CN107641894A - Corrosion-resistant Quick Response Code braider steel fibre kernmantle - Google Patents
Corrosion-resistant Quick Response Code braider steel fibre kernmantle Download PDFInfo
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- CN107641894A CN107641894A CN201710789528.5A CN201710789528A CN107641894A CN 107641894 A CN107641894 A CN 107641894A CN 201710789528 A CN201710789528 A CN 201710789528A CN 107641894 A CN107641894 A CN 107641894A
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- response code
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Abstract
The invention discloses a kind of corrosion-resistant Quick Response Code braider steel fibre kernmantle, corrosion-resistant Quick Response Code braider steel fibre kernmantle is formed by steel fibre braiding, the surface of steel fibre is provided with corrosion resistant coating layer, the corrosion resistant coating layer is formed by dry after the surface coating corrosion-resistant of the steel fibre, and the corrosion resistant coating is prepared by following steps：1) organic siliconresin, epoxy resin, castor oil, trbasic zinc phosphate, cyclohexanone, cobalt naphthenate, alumina silicate fibre, ethylene glycol is heat-treated so that component I is made；2) chlorinated rubber, mannitol, ethylene-vinyl acetate emulsion, expanded graphite, nano-cerium oxide, nano silicon oxide, propane diols is heat-treated so that component II is made；3) under pressure, the component I is mixed with component II so that the corrosion resistant coating is made.The corrosion-resistant Quick Response Code braider steel fibre kernmantle has excellent decay resistance.
Description
Technical field
The present invention relates to motor, in particular it relates to a kind of corrosion-resistant Quick Response Code braider steel fibre kernmantle.
Background technology
Quick Response Code only needs to scan in daily life two-dimentional in many cases as a kind of simply and easily technology
Code can be operated a lot, thus its use range is more and more extensive, and the field used is also more and more.And Quick Response Code conduct
A kind of pattern, its carrier is also a lot, and yarn fabric is as the necessary article in daily life, although application field is extremely wide, it is made
For Quick Response Code carrier when often because Quick Response Code is pattern, thus need to be printed on fabric by printing, and the figure of Quick Response Code
Case is also often changing, thus needs often to change the mould of printing, so as to bring great loss to production, greatly increases life
Produce cost.And be knitted on fabric then often because two-dimentional code line discoloration change it is complex so that in practical operation often
Braider is easily damaged, especially chain wheel rope long term wear, easily causes the damage of chain wheel rope, so as to greatly increase maintenance into
This.
The content of the invention
It is an object of the invention to provide a kind of corrosion-resistant Quick Response Code braider steel fibre kernmantle, the corrosion-resistant Quick Response Code is compiled
Loom steel fibre kernmantle has excellent decay resistance.
To achieve these goals, the invention provides a kind of corrosion-resistant Quick Response Code braider steel fibre kernmantle, corrosion resistant
Erosion Quick Response Code braider steel fibre kernmantle is formed by steel fibre braiding, and the surface of steel fibre is provided with corrosion resistant coating layer, institute
Stating corrosion resistant coating layer is formed by dry after the surface coating corrosion-resistant of the steel fibre, the corrosion resistant coating
It is prepared by following steps：
1) by organic siliconresin, epoxy resin, castor oil, trbasic zinc phosphate, cyclohexanone, cobalt naphthenate, alumina silicate fibre, second two
Alcohol is heat-treated so that component I is made；
2) by chlorinated rubber, mannitol, ethene-vinyl acetate emulsion, expanded graphite, nano-cerium oxide, nano silicon oxide,
Propane diols is heat-treated so that component II is made；
3) under pressure, the component I is mixed with component II so that the corrosion resistant coating is made.
In the above-mentioned technical solutions, the present invention is resistance to be formed by brushing specific corrosion resistant coating on kernmantle shell
Etching ground layer, there is excellent anticorrosion effect by the combination of each component dope layer in corrosion resistant coating,
In particular for the corrosion of wet environment, and then play a part of protecting kernmantle, and then cause the kernmantle to be applied to humidity
Environment.
