CN107673650A - A kind of concrete hollow block early strength agent - Google Patents

A kind of concrete hollow block early strength agent Download PDF

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Publication number
CN107673650A
CN107673650A CN201711052683.5A CN201711052683A CN107673650A CN 107673650 A CN107673650 A CN 107673650A CN 201711052683 A CN201711052683 A CN 201711052683A CN 107673650 A CN107673650 A CN 107673650A
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CN
China
Prior art keywords
parts
early strength
strength agent
concrete hollow
hollow block
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Pending
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CN201711052683.5A
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Chinese (zh)
Inventor
兰新良
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Individual
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Individual
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Priority to CN201711052683.5A priority Critical patent/CN107673650A/en
Publication of CN107673650A publication Critical patent/CN107673650A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0028Aspects relating to the mixing step of the mortar preparation
    • C04B40/0039Premixtures of ingredients
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/10Accelerators; Activators

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses a kind of concrete hollow block early strength agent, the early strength agent comprises at least following raw material:Rosin, phenol, magnesium trisilicate, potassium hydrogen tartrate, triethanolamine, shale ashes, methyl methacrylate, urea and trehalose.Concrete hollow block early strength agent of the present invention, each group bulk-breaking can play cooperative compensating effect.When 1d, compressive strength rate reaches more than 200%, meets the demoulding requirement of concrete hollow block.The slump amount of concrete hollow block during demoulding is also reduced simultaneously.Demoulding time is shortened, improves operating efficiency.

