CN107652511A - A kind of insulation material of the agricultural booth side skirt film based on polyethylene - Google Patents

A kind of insulation material of the agricultural booth side skirt film based on polyethylene Download PDF

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Publication number
CN107652511A
CN107652511A CN201710916236.3A CN201710916236A CN107652511A CN 107652511 A CN107652511 A CN 107652511A CN 201710916236 A CN201710916236 A CN 201710916236A CN 107652511 A CN107652511 A CN 107652511A
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CN
China
Prior art keywords
parts
insulation material
polyethylene
side skirt
film based
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Pending
Application number
CN201710916236.3A
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Chinese (zh)
Inventor
徐磊
蒋希芝
柳军
夏礼如
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Jiangsu Academy of Agricultural Sciences
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Jiangsu Academy of Agricultural Sciences
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Priority to CN201710916236.3A priority Critical patent/CN107652511A/en
Publication of CN107652511A publication Critical patent/CN107652511A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G9/00—Cultivation in receptacles, forcing-frames or greenhouses; Edging for beds, lawn or the like
    • A01G9/14—Greenhouses
    • A01G9/1438—Covering materials therefor; Materials for protective coverings used for soil and plants, e.g. films, canopies, tunnels or cloches
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02—Organic and inorganic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/02—Halogenated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/098—Metal salts of carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04—Homopolymers or copolymers of ethene
    • C08J2323/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/38—Boron-containing compounds
    • C08K2003/387—Borates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/16—Applications used for films
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
    • Y02A40/25—Greenhouse technology, e.g. cooling systems therefor

Abstract

The invention discloses a kind of insulation material of agricultural booth side skirt film based on polyethylene and a kind of preparation method for the insulation material for preparing the above-mentioned agricultural booth side skirt film based on polyethylene, the insulation material to include the raw material of following parts by weight：65 80 parts of polyethylene, 4,424 parts of OBSHs, 13 parts of zinc acetate, 26 parts of nano titanium oxide, 48 parts of dripless agent, 27 parts of fire retardant, 5 10 parts of antioxidant, wherein the antioxidant is а tocopherols.The advantages that insulation material provided by the present invention has from heavy and light, high insulating effect, and service life is long, disclosure satisfy that the requirement of agricultural production.

