CN107662983A - A kind of processing method and system of salt-soda soil bitter - Google Patents
A kind of processing method and system of salt-soda soil bitter Download PDFInfo
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- CN107662983A CN107662983A CN201610611943.7A CN201610611943A CN107662983A CN 107662983 A CN107662983 A CN 107662983A CN 201610611943 A CN201610611943 A CN 201610611943A CN 107662983 A CN107662983 A CN 107662983A
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- water
- salt
- bitter
- pond
- softening
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- 239000002689 soil Substances 0.000 title claims abstract description 57
- 238000003672 processing method Methods 0.000 title claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 225
- 150000003839 salts Chemical class 0.000 claims abstract description 78
- 238000001914 filtration Methods 0.000 claims abstract description 69
- 238000000151 deposition Methods 0.000 claims abstract description 52
- 239000004576 sand Substances 0.000 claims abstract description 36
- 230000008719 thickening Effects 0.000 claims abstract description 36
- 238000000034 method Methods 0.000 claims abstract description 19
- 238000009287 sand filtration Methods 0.000 claims abstract description 17
- 238000001179 sorption measurement Methods 0.000 claims abstract description 13
- 239000010802 sludge Substances 0.000 claims description 60
- 239000010902 straw Substances 0.000 claims description 57
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 34
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 31
- 238000010521 absorption reaction Methods 0.000 claims description 29
- 239000007787 solid Substances 0.000 claims description 25
- 238000004519 manufacturing process Methods 0.000 claims description 20
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 17
- 229910052757 nitrogen Inorganic materials 0.000 claims description 17
- 229910052698 phosphorus Inorganic materials 0.000 claims description 17
- 239000011574 phosphorus Substances 0.000 claims description 17
- 238000002386 leaching Methods 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 13
- 238000005189 flocculation Methods 0.000 claims description 12
- 230000016615 flocculation Effects 0.000 claims description 12
- 238000003860 storage Methods 0.000 claims description 12
- 235000007164 Oryza sativa Nutrition 0.000 claims description 10
- 235000009566 rice Nutrition 0.000 claims description 10
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 9
- 239000005871 repellent Substances 0.000 claims description 9
- 230000002940 repellent Effects 0.000 claims description 9
- 239000011780 sodium chloride Substances 0.000 claims description 9
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 8
- 235000014676 Phragmites communis Nutrition 0.000 claims description 5
- 240000008042 Zea mays Species 0.000 claims description 5
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 claims description 5
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims description 5
- 230000008021 deposition Effects 0.000 claims description 5
- 235000009973 maize Nutrition 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 239000011148 porous material Substances 0.000 claims description 5
- 238000010992 reflux Methods 0.000 claims description 5
- 229920000742 Cotton Polymers 0.000 claims description 4
- 240000000111 Saccharum officinarum Species 0.000 claims description 4
- 235000007201 Saccharum officinarum Nutrition 0.000 claims description 4
- 244000061456 Solanum tuberosum Species 0.000 claims description 4
- 235000002595 Solanum tuberosum Nutrition 0.000 claims description 4
- 230000008859 change Effects 0.000 claims description 4
- 230000001112 coagulating effect Effects 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- 239000004411 aluminium Substances 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 239000010801 sewage sludge Substances 0.000 claims description 3
- 238000005352 clarification Methods 0.000 claims description 2
- 241000209094 Oryza Species 0.000 claims 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 239000010977 jade Substances 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 239000003513 alkali Substances 0.000 abstract description 18
- 230000008720 membrane thickening Effects 0.000 abstract description 5
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 8
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 8
- 229910052731 fluorine Inorganic materials 0.000 description 8
- 239000011737 fluorine Substances 0.000 description 8
- 241000196324 Embryophyta Species 0.000 description 7
- 239000012528 membrane Substances 0.000 description 7
- 239000000725 suspension Substances 0.000 description 7
- 239000004571 lime Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 5
- 240000007594 Oryza sativa Species 0.000 description 5
- 235000011941 Tilia x europaea Nutrition 0.000 description 5
- 230000008901 benefit Effects 0.000 description 5
- 238000005345 coagulation Methods 0.000 description 5
- 230000015271 coagulation Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000003344 environmental pollutant Substances 0.000 description 5
- 239000005416 organic matter Substances 0.000 description 5
- 231100000719 pollutant Toxicity 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 241000195493 Cryptophyta Species 0.000 description 4
- 239000000701 coagulant Substances 0.000 description 4
- 239000003337 fertilizer Substances 0.000 description 4
- 238000003973 irrigation Methods 0.000 description 4
- 230000002262 irrigation Effects 0.000 description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000004062 sedimentation Methods 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000010612 desalination reaction Methods 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000013505 freshwater Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 230000004083 survival effect Effects 0.000 description 2
- 238000010408 sweeping Methods 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 241000223025 Caragana microphylla Species 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- NOQGZXFMHARMLW-UHFFFAOYSA-N Daminozide Chemical compound CN(C)NC(=O)CCC(O)=O NOQGZXFMHARMLW-UHFFFAOYSA-N 0.000 description 1
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- 239000001828 Gelatine Substances 0.000 description 1
- 240000008917 Glycyrrhiza uralensis Species 0.000 description 1
- 235000000554 Glycyrrhiza uralensis Nutrition 0.000 description 1
- 244000273256 Phragmites communis Species 0.000 description 1
- 241000219000 Populus Species 0.000 description 1
- 244000126002 Ziziphus vulgaris Species 0.000 description 1
- 235000008529 Ziziphus vulgaris Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000003679 aging effect Effects 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 238000009954 braiding Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000003657 drainage water Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000009313 farming Methods 0.000 description 1
- 239000011790 ferrous sulphate Substances 0.000 description 1