Other features and advantages of the present invention will be described in detail in subsequent specific embodiment part.
Embodiment
The embodiment of the present invention is described in detail below.It is it should be appreciated that described herein specific
Embodiment is merely to illustrate and explain the present invention, and is not intended to limit the invention.
The invention provides a kind of corrosion-resistant Quick Response Code braider steel fibre kernmantle, the corrosion-resistant Quick Response Code braider steel
Fibrage rope is formed by steel fibre braiding, and the surface of steel fibre is provided with corrosion resistant coating layer, and the corrosion resistant coating layer is
By after the surface coating corrosion-resistant of the steel fibre drying form, the corrosion resistant coating by following steps prepare and
Into：
1) by organic siliconresin, epoxy resin, castor oil, trbasic zinc phosphate, cyclohexanone, cobalt naphthenate, alumina silicate fibre, second two
Alcohol is heat-treated so that component I is made；
2) by chlorinated rubber, mannitol, ethene-vinyl acetate emulsion, expanded graphite, nano-cerium oxide, nano silicon oxide,
Propane diols is heat-treated so that component II is made；
3) under pressure, the component I is mixed with component II so that the corrosion resistant coating is made.
In above-mentioned steps 1) in, the dosage of each material can select in wide scope, but in order that kernmantle has
More excellent anticorrosive performance, it is preferable that in step 1), organic siliconresin, epoxy resin, castor oil, trbasic zinc phosphate, cyclohexanone,
Cobalt naphthenate, alumina silicate fibre, the weight ratio of ethylene glycol are 10：2-5：11-15：0.8-1.2：5-10：1-1.5：0.1-0.3：
10-15。
In above-mentioned steps 1) in, be heat-treated condition can select in wide scope, but in order that kernmantle has
More excellent anticorrosive performance, it is preferable that in step 1), heat treatment meets following condition：Temperature is 85-95 DEG C, time 4-
6h, and carried out in the case where rotating speed is 1000-1500rpm stirring condition.
In above-mentioned steps 1) in, the concrete composition and processing mode of organic siliconresin can select in wide scope,
But in order that kernmantle has more excellent anticorrosive performance, it is preferable that in step 1), organic siliconresin is by by methyl
Trichlorosilane, dimethyldichlorosilane, phenyl trichlorosilane, diphenyl dichlorosilane and dichloromethyl phenylsilane are according to 1：1-
1.2：0.4-0.6：0.8-1.2：0.1-0.4 weight ratio is processed 2-5h under conditions of vacuum condition, 150-180 DEG C and formed.
In above-mentioned steps 2) in, the dosage of each material can select in wide scope, but in order that kernmantle has
More excellent anticorrosive performance, it is preferable that in step 2), chlorinated rubber, mannitol, ethene-vinyl acetate emulsion, expansion stone
Ink, nano-cerium oxide, nano silicon oxide, the weight ratio of propane diols are 10：18-22：5-10：0.1-0.4：0.05-0.15：
0.05-0.15：11-15.
In above-mentioned steps 2) in, the condition of heat treatment in wide scope to select, but in order that kernmantle has more
Excellent anticorrosive performance, it is preferable that in step 2), heat treatment meets following condition：Temperature is 65-75 DEG C, time 4-6h,
And carried out in the case where rotating speed is 1000-1500rpm stirring condition.
In above-mentioned steps 2) in, the average grain diameter of trbasic zinc phosphate in wide scope to select, but in order that kernmantle has
There is more excellent anticorrosive performance, it is preferable that in step 2), nano-cerium oxide, the average grain diameter of nano silicon oxide are 5-10nm.
In above-mentioned steps 2) in, the weight average molecular weight of chlorinated rubber in wide scope to select, but in order that braiding
Rope has more excellent anticorrosive performance, it is preferable that in step 2), the weight average molecular weight of chlorinated rubber is 3000-5000.
