CN107641736A - It is a kind of can anodic oxidation pack alloy - Google Patents
It is a kind of can anodic oxidation pack alloy Download PDFInfo
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- CN107641736A CN107641736A CN201610578334.6A CN201610578334A CN107641736A CN 107641736 A CN107641736 A CN 107641736A CN 201610578334 A CN201610578334 A CN 201610578334A CN 107641736 A CN107641736 A CN 107641736A
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Abstract
The present invention relates to it is a kind of can anodic oxidation pack alloy, be made up of the component of following mass percent:Fe:0.1% 4%;Mn:0.2% 4.5%;Si:0.1% 4%;Surplus is Al and inevitable impurity, and the content summation of the impurity is less than 0.05%, and the single content of the impurity is less than 0.01%.The aluminium alloy compression casting performance is strong, and yields is higher, and the film layer of continuous uniform can be obtained in anode oxidation process, and coloring effect more preferably, after colouring obtains the appearance of beauty, and the combination property of material is preferable.
Description
Technical field
The present invention relates to non-ferrous metal technical field, more particularly, to it is a kind of can anodic oxidation pressure
Cast aluminium alloy.
Background technology
With the rise of smart mobile phone, people require increasing to mobile phone screen size, to core
Piece performance requires more and more higher, so handles work to the intensity of phone structural, radiating, outward appearance
Skill proposes very high requirement, and then a line classic brands use aluminium sheet+CNC+ anodes one after another
Mode as oxidized surface processing carries out the processing of phone structural, but this can be used largely
CNC boards, consumptive material, take, raised the cost of structural member, this method can not meet
The processing of many shaped pieces such as the lightweight of automobile, unmanned plane, robot.It is conventional at present to use
Casting aluminium workpiece, belong to high sial, radiating effect is poor, can not anodic oxidation connected
Continue uniform film layer, be unable to reach product appearance requirement.Conventional deformation aluminium alloy is due to mobility
Difference, removal is low, can not die cast.In such high-intelligentization, high lightweight, high standard
Quasi- appearance requirement, in the case of efficient capacity requirements, it is badly in need of the appearance of new material.
In the prior art, disclosing one kind in the patent of application number 201510298135.5 can
The pack alloy of anodic oxidation, in addition to containing Al, Si, Fe and Mn, in alloy
In be also added into Mg and Ti, but after adding Mg and Ti in the aluminium alloy of die casting, making
It is standby that into during casting, yields is relatively low, and its as anode in use, can show
Dark red is heterochromatic, influences using effect.In addition, in the special of application number 201510278230.9
Also disclosed that in profit it is a kind of can die casting can anodic oxidation ferro-silicon-aluminium manganese rare earth alloy, except containing
Beyond Al, Si, Fe and Mn, rare earth metal and additive A are also added into the alloy, its
Middle additive A be Co, either Ni or Mg, or Cr, or Co, Ni, Mg,
Cr two of which or three kinds or four kinds of mixtures, not only increased wherein adding rare earth metal
Production cost, while also and do not solve the low technology of the yields during casting is prepared into and ask
Topic, and the addition of additive A equally exists above-mentioned technical problem:It is being prepared into casting
During, yields is relatively low, and its as anode in use, heterochromatic, shadow can be showed
Ring using effect.
The content of the invention
It is an object of the invention to provide it is a kind of can anodic oxidation pack alloy, solve existing skill
The pack alloy for anodic oxidation in art is the yields that is prepared into casting is low, die casting
The problem of heterochromatic influence uses is presented when energy is poor and is used as anode.
The technical proposal for solving the technical problem of the invention is:It is a kind of can anodic oxidation pressure
Cast aluminium alloy, it is made up of the component of following mass percent:Fe:0.1%-4%;Mn:
0.2%-4.5%;Si:0.1%-4%;Surplus is Al and inevitable impurity, described miscellaneous
The content summation of matter is less than 0.05%, and the single content of the impurity is less than 0.01%.
In the present invention can be in the pack alloy of anodic oxidation, by the group of following mass percent
It is grouped into:Fe:0.39%-1.3%;Mn:0.7%-1.9%;Si:0.4%-1.3%;Surplus
It is described less than 0.05% for Al and inevitable impurity, the content summation of the impurity
The single content of impurity is less than 0.01%.
In the present invention can be in the pack alloy of anodic oxidation, by the group of following mass percent
It is grouped into:Fe:0.5%-1.3%;Mn:0.7%-1.9%;Si:0.5%-1.3%;Surplus is
Al and inevitable impurity, the content summation of the impurity are less than 0.05%, the impurity
Single content be less than 0.01%.
