CN107663417A - A kind of organic silicon flame-retardant fireproof coating - Google Patents

A kind of organic silicon flame-retardant fireproof coating Download PDF

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Publication number
CN107663417A
CN107663417A CN201711126713.2A CN201711126713A CN107663417A CN 107663417 A CN107663417 A CN 107663417A CN 201711126713 A CN201711126713 A CN 201711126713A CN 107663417 A CN107663417 A CN 107663417A
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CN
China
Prior art keywords
parts
fireproof coating
organic silicon
retardant fireproof
retardant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711126713.2A
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Chinese (zh)
Inventor
李鹏
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sichuan Kelixin New Material Co Ltd
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Sichuan Kelixin New Material Co Ltd
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Publication date
Application filed by Sichuan Kelixin New Material Co Ltd filed Critical Sichuan Kelixin New Material Co Ltd
Priority to CN201711126713.2A priority Critical patent/CN107663417A/en
Publication of CN107663417A publication Critical patent/CN107663417A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04Polysiloxanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/36Silica
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention discloses a kind of organic silicon flame-retardant fireproof coating, and in parts by weight, the organic silicon flame-retardant fireproof coating includes:500 800 parts of organic siliconresin, 200 300 parts of nano-ceramic powder, 100 150 parts of carbon series conductive particle, 300 500 parts of auxiliary agent, 100 200 parts of fire-retardant filler, 12 parts of catalyst;The organic silicon flame-retardant fireproof coating can realize the effect of fire-retardant fireproof to combustible material, and have preferable non-deformability and adhesive property.

