CN107632053B - A kind of detection method of quick detection sweat intermediate ion concentration - Google Patents

A kind of detection method of quick detection sweat intermediate ion concentration Download PDF

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CN107632053B
CN107632053B CN201710802257.2A CN201710802257A CN107632053B CN 107632053 B CN107632053 B CN 107632053B CN 201710802257 A CN201710802257 A CN 201710802257A CN 107632053 B CN107632053 B CN 107632053B
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sweat
perspiration sensor
detection
adsorption layer
ion concentration
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CN107632053A (en
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易龙
糜漫天
张乾勇
张婷
陈卡
秦玉
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Third Military Medical University TMMU
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Abstract

The invention discloses a kind of detection methods of quickly detection sweat intermediate ion concentration, before use, putting sweat scavenger layer in sweat collection box first using deionized water cleaning sweat adsorption layer;Before movement, sweat adsorption layer is covered on to the surface of skin, after skin perspiration, sweat is adsorbed and collected;When perspiration sensor and sweat adsorption layer contact, ion detection is carried out to the sweat on sweat adsorption layer by perspiration sensor, sweat simultaneously adheres on perspiration sensor;Shaft drives perspiration sensor to continue to rotate, and when perspiration sensor, which is rotated to, to be contacted with sweat scavenger layer, sweat scavenger layer can absorb the sweat adhered on perspiration sensor.The present invention can be during the motion, the sweat generated in real time to sporter is measured in real time, it reminds sporter to make movement adjustment and supplement electrolyte in time, can be avoided sporter because largely sweating, body Inner electrolysis mass flow is lost and leads to the injury to sporter's body.

