs to self-adhesive paper technical field, more particularly to a kind of self-adhesive paper containing environmentally friendly air purifying type water-base cement.Self-adhesive paper of the present invention containing environmentally friendly air purifying type water-base cement, off-style paper layer is mixed to prepare ventilative release liners using Chinese herb residues and maize straw slag with wood pulp, raw material sources are wide, cost is low to be easy to get, turn waste into wealth, the simple science of preparation method is green, release liners are degradable, and environment will not be polluted；Non-drying glue layer uses environment-friendly water-based adhesive material, cost is low, cohesive force is strong, it is degradable, easy-clear, environmentally safe, modified starch can effectively strengthen non-drying glue layer cohesive force and water resistance, gelatin and sodium alginate compounding can play good synergy, further enhance the adhesion strength of non-drying glue layer.

Description

A kind of self-adhesive paper containing environmentally friendly air purifying type water-base cement
Technical field
The invention belongs to self-adhesive paper technical field, more particularly to a kind of self-adhesive paper containing environmentally friendly air purifying type water-base cement.
Background technology
Self-adhesive paper is the backsize adhesive sticker using paper, film or special material as facial tissue, to apply silicone oil base stock as guarantor A kind of composite of paper is protected, it is that self-adhesive paper prints trade mark, label to commonly use purposes.Self-adhesive paper is widely used in medicine, food The industries such as product, daily use chemicals, office, logistics, industry.
Existing self-adhesive paper is formed using incorporation mechanical pulp copy paper in secondary stock or paper pulp mostly, and existing is not done The adhesive that gummed paper uses, in order to obtain preferable sticking effect, it adds curing agent in being formulated, and curing agent is organic original Material, it is not soluble in water, it is difficult to remove, and it is difficult degraded, recovery, immense pressure is caused to environment.With people's living standard Raising and attention to environment-friendly materials, be highly desirable to be improved the self-adhesive paper of existing market.
The content of the invention
Goal of the invention：In order to overcome problem above, it is an object of the invention to provide a kind of containing environmentally friendly air purifying type water-base cement Self-adhesive paper.
Technical scheme：It is an object of the invention to provide a kind of self-adhesive paper containing environmentally friendly air purifying type water-base cement, including from Type ply of paper, the non-drying glue layer for being coated on off-style paper layer and the facial tissue layer for being covered in non-drying glue layer another side, described off-style paper layer For release liners of being breathed freely made of the degradable fibrous material of environmental protection, described non-drying glue layer is environment-friendly water-based adhesive sticker, described Facial tissue layer is PP synthetic papers or electrostatic PVC paper.
Preferably, the fibrous material breathed freely made of described fibrous material described in release liners includes following parts by weight Raw material：Chinese herb residues 20-40 parts, maize straw slag 10-30 parts, kp softwood pulp 50-60 parts, hardwood pulp 1-25 parts.
Preferably, described Chinese herb residues are the Chinese herb residues that ganoderma lucidum mass content is 12%-18%.
Preferably, the preparation method for release liners of being breathed freely made of described fibrous material, comprises the following steps：
1）It is used in combination being dried after NaCl solution that Chinese herb residues, maize straw slag are respectively 2-4% with mass concentration immersion 16-20h Pulverizer is ground into powder；Then the kp softwood pulp with formula ratio, hardwood pulp and the wood for accounting for gross weight 0.2%-0.4% The mixing of fiber softening enzyme carries out size degradation, then adds and accounts for gross weight 6%-8% nano-calcium carbonate and account for gross weight 0.5%-1.5%'s Wet strength agent stirring continues size degradation and obtains size degradation slurry；
2）By above-mentioned steps 1）In after obtained size degradation slurry mixes with poly-vinyl alcohol solution and carries out a mill, add applying glue Agent carries out second of mill and is configured to sizing material；
3）By above-mentioned steps 2）Middle sizing material carry out copy paper and being glued with sizing applicator produce breathed freely made of described fibrous material from Type paper.
Preferably, described step 1）Middle pulverizer is crushed to 100-200 mesh powder.
Preferably, the step 1）Middle nano-calcium carbonate is precipitated calcium carbonate, and granularity is 10-20nm.
Preferably, the step 1）Middle wet strength agent is chitosan.