Description

A kind of insulation material of the agricultural booth side skirt film based on polyethylene
Technical field
The present invention relates to a kind of insulation material of the agricultural booth side skirt film based on polyethylene, belongs to the life of plastic sheeting product Production field.
Background technology
Because the northern area of China winter climate is cold, it is not suitable for plant growth, in order to boost agricultural yield, reaches precocious Volume increase, the purpose of abundant common people's dining table, the effect of warmhouse booth are particularly significant.For a long time, warmhouse booth covering material uses Cotton-wadded quilt, felt etc., with the development of polymer material science, insulation material, which updates, to be accelerated, and has engendered that polyethylene covers Film, polyvinyl chloride overlay film, ethylene-vinyl acetate copolymer composite membrane etc., but these covering materials generally conduct oneself with dignity it is larger, it is right Temperature change is sensitive, and heat insulating ability is poor, and service life is shorter.Particularly greenhouse side skirt film, it is right because it is often crimped operation Pull resistance, the requirement of resistance to ag(e)ing are especially harsh, and common greenhouse side skirt membrane material heat insulating ability quality itself is not on the market at present One, after a particular period of use, material is necessarily damaged in itself, and its light transmission, heat-insulating property etc. are all notable Decline, studies have found that, winter greenhouse have more than 60% heat energy be due to side skirt film heat-proof quality difference and scatter and disappear, therefore In order to provide the greenhouse side skirt membrane material of a kind of lightweight, tension, good heat insulating, the invention provides a kind of polyethylene foam material Material, has preferable pull resistance and heat-insulating property, the heat that can effectively reduce inside greenhouse scatters and disappears, and lifts the heat insulating ability of facility Energy.
The content of the invention
The defects of purpose of the present invention is for agricultural booth side skirt membrane material in the prior art, there is provided one kind is based on poly- second The insulation material of the agricultural booth side skirt film of alkene, there is preferable pull resistance and heat-insulating property, service life length, can effectively drop Heat inside low greenhouse scatters and disappears, and improves the heat-insulating property of facility.
The present invention is achieved through the following technical solutions：
A kind of insulation material of the agricultural booth side skirt film based on polyethylene, include the raw material of following parts by weight：Polyethylene 65-80 parts, 4,4- OBSH 2-4 parts, zinc acetate 1-3 parts, nano titanium oxide 2-6 parts, dripless agent 4-8 parts, resistance Fire agent 2-7 parts, antioxidant 5-10 parts.
Wherein described 4,4- OBSHs are more preferably 2.5-3,5 parts, and zinc acetate is more preferably 1.5-2.5 part；
Wherein described dripless agent is ethylene oxide adduct, sorbitan fatty acid ester, Vinlub 73 Etc. one or more therein；
Wherein described fire retardant is alkylphosphonate, aryl phosphate, dicyclopentadiene, methylene bromide, magnesium hydroxide, boron One or more in hydrochlorate etc.；
Wherein described antioxidant is alpha-tocopherol.
The present invention also provides a kind of preparation method for preparing the above-mentioned insulation material for agricultural booth side skirt film, and step is such as Under：At a temperature of 170 DEG C -210 DEG C, first polyethylene and 4,4- OBSHs, zinc acetate are sufficiently mixed, add and receive Rice titanium dioxide, dripless agent, fire retardant, less than 100 DEG C are cooled to after high speed shear is well mixed, adds antioxidant, again Extruded, stretched after stirring, that is, obtain finished product.
Insulation material main body provided by the present invention for agricultural booth side skirt film is polyethylene foamed, with the market its His expanded material is different, and insulation material of the present invention is not easy to lose, the present invention is by adjusting the species of raw material and containing from heavy and light Amount so that abscess is fine and closely woven, stably, not only causes material to have good toughness in itself, also effectively reduces the heat conduction system of material Number, substantially increases heat insulation effect, and in addition, insulation material provided by the present invention also has good water proof, uvioresistant Effect, service life length, and process simply, cost is cheap.
Embodiment
The insulation material of the present invention for agricultural booth side skirt film is carried out in detail below by specific embodiment Description, following examples can not be limited the scope of the invention with this simply to illustrate that technical scheme, Conversion made by with good grounds essence of the present invention should all be included within protection scope of the present invention.
Embodiment 1：
A kind of insulation material of the agricultural booth side skirt film based on polyethylene, each component is by weight：65 parts of polyethylene, 4,4- 2 parts of OBSHs, 2 parts of zinc acetate, 3.5 parts of nano titanium oxide, 5.5 parts of ethylene oxide adduct, borate 3 Part, 8 parts of alpha-tocopherol.
First polyethylene and 4,4- OBSHs, zinc acetate are sufficiently mixed at 170 DEG C, add nano-silica Change titanium, ethylene oxide adduct and borate, high speed shear to be well mixed, α-fertility is added when temperature is down to below 100 DEG C Phenol, extruded, stretched after being again stirring for uniformly, that is, obtain finished product.
Embodiment 2：
70 parts of polyethylene, 4,4- 3.5 parts of OBSHs, 1.7 parts of zinc acetate, 3 parts of nano titanium oxide, polyoxy second 5 parts of alkene monolaurate, 4.5 parts of methylene bromide, 7.5 parts of а-tocopherol.
First polyethylene and 4,4- OBSHs, zinc acetate are sufficiently mixed at 175 DEG C, add nano-silica Change titanium, Vinlub 73 and methylene bromide, high speed shear to be well mixed, added when temperature is down to below 100 DEG C Alpha-tocopherol, extruded, stretched after being again stirring for uniformly, that is, obtain finished product.
Embodiment 3：
80 parts of polyethylene, 4,4- 4 parts of OBSHs, 3 parts of zinc acetate, 5.5 parts of nano titanium oxide, D-sorbite 7 parts of acid anhydride fatty acid ester, 7 parts of methylene bromide, 9 parts of alpha-tocopherol.
First polyethylene and 4,4- OBSHs, zinc acetate are sufficiently mixed at 175 DEG C, add nano-silica Change titanium, sorbitan fatty acid ester and methylene bromide, high speed shear to be well mixed, added when temperature is down to below 100 DEG C Alpha-tocopherol, extruded, stretched after being again stirring for uniformly, that is, obtain finished product.
Comparative example：
65 parts of polyethylene, 3.5 parts of nano titanium oxide, 5.5 parts of ethylene oxide adduct, 3 parts of borate, age resistor 40208 parts.
Product is prepared according to a conventional method.
Performance test will be carried out according to embodiment 1-3 and the preparation-obtained membrane material of comparative example, while also commercially It has purchased conventional greenhouse PVC overlay films and carry out contrast test.
1st, tensile strength
The tensile strength of each test sample is detected, each sample Sampling Area is 30mmX200mm, is fixed on drawing Between force tester fixture, untill sample fracture, its maximum stretching force born is calculated, as a result as shown in table 1：
The insulation material quantitative measurement result of table 1.
Embodiment 1 Embodiment 2 Embodiment 3 Comparative example PVC overlay films
Intensity (kN/m2) 20.8 22.1 19.7 18.4 18.2
From the testing result described in table 1, three kinds of side skirt membrane materials provided by the present invention are provided with preferably anti- Tensile strength, wherein it is especially best with the membrane material stretch-proof effect prepared by embodiment 2, it disclosure satisfy that in agricultural production to greenhouse The requirement of side skirt film-strength.
2nd, outdoor heat insulation effect
With it is a piece of experimental field in build the consistent experiment greenhouse of 5 specifications, respectively by 5 kinds of materials to be tested according to same Mounting means is installed, and duration of experiment is 24 hours, and greenhouse middle position is provided with mercurial thermometer, is remembered per half an hour A temperature of shed is recorded, when experiment is carried out, outdoor 10.6 DEG C of maximum temperature, 1.2 DEG C of minimum temperature, 3.8 DEG C of mean temperature, detection As a result it is as follows：
Table 2 is incubated result of the test outside Room
Sequence number Test sample Maximum temperature (DEG C) Minimum temperature (DEG C) Mean temperature (DEG C)
1 Embodiment 1 37.9 9.3 20.2
2 Embodiment 2 38.2 7.4 19.8
3 Embodiment 3 37.3 7.6 18.2
4 Comparative example 33.8 5.9 14.7
5 PVC overlay films 28.4 4.3 13.4
Outdoor temperature is higher between experiment periods, and experimental result tool is had a certain impact, but comes from the data described in table 2 See, greenhouse side skirt membrane material provided by the present invention can effectively keep the temperature in greenhouse, mean temperature with to photograph Than improving 10 DEG C or so, disclosure satisfy that crop growth demand.

