CN107641351A - A kind of water-based gloss oil with anti-beer adhesion performance and preparation method thereof - Google Patents
A kind of water-based gloss oil with anti-beer adhesion performance and preparation method thereof Download PDFInfo
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- CN107641351A CN107641351A CN201711002585.0A CN201711002585A CN107641351A CN 107641351 A CN107641351 A CN 107641351A CN 201711002585 A CN201711002585 A CN 201711002585A CN 107641351 A CN107641351 A CN 107641351A
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Abstract
The present invention discloses a kind of water-based gloss oil with anti-beer adhesion performance and preparation method thereof, is made up of the raw material of following parts by weight：Water-based 20 50 parts of phenylpropyl alcohol animi resin emulsion, water-based 5 15 parts of phenylpropyl alcohol barras emulsion, water-based 30 50 parts of phenylpropyl alcohol intaglio plate emulsion resin, 5 20 parts of 0.1 10 parts of 15 parts of 0.01 0.5 parts of 10 30 parts of 5 10 parts of nanoparticle, dimethyl silicone polymer, catalyst, organosiloxane auxiliary agent, organic silicon defoamer, the polythene wax emulsion of surface isocyanation esterification, 2 10 parts of deionized water, 2 10 parts of absolute ethyl alcohol.The present invention in water-based gloss oil by introducing nanoparticle and dimethyl silicone polymer, the characteristics of water-based gloss oil is had self-cleaning function, while be not easy to be bonded in organo-silicon compound surface using sugar in beer, effectively reduces the adhesion performance of beer.
Description
Technical field
The present invention relates to a kind of water-based gloss oil and preparation method thereof, more particularly to a kind of with anti-beer adhesion performance
Water-based gloss oil and preparation method thereof.
Background technology
Gloss oil is surface-treated materials as a kind of printing, is widely used in printing industry, by the way that gloss oil is coated in into thing
Part surface, formed with the smooth solid-film layer in some strength, surface, can play a part of protecting printing figure message well, because
This gloss oil is printed on food and drink, footwear clothes, the packaging box outer surfac of tobacco and wine extensively.But in use, gloss oil is formed
Solid-film layer is easily influenceed because of water and greasy dirt, and particularly beer is easily sticked on solid-film layer, is caused solid-film layer to be difficult to clean, is entered
And printing figure message surface blur is caused, it can not recognize.
The content of the invention
It is existing at least to solve the invention provides a kind of water-based gloss oil with anti-beer adhesion performance and preparation method thereof
There is the problem of beer is easily sticked on the solid-film layer of water-based gloss oil formation in technology.
The invention provides a kind of water-based gloss oil with anti-beer adhesion performance, it is made up of the raw material of following parts by weight：
Water-based phenylpropyl alcohol animi resin emulsion 20-50 parts, water-based phenylpropyl alcohol barras emulsion 5-15 parts, water-based phenylpropyl alcohol intaglio plate emulsion resin 30-50
It is part, nanoparticle 5-10 parts of surface isocyanation esterification, dimethyl silicone polymer 10-30 parts, catalyst 0.01-0.5 parts, organic
Siloxanes auxiliary agent 1-5 parts, organic silicon defoamer 0.1-10 parts, polythene wax emulsion 5-20 parts, deionized water 2-10 parts, anhydrous second
Alcohol 2-10 parts.
Further, the water-based phenylpropyl alcohol animi resin emulsion is made up of the raw material of following parts by weight：Acrylic solid resin
10-35 parts, styrene 10-35 parts, methyl methacrylate 10-30 parts, water 5-25 parts.
Further, the water-based phenylpropyl alcohol barras emulsion is made up of the raw material of following parts by weight：Acrylic solid resin
10-35 parts, styrene 10-35 parts, butyl acrylate 10-30 parts, water 5-25 parts.
Further, one or more of the catalyst in stannous octoate or dibutyl tin laurate.