In above-mentioned steps 3) in, the dosage of each material can select in wide scope, but in order that kernmantle has
More excellent anticorrosive performance, it is preferable that in step 3), component I and component II weight ratio is 2：0.6-0.8.
In above-mentioned steps 3) in, the condition of mixing can select in wide scope, but in order that kernmantle has more
Excellent anticorrosive performance, it is preferable that in step 3), mixing meets following condition：Temperature is 45-55 DEG C, time 2-3h, and
And carried out in the case where rotating speed is 1000-1500rpm stirring condition.
The present invention will be described in detail by way of examples below.
Preparation example 1
By methyl trichlorosilane, dimethyldichlorosilane, phenyl trichlorosilane, diphenyl dichlorosilane and aminomethyl phenyl two
Chlorosilane is according to 1：1.1：0.5：0.9：0.3 weight ratio processes 3h under conditions of vacuum condition, 170 DEG C and organosilicon tree is made
Fat A1.
Preparation example 2
By methyl trichlorosilane, dimethyldichlorosilane, phenyl trichlorosilane, diphenyl dichlorosilane and aminomethyl phenyl two
Chlorosilane is according to 1：1：0.4：0.8：0.1 weight ratio processes 2h under conditions of vacuum condition, 150 DEG C and organic siliconresin is made
A1。
Preparation example 3
By methyl trichlorosilane, dimethyldichlorosilane, phenyl trichlorosilane, diphenyl dichlorosilane and aminomethyl phenyl two
Chlorosilane is according to 1：1.2：0.6：1.2：0.4 weight ratio processes 5h under conditions of vacuum condition, 180 DEG C and organosilicon tree is made
Fat A1.
Embodiment 1
Corrosion-resistant Quick Response Code braider steel fibre kernmantle B1：
The corrosion-resistant Quick Response Code braider steel fibre kernmantle is formed by steel fibre braiding, and the surface of steel fibre is provided with resistance to
Etching ground layer, the corrosion resistant coating layer are formed by dry after the surface coating corrosion-resistant of the steel fibre,
The corrosion resistant coating is prepared by following steps：
1) by organic siliconresin A1, epoxy resin, castor oil, trbasic zinc phosphate, cyclohexanone, cobalt naphthenate, alumina silicate fibre, second
Glycol is according to 10：4：13：1.0：8：1.3：0.2：13 weight ratio be heat-treated (temperature be 90 DEG C, time 5h, and
Rotating speed is to be carried out under 1300rpm stirring condition) with obtained component I；
2) by chlorinated rubber (weight average molecular weight 4000), mannitol, ethene-vinyl acetate emulsion, expanded graphite, nanometer
Cerium oxide (average grain diameter 8nm), nano silicon oxide (average grain diameter 8nm), propane diols are according to 10：20：8：0.3：0.09：
0.08：13 weight ratio be heat-treated (temperature be 70 DEG C, time 5h, and rotating speed be 120rpm stirring condition under
Carry out) with obtained component II；
3) under pressure, by component I and component II according to 2：0.7 weight ratio mixed (temperature be 50 DEG C,
Time is 2.5h, and is carried out in the case where rotating speed is 1300rpm stirring condition) with obtained corrosion resistant coating.