- 235000003891 ferrous sulphate Nutrition 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 230000003311 flocculating effect Effects 0.000 description 1
- -1 flocculation aid Substances 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 239000003673 groundwater Substances 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- 229910000360 iron(III) sulfate Inorganic materials 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 235000012204 lemonade/lime carbonate Nutrition 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000032696 parturition Effects 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000001223 reverse osmosis Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical class O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 229940074404 sodium succinate Drugs 0.000 description 1
- ZDQYSKICYIVCPN-UHFFFAOYSA-L sodium succinate (anhydrous) Chemical compound [Na+].[Na+].[O-]C(=O)CCC([O-])=O ZDQYSKICYIVCPN-UHFFFAOYSA-L 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 239000002352 surface water Substances 0.000 description 1
- 238000003911 water pollution Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/001—Processes for the treatment of water whereby the filtration technique is of importance
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
- C02F1/441—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
- C02F1/442—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by nanofiltration
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
- C02F1/444—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/5236—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/54—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
- C02F1/56—Macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2301/00—General aspects of water treatment
- C02F2301/08—Multistage treatments, e.g. repetition of the same process step under different conditions
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/22—Eliminating or preventing deposits, scale removal, scale prevention
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
- C02F5/08—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
- C02F5/08—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
- C02F5/10—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
- C02F5/08—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
- C02F5/10—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
- C02F5/14—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances containing phosphorus
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Filtering Materials (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Abstract
The invention discloses a kind of processing method and system of salt-soda soil bitter, this method includes:Bitter is carried out to adsorption treatment, softening clarifying treatment, sand filtration processing, secondary filter processing and the processing of film thickening filtration successively, obtains brackish water.The method and system of the present invention can utilize salt-soda soil row's alkali water in a canal purified treatment to obtain brackish water recharge soil, plant not only Salt And Alkali Tolerance but also there is the plant of economic value, and the treating capacity of softening depositing reservoir, sand filter, accurate filter and film thickening filtration device can be reduced, improve the life-span of high performance membrane thickening filtration device film.
Description
Technical field
The present invention relates to the purified treatment reuse technology field of rural sewage, in particular it relates to a kind of salt-soda soil bitter
Processing method and system.
Background technology
China there are about 0.27 hundred million hectares of salt-soda soil, wherein 0.06 hundred million hectares of arable land, 0.21 hundred million hectares of saline-alkali wasteland, main point
Cloth compares and concentrates the area that is distributed in flakes to have Qaidam in northeast, North China, Northwest inland area and North of Yangtze River coastal area
Basin, Tarim Basin periphery oasis and Northern Piedmont of Tianshan Mountains bajada area, Hetao Plain, Yinchuan Plain, North China are put down
The former and Huanghe delta.
Salt-soda soil is formed under certain natural conditions, and its essence formed is mainly various ease of solubility salts on ground
Redistributing for horizontal direction and vertical direction is made in face, so that upper soll layer of the salinity in collection salt area is built up.
The factors such as weather acts on, farming technique is unreasonable, level of ground water is raised, can cause the salinization of soil.
Perniciousness harm cause it is a large amount of in, low-yield land, the anions and canons being harmful to crop are more, make large area soil resource difficult
To utilize, overall productivity in agriculture declines.Saline-alkali soil is administered at present it is most useful that to soil by the way of washed off soil
Carry out salt discharge alkali, the i.e. desalinization of soil by flooding or leaching.Irrigation and drainage system is excavated on salt-soda soil, water is poured into salt-soda soil in a manner of broad irrigation, is made
Soil salt dissolves, oozed under in topsoil it is soluble it is saline and alkaline be discharged in deep soil or elute away, alkali is arranged in side infiltration
Canal is excluded.It is to water resource degree of dependence height, it is necessary to consume around salt-soda soil more than 50% freshwater resources.
China's saline alkali land drainage water is very big, and this part is leached the salt and alkali to get off, if do not handled scientifically,
Over time, the serious ecological problems such as Secondary Saline and the surface water pollution of non-wetland with saline-alkaline certainly will be caused.
Brackish water recharge soil is obtained using salt-soda soil row's alkali water in a canal purified treatment, not only Salt And Alkali Tolerance is planted but also there is economic valency
The plant of value, make salt-soda soil is throughout the year green to plant covering, the improvement of essence will be produced to the overall ecological environment of China.General feelings
Under condition, irrigated land using salt-soda soil row's alkali water in a canal purified treatment, chemical fertilizer, pollution by pesticides are few, particularly salination desert, are even more
No pollution.Tight balance is in national cultivated land resource and population speedup, and generally by the overall background of different degrees of agricultural pollution
Under, it transform saline-alkali wasteland as good farmland, not only can provides newly-increased farmland for country, but also freshwater resources danger can be alleviated significantly
Machine, arable land crisis of resource and soil Saline-alkalized land crisis.The plantation of green ecological circular agriculture pattern is promoted for China, is being produced
While giving birth to huge economic benefit, huge ecology and social benefit more are brought to country.