It is to provide a kind of preparation side of the above-mentioned water-based gloss oil with anti-beer adhesion performance another mesh of the present invention
Method, comprise the following steps：
Step 1. takes dimethyl silicone polymer, adds the nanoparticle of surface isocyanation esterification, stirring under nitrogen protection
Catalyst is added after uniformly, 1-24 hours is reacted in anhydrous conditions, 20-70 DEG C of reaction temperature, obtains nanoparticle and poly- two
Methylsiloxane is grafted solid suspension；
The aqueous phenylpropyl alcohol gravure animi resin emulsion of step 2. is added in step 1 resulting solution, at 500-3000 revs/min
Under the conditions of be dispersed with stirring 20-35 minutes；Interval using 20-40 minutes as each addition raw material, adds the soft tree of water-based phenylpropyl alcohol successively
Fat liquor, polythene wax emulsion polyethers, modified organic silicon levelling agent, organosiloxane adhesion promoter, organic silicon defoamer；
After addition, it is 1 to add mass ratio:1 water and absolute ethyl alcohol, is dispersed with stirring 5-20 minutes, and gained liquid is water-based light
Oil.
Further, the nanoparticle preparation process of the surface isocyanation esterification is as follows：
By weight, diisocyanate 80-100 parts are taken, nitrogen protection is lower to add nanoparticle 80-100 parts, in room temperature
Under be stirring evenly and then adding into the dibutyl tin laurate for accounting for reaction solution gross weight 0.5-2%, in anhydrous conditions react 5-20 it is small
When, 20-70 DEG C of reaction temperature, under nitrogen protection, solid filter drying, obtain the nanoparticle of surface isocyanation esterification.
Further, the nanoparticle is selected from silicon dioxide microsphere, aluminum oxide micro-sphere, titanium dioxide microballoon sphere, carbonic acid
One kind in the polymer nano-microspheres of hydroxyl is contained on calcium microballoon, iron oxide microballoon or surface；The particle diameter of the nanoparticle is
50-1000nm。
Further, the diisocyanate is selected from methyl diphenylene diisocyanate, toluene di-isocyanate(TDI), to benzene
In diisocyanate, 1,5 '-naphthalene diisocyanate, tetramethyl xylylene diisocyanate, more phenylmethane polyisocyanates
One or more.
The present invention is relative to prior art, by using nanoparticle, after water-based gloss oil solidifies and to form solid-film layer, its
The surface of solid-film layer can form super-amphiphobic structure, prevent water and organic liquid in water-based gloss oil superficial residence, and then prevent
Greasy dirt and it is water stain be covered in water-based gloss oil surface, make water-based gloss oil that there is automatical cleaning ability.In addition, the present invention is by micro- in nanometer
Grain surface grafting silicide, the characteristics of being not easy to bond organo-silicon compound using the saccharide compound in beer, reduces beer
Adhesion performance, and then water-based gloss oil has anti-beer adhesive.
Embodiment
In order that those skilled in the art more fully understand the present invention program, below by the skill in the embodiment of the present invention
Art scheme is clearly and completely described, it is clear that and described embodiment is only the embodiment of a present invention part, without
It is whole embodiments.
The nanoparticle preparation process of surface isocyanation esterification used in embodiment 1-3 is as follows：By weight, toluene two is taken
100 parts of isocyanates, 80 parts of aluminum oxide micro-sphere is added under nitrogen protection, is stirring evenly and then adding into and accounts for reaction solution gross weight 0.5-
2% dibutyl tin laurate, 1-24 hours, 20-70 DEG C of reaction temperature are reacted in anhydrous conditions.Under nitrogen protection,
Solid filters drying, obtains the aluminum oxide micro-sphere of surface isocyanation esterification.
Water-based phenylpropyl alcohol animi resin emulsion used in embodiment 1-3 and reference examples is made up of the raw material of following parts by weight：Acrylic acid
10 parts of hard resin, 35 parts of styrene, 30 parts of methyl methacrylate, 5 parts of water.
Water-based phenylpropyl alcohol barras emulsion used in embodiment 1-3 and reference examples is made up of the raw material of following parts by weight：Acrylic acid
10 parts of hard resin, 35 parts of styrene, 30 parts of butyl acrylate, 5 parts of water.