Claims (6)

  1. A kind of 1. insulation material of the agricultural booth side skirt film based on polyethylene, it is characterised in that the insulation material include with The raw material of lower parts by weight：Polyethylene 65-80 parts, 4,4- OBSH 2-4 parts, zinc acetate 1-3 parts, nano titanium oxide 2-6 parts, dripless agent 4-8 parts, fire retardant 2-7 parts, antioxidant 5-10 parts.
  2. 2. insulation material according to claim 1, it is characterised in that 4, the 4- OBSHs are further preferred For 2.5-3,5 parts, zinc acetate is more preferably 1.5-2.5 parts.
  3. 3. insulation material according to claim 2, it is characterised in that the dripless agent is ethylene oxide adduct, sorbose The one or more therein such as alcohol acid anhydride fatty acid ester, Vinlub 73.
  4. 4. insulation material according to claim 2, it is characterised in that the fire retardant is alkylphosphonate, aryl phosphate One or more in ester, dicyclopentadiene, methylene bromide, magnesium hydroxide, borate etc..
  5. 5. insulation material according to claim 2, it is characterised in that the antioxidant is alpha-tocopherol.
  6. 6. the preparation method of the insulation material of the agricultural booth side skirt film based on polyethylene described in claim any one of 1-5, At a temperature of 170 DEG C -210 DEG C, first polyethylene and 4,4- OBSHs, zinc acetate are sufficiently mixed, add nanometer Titanium dioxide, dripless agent, fire retardant, less than 100 DEG C are cooled to after high speed shear is well mixed, antioxidant is added, stirs again Extruded, stretched after mixing uniformly, that is, obtain finished product.
CN201710916236.3A 2017-09-30 2017-09-30 A kind of insulation material of the agricultural booth side skirt film based on polyethylene Pending CN107652511A (en)