Embodiment 2
Corrosion-resistant Quick Response Code braider steel fibre kernmantle B2：
The corrosion-resistant Quick Response Code braider steel fibre kernmantle is formed by steel fibre braiding, and the surface of steel fibre is provided with resistance to
Etching ground layer, the corrosion resistant coating layer are formed by dry after the surface coating corrosion-resistant of the steel fibre,
The corrosion resistant coating is prepared by following steps：
1) by organic siliconresin A2, epoxy resin, castor oil, trbasic zinc phosphate, cyclohexanone, cobalt naphthenate, alumina silicate fibre, second
Glycol is according to 10：2：11：0.8：5：1：0.1：10 weight ratio is heat-treated, and (temperature is 85 DEG C, time 4h, and is being turned
Speed is to be carried out under 1000rpm stirring condition) with obtained component I；
2) by chlorinated rubber (weight average molecular weight 3000), mannitol, ethene-vinyl acetate emulsion, expanded graphite, nanometer
Cerium oxide (average grain diameter 5nm), nano silicon oxide (average grain diameter 5nm), propane diols are according to 10：18：5：0.1：0.05：
0.05：11 weight ratio be heat-treated (temperature be 65 DEG C, time 4h, and rotating speed be 1000rpm stirring condition under
Carry out) with obtained component II；
3) under pressure, by component I and component II according to 2：0.6 weight ratio mixed (temperature be 45 DEG C,
Time is 2h, and is carried out in the case where rotating speed is 1000rpm stirring condition) with obtained corrosion resistant coating.
Embodiment 3
Corrosion-resistant Quick Response Code braider steel fibre kernmantle B3：
The corrosion-resistant Quick Response Code braider steel fibre kernmantle is formed by steel fibre braiding, and the surface of steel fibre is provided with resistance to
Etching ground layer, the corrosion resistant coating layer are formed by dry after the surface coating corrosion-resistant of the steel fibre,
The corrosion resistant coating is prepared by following steps：
1) by organic siliconresin A3, epoxy resin, castor oil, trbasic zinc phosphate, cyclohexanone, cobalt naphthenate, alumina silicate fibre, second
Glycol is according to 10：5：15：1.2：10：1.5：0.3：15 weight ratio be heat-treated (temperature be 95 DEG C, time 6h, and
Carried out in the case where rotating speed is 1500rpm stirring condition) with obtained component I；
2) by chlorinated rubber (weight average molecular weight 5000), mannitol, ethene-vinyl acetate emulsion, expanded graphite, nanometer
Cerium oxide (average grain diameter 10nm), nano silicon oxide (average grain diameter 10nm), propane diols are according to 10：22：10：0.4：
0.15：0.15：15 weight ratio is heat-treated, and (temperature is 75 DEG C, time 6h, and the stirring in rotating speed for 1500rpm
Under the conditions of carry out) be made component II；
3) under pressure, by component I and component II according to 2：0.8 weight ratio mixed (temperature be 55 DEG C,
Time is 3h, and is carried out in the case where rotating speed is 1500rpm stirring condition) with obtained corrosion resistant coating.
Comparative example 1
Corrosion-resistant Quick Response Code braider steel fibre kernmantle C1 is made in setting according to embodiment 1, unlike, step 3)
In component I is not used.
Comparative example 2
Corrosion-resistant Quick Response Code braider steel fibre kernmantle C2 is made in setting according to embodiment 1, unlike, step 3)
In component II is not used.
Detect example 1
Above-mentioned corrosion-resistant Quick Response Code braider steel fibre kernmantle is placed at 80 DEG C and dries 5h, note of then weighing W1；So
Above-mentioned kernmantle is placed in 35 DEG C afterwards, humidity is to be placed 30 days in 60% environment, note of then weighing W2；Then W2/W1 is calculated
Ratio, concrete outcome is shown in Table 1.
Table 1
| B1 | B1 | B3 | C1 | C2 | |
| W2/W1 | 1.011 | 1.012 | 1.009 | 1.118 | 1.122 |
By above-described embodiment and comparative example, Quick Response Code braider steel fibre kernmantle provided by the invention has excellent
Different corrosion resistance.
The preferred embodiment of the present invention described in detail above, still, the present invention are not limited in above-mentioned embodiment
Detail, in the range of the technology design of the present invention, a variety of simple variants can be carried out to technical scheme, this
A little simple variants belong to protection scope of the present invention.
It is further to note that each particular technique feature described in above-mentioned embodiment, in not lance
In the case of shield, can be combined by any suitable means, in order to avoid unnecessary repetition, the present invention to it is various can
The combination of energy no longer separately illustrates.