The content of the invention
It is an object of the invention to provide a kind of processing method and system of salt-soda soil bitter, this method and system being capable of profits
Brackish water recharge soil, plantation not only Salt And Alkali Tolerance but also the plant with economic value, and can drop are obtained with bitter purified treatment
It is low to soften the treating capacity of depositing reservoir, sand filter, accurate filter and film thickening filtration device, and improve in film thickening filtration device
The life-span of film.
To achieve these goals, the present invention provides a kind of processing method of salt-soda soil bitter, and this method includes:A, will
Bitter is sent into grid pond and carries out adsorption treatment using stalk straw screen or mat, obtains adsorbing water;Wherein, it is fixed in the stalk straw screen or mat
There is alumina layer, the mass ratio of the stalk straw screen or mat and alumina layer is 1:(0.1-10);B, gained absorption water in step a is entered
Row softening clarifying treatment, obtains sludge and softened water;C, gained softened water in step b is subjected to sand filtration processing, obtains sand leaching water;
D, gained sand leaching water in step c is subjected to secondary filter processing using accurate filter, obtains refined filtration water;E, by institute in step d
Obtain refined filtration water and carry out film thickening filtration processing, obtain concentrated water and low-solids water;Wherein, the Oil repellent of bitter is described in step a
1.0-4.0 mg/litres, nitrogen content are 3-20 mg/litres, and phosphorus content is 0.1-3.5 mg/litres, gained absorption water in step a
Oil repellent is 0.4-1.5 mg/litres, and nitrogen content is 0.2-4 mg/litres, and phosphorus content is 0.02-0.6 mg/litres.
The present invention also provides a kind of processing system of salt-soda soil bitter, and the system includes:It is balancing tank, grid pond, soft
Change depositing reservoir, sand filter, accurate filter and film thickening filtration device;The balancing tank is provided with water inlet and bitter goes out
Mouthful, the grid pond is provided with stalk straw screen or mat, bitter entrance and absorption water out, and the softening depositing reservoir is provided with absorption water
Entrance, softening depositing reservoir sludge outlet and softening water out, the sand filter are provided with sand filter softening water inlet and sand leaching water
Outlet, the accurate filter are provided with sand filtration water inlet and refined filtration water out, and the film thickening filtration device is provided with refined filtration
Water inlet, concentrated water outlet and less salt water out;Wherein, be fixed with alumina layer in the stalk straw screen or mat, the stalk straw screen or mat and
The mass ratio of alumina layer is 1:(0.1-10);The bitter outlet of the balancing tank and the bitter entrance of grid pond connect
Logical, the grid pond absorption water out connects with the absorption water inlet for softening depositing reservoir, and the softened water of the softening depositing reservoir goes out
Mouth connects with sand filter softening water inlet, and the sand filtration water out of the sand filter connects with the sand filtration water inlet of accurate filter,
The refined filtration water out of the accurate filter connects with the refined filtration water inlet of film thickening filtration device.
The beneficial effects of the present invention are:
When carrying out bitter advanced treating using the method and system of the present invention, grid pond, softening depositing reservoir, sand are employed
Filter tank, accurate filter, the integrated technique system of film thickening filtration device, can not only have to the pollutant in bitter
Effect separation, plays a part of purification of water quality, moreover it is possible to retain utility, improve the utilization rate of water resource.
The stalk straw screen or mat used in the method and system of the present invention is compiled by crop materials such as maize straw or straw or reeds
Knit and form, tentatively interception, mistake are carried out to planktonic organisms such as the pollutants such as the organic matter in bitter, nitrogen, phosphorus, silt and algae
Filter, absorption, sedimentation, degraded, the suspended solid treating capacity of softening depositing reservoir, sand filter and accurate filter can be reduced, is improved
The efficiency of the equipment series and life-span.In use, stalk straw screen or mat can regularly replace according to water quality requirement, change
Stalk straw screen or mat can be additionally used in the production of biogas, bio-fertilizer etc., realize the recycling of discarded object.
Due to film thickening filtration device membrane material to the adsorption effect of fluorine be not as good as other divalent ions, and fluorine ion
Larger to the aging effects of membrane material, therefore, general bitter carries out carrying out fluorine removal processing before film thickening filtration processing.This
Alumina layer in the stalk straw screen or mat of invention can reduce the content of nitrogen in bitter, phosphorus and fluorine, reduce the agriculture in bitter
The content of medicine and chemical fertilizer, enable in particular to be greatly lowered the Oil repellent in bitter, so that bitter is concentrated in progress film
Filter before processing need not carry out fluorine removal processing, reduce cost, and can reduce the fluorine treating capacity of subsequent film thickening filtration device, simultaneously
Improve efficiency and the life-span of film thickening filtration system.
Softening depositing reservoir includes more table apparatus, and floor space is small, it is strong to save construction investment, capacity of resisting impact load, imitates
Rate is high;The suspension and organic matter that sand filter is gone in water removal, guarantee, film thickening filtration device tool are provided for subsequent treatment process
There is the features such as compared with low operating pressure, higher flux, relatively low operation and maintenance of equipment expense.