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CN201710916236.3A CN107652511A (en) 2017-09-30 2017-09-30 A kind of insulation material of the agricultural booth side skirt film based on polyethylene

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109006052A (en) * 2018-05-07 2018-12-18 浙江工贸职业技术学院 A kind of agricultural booth composite plastic film and preparation method thereof
CN110483964A (en) * 2018-05-15 2019-11-22 湖北文理学院 A kind of modified expanded polylactic acid plate and preparation method thereof
CN111605279A (en) * 2020-06-30 2020-09-01 韩克军 Constant-temperature polyethylene composite material and production method thereof
CN111716855A (en) * 2020-06-30 2020-09-29 韩克军 Self-cleaning polyethylene composite material and production method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101628998A (en) * 2009-07-28 2010-01-20 上海三承高分子材料科技有限公司 Environment friendly low calorific value and heat preservation master batch, membrane master batch and composite membrane
CN102934594A (en) * 2012-11-23 2013-02-20 青岛供八方塑料有限公司 Constant-temperature self-cleaning agricultural greenhouse film and production method thereof
CN103059371A (en) * 2011-10-24 2013-04-24 滁州格美特科技有限公司 Modified polyethylene film material and preparation method thereof
CN104401076A (en) * 2014-11-25 2015-03-11 苏州九鼎珍珠棉有限公司 HDPE(high-density polyethylene) membrane composited by high foaming of LDPE(Low-Density Polyethylene) and preparation method of HDPE membrane
CN106674695A (en) * 2016-12-29 2017-05-17 福州永鑫塑料包装用品有限公司 Novel high-polymer plastic film and preparation technique thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101628998A (en) * 2009-07-28 2010-01-20 上海三承高分子材料科技有限公司 Environment friendly low calorific value and heat preservation master batch, membrane master batch and composite membrane
CN103059371A (en) * 2011-10-24 2013-04-24 滁州格美特科技有限公司 Modified polyethylene film material and preparation method thereof
CN102934594A (en) * 2012-11-23 2013-02-20 青岛供八方塑料有限公司 Constant-temperature self-cleaning agricultural greenhouse film and production method thereof
CN104401076A (en) * 2014-11-25 2015-03-11 苏州九鼎珍珠棉有限公司 HDPE(high-density polyethylene) membrane composited by high foaming of LDPE(Low-Density Polyethylene) and preparation method of HDPE membrane
CN106674695A (en) * 2016-12-29 2017-05-17 福州永鑫塑料包装用品有限公司 Novel high-polymer plastic film and preparation technique thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109006052A (en) * 2018-05-07 2018-12-18 浙江工贸职业技术学院 A kind of agricultural booth composite plastic film and preparation method thereof
CN110483964A (en) * 2018-05-15 2019-11-22 湖北文理学院 A kind of modified expanded polylactic acid plate and preparation method thereof
CN111605279A (en) * 2020-06-30 2020-09-01 韩克军 Constant-temperature polyethylene composite material and production method thereof
CN111716855A (en) * 2020-06-30 2020-09-29 韩克军 Self-cleaning polyethylene composite material and production method thereof

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