Preferably, the step 2）The weight ratio of middle poly-vinyl alcohol solution and size degradation slurry is 5-20:1.
Preferably, described environment-friendly water-based adhesive sticker includes the raw material of following parts by weight：Gelatin 40-60 parts, sodium alginate 10-15 parts, modified starch 30-50 parts, polyvinylpyrrolidone 10-20 parts, precipitated calcium carbonate 10-20 parts, carboxy-propyl cellulose 1-5 parts, glycerine 10-20 parts, glycerine 10-20 parts, polyoxyethylene oxypropylene oleate 2-6 parts, ammoniacal liquor 0.5-0.8 parts, inclined aluminium Sour sodium 1-3 parts, nanometer grade silica 1-3 parts, chitosan 1-3 parts, water 90-110 parts.
Preferably, described modified starch is that lactic modified cornstarch rear oxidation is made, the matter of lactic acid and cornstarch Measuring ratio is（1-3）:1.
Above-mentioned technical proposal can be seen that the present invention and have the advantages that：It is of the present invention to contain environmentally friendly air purifying type The self-adhesive paper of water-base cement, off-style paper layer are mixed to prepare ventilative release liners using Chinese herb residues and maize straw slag with wood pulp, former Expect that source is wide, cost is low to be easy to get, and turns waste into wealth, and the simple science of preparation method, green, release liners are degradable, will not be to ring Border pollutes；Non-drying glue layer uses environment-friendly water-based adhesive material, and cost is low, and cohesive force is strong, degradable, and easy-clear is right Environmental nonpollution, modified starch can effectively strengthen non-drying glue layer cohesive force and water resistance, and gelatin and sodium alginate compounding can be with Good synergy is played, further enhances the adhesion strength of non-drying glue layer；Glycerine in adhesive sticker raw material can be from sky The moisture absorption in gas, hydrogen sulfide, sulfur dioxide, hydrogen cyanide are absorbed, purify air；Nanometer grade silica has very big ratio surface Product, the more meso-hole structures in surface, has superpower adsorption capacity.
Embodiment
Following examples are used to illustrate the present invention, but can not be used for limiting the scope of the present invention.
Embodiment 1
A kind of self-adhesive paper containing environmentally friendly air purifying type water-base cement described in the present embodiment, including off-style paper layer, it is coated on release liners The non-drying glue layer of layer and the facial tissue layer for being covered in non-drying glue layer another side, described off-style paper layer are the degradable undulation degree of environmental protection Ventilative release liners made of material, described non-drying glue layer is environment-friendly water-based adhesive sticker, and described facial tissue layer is PP synthetic papers or quiet Electric PVC paper.
The fibrous material breathed freely made of described fibrous material described in release liners includes the raw material of following parts by weight：In 20 parts of herbal medicine slag, 10 parts of maize straw slag, 50 parts of kp softwood pulp, 1 part of hardwood pulp.
Described Chinese herb residues are the Chinese herb residues that ganoderma lucidum mass content is 12%.
The preparation method for release liners of being breathed freely made of described fibrous material, comprises the following steps：
1）By Chinese herb residues, maize straw slag respectively with mass concentration be 2% NaCl solution soak 16h after dry and with crushing Machine is ground into powder；Then the kp softwood pulp with formula ratio, hardwood pulp and the wood-fibred softening for accounting for gross weight 0.2% Enzyme mixing carries out size degradation, and it is broken then to add wet strength agent stirring continuation of the nano-calcium carbonate for accounting for gross weight 6% with accounting for gross weight 0.5% Solution obtains size degradation slurry；
2）By above-mentioned steps 1）In after obtained size degradation slurry mixes with poly-vinyl alcohol solution and carries out a mill, add applying glue Agent carries out second of mill and is configured to sizing material；
3）By above-mentioned steps 2）Middle sizing material carry out copy paper and being glued with sizing applicator produce breathed freely made of described fibrous material from Type paper.
Described step 1）Middle pulverizer is crushed to 100 mesh powder.
The step 1）Middle nano-calcium carbonate is precipitated calcium carbonate, and granularity is 10nm.
The step 1）Middle wet strength agent is chitosan.
The step 2）The weight ratio of middle poly-vinyl alcohol solution and size degradation slurry is 5:1.