The bitter for rinsing salt-soda soil may be reused using the method and system of the present invention, using water wisely, do not pollute
Environment.Using the brackish water irrigation common saline land and serious saline land of the inventive method and system processing institute output, the saline and alkaline of soil can be reduced
Degree, the saline and alkaline of soil can be kept for a long time in proper level, the brackish water obtained using salt-soda soil row's alkali water in a canal purified treatment
Recharge soil, the plantation not only Salt And Alkali Tolerance plant with economic value again make that plant growing way is more preferable, yield is higher, to Chinese whole
The ecological environment of body will produce the improvement of essence.
Other features and advantages of the present invention will be described in detail in subsequent specific embodiment part.
Brief description of the drawings
Accompanying drawing is for providing a further understanding of the present invention, and a part for constitution instruction, with following tool
Body embodiment is used to explain the present invention together, but is not construed as limiting the invention.In the accompanying drawings:
Fig. 1 includes a kind of schematic flow sheet of embodiment of the processing method of salt-soda soil bitter of the present invention,
A kind of structural representation of embodiment of processing system including salt-soda soil bitter of the present invention.
Embodiment
The embodiment of the present invention is described in detail below in conjunction with accompanying drawing.It should be appreciated that this place is retouched
The embodiment stated is merely to illustrate and explain the present invention, and is not intended to limit the invention.
The present invention provides a kind of processing method of salt-soda soil bitter, and this method includes:A, bitter is sent into grid pond
It is middle that adsorption treatment is carried out using stalk straw screen or mat, obtain adsorbing water;Wherein, alumina layer is fixed with the stalk straw screen or mat, it is described
The mass ratio of stalk straw screen or mat and alumina layer is 1:(0.1-10);B, gained absorption water in step a is subjected to softening clarifying treatment,
Obtain sludge and softened water;C, gained softened water in step b is subjected to sand filtration processing, obtains sand leaching water;D, by gained in step c
Sand leaching water carries out secondary filter processing using accurate filter, obtains refined filtration water;E, it is gained refined filtration water progress film in step d is dense
Contracting filtration treatment, obtains concentrated water and low-solids water;Wherein, the Oil repellent of bitter described in step a is 1.0-4.0 mg/litres, nitrogen
Content is 3-20 mg/litres, and phosphorus content is 0.1-3.5 mg/litres, and the Oil repellent of gained absorption water is 0.4-1.5 millis in step a
G/l, nitrogen content is 0.2-4 mg/litres, and phosphorus content is 0.02-0.6 mg/litres.
According to the present invention, the bitter refers to that basicity is more than hardness, and contains a large amount of neutral salt, and pH value is more than 7 water, I
State is mainly distributed on the north and the coastal region in east China.The bitter of the present invention can come from the row of gained after elution alkaline land soil
Alkali water in a canal, substantial amounts of agricultural chemicals and chemical fertilizer are contained in row's alkali water in a canal, and nitrogen content and phosphorus content are high.
According to the present invention, stalk straw screen or mat can be to the pollutants such as the organic matter in bitter, nitrogen, phosphorus, silt and algae etc.
Planktonic organism tentatively intercept, filtered, absorption, sedimentation, degraded, the stalk in stalk straw screen or mat can be selected from rice straw,
At least one of potato class stalk, rape stalk, cotton stalk, sugarcane stalk, maize straw, straw and reed straw.Stalk
Alumina layer in straw screen or mat can reduce the content of phosphorus in bitter, nitrogen and fluorine, reduce the place of subsequent film thickening filtration device
Reason is born, and the ratio surface of aluminum oxide can be 50-300 rice in alumina layer2/ gram, pore volume can be 0.2-1.2 mls/g.
The existence form present invention of aluminum oxide is not restricted in alumina layer, such as can be the alumina globule closely arranged, this
Art personnel can adjust the gap length of alumina layer as needed.
According to the present invention, in order to which larger suspended solid is intercepted, the treating capacity of stalk straw screen or mat is reduced, this method is also
It can include:The absorption water of gained after the bitter before the adsorption treatment and adsorption treatment is entered using grid in step a
Row intercept process.
According to the present invention, the softening clarifying treatment refers to will absorption in softening depositing reservoir or high density softening depositing reservoir
Water is with removing the suspended solid in water inlet after coagulant and flocculation aid hybrid reaction, while feeding lime, sodium carbonate are softened,
Remove temporary hardness and part permanent hardness, recycled after caused sludge condensation, the coagulant can be selected from
At least one of aluminum sulfate, ferric trichloride, ferrous sulfate, magnesium carbonate, frerrous chloride, aluminium polychloride and bodied ferric sulfate;
The flocculation aid can be in sulfuric acid, phosphoric acid, lime, chlorine, polyacrylamide, activated silicic acid, gelatine and sodium alginate
At least one.
According to the present invention it is possible to by least part step b gained sludge be back to use it is described softening clarifying treatment in and/or
The processing system of salt-soda soil bitter is sent out after being dehydrated.Soften depositing reservoir by inside and outside sludge circulation, backflow can be made dirty
Mud and absorption water form " the muddy water floccule body " of high concentration again, sludge is had very strong adsorption bridging and the volume effect of sweeping,
Fully after flocculation, the larger molecular organicses adsorbed in water are adsorbed and precipitated.