In the present invention can be in the pack alloy of anodic oxidation, by the group of following mass percent
It is grouped into:Fe:0.6%-1.1%;Mn:0.8%-1.8%;Si:0.6%-1.1%;Surplus is
Al and inevitable impurity, the content summation of the impurity are less than 0.05%, the impurity
Single content be less than 0.01%.
In the present invention can be in the pack alloy of anodic oxidation, by the group of following mass percent
It is grouped into:Fe:0.8%;Mn:1.4%;Si:0.8%;Surplus is for Al and unavoidably
Impurity, the content summation of the impurity is less than 0.05%, and the single content of the impurity is less than
0.01%.
In the present invention can be in the pack alloy of anodic oxidation, Fe and Si mass values are
0.9~1.
In the present invention can be in the pack alloy of anodic oxidation, Al, Si, Fe and Mn are formed
Alloy cpd form uniformly firm skeleton crystal in the material.
Implement the present invention can anodic oxidation pack alloy, have the advantages that:This
Invention can anodic oxidation pack alloy die casting performance it is strong, yields is higher, in anodic oxygen
The film layer of continuous uniform can be obtained during change, coloring effect more preferably, obtains beauty after colouring
Appearance, the combination property of material is preferable.
Embodiment
With reference to embodiment, to the present invention can anodic oxidation pack alloy make it is further
Explanation:
In the prior art, the film layer of usual anodic oxidation generation continuous uniform requires that the content of aluminium reaches
More than 95%, for conventional electrolytic aluminium (fine aluminium) because of poor fluidity, elevated temperature strength is weak, is stripped energy
Power not enough and can not die cast, show to add on the basis of electrolytic aluminium through substantial amounts of experiment
Si, Fe carry out melting, and according to Metallographic Analysis, Al is included in material12Si2Fe3Nucleus, Mn is thin
Change crystal grain and form new big skeleton nucleus Al simultaneously6MnFeSi2, test the base shown in electrolytic aluminium
Si, Fe and Mn are only added on plinth, it is possible to reach make alloy have preferable mobility with
The effect of removal, while there is preferable die casting performance, anode oxidation film-forming is more uniform,
Coloring effect is preferable.Wherein, can add in the pack alloy of anodic oxidation in the present invention
Si can improve intensity when mobility, tensile strength, hardness, machinability and high temperature, enhancing
The removal of aluminium alloy;The Fe added, acicular crystal can be formed with other metals, by
It is chilling in die casting, can be advantageous to separate out fine grain, strengthen the mobility of alloy, beneficial to the demoulding,
Improve die casting performance and then improve the quality of casting,;The Mn added, the height of alloy can be improved
Warm intensity, aluminium alloy recrystallization process can be prevented, improve recrystallization temperature, significantly refinement again
Crystal grain, mobile performance is improved, improve die casting performance, prevent from ftractureing, improve casting quality.
Above-mentioned metallic element amount cannot add excessive, avoid the formation of oxide.
The present invention can the pack alloy of anodic oxidation be prepared using traditional handicraft, this
In be no longer described in detail, its form embodiment it is as follows.
Embodiment 1:
Can the pack alloy of anodic oxidation be made up of the component of following mass percent:Al:
98.5%;Fe:0.39%;Mn:0.70%;Si:0.40%;The content summation of impurity:0.01%.
Embodiment 2:
Can the pack alloy of anodic oxidation be made up of the component of following mass percent:Al:
98.2%;Fe:0.48%;Mn:0.82%;Si:0.49%;The content summation of impurity:0.01%.
Embodiment 3:
Can the pack alloy of anodic oxidation be made up of the component of following mass percent:Al:
98.29%;Fe:0.50%;Mn:0.70%;Si:0.50%;The content summation of impurity:0.01%.
Embodiment 4:
Can the pack alloy of anodic oxidation be made up of the component of following mass percent:Al:
97.9%;Fe:0.57%;Mn:0.94%;Si:0.58%;The content summation of impurity:0.01%.
Embodiment 5:
Can the pack alloy of anodic oxidation be made up of the component of following mass percent:Al:
97.99%;Fe:0.60%;Mn:0.80%;Si:0.60%;The content summation of impurity:0.01%.
Embodiment 6:
Can the pack alloy of anodic oxidation be made up of the component of following mass percent:Al:
97.6%;Fe:0.66%;Mn:1.06%;Si:0.67%;The content summation of impurity:0.01%.
Embodiment 7:
Can the pack alloy of anodic oxidation be made up of the component of following mass percent:Al:
97.3%;Fe:0.75%;Mn:1.18%;Si:0.76%;The content summation of impurity:0.01%.