Described environment-friendly water-based adhesive sticker includes the raw material of following parts by weight：40 parts of gelatin, 10 parts of sodium alginate, modified shallow lake 30 parts of powder, 10 parts of polyvinylpyrrolidone, 10 parts of precipitated calcium carbonate, 1 part of carboxy-propyl cellulose, 10 parts of glycerine, 10 parts of glycerine, 2 parts of polyoxyethylene oxypropylene oleate, 0.5 part of ammoniacal liquor, 1 part of sodium metaaluminate, 1 part of nanometer grade silica, 1 part of chitosan, water 90 parts.
Described modified starch is that lactic modified cornstarch rear oxidation is made, and the mass ratio of lactic acid and cornstarch is 1: 1。
Embodiment 2
A kind of self-adhesive paper containing environmentally friendly air purifying type water-base cement described in the present embodiment, including off-style paper layer, it is coated on release liners The non-drying glue layer of layer and the facial tissue layer for being covered in non-drying glue layer another side, described off-style paper layer are the degradable undulation degree of environmental protection Ventilative release liners made of material, described non-drying glue layer is environment-friendly water-based adhesive sticker, and described facial tissue layer is PP synthetic papers or quiet Electric PVC paper.
The fibrous material breathed freely made of described fibrous material described in release liners includes the raw material of following parts by weight：In 40 parts of herbal medicine slag, 30 parts of maize straw slag, 60 parts of kp softwood pulp, 25 parts of hardwood pulp.
Described Chinese herb residues are the Chinese herb residues that ganoderma lucidum mass content is 18%.
The preparation method for release liners of being breathed freely made of described fibrous material, comprises the following steps：
1）By Chinese herb residues, maize straw slag respectively with mass concentration be 4% NaCl solution soak 20h after dry and with crushing Machine is ground into powder；Then the kp softwood pulp with formula ratio, hardwood pulp and the wood-fibred softening for accounting for gross weight 0.4% Enzyme mixing carries out size degradation, and it is broken then to add wet strength agent stirring continuation of the nano-calcium carbonate for accounting for gross weight 8% with accounting for gross weight 1.5% Solution obtains size degradation slurry；
2）By above-mentioned steps 1）In after obtained size degradation slurry mixes with poly-vinyl alcohol solution and carries out a mill, add applying glue Agent carries out second of mill and is configured to sizing material；
3）By above-mentioned steps 2）Middle sizing material carry out copy paper and being glued with sizing applicator produce breathed freely made of described fibrous material from Type paper.
Described step 1）Middle pulverizer is crushed to 200 mesh powder.
The step 1）Middle nano-calcium carbonate is precipitated calcium carbonate, and granularity is 20nm.
The step 1）Middle wet strength agent is chitosan.
The step 2）The weight ratio of middle poly-vinyl alcohol solution and size degradation slurry is 20:1.
Described environment-friendly water-based adhesive sticker includes the raw material of following parts by weight：60 parts of gelatin, 15 parts of sodium alginate, modified shallow lake 50 parts of powder, 20 parts of polyvinylpyrrolidone, 20 parts of precipitated calcium carbonate, 5 parts of carboxy-propyl cellulose, 20 parts of glycerine, 20 parts of glycerine, 6 parts of polyoxyethylene oxypropylene oleate, 0.8 part of ammoniacal liquor, 3 parts of sodium metaaluminate, 3 parts of nanometer grade silica, 3 parts of chitosan, water 110 parts.
Described modified starch is that lactic modified cornstarch rear oxidation is made, and the mass ratio of lactic acid and cornstarch is 3: 1。
Embodiment 3
A kind of self-adhesive paper containing environmentally friendly air purifying type water-base cement described in the present embodiment, including off-style paper layer, it is coated on release liners The non-drying glue layer of layer and the facial tissue layer for being covered in non-drying glue layer another side, described off-style paper layer are the degradable undulation degree of environmental protection Ventilative release liners made of material, described non-drying glue layer is environment-friendly water-based adhesive sticker, and described facial tissue layer is PP synthetic papers or quiet Electric PVC paper.
The fibrous material breathed freely made of described fibrous material described in release liners includes the raw material of following parts by weight：In 30 parts of herbal medicine slag, 20 parts of maize straw slag, 55 parts of kp softwood pulp, 13 parts of hardwood pulp.