Embodiment 1
The present embodiment water-based gloss oil, it is made up of the raw material of following parts by weight：Water-based 20 parts of phenylpropyl alcohol animi resin emulsion, water-based benzene
Third 5 parts of barras emulsion, water-based 30 parts of phenylpropyl alcohol intaglio plate emulsion resin, 5 parts of nanoparticle, the poly dimethyl of surface isocyanation esterification
20 parts of siloxanes, 0.01 part of dibutyl tin laurate, 1 part of organosiloxane auxiliary agent, 0.1 part of organic silicon defoamer, polyethylene
5 parts of wax emulsion, 2 parts of deionized water, 2 parts of absolute ethyl alcohol.
The preparation method of the present embodiment water-based gloss oil is as follows：
Step 1. takes dimethyl silicone polymer, adds the nanoparticle of surface isocyanation esterification, stirring under nitrogen protection
Uniformly after add dibutyl tin laurate, in anhydrous conditions react 18 hours, 70 DEG C of reaction temperature, obtain nanoparticle with
Dimethyl silicone polymer is grafted solid suspension；
The aqueous phenylpropyl alcohol gravure animi resin emulsion of step 2. is added in step 1 resulting solution, in 500 revs/min of condition
Under be dispersed with stirring 35 minutes；With 40 minutes intervals for addition raw material every time, water-based phenylpropyl alcohol barras emulsion, poly- second were added successively
Alkene wax emulsion polyethers, modified organic silicon levelling agent, organosiloxane adhesion promoter, organic silicon defoamer；After addition,
It is 1 to add mass ratio:1 water and absolute ethyl alcohol, it is dispersed with stirring 20 minutes, gained liquid is the present embodiment water-based gloss oil.
Embodiment 2
The present embodiment water-based gloss oil, it is made up of the raw material of following parts by weight：Water-based phenylpropyl alcohol animi resin emulsion 50, water-based phenylpropyl alcohol
15 parts of barras emulsion, water-based 50 parts of phenylpropyl alcohol intaglio plate emulsion resin, 10 parts of nanoparticle, the poly dimethyl of surface isocyanation esterification
30 parts of siloxanes, 0.5 part of stannous octoate, 5 parts of organosiloxane auxiliary agent, 10 parts of organic silicon defoamer, 20 parts of polythene wax emulsion,
10 parts of deionized water, 10 parts of absolute ethyl alcohol.
The preparation method of the present embodiment water-based gloss oil is as follows：
Step 1. takes dimethyl silicone polymer, adds the nanoparticle of surface isocyanation esterification, stirring under nitrogen protection
Stannous octoate is added after uniformly, reacts 24 hours in anhydrous conditions, 50 DEG C of reaction temperature, obtains nanoparticle and poly dimethyl
Polysiloxane grafted solid suspension；
The aqueous phenylpropyl alcohol gravure animi resin emulsion of step 2. is added in step 1 resulting solution, under conditions of 50 revs/min
It is dispersed with stirring 35 minutes；With 20 minutes intervals for addition raw material every time, water-based phenylpropyl alcohol barras emulsion, polyethylene were added successively
Wax emulsion polyethers, modified organic silicon levelling agent, organosiloxane adhesion promoter, organic silicon defoamer；After addition, add
Enter mass ratio for 1:1 water and absolute ethyl alcohol, it is dispersed with stirring 15 minutes, gained liquid is water-based gloss oil.
Embodiment 3
The present embodiment water-based gloss oil, it is made up of the raw material of following parts by weight：Water-based phenylpropyl alcohol animi resin emulsion 50, water-based phenylpropyl alcohol
5 parts of barras emulsion, water-based 50 parts of phenylpropyl alcohol intaglio plate emulsion resin, 5 parts of nanoparticle, the poly dimethyl silicon of surface isocyanation esterification
20 parts of oxygen alkane, 0.5 part of stannous octoate, 5 parts of organosiloxane auxiliary agent, 10 parts of organic silicon defoamer, 20 parts of polythene wax emulsion, go
2 parts of ionized water, 2 parts of absolute ethyl alcohol.