According to the present invention, salt content reduces in the bitter after series of processing steps is handled, for example, in step a
The salt content of the bitter can be 3-15 g/l, and suspension content can be 15-30 mg/litres;Gained is inhaled in step a
The salt content of attached water can be 2.9-14.8 g/l, and suspension content can be 5-10 mg/litres;Gained softened water in step b
Salt content can be 2.5-14 g/l;The salt content of gained sand leaching water can be 2.5-14 g/l in step c;In step d
The salt content of gained refined filtration water can be 2.5-14 g/l;The salt content of gained concentrated water can be 5-42 g/l in step e, institute
The salt content for obtaining low-solids water can be 0.2-2 g/l;Wherein, the salt in the salt content includes all soluble inorganics in water
Salt.
According to the present invention, in order to recycle concentrated water, gained concentrated water at least part step e can be sent into salt making apparatus
It is middle to carry out salt manufacturing processing and/or carry out film thickening filtration processing described in step e.
, can after the softened water by softening clarification carries out secondary filter processing by accurate filter according to the present invention
To add the antisludging agents such as organic phosphonate, polycarboxylic acids and polyepoxy sodium succinate, film concentration is carried out by film thickening filtration device
Filtration treatment carries out desalination, and the temperature of the filtration treatment can be at 5-45 DEG C or so, and pressure can be controlled on a 0.3-2.2 MPas of left side
It is right.
According to the present invention, in order to reduce the usage quantity of film and save energy consumption, gained low-solids water in step e can be sent into
Produce in pond;If the salt content of the low-solids water is less than 1.5 g/l, it can be sent into and blend in pond and at least part step b
Gained softened water mixes, and obtains the processing system that the brackish water that salt content is 1.5-2 g/l sends out salt-soda soil bitter;If institute
The salt content for stating low-solids water is 1.5-2 g/l, then the processing system of salt-soda soil bitter can be sent out directly as brackish water.
The present invention also provides a kind of processing system of salt-soda soil bitter, and the system includes:It is balancing tank, grid pond, soft
Change depositing reservoir, sand filter, accurate filter and film thickening filtration device;The balancing tank is provided with water inlet and bitter goes out
Mouthful, the grid pond is provided with stalk straw screen or mat, bitter entrance and absorption water out, and the softening depositing reservoir is provided with absorption water
Entrance, softening depositing reservoir sludge outlet and softening water out, the sand filter are provided with sand filter softening water inlet and sand leaching water
Outlet, the accurate filter are provided with sand filtration water inlet and refined filtration water out, and the film thickening filtration device is provided with refined filtration
Water inlet, concentrated water outlet and less salt water out;Wherein, be fixed with alumina layer in the stalk straw screen or mat, the stalk straw screen or mat and
The mass ratio of alumina layer is 1:(0.1-10);The bitter outlet of the balancing tank and the bitter entrance of grid pond connect
Logical, the grid pond absorption water out connects with the absorption water inlet for softening depositing reservoir, and the softened water of the softening depositing reservoir goes out
Mouth connects with sand filter softening water inlet, and the sand filtration water out of the sand filter connects with the sand filtration water inlet of accurate filter,
The refined filtration water out of the accurate filter connects with the refined filtration water inlet of film thickening filtration device.
According to the present invention, stalk straw screen or mat can be to the pollutants such as the organic matter in bitter, nitrogen, phosphorus, silt and algae etc.
Planktonic organism tentatively intercept, filtered, absorption, sedimentation, degraded, the stalk in stalk straw screen or mat can be selected from rice straw,
At least one of potato class stalk, rape stalk, cotton stalk, sugarcane stalk, maize straw, straw and reed straw.Stalk
Alumina layer in straw screen or mat can reduce the content of phosphorus in bitter, nitrogen and fluorine, reduce the place of subsequent film thickening filtration device
Reason is born, and the ratio surface of aluminum oxide can be 50-300 rice in alumina layer2/ gram, pore volume can be 0.2-1.2 mls/g.
The existence form present invention of aluminum oxide is not restricted in alumina layer, such as can be the alumina globule closely arranged, this
Art personnel can adjust the gap length of alumina layer as needed.
According to the present invention, soften depositing reservoir, be referred to as high density softening depositing reservoir, be that those skilled in the art institute is ripe
Know, coagulating basin, coagulation apparatus, softening pond, softening equipment and flocculation tank and sloping plate deposition concentration basin can be included;Coagulation
Pond, softening pond, flocculation tank and sloping plate deposition concentration basin are sequentially communicated;Coagulation apparatus, it is positioned in coagulating basin, for that will mix
Solidifying agent, flocculation aid mix with absorption water, remove suspension therein;Softening equipment, be positioned over softening pond in, for by lime,
Sodium carbonate mixes with absorption water, removes temporary hardness and part permanent hardness, the softening depositing reservoir sludge outlet is positioned at softening
Chi Shang.Described coagulation apparatus and softening equipment are well-known to those skilled in the art, and the present invention repeats no more.