Description

A kind of concrete hollow block early strength agent
Technical field
The present invention relates to building material field, more particularly to a kind of concrete hollow block early strength agent.
Background technology
Early strength agent is one of additive of cement and cement matrix.Refer to that cement can be improved and cement-based articles early stage is strong Degree, and the additive not made significant difference to later strength.The main function of early strength agent is to accelerate hydrated cementitious speed, promoted The development of early age strength of concrete;Both there is early powerful, there is certain water reducing and strength increasing function again.Existing concrete hollow brick is given birth to During production, demoulding time length, production efficiency is had a strong impact on, using existing early strength agent, it is bad using effect to be still present, during the demoulding Between it is longer the shortcomings that.
The information for being disclosed in the background section is merely intended to understanding of the increase to the general background of the present invention, without answering It has been the prior art well known to persons skilled in the art when being considered as recognizing or implying the information structure in any form.
The content of the invention
It is an object of the invention to provide a kind of concrete hollow block early strength agent, so as to overcome cement products demoulding time It is long, the shortcomings that low production efficiency.
To achieve the above object, the invention provides a kind of concrete hollow block early strength agent, the early strength agent at least to wrap Include following raw material:Rosin, phenol, magnesium trisilicate, potassium hydrogen tartrate, triethanolamine, shale ashes, methyl methacrylate, urea And trehalose.
Preferably, in above-mentioned technical proposal, described concrete hollow block early strength agent, count in parts by weight, the morning Strong agent comprises at least following raw material:Rosin 2-9 parts, phenol 3-5 parts, magnesium trisilicate 1-5 parts, potassium hydrogen tartrate 4-11 parts, three second Hydramine 5-11 parts, shale ashes 1-3 parts, methyl methacrylate 5-9 parts, urea 7-13 parts and trehalose 3-7 parts.
Preferably, in above-mentioned technical proposal, described concrete hollow block early strength agent, the early strength agent also includes following Raw material:One kind, isopropanol, soda, glycolic, kaolin, p-methyl benzenesulfonic acid in cellulose ether, calcium oxalate or calcium formate and Nano-calcium carbonate.
Preferably, in above-mentioned technical proposal, described concrete hollow block early strength agent, count in parts by weight, the morning Strong agent also includes following raw material:A kind of 6-10 parts, isopropanol 2-7 parts in cellulose ether 9-15 parts, calcium oxalate or calcium formate, Soda 3-8 parts, glycolic 1-5 parts, kaolin 7-12 parts, p-methyl benzenesulfonic acid 1-4 parts and nano-calcium carbonate 6-13 parts.
Preferably, in above-mentioned technical proposal, described concrete hollow block early strength agent, count in parts by weight, the morning Strong agent includes following raw material:Rosin 2-9 parts, phenol 3-5 parts, magnesium trisilicate 1-5 parts, potassium hydrogen tartrate 4-11 parts, triethanolamine 5-11 parts, shale ashes 1-3 parts, methyl methacrylate 5-9 parts, urea 7-13 parts, trehalose 3-7 parts, cellulose ether 9-15 parts, A kind of 6-10 parts, isopropanol 2-7 parts in calcium oxalate or calcium formate, soda 3-8 parts, glycolic 1-5 parts, kaolin 7-12 Part, p-methyl benzenesulfonic acid 1-4 parts and nano-calcium carbonate 6-13 parts.
Preferably, in above-mentioned technical proposal, described concrete hollow block early strength agent, count in parts by weight, the morning Strong agent includes following raw material:5 parts of rosin, 4 parts of phenol, 3 parts of magnesium trisilicate, 7 parts of potassium hydrogen tartrate, 8 parts of triethanolamine, shale ashes One kind in 2 parts, 6 parts of methyl methacrylate, 9 parts of urea, 5 parts of trehalose, 12 parts of cellulose ether, calcium oxalate or calcium formate 8 parts of 7 parts, 5 parts of isopropanol, 6 parts of soda, 3 parts of glycolic, 9 parts of kaolin, 3 parts of p-methyl benzenesulfonic acid and nano-calcium carbonate.
Preferably, in above-mentioned technical proposal, the cellulose ether is hydroxyethylmethylcellulose, carboxymethyl cellulose, second One or more in base cellulose, benzylcellulose, hydroxyethyl cellulose, hydroxypropyl methyl cellulose.
Preferably, in above-mentioned technical proposal, the mass ratio that the early strength agent uses in cement products is early strength agent: Cement is 1-5:100.
Compared with prior art, the present invention has the advantages that:Concrete hollow block early strength agent of the present invention, each group Bulk-breaking can play cooperative compensating effect.When 1d, compressive strength rate reaches more than 200%, meets concrete hollow block The demoulding requirement.The slump amount of concrete hollow block during demoulding is also reduced simultaneously.Demoulding time is shortened, improves work Efficiency.