Described Chinese herb residues are the Chinese herb residues that ganoderma lucidum mass content is 15%.
The preparation method for release liners of being breathed freely made of described fibrous material, comprises the following steps：
1）By Chinese herb residues, maize straw slag respectively with mass concentration be 3% NaCl solution soak 18h after dry and with crushing Machine is ground into powder；Then the kp softwood pulp with formula ratio, hardwood pulp and the wood-fibred softening for accounting for gross weight 0.3% Enzyme mixing carries out size degradation, then adds wet strength agent stirring of the nano-calcium carbonate for accounting for gross weight 7% with accounting for gross weight 1% and continues size degradation Obtain size degradation slurry；
2）By above-mentioned steps 1）In after obtained size degradation slurry mixes with poly-vinyl alcohol solution and carries out a mill, add applying glue Agent carries out second of mill and is configured to sizing material；
3）By above-mentioned steps 2）Middle sizing material carry out copy paper and being glued with sizing applicator produce breathed freely made of described fibrous material from Type paper.
Described step 1）Middle pulverizer is crushed to 150 mesh powder.
The step 1）Middle nano-calcium carbonate is precipitated calcium carbonate, and granularity is 15nm.
The step 1）Middle wet strength agent is chitosan.
The step 2）The weight ratio of middle poly-vinyl alcohol solution and size degradation slurry is 12:1.
Described environment-friendly water-based adhesive sticker includes the raw material of following parts by weight：50 parts of gelatin, 13 parts of sodium alginate, modified shallow lake 40 parts of powder, 15 parts of polyvinylpyrrolidone, 15 parts of precipitated calcium carbonate, 3 parts of carboxy-propyl cellulose, 15 parts of glycerine, 15 parts of glycerine, 4 parts of polyoxyethylene oxypropylene oleate, 0.6 part of ammoniacal liquor, sodium metaaluminate 2 part, nanometer connect 2 parts of silica, 2 parts of chitosan, water 100 parts.
Described modified starch is that lactic modified cornstarch rear oxidation is made, and the mass ratio of lactic acid and cornstarch is 2: 1。
Described above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For member, under the premise without departing from the principles of the invention, some improvement can also be made, these improvement also should be regarded as the present invention's Protection domain.

Claims (10)

  1. A kind of 1. self-adhesive paper containing environmentally friendly air purifying type water-base cement, it is characterised in that：Including off-style paper layer, it is coated on off-style paper layer Non-drying glue layer and be covered in the facial tissue layer of non-drying glue layer another side, described off-style paper layer is the degradable fibrous material of environmental protection Manufactured ventilative release liners, described non-drying glue layer are environment-friendly water-based adhesive sticker, and described facial tissue layer is PP synthetic papers or electrostatic PVC paper.
  2. A kind of 2. self-adhesive paper containing environmentally friendly air purifying type water-base cement according to claim 1, it is characterised in that：Described fibre The fibrous material breathed freely made of dimension material described in release liners includes the raw material of following parts by weight：Chinese herb residues 20-40 parts, jade Rice stalk slag 10-30 parts, kp softwood pulp 50-60 parts, hardwood pulp 1-25 parts.
  3. A kind of 3. self-adhesive paper containing environmentally friendly air purifying type water-base cement according to claim 2, it is characterised in that：In described Herbal medicine slag is the Chinese herb residues that ganoderma lucidum mass content is 12%-18%.
  4. A kind of 4. self-adhesive paper containing environmentally friendly air purifying type water-base cement according to claim 2, it is characterised in that：Described fibre The preparation method for release liners of being breathed freely made of material is tieed up, is comprised the following steps：
    1）It is used in combination being dried after NaCl solution that Chinese herb residues, maize straw slag are respectively 2-4% with mass concentration immersion 16-20h Pulverizer is ground into powder；Then the kp softwood pulp with formula ratio, hardwood pulp and the wood for accounting for gross weight 0.2%-0.4% The mixing of fiber softening enzyme carries out size degradation, then adds and accounts for gross weight 6%-8% nano-calcium carbonate and account for gross weight 0.5%-1.5%'s Wet strength agent stirring continues size degradation and obtains size degradation slurry；
    2）By above-mentioned steps 1）In after obtained size degradation slurry mixes with poly-vinyl alcohol solution and carries out a mill, add applying glue Agent carries out second of mill and is configured to sizing material；
    3）By above-mentioned steps 2）Middle sizing material carry out copy paper and being glued with sizing applicator produce breathed freely made of described fibrous material from Type paper.