According to the present invention, the softening depositing reservoir can also include sewage sludge storage pond, sludge dewatering equipment and sludge reflux dress
Put;The sewage sludge storage pond can include storage pool sludge inlet and storage pool sludge outlet, and the sludge dewatering equipment includes de-
Water dispenser sludge inlet, dewatered sludge outlet and water out, the sludge refluxing apparatus can be provided with returned sludge entrance and return
Sludge outlet is flowed, the softening depositing reservoir is also provided with softening depositing reservoir sludge inlet;The storage pool sludge inlet can
To be connected with softening depositing reservoir sludge outlet, the storage pool sludge outlet can connect with dewaterer sludge inlet, described time
Stream sludge inlet can connect with softening depositing reservoir sludge outlet, and the returned sludge outlet can enter with softening depositing reservoir sludge
Mouth connection.It should be noted that the sludge inlet of the softening depositing reservoir softens with being arranged on the flocculation tank of depositing reservoir,
Returned sludge and raw water is formed " the muddy water floccule body " of high concentration again, make sludge that there is very strong adsorption bridging and volume to sweep work
With after abundant flocculation, the larger molecular organicses in raw water being adsorbed and precipitated, the sludge of precipitation is dense by sloping plate deposition
After contracting pond is concentrated, softening depositing reservoir is sent out again.
According to the present invention, the sand filter is well-known to those skilled in the art, can be that TGV sand filters or TGV are high
The active sand filter of speed, can further remove oil removal wherein;Blowback filter bed is may be provided in the sand filter
Backpurge system, the filtration of particulate matters body of close attachment on deep layer filter bed can be removed, the backwash of the high rate activated sand filters of TGV can
With including the step such as isolation filter tank, air backwash, air and water mixing backwash and final rinsing.
According to the present invention, the accurate filter, also referred to as cartridge filter, it is well-known to those skilled in the art, uses
In removing the suspended solid in sand leaching water.
According to the present invention, the film thickening filtration device is well-known to those skilled in the art, can include membrane material
Material, the membrane material can be selected from least one of milipore filter, NF membrane and reverse osmosis membrane.
According to the present invention, the processing system of the salt-soda soil bitter can also include salt making apparatus;The film is concentrated
The concentrated water outlet of filter device can connect with the concentrated water entrance of the salt making apparatus, and/or the film thickening filtration device is dense
Water out can connect with the refined filtration water inlet of the film thickening filtration device.The salt making apparatus is those skilled in the art institute
It is well known, can be including crystallizing pond etc..
According to the present invention, the processing system of salt-soda soil bitter can also include production pond and blend pond;The production water
Pond can be provided with production pond less salt water inlet, production pond less salt water out and the outlet of production pond brackish water, described to blend pond
It can be provided with and blend pond softening water inlet, blend pond less salt water inlet and blend pond brackish water outlet;The production water
Pond less salt water inlet can be with the low-solids water outlet of the film thickening filtration device, and the production pond less salt water out can be with
Connected with the pond less salt water inlet of blending, the pond softening water inlet of blending can be with the softening of the softening depositing reservoir
Water out connects.
The present invention will be further illustrated by embodiment below, but the present invention is not therefore subject to any restriction.
Device, operating procedure and range of operating parameters are as follows used in the embodiment of the present invention:
The bitter of row's alkali canal from Xinjiang Alar City 11 is first sent into balancing tank, made big in bitter
Particle precipitates, and is then fed into grid pond and carries out intercept process through grid, intercepts floating object and impurity big in bitter,
The salt content for making bitter is 3-15 g/l, and Oil repellent is 1.0-4.0 mg/litres, and nitrogen content is 3-20 mg/litres, phosphorus content
For 0.1-3.5 mg/litres, suspension is 15-30 mg/litres.
To carry out adsorption treatment in stalk straw screen or mat of the bitter through intercept process Jing Guo grid pond, in grid pond placement by
The straw screen or mat of maize straw braiding, is provided with one layer of alumina layer in straw screen or mat, the ratio surface of aluminum oxide is 50-300 rice2/ gram, hole body
Product is 0.2-1.2 mls/g, and the mass ratio of stalk straw screen or mat and alumina layer is 1:In (0.1-10), bitter and grid pond
Straw screen or mat fully contacts, and the planktonic organisms such as the pollutants such as the organic matter in bitter, nitrogen, phosphorus, silt and algae are tentatively blocked
Cut, filter, adsorbing, settling, degraded, and bitter is also contacted with aluminum oxide, absorption which part nitrogen, phosphorus and fluorine etc.,
The salt content of obtained absorption water is 2.9-14.8 g/l, and Oil repellent be 0.4-1.5 mg/litres, nitrogen content for 0.2-4 milligrams/
Rise, phosphorus content is 0.02-0.6 mg/litres, and suspension content can be 5-10 mg/litres.
Water will be adsorbed to be sent into the coagulating basin of high density softening depositing reservoir and add PAC coagulant and white lime flocculation aid mixes
The suspension in water inlet is removed under the stirring of coagulation apparatus after conjunction, is then fed into softening pond and adds lime, sodium carbonate to enter
Row softening, temporary hardness and part permanent hardness are removed, is recycled after caused partial sludge concentration, another part leads to
Sludge circulation inside and outside sludge refluxing apparatus is crossed, the flocculation tank of high density softening depositing reservoir is sent into, makes returned sludge and absorption
Water forms " the muddy water floccule body " of high concentration again, sludge is had very strong adsorption bridging and the volume effect of sweeping, is fully flocculating
Afterwards, the larger molecular organicses adsorbed in water are adsorbed and precipitated, the sludge after adsorbing again is sent into sloping plate deposition concentration basin
Precipitated, the softening clarifying treatment condition and coagulant, flocculation aid, lime and sodium carbonate of control high density softening depositing reservoir
Addition, can cause softened water salt content be 2.5-14 g/l.