Embodiment
With reference to specific embodiment, the embodiment of the present invention is described in detail, it is to be understood that this hair Bright protection domain is not limited by embodiment.
Embodiment 1
A kind of concrete hollow block early strength agent, is counted in parts by weight, and the early strength agent includes following raw material:5 parts of rosin, 4 parts of phenol, 3 parts of magnesium trisilicate, 7 parts of potassium hydrogen tartrate, 8 parts of triethanolamine, 2 parts of shale ashes, 6 parts of methyl methacrylate, urine Element 9 parts, 5 parts of trehalose, 12 parts of cellulose ether, 7 parts of calcium formate, 5 parts of isopropanol, 6 parts of soda, 3 parts of glycolic, 9 parts of kaolin, 8 parts of 3 parts of p-methyl benzenesulfonic acid and nano-calcium carbonate.
The cellulose ether is ethyl cellulose and benzylcellulose, and the mass ratio of mixing is 1:1.
Concrete hollow block is prepared using early strength agent manufactured in the present embodiment, the early strength agent makes in concrete hollow block Mass ratio is early strength agent:Cement is 3:100.
Embodiment 2
A kind of concrete hollow block early strength agent, is counted in parts by weight, and the early strength agent includes following raw material:2 parts of rosin, 5 parts of phenol, 1 part of magnesium trisilicate, 11 parts of potassium hydrogen tartrate, 11 parts of triethanolamine, 3 parts of shale ashes, 5 parts of methyl methacrylate, 13 parts of urea, 3 parts of trehalose, 15 parts of cellulose ether, 6 parts of calcium oxalate, 2 parts of isopropanol, 8 parts of soda, 5 parts of glycolic, kaolin 7 6 parts of part, 4 parts of p-methyl benzenesulfonic acid and nano-calcium carbonate.
The cellulose ether is carboxymethyl cellulose and ethyl cellulose, and the mass ratio of mixing is 1:1.
Concrete hollow block is prepared using early strength agent manufactured in the present embodiment, the early strength agent makes in concrete hollow block Mass ratio is early strength agent:Cement is 1:100.
Embodiment 3
A kind of concrete hollow block early strength agent, is counted in parts by weight, and the early strength agent includes following raw material:9 parts of rosin, 3 parts of phenol, 5 parts of magnesium trisilicate, 4 parts of potassium hydrogen tartrate, 5 parts of triethanolamine, 1 part of shale ashes, 9 parts of methyl methacrylate, urine 7 parts of element, 7 parts of trehalose, 9 parts of cellulose ether, 10 parts of calcium oxalate, 7 parts of isopropanol, 3 parts of soda, 1 part of glycolic, kaolin 12 13 parts of part, 1 part of p-methyl benzenesulfonic acid and nano-calcium carbonate.
The cellulose ether is hydroxyethylmethylcellulose.
Concrete hollow block is prepared using early strength agent manufactured in the present embodiment, the early strength agent makes in concrete hollow block Mass ratio is early strength agent:Cement is 5:100.
Comparative example 1
A kind of concrete hollow block early strength agent, is counted in parts by weight, and the early strength agent includes following raw material:Cellulose ether 12 parts, 7 parts of calcium formate, 5 parts of isopropanol, 6 parts of soda, 3 parts of glycolic, 9 parts of kaolin, 3 parts of p-methyl benzenesulfonic acid and nano-calcium carbonate 8 parts of calcium.
The cellulose ether is ethyl cellulose and benzylcellulose, and the mass ratio of mixing is 1:1.
Concrete hollow block is prepared using early strength agent manufactured in the present embodiment, the early strength agent makes in concrete hollow block Mass ratio is early strength agent:Cement is 3:100.
By the early strength agent of embodiment and comparative example, for making concrete hollow block, (concrete hollow block is that in the market is common Concrete hollow block, the difference of production process is the early strength agent that with the addition of the application and comparative example), and then detect concrete The indices of hollow brick.Performance test is as shown in table 1.Comparative example 2 is the common concrete hollow block of in the market in table 1, In production process and it is not added with early strength agent.Table 1 is the contrast of embodiment and comparative example concrete hollow block setting time and intensity.
Table 1 is the contrast of concrete hollow block setting time and intensity
The description of the foregoing specific illustrative embodiment to the present invention is to illustrate and the purpose of illustration.These descriptions It is not wishing to limit the invention to disclosed precise forms, and it will be apparent that according to above-mentioned teaching, can be much changed And change.The purpose of selecting and describing the exemplary embodiment is that explain that the certain principles of the present invention and its reality should With so that those skilled in the art can realize and utilize the present invention a variety of exemplaries and Various chooses and changes.The scope of the present invention is intended to be limited by claims and its equivalents.