  5. A kind of 5. self-adhesive paper containing environmentally friendly air purifying type water-base cement according to claim 4, it is characterised in that：Described step Rapid 1）Middle pulverizer is crushed to 100-200 mesh powder.
  6. A kind of 6. self-adhesive paper containing environmentally friendly air purifying type water-base cement according to claim 4, it is characterised in that：The step 1）Middle nano-calcium carbonate is precipitated calcium carbonate, and granularity is 10-20nm.
  7. A kind of 7. self-adhesive paper containing environmentally friendly air purifying type water-base cement according to claim 4, it is characterised in that：The step Rapid 1）Middle wet strength agent is chitosan.
  8. 8. the self-adhesive paper according to claim 4 containing environmentally friendly air purifying type water-base cement, it is characterised in that：The step 2）In The weight ratio of poly-vinyl alcohol solution and size degradation slurry is 5-20:1.
  9. 9. the self-adhesive paper according to claim 1 containing environmentally friendly air purifying type water-base cement, it is characterised in that：Described environment-protective water Property adhesive sticker includes the raw material of following parts by weight：Gelatin 40-60 parts, sodium alginate 10-15 parts, modified starch 30-50 parts, poly- second Alkene pyrrolidone 10-20 parts, precipitated calcium carbonate 10-20 parts, carboxy-propyl cellulose 1-5 parts, glycerine 10-20 parts, glycerine 10-20 Part, polyoxyethylene oxypropylene oleate 2-6 parts, ammoniacal liquor 0.5-0.8 parts, sodium metaaluminate 1-3 parts, nanometer grade silica 1-3 parts, Chitosan 1-3 parts, water 90-110 parts.
  10. 10. the self-adhesive paper according to claim 9 containing environmentally friendly air purifying type water-base cement, it is characterised in that：Described modification Starch is that lactic modified cornstarch rear oxidation is made, and the mass ratio of lactic acid and cornstarch is（1-3）:1.
CN201710643835.2A 2017-07-31 2017-07-31 A kind of self-adhesive paper containing environmentally friendly air purifying type water-base cement Pending CN107674604A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110835505A (en) * 2019-11-12 2020-02-25 苏州淼昇电子有限公司 Environment-friendly high-temperature-resistant special double-sided adhesive tape and preparation method thereof
CN113088213A (en) * 2021-04-08 2021-07-09 郭秋婷 Environment-friendly adhesive label and preparation method thereof
CN113881106A (en) * 2021-11-17 2022-01-04 广州市欣竹不干胶材料有限公司 Environment-friendly degradable self-adhesive paper and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN203118336U (en) * 2013-03-28 2013-08-07 山东亿铭新材料科技有限公司 Novel self-adhesive paper
CN106480774A (en) * 2016-11-11 2017-03-08 无限极（中国）有限公司 A kind of self-adhesive paper and preparation method thereof
CN106800912A (en) * 2016-12-23 2017-06-06 惠州市泽信实业有限公司 A kind of water-soluble adhesive sticker adhesive

Patent Citations (3)

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Publication number Priority date Publication date Assignee Title
CN203118336U (en) * 2013-03-28 2013-08-07 山东亿铭新材料科技有限公司 Novel self-adhesive paper
CN106480774A (en) * 2016-11-11 2017-03-08 无限极（中国）有限公司 A kind of self-adhesive paper and preparation method thereof
CN106800912A (en) * 2016-12-23 2017-06-06 惠州市泽信实业有限公司 A kind of water-soluble adhesive sticker adhesive

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110835505A (en) * 2019-11-12 2020-02-25 苏州淼昇电子有限公司 Environment-friendly high-temperature-resistant special double-sided adhesive tape and preparation method thereof
CN113088213A (en) * 2021-04-08 2021-07-09 郭秋婷 Environment-friendly adhesive label and preparation method thereof
CN113881106A (en) * 2021-11-17 2022-01-04 广州市欣竹不干胶材料有限公司 Environment-friendly degradable self-adhesive paper and preparation method thereof

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Application publication date: 20180209