The softened water feeding high rate activated sand filters of TGV are further removed into suspended particulate substance, by the sand filtration obtained by sand filtration
The salt content of water is 2.5-14 g/l.
Sand leaching water is subjected to secondary filter processing by cartridge filter, it is 2.5-14 g/l of refined filtration water to obtain salt content.
HEDP antisludging agents are added in refined filtration water, carrying out film thickening filtration by high performance membrane thickening filtration device handles desalination, film concentration
5-45 DEG C of the temperature of filtration treatment, Stress control obtain the low-solids water and contain that salt content is 0.2-2 g/l at 0.3-2.2 MPas
Salt amount is 5-42 g/l of concentrated water.Less salt aquatic products water enters production pond, and another part then contains the concentrated water of remaining salinity,
This partial moisture two-way, concentrated water progress salt manufacturing processing all the way, concentrated water feeding high performance membrane concentration systems, continue cycling through processing all the way,
Such technique can reduce the usage quantity of film and save energy consumption.
The detection of salt content is carried out to low-solids water, if salt content concentration is less than 1.5g/l, brackish water and softened water are existed
Blend and mixing is blent in pond, the final brackish water water outlet for obtaining salt content in 1.5-2g/l.
Plantation of the water brackish water for economical salt-tolerant plant on salt-soda soil will be produced to irrigate, the salt tolerant of selected plantation is planted
Thing is that the obvious salt-tolerant plant of survival rate economic benefit more than 85% is (sweet in the environment that salt content concentration is 0.5-5g/l
Grass, caragana microphylla, jujube tree and diversiform-leaved poplar etc.).
Embodiment
Bitter processing is carried out according to the following condition of abovementioned steps:
One layer of alumina layer is provided with straw screen or mat, alumina layer is the oxidation by the cm of metal grill fixed diameter 2
Aluminium bead, the ratio surface of aluminum oxide is 151 meters2/ gram, pore volume is 0.45 ml/g, the quality of stalk straw screen or mat and alumina layer
Than for 1:7, the bitter of average every gram of alumina layer processing per second is 1 kilogram.
The flow of inlet water of bitter is 27.8 meters3/ hour, pH value 8.2, electrical conductivity are 12.2 μ s/cm, and salt content is
8.17 g/l, the water flow of low-solids water is 19.8 meters3/ hour, pH value 7.4, electrical conductivity are 3.4 μ s/cm, low-solids water
Salt content is 1.88 g/l.
Produce water brackish water and be used for Glycyrrhiza Uralensis plantation irrigation, radix glycyrrhizae growing way is vigorous, and survival rate is more than 93%, economy effect
Beneficial high, ecological benefits are obvious, and the life-span of high performance membrane thickening filtration device film is 5 years.
Comparative example
Comparative example with the step of embodiment and condition is identical, difference is bitter without adsorption treatment, but
Softening clarifying treatment is directly carried out after intercept process.
The flow of inlet water of bitter is 27.8 meters3/ hour, pH value 8.2, electrical conductivity are 12.2 μ s/cm, and salt content is
8.17 g/l, the water flow of low-solids water is 16.3 meters3/ hour, pH value 7.4, electrical conductivity are 3.4 μ s/cm, low-solids water
Salt content is 1.88 g/l, and the life-span of high performance membrane thickening filtration device film is 3 years.
The adsorption treatment of the stalk straw screen or mat by the present invention, low-solids water are can be seen that from the comparison of embodiment and comparative example
Water flow improve, salt content reduces, and reduces softening depositing reservoir, sand filter, accurate filter and film thickening filtration
The treating capacity of device, improve the life-span of high performance membrane thickening filtration device film.
Claims (10)
1. a kind of processing method of salt-soda soil bitter, this method include:
A, bitter is sent into grid pond and adsorption treatment is carried out using stalk straw screen or mat, obtain adsorbing water;Wherein, the Stalk
Alumina layer is fixed with curtain, the mass ratio of the stalk straw screen or mat and alumina layer is 1:(0.1-10);
B, gained absorption water in step a is subjected to softening clarifying treatment, obtains sludge and softened water;
C, gained softened water in step b is subjected to sand filtration processing, obtains sand leaching water;
D, gained sand leaching water in step c is subjected to secondary filter processing using accurate filter, obtains refined filtration water;
E, gained refined filtration water in step d is subjected to film thickening filtration processing, obtains concentrated water and low-solids water;
Wherein, the Oil repellent of bitter described in step a is 1.0-4.0 mg/litres, and nitrogen content is 3-20 mg/litres, phosphorus content
For 0.1-3.5 mg/litres, the Oil repellent of gained absorption water be 0.4-1.5 mg/litres in step a, nitrogen content for 0.2-4 milligrams/
Rise, phosphorus content is 0.02-0.6 mg/litres.
2. the processing method of salt-soda soil bitter according to claim 1, wherein, oxygen in alumina layer described in step a
The ratio surface for changing aluminium is 50-300 rice2/ gram, pore volume is 0.2-1.2 mls/g;
Stalk described in step a in stalk straw screen or mat is selected from rice straw, potato class stalk, rape stalk, cotton stalk, sugarcane
At least one of stalk, maize straw, straw and reed straw.