Description

A kind of organic silicon flame-retardant fireproof coating
Technical field
The present invention relates to technical field of coatings, and in particular to a kind of organic silicon flame-retardant fireproof coating.
Background technology
At present, architecture exterior wall insulating materials are the main materials of insulation, are widely used.The organic guarantor used Adiabator mainly includes three kinds of styrofoam (EPS), extruded sheet (XPS) and polyurethane (PU), its biggest advantage is that light, guarantor Temperature, thermal insulation are good.But the defects of maximum is that fire savety is poor, easy to aging, easy firing.For example CCTV's building fire is with regard to source In employing not fire-retardant organic insulation material.These materials are while extensive fire is triggered, because of imperfect combustion and heat Solution, more flue dust and toxic gas can be produced, and majority are exactly that suction cigarette and toxic gas are died of asphyxiation in fire incident. Therefore, architecture exterior wall insulating materials fire risk is high, easily causes major casualties.
The content of the invention
In view of this, this application provides a kind of organic silicon flame-retardant fireproof coating, the organic silicon flame-retardant fireproof coating energy The effect of fire-retardant fireproof is realized to combustible material, and there is preferable non-deformability and adhesive property.
To solve above technical problem, technical scheme provided by the invention is a kind of organic silicon flame-retardant fireproof coating, with weight Part meter is measured, the organic silicon flame-retardant fireproof coating includes:Organic siliconresin 500-800 parts, nano-ceramic powder 200-300 parts, Carbon series conductive particle 100-150 parts, auxiliary agent 300-500 parts, fire-retardant filler 100-200 parts, catalyst 1-2 parts.
Preferably, in parts by weight, the organic silicon flame-retardant fireproof coating includes:Organic siliconresin 500-650 parts, nanometer Ceramic powder 200-250 parts, carbon series conductive particle 100-125 parts, auxiliary agent 300-400 parts, fire-retardant filler 100-150 parts, catalysis Agent 1-1.5 parts.
Preferably, in parts by weight, the organic silicon flame-retardant fireproof coating includes:650 parts of organic siliconresin, nano ceramics 250 parts of powder, 125 parts of carbon series conductive particle, 400 parts of auxiliary agent, 150 parts of fire-retardant filler, 1.5 parts of catalyst.
Preferably, the carbon series conductive particle is graphite or conductive carbon black.
Preferably, described auxiliary agent is silane coupler or silicone oil.
Preferably, described silicone oil is vinyl silicone oil, containing hydrogen silicone oil.
Preferably, described fire-retardant filler is silica or graphene.
Preferably, described catalyst is chloroplatinic acid or platinum catalyst.
The present invention, with reference to low viscosity auxiliary agent and catalyst, is prepared for no-solvent type organosilicon using organic siliconresin as matrix Cold coating, the coating can not only realize the performances such as room temperature fast-curing, fire-retardant fireproof, and with good adhesive property, Hydrophobic performance and deformability.It is organic based on organic siliconresin good high temperature resistant and heat endurance, a kind of described environment-friendly type Silicon fire-retardant fireproof coating is in the fields such as architecture exterior wall insulating materials, electric appliance and electronic, instrument and equipment, packaging material, fitting-up Application on combustible material surface.The nano-ceramic powder of addition, organic silicon coating is formed the netted coating structure of densification, carry The high corrosion resistance of coating.The coating can carry out anti-corrosion simultaneously in steel pipe surfaces externally and internally.Corrosion resistance is strong, can acid-alkali-corrosive-resisting.
Compared with prior art, its detailed description is as follows by the application:
(1) there is excellent fire retardant performance, while there is good adhesive property, rotproofness, hydrophobic performance and change Shape ability;
(2) preparation method for coating is easy, quick, and cold curing and no coupling product can be achieved, be environmental-protection flame-retardant coating.
Embodiment
In order that those skilled in the art more fully understands technical scheme, with reference to specific embodiment pair The present invention is described in further detail.
Embodiment 1
A kind of organic silicon flame-retardant fireproof coating, in parts by weight, the organic silicon flame-retardant fireproof coating include:Organosilicon tree 500 parts of fat, 200 parts of nano-ceramic powder, 100 parts of carbon series conductive particle, 300 parts of auxiliary agent, 100 parts of fire-retardant filler, catalyst 1 Part.
Wherein, the carbon series conductive particle is graphite, and described auxiliary agent is silane coupler, and described silicone oil is vinyl Silicone oil, described fire-retardant filler are silica, and described catalyst is chloroplatinic acid.
Embodiment 2
A kind of organic silicon flame-retardant fireproof coating, in parts by weight, the organic silicon flame-retardant fireproof coating include:Organosilicon tree 800 parts of fat, 300 parts of nano-ceramic powder, 150 parts of carbon series conductive particle, 500 parts of auxiliary agent, 200 parts of fire-retardant filler, catalyst 2 Part.
Wherein, the carbon series conductive particle is conductive carbon black, and described auxiliary agent is silicone oil, and described silicone oil is Silicon Containing Hydrogen Oil, described fire-retardant filler are graphene, and described catalyst is platinum catalyst.
Embodiment 3
A kind of organic silicon flame-retardant fireproof coating, in parts by weight, the organic silicon flame-retardant fireproof coating include:Organosilicon tree 650 parts of fat, 250 parts of nano-ceramic powder, 125 parts of carbon series conductive particle, 400 parts of auxiliary agent, 150 parts of fire-retardant filler, catalyst 1.5 Part.
Wherein, the carbon series conductive particle is conductive carbon black, and described auxiliary agent is silicone oil, and described silicone oil is Silicon Containing Hydrogen Oil, described fire-retardant filler are graphene, and described catalyst is platinum catalyst.
It the above is only the preferred embodiment of the present invention, it is noted that above-mentioned preferred embodiment is not construed as pair The limitation of the present invention, protection scope of the present invention should be defined by claim limited range.For the art For those of ordinary skill, without departing from the spirit and scope of the present invention, some improvements and modifications can also be made, these change Enter and retouch and also should be regarded as protection scope of the present invention.