In addition, various embodiments of the present invention can be combined randomly, as long as it is without prejudice to originally
The thought of invention, it should equally be considered as content disclosed in this invention.
Claims (10)
- A kind of 1. corrosion-resistant Quick Response Code braider steel fibre kernmantle, it is characterised in that the corrosion-resistant Quick Response Code braider steel Fibrage rope is formed by steel fibre braiding, and the surface of steel fibre is provided with corrosion resistant coating layer, and the corrosion resistant coating layer is By after the surface coating corrosion-resistant of the steel fibre drying form, the corrosion resistant coating by following steps prepare and Into：1) organic siliconresin, epoxy resin, castor oil, trbasic zinc phosphate, cyclohexanone, cobalt naphthenate, alumina silicate fibre, ethylene glycol are entered Row heat treatment is with obtained component I；2) by chlorinated rubber, mannitol, ethene-vinyl acetate emulsion, expanded graphite, nano-cerium oxide, nano silicon oxide, the third two Alcohol is heat-treated so that component II is made；3) under pressure, the component I is mixed with component II so that the corrosion resistant coating is made.
- 2. corrosion-resistant Quick Response Code braider steel fibre kernmantle according to claim 1, it is characterised in that in step 1) In, the organic siliconresin, epoxy resin, castor oil, trbasic zinc phosphate, cyclohexanone, cobalt naphthenate, alumina silicate fibre, ethylene glycol Weight ratio is 10：2-5：11-15：0.8-1.2：5-10：1-1.5：0.1-0.3：10-15.
- 3. corrosion-resistant Quick Response Code braider steel fibre kernmantle according to claim 1, it is characterised in that in step 1) In, the heat treatment meets following condition：Temperature is 85-95 DEG C, time 4-6h, and is 1000-1500rpm's in rotating speed Carried out under stirring condition.
- 4. corrosion-resistant Quick Response Code braider steel fibre kernmantle according to claim 1, it is characterised in that in step 1) In, the organic siliconresin is by by methyl trichlorosilane, dimethyldichlorosilane, phenyl trichlorosilane, diphenyl dichloro Silane and dichloromethyl phenylsilane are according to 1：1-1.2：0.4-0.6：0.8-1.2：0.1-0.4 weight ratio vacuum condition, 2-5h is processed under conditions of 150-180 DEG C to form.
- 5. the corrosion-resistant Quick Response Code braider steel fibre kernmantle according to any one in claim 1-4, its feature exist In, in step 2), the chlorinated rubber, mannitol, ethene-vinyl acetate emulsion, expanded graphite, nano-cerium oxide, nanometer Silica, the weight ratio of propane diols are 10：18-22：5-10：0.1-0.4：0.05-0.15：0.05-0.15：11-15.
- 6. corrosion-resistant Quick Response Code braider steel fibre kernmantle according to claim 5, it is characterised in that in step 2) In, the heat treatment meets following condition：Temperature is 65-75 DEG C, time 4-6h, and is 1000-1500rpm's in rotating speed Carried out under stirring condition.
- 7. corrosion-resistant Quick Response Code braider steel fibre kernmantle according to claim 5, it is characterised in that in step 2) In, the nano-cerium oxide, the average grain diameter of nano silicon oxide are 5-10nm.
- 8. corrosion-resistant Quick Response Code braider steel fibre kernmantle according to claim 5, it is characterised in that the chlorination rubber The weight average molecular weight of glue is 3000-5000.
- 9. the corrosion-resistant Quick Response Code braider steel fibre kernmantle according to any one in claim 1-4,6-8, it is special Sign is, in step 3), the component I and component II weight ratio is 2：0.6-0.8.
- 10. corrosion-resistant Quick Response Code braider steel fibre kernmantle according to claim 9, it is characterised in that in step 3) In, the mixing meets following condition：Temperature is 45-55 DEG C, time 2-3h, and is stirring for 1000-1500rpm in rotating speed Carried out under the conditions of mixing.
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Application publication date: 20180130 |