The preparation method of the present embodiment water-based gloss oil is as follows：
Step 1. takes dimethyl silicone polymer, adds the nanoparticle of surface isocyanation esterification, stirring under nitrogen protection
Catalyst is added after uniformly, reacts 24 hours in anhydrous conditions, 60 DEG C of reaction temperature, obtains nanoparticle and poly dimethyl silicon
Oxygen alkane is grafted solid suspension；
The aqueous phenylpropyl alcohol gravure animi resin emulsion of step 2. is added in step 1 resulting solution, in 1000 revs/min of condition
Under be dispersed with stirring 35 minutes；With 40 minutes intervals for addition raw material every time, water-based phenylpropyl alcohol gravure PE barras breast was added successively
Liquid, polythene wax emulsion polyethers, modified organic silicon levelling agent, organosiloxane adhesion promoter, organic silicon defoamer；Addition
After, it is 1 to add mass ratio:1 water and absolute ethyl alcohol, it is dispersed with stirring 20 minutes, gained liquid is water-based gloss oil.
Reference examples
The present embodiment water-based gloss oil, it is made up of the raw material of following parts by weight：Water-based 20 parts of phenylpropyl alcohol animi resin emulsion, water-based benzene
Third 5 parts of barras emulsion, water-based 30 parts of phenylpropyl alcohol intaglio plate emulsion resin, 1 part of organosiloxane auxiliary agent, 0.1 part of organic silicon defoamer,
5 parts of polythene wax emulsion, 2 parts of deionized water, 2 parts of absolute ethyl alcohol.
The preparation method of the present embodiment water-based gloss oil is as follows：
Aqueous phenylpropyl alcohol animi resin emulsion is dispersed with stirring 35 minutes under conditions of 500 revs/min；It was each with 40 minutes
Add raw material interval, add successively water-based phenylpropyl alcohol barras emulsion, polythene wax emulsion polyethers, modified organic silicon levelling agent,
Organosiloxane adhesion promoter, organic silicon defoamer；After addition, it is 1 to add mass ratio:1 water and absolute ethyl alcohol,
It is dispersed with stirring 20 minutes, gained liquid is the present embodiment water-based gloss oil.
Example 1-3 and reference examples are made water-based gloss oil and are coated in printed patterns surface, form solid film after drying
Layer, water droplet and oil droplet is added dropwise on the solid-film layer surface of embodiment 1-3 and reference examples respectively, and detects water droplet and oil droplet and solid-state
Film layer contact angle.
The performance detection that water-based gloss oil is made in above-described embodiment 1-3 and reference examples is as shown in the table：
As shown above, 1-3 of the embodiment of the present invention makes water-based gloss oil surface by adding nanoparticle in water-based gloss oil
With nanostructured, and then the solid-film layer surface for forming water-based gloss oil has nanometer super-amphiphobic structure, compared to reference examples,
The wetting to solid-film layer surface of water and oil can effectively be prevented, so avoid water and oil formed on solid-film layer surface it is water stain or
Greasy dirt, water-based gloss oil is set to have self-cleaning performance.In addition, 1-3 of the embodiment of the present invention is siliconated by being introduced on nanoparticle
Compound, prevent the sugar in beer to be bonded on solid-film layer, reduce beer to the adhesive of solid-film layer, beer is existed
Flowed down naturally on solid-film layer.
Finally it should be noted that the above embodiments are merely illustrative of the technical scheme of the present invention and are not intended to be limiting thereof, to the greatest extent
The present invention is described in detail with reference to above-described embodiment for pipe, it should be understood by a person of ordinary skill in the art that technology
Still the embodiment of the present invention can be modified after reading present specification by personnel or equivalent substitution, but this
A little modifications are changed within all without departing from the present patent application accompanying claims protection domain.
Claims (8)
1. a kind of water-based gloss oil with anti-beer adhesion performance, it is characterised in that the water-based gloss oil is by following parts by weight
Raw material forms：Water-based phenylpropyl alcohol animi resin emulsion 20-50 parts, water-based phenylpropyl alcohol barras emulsion 5-15 parts, water-based phenylpropyl alcohol intaglio plate emulsion
Resin 30-50 parts, nanoparticle 5-10 parts of surface isocyanation esterification, dimethyl silicone polymer 10-30 parts, catalyst 0.01-
0.5 part, organosiloxane auxiliary agent 1-5 parts, organic silicon defoamer 0.1-10 parts, polythene wax emulsion 5-20 parts, deionized water 2-
10 parts, absolute ethyl alcohol 2-10 parts.