Claims (8)

1. a kind of concrete hollow block early strength agent, it is characterised in that the early strength agent comprises at least following raw material:Rosin, benzene Phenol, magnesium trisilicate, potassium hydrogen tartrate, triethanolamine, shale ashes, methyl methacrylate, urea and trehalose.
2. concrete hollow block early strength agent according to claim 1, it is characterised in that count in parts by weight, the morning Strong agent comprises at least following raw material:Rosin 2-9 parts, phenol 3-5 parts, magnesium trisilicate 1-5 parts, potassium hydrogen tartrate 4-11 parts, three second Hydramine 5-11 parts, shale ashes 1-3 parts, methyl methacrylate 5-9 parts, urea 7-13 parts and trehalose 3-7 parts.
3. concrete hollow block early strength agent according to claim 1, it is characterised in that the early strength agent also includes following Raw material:One kind, isopropanol, soda, glycolic, kaolin, p-methyl benzenesulfonic acid in cellulose ether, calcium oxalate or calcium formate and Nano-calcium carbonate.
4. concrete hollow block early strength agent according to claim 1, it is characterised in that count in parts by weight, the morning Strong agent also includes following raw material:A kind of 6-10 parts, isopropanol 2-7 parts in cellulose ether 9-15 parts, calcium oxalate or calcium formate, Soda 3-8 parts, glycolic 1-5 parts, kaolin 7-12 parts, p-methyl benzenesulfonic acid 1-4 parts and nano-calcium carbonate 6-13 parts.
5. concrete hollow block early strength agent according to claim 1, it is characterised in that count in parts by weight, the morning Strong agent includes following raw material:Rosin 2-9 parts, phenol 3-5 parts, magnesium trisilicate 1-5 parts, potassium hydrogen tartrate 4-11 parts, triethanolamine 5-11 parts, shale ashes 1-3 parts, methyl methacrylate 5-9 parts, urea 7-13 parts, trehalose 3-7 parts, cellulose ether 9-15 parts, A kind of 6-10 parts, isopropanol 2-7 parts in calcium oxalate or calcium formate, soda 3-8 parts, glycolic 1-5 parts, kaolin 7-12 Part, p-methyl benzenesulfonic acid 1-4 parts and nano-calcium carbonate 6-13 parts.
6. concrete hollow block early strength agent according to claim 1, it is characterised in that count in parts by weight, the morning Strong agent includes following raw material:5 parts of rosin, 4 parts of phenol, 3 parts of magnesium trisilicate, 7 parts of potassium hydrogen tartrate, 8 parts of triethanolamine, shale ashes One kind in 2 parts, 6 parts of methyl methacrylate, 9 parts of urea, 5 parts of trehalose, 12 parts of cellulose ether, calcium oxalate or calcium formate 8 parts of 7 parts, 5 parts of isopropanol, 6 parts of soda, 3 parts of glycolic, 9 parts of kaolin, 3 parts of p-methyl benzenesulfonic acid and nano-calcium carbonate.
7. concrete hollow block early strength agent according to claim 1, it is characterised in that the cellulose ether is ethoxy In methylcellulose, carboxymethyl cellulose, ethyl cellulose, benzylcellulose, hydroxyethyl cellulose, hydroxypropyl methyl cellulose One or more.
8. concrete hollow block early strength agent according to claim 1, it is characterised in that the early strength agent is in cement products The middle mass ratio used is early strength agent:Cement is 1-5:100.
CN201711052683.5A 2017-10-30 2017-10-30 A kind of concrete hollow block early strength agent Pending CN107673650A (en)

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Application Number Priority Date Filing Date Title
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CN107673650A true CN107673650A (en) 2018-02-09

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110683785A (en) * 2019-11-14 2020-01-14 江苏博思通新材料有限公司 Concrete crystal nucleus early strength agent
WO2020109186A1 (en) * 2018-11-26 2020-06-04 Sika Technology Ag Additives for cements comprising ye'elimite

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104944824A (en) * 2015-07-10 2015-09-30 重庆大学 Cement concrete early strength agent and early strength and water reduction agent
CN105417988A (en) * 2015-12-30 2016-03-23 卓达新材料科技集团威海股份有限公司 Early strength agent for ordinary portland cement fiber board
CN105503006A (en) * 2015-12-30 2016-04-20 卓达新材料科技集团威海股份有限公司 Early strength agent used for ordinary Portland cement fiberboards
CN105503020A (en) * 2015-12-30 2016-04-20 卓达新材料科技集团威海股份有限公司 Early strength agent used for ordinary Portland cement fiberboards

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104944824A (en) * 2015-07-10 2015-09-30 重庆大学 Cement concrete early strength agent and early strength and water reduction agent
CN105417988A (en) * 2015-12-30 2016-03-23 卓达新材料科技集团威海股份有限公司 Early strength agent for ordinary portland cement fiber board
CN105503006A (en) * 2015-12-30 2016-04-20 卓达新材料科技集团威海股份有限公司 Early strength agent used for ordinary Portland cement fiberboards
CN105503020A (en) * 2015-12-30 2016-04-20 卓达新材料科技集团威海股份有限公司 Early strength agent used for ordinary Portland cement fiberboards

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020109186A1 (en) * 2018-11-26 2020-06-04 Sika Technology Ag Additives for cements comprising ye'elimite
CN112839916A (en) * 2018-11-26 2021-05-25 Sika技术股份公司 Additive for cement containing tialite
CN112839916B (en) * 2018-11-26 2024-03-26 Sika技术股份公司 Additive for cement containing sulfur-containing bauxite
CN110683785A (en) * 2019-11-14 2020-01-14 江苏博思通新材料有限公司 Concrete crystal nucleus early strength agent

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Application publication date: 20180209

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