3. the processing method of salt-soda soil bitter according to claim 1, wherein, gained at least part step b is dirty
Mud is back to use in the softening clarifying treatment and/or sent out after being dehydrated the processing system of salt-soda soil bitter.
4. the processing method of salt-soda soil bitter according to claim 1, wherein, the saliferous of bitter described in step a
Measure as 3-15 g/l;The salt content of gained absorption water is 2.9-14.8 g/l in step a;Gained softened water contains in step b
Salt amount is 2.5-14 g/l;The salt content of gained sand leaching water is 2.5-14 g/l in step c;Gained refined filtration water in step d
Salt content is 2.5-14 g/l;The salt content of gained concentrated water is 5-42 g/l in step e, and the salt content of gained low-solids water is
0.2-2 g/l;Wherein, the salt in the salt content includes all soluble inorganic salts in water.
5. the processing method of salt-soda soil bitter according to claim 1, wherein, gained at least part step e is dense
Water, which is sent into salt making apparatus, carries out film thickening filtration processing described in salt manufacturing processing and/or progress step e;
Gained low-solids water in step e is sent into production pond;If the salt content of the low-solids water is less than 1.5 g/l, it is sent into and hooks
It is watered pond to mix with gained softened water at least part step b, it is saline and alkaline obtains the brackish water submitting that salt content is 1.5-2 g/l
The processing system of ground bitter;If the salt content of the low-solids water is 1.5-2 g/l, sent out directly as brackish water saline and alkaline
The processing system of ground bitter.
6. a kind of processing system of salt-soda soil bitter, the system include:Balancing tank, grid pond, softening depositing reservoir, sand filtration
Pond, accurate filter and film thickening filtration device;
The balancing tank is provided with water inlet and bitter outlet, and the grid pond is provided with stalk straw screen or mat, bitter entrance
With absorption water out, the softening depositing reservoir is provided with absorption water inlet, softening depositing reservoir sludge outlet and softening water out, institute
State sand filter be provided with sand filter softening water inlet and sand filtration water out, the accurate filter be provided with sand filtration water inlet and essence
Filtered water outlet, the film thickening filtration device are provided with refined filtration water inlet, concentrated water outlet and less salt water out;Wherein, the straw
Alumina layer is fixed with stalk straw screen or mat, the mass ratio of the stalk straw screen or mat and alumina layer is 1:(0.1-10);
The bitter outlet of the balancing tank connects with the bitter entrance of grid pond, and the grid pond adsorbs water out and soft
Change the absorption water inlet connection of depositing reservoir, the softening water out of the softening depositing reservoir connects with sand filter softening water inlet, institute
The sand filtration water out of sand filter is stated to connect with the sand filtration water inlet of accurate filter, the refined filtration water out of the accurate filter and
The refined filtration water inlet connection of film thickening filtration device.
7. the processing system of salt-soda soil bitter according to claim 6, wherein, the ratio of aluminum oxide in the alumina layer
Surface is 50-300 rice2/ gram, pore volume is 0.5-1.5 mls/g;
Stalk in the stalk straw screen or mat is selected from rice straw, potato class stalk, rape stalk, cotton stalk, sugarcane stalk, jade
At least one of rice stalk, straw and reed straw.
8. the processing system of salt-soda soil bitter according to claim 6, wherein, the softening depositing reservoir is also included successively
Coagulating basin, softening pond, flocculation tank and the sloping plate deposition concentration basin of connection.
9. the processing system of salt-soda soil bitter according to claim 6, wherein, the softening depositing reservoir also includes sludge
Storage pool, sludge dewatering equipment and sludge refluxing apparatus;
The sewage sludge storage pond includes storage pool sludge inlet and storage pool sludge outlet, and the sludge dewatering equipment includes dewaterer
Sludge inlet, dewatered sludge outlet and water out, the sludge refluxing apparatus is provided with returned sludge entrance and returned sludge goes out
Mouthful, the softening depositing reservoir is additionally provided with softening depositing reservoir sludge inlet;
The storage pool sludge inlet connects with softening depositing reservoir sludge outlet, the storage pool sludge outlet and dewaterer sludge
Entrance connects, and the returned sludge entrance connects with softening depositing reservoir sludge outlet, the returned sludge outlet and softening clarification
Pond sludge inlet connection.
10. the processing system of salt-soda soil bitter according to claim 6, wherein, the processing of the salt-soda soil bitter
System also includes salt making apparatus;The concentrated water outlet of the film thickening filtration device connects with the concentrated water entrance of the salt making apparatus,
And/or the concentrated water outlet of the film thickening filtration device connects with the refined filtration water inlet of the film thickening filtration device;
The processing system of salt-soda soil bitter also includes production pond and blends pond;The production pond is provided with production pond low-solids water
Entrance, production pond less salt water out and production pond brackish water outlet, it is described blend pond be provided with blend pond softening water inlet,
Blend pond less salt water inlet and blend pond brackish water outlet;The production pond less salt water inlet fills with the film thickening filtration
The low-solids water outlet put, the production pond less salt water out connects with the pond less salt water inlet of blending, described to blend
Pond softens the softened water outlet of water inlet and the softening depositing reservoir.
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