2. water-based gloss oil according to claim 1, it is characterised in that the water-based phenylpropyl alcohol animi resin emulsion is by following parts by weight
Raw material composition：Acrylic solid resin 10-35 parts, styrene 10-35 parts, methyl methacrylate 10-30 parts, water 5-25
Part.
3. water-based gloss oil according to claim 1, it is characterised in that the water-based phenylpropyl alcohol barras emulsion is by following parts by weight
Raw material composition：Acrylic solid resin 10-35 parts, styrene 10-35 parts, butyl acrylate 10-30 parts, water 5-25 parts.
4. water-based gloss oil according to claim 1, it is characterised in that the catalyst is selected from stannous octoate or tin dilaurate two
One or more in butyl tin.
5. a kind of water-based gloss oil preparation method as claimed in claim 1 with anti-beer adhesion performance, it is characterised in that described
Method comprises the following steps：
Step 1. takes dimethyl silicone polymer, adds the nanoparticle of surface isocyanation esterification under nitrogen protection, stirs
After add catalyst, in anhydrous conditions react 1-24 hours, 20-70 DEG C of reaction temperature, obtain nanoparticle and poly dimethyl
Polysiloxane grafted solid suspension；
The aqueous phenylpropyl alcohol gravure animi resin emulsion of step 2. is added in step 1 resulting solution, in 500-3000 revs/min of condition
Under be dispersed with stirring 20-35 minutes；Interval using 20-40 minutes as each addition raw material, adds water-based phenylpropyl alcohol barras breast successively
Liquid, polythene wax emulsion polyethers, modified organic silicon levelling agent, organosiloxane adhesion promoter, organic silicon defoamer；Addition
After, it is 1 to add mass ratio:1 water and absolute ethyl alcohol, is dispersed with stirring 5-20 minutes, and gained liquid is water-based gloss oil.
6. preparation method according to claim 5, it is characterised in that prepared by the nanoparticle of the surface isocyanation esterification
Step is as follows：
By weight, diisocyanate 80-100 parts are taken, nitrogen protection is lower to add nanoparticle 80-100 parts, stirs at room temperature
The dibutyl tin laurate for accounting for reaction solution gross weight 0.5-2% is added after mixing uniformly, reacts 5-20 hours in anhydrous conditions, instead
20-70 DEG C of temperature is answered, under nitrogen protection, solid filters drying, obtains the nanoparticle of surface isocyanation esterification.
7. preparation method according to claim 6, it is characterised in that the nanoparticle is selected from silicon dioxide microsphere, oxygen
Change aluminium microballoon, titanium dioxide microballoon sphere, calcium carbonate microspheres, iron oxide microballoon or surface to contain in the polymer nano-microspheres of hydroxyl
It is a kind of；The particle diameter of the nanoparticle is 50-1000nm.
8. preparation method according to claim 6, it is characterised in that it is different that the diisocyanate is selected from diphenyl methane two
Cyanate, toluene di-isocyanate(TDI), PPDI, 1,5 '-naphthalene diisocyanate, the isocyanic acid of durol dimethyl two
One or more in ester, more phenylmethane polyisocyanates.
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| CN201711002585.0A CN107641351A (en) | 2017-10-24 | 2017-10-24 | A kind of water-based gloss oil with anti-beer adhesion performance and preparation method thereof |
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| CN201711002585.0A CN107641351A (en) | 2017-10-24 | 2017-10-24 | A kind of water-based gloss oil with anti-beer adhesion performance and preparation method thereof |
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Cited By (2)
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| CN108774915A (en) * | 2018-06-29 | 2018-11-09 | 湖北黄鹤楼特色包装材料有限公司 | A kind of high temperature resistant prevents adhesion finishing oil |
| CN110607709A (en) * | 2019-09-29 | 2019-12-24 | 武汉迪赛环保新材料股份有限公司 | Water-based gloss oil with beer adhesion prevention performance and preparation method thereof |
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| CN108774915A (en) * | 2018-06-29 | 2018-11-09 | 湖北黄鹤楼特色包装材料有限公司 | A kind of high temperature resistant prevents adhesion finishing oil |
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