Claims (8)

  1. A kind of 1. organic silicon flame-retardant fireproof coating, it is characterised in that in parts by weight, the organic silicon flame-retardant fireproof coating bag Include:Organic siliconresin 500-800 parts, nano-ceramic powder 200-300 parts, carbon series conductive particle 100-150 parts, auxiliary agent 300- 500 parts, fire-retardant filler 100-200 parts, catalyst 1-2 parts.
  2. 2. organic silicon flame-retardant fireproof coating according to claim 1, it is characterised in that in parts by weight, the organosilicon Fire-retardant fireproof coating includes:Organic siliconresin 500-650 parts, nano-ceramic powder 200-250 parts, carbon series conductive particle 100- 125 parts, auxiliary agent 300-400 parts, fire-retardant filler 100-150 parts, catalyst 1-1.5 parts.
  3. 3. organic silicon flame-retardant fireproof coating according to claim 1, it is characterised in that in parts by weight, the organosilicon Fire-retardant fireproof coating includes:650 parts of organic siliconresin, 250 parts of nano-ceramic powder, 125 parts of carbon series conductive particle, auxiliary agent 400 Part, 150 parts of fire-retardant filler, 1.5 parts of catalyst.
  4. 4. organic silicon flame-retardant fireproof coating according to claim 1, it is characterised in that the carbon series conductive particle is graphite Or conductive carbon black.
  5. 5. organic silicon flame-retardant fireproof coating according to claim 1, it is characterised in that described auxiliary agent is silane coupler Or silicone oil.
  6. 6. a kind of organic silicon flame-retardant fireproof coating according to claim 1, it is characterised in that described silicone oil is vinyl Silicone oil, containing hydrogen silicone oil.
  7. 7. a kind of organic silicon flame-retardant fireproof coating according to claim 1, it is characterised in that described fire-retardant filler is two Silica or graphene.
  8. 8. a kind of organic silicon flame-retardant fireproof coating according to claim 1, it is characterised in that described catalyst is chlorine platinum Acid or platinum catalyst.
CN201711126713.2A 2017-11-15 2017-11-15 A kind of organic silicon flame-retardant fireproof coating Pending CN107663417A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711126713.2A CN107663417A (en) 2017-11-15 2017-11-15 A kind of organic silicon flame-retardant fireproof coating

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711126713.2A CN107663417A (en) 2017-11-15 2017-11-15 A kind of organic silicon flame-retardant fireproof coating

Publications (1)

Publication Number Publication Date
CN107663417A true CN107663417A (en) 2018-02-06

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109468058A (en) * 2018-09-30 2019-03-15 浙江凌志新材料有限公司 A kind of weather-proof cracking resistance organosilicon fireproof coating of ultrathin type
CN111303739A (en) * 2020-02-17 2020-06-19 陈家珺 Hydrophobic flame-retardant coating and preparation process thereof
CN112238660A (en) * 2020-10-20 2021-01-19 广东和丰创美新型材料有限公司 Paint-free fireproof solid wood facing material and preparation method thereof
CN112358756A (en) * 2020-10-14 2021-02-12 航天材料及工艺研究所 High-strength stain-resistant silicone rubber four-prevention coating and preparation method thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109468058A (en) * 2018-09-30 2019-03-15 浙江凌志新材料有限公司 A kind of weather-proof cracking resistance organosilicon fireproof coating of ultrathin type
CN109468058B (en) * 2018-09-30 2020-12-29 浙江凌志新材料有限公司 Ultrathin weather-resistant anti-cracking organic silicon fireproof coating
CN111303739A (en) * 2020-02-17 2020-06-19 陈家珺 Hydrophobic flame-retardant coating and preparation process thereof
CN111303739B (en) * 2020-02-17 2021-06-15 四川天道易科技有限公司 Hydrophobic flame-retardant coating and preparation process thereof
CN112358756A (en) * 2020-10-14 2021-02-12 航天材料及工艺研究所 High-strength stain-resistant silicone rubber four-prevention coating and preparation method thereof
CN112238660A (en) * 2020-10-20 2021-01-19 广东和丰创美新型材料有限公司 Paint-free fireproof solid wood facing material and preparation method thereof

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Application publication date: 20180206

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