Embodiment 8:
Can the pack alloy of anodic oxidation be made up of the component of following mass percent:Al:
96.99%;Fe:0.80%;Mn:1.40%;Si:0.80%;The content summation of impurity:0.01%.
Embodiment 9:
Can the pack alloy of anodic oxidation be made up of the component of following mass percent:Al:
97.0%;Fe:0.84%;Mn:1.30%;Si:0.85%;The content summation of impurity:0.01%.
Embodiment 10:
Can the pack alloy of anodic oxidation be made up of the component of following mass percent:Al:
96.7%;Fe:0.93%;Mn:1.42%;Si:0.94%;The content summation of impurity:0.01%.
Embodiment 11:
Can the pack alloy of anodic oxidation be made up of the component of following mass percent:Al:
96.4%;Fe:1.02%;Mn:1.54%;Si:1.03%;The content summation of impurity:0.01%.
Embodiment 12:
Can the pack alloy of anodic oxidation be made up of the component of following mass percent:Al:
95.99%;Fe:1.10%;Mn:1.80%;Si:1.10%;The content summation of impurity:0.01%.
Embodiment 13:
Can the pack alloy of anodic oxidation be made up of the component of following mass percent:Al:
96.1%;Fe:1.11%;Mn:1.66%;Si:1.12%;The content summation of impurity:0.01%.
Embodiment 14:
Can the pack alloy of anodic oxidation be made up of the component of following mass percent:Al:
95.8%;Fe:1.20%;Mn:1.78%;Si:1.21%;The content summation of impurity:0.01%.
Embodiment 15:
Can the pack alloy of anodic oxidation be made up of the component of following mass percent:Al:
95.5%;Fe:1.29%;Mn:1.90%;Si:1.30%;The content summation of impurity:0.01%.
Embodiment 16:
Can the pack alloy of anodic oxidation be made up of the component of following mass percent:Al:
95.49%;Fe:1.30%;Mn:1.90%;Si:1.30%;The content summation of impurity:0.01%.
Embodiment 17:
Can the pack alloy of anodic oxidation be made up of the component of following mass percent:Al:
95.29%;Fe:0.1%;Mn:4.5%;Si:0.1%;The content summation of impurity:0.01%.
Embodiment 18:
Can the pack alloy of anodic oxidation be made up of the component of following mass percent:Al:
95.69%;Fe:4%;Mn:0.2%;Si:0.1%;The content summation of impurity:0.01%.
Embodiment 19:
Can the pack alloy of anodic oxidation be made up of the component of following mass percent:Al:
95.69%;Fe:0.1%;Mn:0.2%;Si:4%;The content summation of impurity:0.01%.
In the prior art can anodic oxidation pack alloy comparison example it is as follows.
Comparative example 1:Form and be:Al:96.9%;Fe:0.84%;Mn:1.82%;Si:
0.19%;Mg:0.22%;The content summation of impurity:0.03%.
Comparative example 2:Form and be:Al:95.5%;Fe:0.84%;Mn:1.83%;Si:
0.2%;Mg:0.67%;Cr:0.15%;C0:0.13%;Zr:0.11%;Ni:0.56%;
The content summation of impurity:0.01%.
Comparative example 3:Form and be:Al:96.9%;Fe:0.84%;Mn:1.82%;Si:
0.19%;Mg:1.16%;Ti:1.21;The content summation of impurity:0.03%.
Comparative example 4:Form and be:Al:95.5%;Fe:0.84%;Mn:1.83%;Si:
0.2%;Mg:0.67%;Cr:0.15%;C0:0.13%;Ni:0.56%;Impurity
Content summation:0.01%.
To in above-described embodiment and comparative example can the pack alloy of anodic oxidation test
Research, result of study see the table below:
It can be seen from result in table can anodic oxidation pack alloy only add Fe,
Si, Mn, it is possible to reach die casting performance is good, anode oxidation film-forming uniformly and coloring effect
Good effect, without adding other metallic elements again.
It should be appreciated that for those of ordinary skills, can be according to the above description
Improved or converted, all these improvement or conversion should all belong to the appended desired guarantor of the present invention
Within the scope of shield.
Claims (7)
1. it is a kind of can anodic oxidation pack alloy, it is characterised in that by following quality hundred
Divide the component composition of ratio:Fe:0.1%-4%;Mn:0.2%-4.5%;Si:0.1%-4%;
Surplus is Al and inevitable impurity, and the content summation of the impurity is less than 0.05%,
The single content of the impurity is less than 0.01%.
2. it is according to claim 1 can anodic oxidation pack alloy, its feature exists
In being made up of the component of following mass percent:Fe:0.39%-1.3%;Mn:0.7%-1.9%;
Si:0.4%-1.3%;Surplus is Al and inevitable impurity, and the content of the impurity is total
With less than 0.05%, the single content of the impurity is less than 0.01%.
3. it is according to claim 2 can anodic oxidation pack alloy, its feature exists
In being made up of the component of following mass percent:Fe:0.5%-1.3%;Mn:0.7%-1.9%;
Si:0.5%-1.3%;Surplus is Al and inevitable impurity, and the content of the impurity is total
With less than 0.05%, the single content of the impurity is less than 0.01%.
4. it is according to claim 3 can anodic oxidation pack alloy, its feature exists
In being made up of the component of following mass percent:Fe:0.6%-1.1%;Mn:0.8%-1.8%;
Si:0.6%-1.1%;Surplus is Al and inevitable impurity, and the content of the impurity is total
With less than 0.05%, the single content of the impurity is less than 0.01%.
5. it is according to claim 4 can anodic oxidation pack alloy, its feature exists
In being made up of the component of following mass percent:Fe:0.8%;Mn:1.4%;Si:0.8%;
Surplus is Al and inevitable impurity, and the content summation of the impurity is less than 0.05%,
The single content of the impurity is less than 0.01%.
6. it is according to claim 1 can anodic oxidation pack alloy, its feature exists
In Fe and Si mass values are 0.9~1.
7. it is according to claim 1 can anodic oxidation pack alloy, its feature exists
In the alloy cpd that Al, Si, Fe and Mn are formed forms uniformly firm bone in the material
Frame crystal.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109280815A (en) * | 2018-10-19 | 2019-01-29 | 上海中天铝线有限公司 | A kind of explosion-proof aluminium alloy and preparation method thereof |
CN109355532A (en) * | 2018-10-25 | 2019-02-19 | 浙江日晟农林科技有限公司 | One kind can anodic oxidation die-cast aluminum alloy material |
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JPH01259146A (en) * | 1988-04-07 | 1989-10-16 | Nippon Light Metal Co Ltd | Manufacture of aluminum alloy plate having excellent heat resistance |
JPH0881726A (en) * | 1994-09-14 | 1996-03-26 | Showa Denko Kk | Aluminum alloy for casting |
JPH08135922A (en) * | 1994-11-10 | 1996-05-31 | Showa Denko Kk | Liquid fuel combustion device |
CN104060132A (en) * | 2014-07-23 | 2014-09-24 | 卢德强 | Novel aluminum alloy and method for manufacturing aluminum foil with high deep-drawing performance by continuous cast-rolling |
CN104831128A (en) * | 2015-05-28 | 2015-08-12 | 朱岳群 | Aluminum, silicon, iron, manganese and rare-earth alloy with die-casting and anodizing functions |
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2016
- 2016-07-20 CN CN201610578334.6A patent/CN107641736A/en active Pending
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
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JPS60200943A (en) * | 1984-03-23 | 1985-10-11 | Sumitomo Light Metal Ind Ltd | Aluminum alloy having superior strength and workability |
JPS62182257A (en) * | 1986-02-07 | 1987-08-10 | Sky Alum Co Ltd | Manufacture of hard aluminum alloy rolled sheet for forming |
JPH01259146A (en) * | 1988-04-07 | 1989-10-16 | Nippon Light Metal Co Ltd | Manufacture of aluminum alloy plate having excellent heat resistance |
JPH0881726A (en) * | 1994-09-14 | 1996-03-26 | Showa Denko Kk | Aluminum alloy for casting |
JPH08135922A (en) * | 1994-11-10 | 1996-05-31 | Showa Denko Kk | Liquid fuel combustion device |
CN104060132A (en) * | 2014-07-23 | 2014-09-24 | 卢德强 | Novel aluminum alloy and method for manufacturing aluminum foil with high deep-drawing performance by continuous cast-rolling |
CN104831128A (en) * | 2015-05-28 | 2015-08-12 | 朱岳群 | Aluminum, silicon, iron, manganese and rare-earth alloy with die-casting and anodizing functions |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN109280815A (en) * | 2018-10-19 | 2019-01-29 | 上海中天铝线有限公司 | A kind of explosion-proof aluminium alloy and preparation method thereof |
CN109355532A (en) * | 2018-10-25 | 2019-02-19 | 浙江日晟农林科技有限公司 | One kind can anodic oxidation die-cast aluminum alloy material |
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