Description

A kind of detection method of quick detection sweat intermediate ion concentration
Technical field
The present invention relates to human secretory object detecting method technical field, more particularly to a kind of quickly detection sweat intermediate ion are dense The detection method of degree.
Background technique
Human body during exercise, due to internal heat production increase, so the sweat gland in each area skin of Whole Body will be secreted Sweat, it is especially most with positions such as forehead, neck, trunk front and back, waist, the back of the hand and forearms;Perspiring is conducive to keep human body Interior temperature distributes heat, while can also take away the internal rubbish that a small amount of human body is generated by movement.In sweat Baidupedia The chapters and sections that keep the skin wet point out that main ingredient is water in sweat, are also mingled with some electrolyte in water, these electrolyte are main It is sodium ion and chloride ion, general there are also a small amount of potassium and calcium.Under prolonged movement, containing for sodium is clipped in the sweat of loss Amount is general most, and the loss of sodium ion just can not in time adjust the physiological changes such as body fluid and temperature.
In tired situation or under the movement of superpower physical load, sodium, the potassium content of sweat can change human body, Sodium, potassium ion changes of contents can react the fatigue state of human body, under normal circumstances, during the motion, because in human body The loss of sodium, potassium ion, sodium, potassium concentration of the human secretory in sweat can be lower and lower, " the food and strong of 3 phases in 2001 Health " " sodium potassium imbalance cause a disease the more " text point out, if the concentration of sodium, potassium ion as low as to a certain degree when, can lead to human body group The metabolic disorder of cell and the dysfunction of each organ of whole body are knitted, threat to life is also possible to when serious, because in high-intensitive fortune Under dynamic, sodium, the potassium concentration of sporter are changed and is measured in real time and monitors, makes adjustment in time, can be avoided movement Person because largely sweating, lose and lead to the injury to sporter's body by body Inner electrolysis mass flow.
Application No. is the Chinese patent documents of CN201510315471.6 to disclose after a kind of movement gold in sporter's sweat Belong to the detection method of element, detection method includes the sweat of sporter after collecting movement, sweat is filtered, in qualitative determination sweat The type of metallic element draws atomic emissions intensity-concentration standard curve of metallic element, quantitative determines metallic element in sweat Content;The general method for collecting sweat use is first collected to sweat using sweat patch or sweat collection bag, then again The sweat of collection detects the ion concentration in sweat using ion analysis equipment, but in this case just pretty troublesome, and And detection needs certain time, will lead to the lag of testing result, it can not be to the ion concentration in the sweat of human secretory It is detected in real time, is unable to dehydration and the fatigue conditions of real time reaction sporter, therefore be badly in need of a kind of quickly detection sweat at present The detection method of liquid intermediate ion concentration.
Summary of the invention
In view of this, the object of the present invention is to provide a kind of detection method of quickly detection sweat intermediate ion concentration, we Method can during the motion, and the sodium ion in sweat and potassium ion generated in real time to sporter is measured in real time, real The dehydration of Shi Fanying sporter and fatigue conditions are reminded sporter to make movement adjustment and supplement electrolyte in time, be can be avoided Sporter because largely sweating, lose and lead to the injury to sporter's body by body Inner electrolysis mass flow.
The present invention solves above-mentioned technical problem by following technological means:
A kind of detection method of quick detection sweat intermediate ion concentration, including a kind of sweat ion detection device, detection dress It sets including casing and power supply, power supply is mounted on casing internal, and the surface of casing is provided with information display system and sweat adsorption layer, The side of sweat adsorption layer is rotatably connected to shaft, and micro machine is connected in shaft, and sweat sensing is equipped on the circumferential surface of shaft Device, perspiration sensor are electrically connected with information acquisition system, and shaft is received far from sweat is provided on another circumferential surface of perspiration sensor Collect box, sweat collection box is provided with sweat scavenger layer, sweat scavenger layer and perspiration sensor clearance fit, perspiration sensor, micro- Motor, information acquisition system and information display system are electrically connected to a power source;Detection method is as follows:
A, before use, being dried, and put in sweat collection box first using deionized water cleaning sweat adsorption layer 2-3 times Set sweat scavenger layer;
B, before movement, sweat adsorption layer is covered on to the surface of skin, in motion process, after skin perspiration, is inhaled by sweat Attached layer is adsorbed and collected the sweat on skin;
C, shaft drives perspiration sensor rotation, when perspiration sensor is contacted with sweat adsorption layer, by perspiration sensor Ion detection is carried out to the sweat on sweat adsorption layer, sweat simultaneously adheres on perspiration sensor, and the data of detection enter letter Acquisition system is ceased, detection ion concentration data are then shown by information display system;
D, shaft drives perspiration sensor to continue to rotate, when perspiration sensor, which is rotated to, to be contacted with sweat scavenger layer, sweat Liquid scavenger layer can absorb the sweat adhered on perspiration sensor, guarantee the cleaning of perspiration sensor;
E, shaft continues to rotate, and perspiration sensor is contacted with sweat adsorption layer again, to the ion concentration of sweat again into Row detection.
Further, the sweat adsorption layer includes cation-exchange paper and hydrophobic cloth, and by cation-exchange paper and hydrophobic Cloth is suppressed, and hydrophilic micro-fluidic grid is woven on the hydrophobic cloth.Cation-exchange paper be used for sodium ion and Potassium ion, hydrophobic cloth are used for the collection of sweat, so, it is possible to carry out good absorption to the sweat of sporter, so that sweat phase Pair detection limit it is bigger, the error of detection is smaller, and detection accuracy is high.
Further, the shaft, micro machine, perspiration sensor, collection box and sweat scavenger layer are respectively positioned on casing internal.It will Shaft, micro machine, perspiration sensor, collection box and sweat scavenger layer are arranged in casing, so that the structure of detection device is more Step up to gather, is more convenient for wearing.
Further, the perspiration sensor includes sodium electrode, potassium electrode and reference electrode, the sodium electrode, potassium electrode and Reference electrode is electrically connected with information acquisition system, and the sodium electrode is the carbon nanotube of kayexalate cladding, described Potassium electrode is the carbon nanotube of polystyrolsulfon acid potassium cladding, and the reference electrode is the carbon nanometer of polyvinyl butyral cladding Pipe.Electrode potential signal is generated according to sodium ion, potassium concentration variation in sweat between sodium electrode, potassium electrode and reference electrode Es is transmitted to information acquisition system, then shows detection ion concentration data by information display system.
Further, in step b, sweat adsorption layer is covered on forehead, neck, trunk front and back, waist, the back of the hand or forearm The wherein skin at one on.Studies have shown that during the motion, the forehead of human body, neck, trunk front and back, waist, the back of the hand or The volume of perspiration of person's forearm is maximum, and sweat adsorption layer is covered on forehead, neck, trunk front and back, waist, the back of the hand or forearm Wherein on the skin at one, the amount of sweat is bigger, just more accurate to the detection of sweat intermediate ion ingredient.
Further, high-absorbent material made of the sweat scavenger layer is chitosan and is acrylic acid-grafted.High-absorbent material The sweat being adhered on perspiration sensor can be subjected to absorbing and eliminating, avoid remaining sweat dense to the sweat detected next time Degree has an impact, and high-absorbent material has very strong water absorbing capacity, can adsorb more sweat, so that detection device Time extension is intended for single use.
Further, the method for the high-absorbent material:
A: molecular mass 5.1-6.0*10 is selected5Chitosan 100g, be dissolved in acrylic acid solution, stir, keep shell poly- Sugared sufficiently dissolution, obtains mixed solution A;
B: after dissolution, nitrogen is filled with into solution A, and initiator is added in stirring, initiator is concentration The Mn of 0.006mol/L3+, obtain solution B;
C, 85-95 DEG C is heated to B solution, after reacting 80-100min, using in sodium hydroxide solution and B solution, so that B solution pH value 6.5-7.5, obtains C solution after neutralization;
D, C solution is dehydrated, obtains high-absorbent material after crushing drying.
Further, in the step a, after stirring finishes to obtain mixed liquor A, into mixed solution A, molecular weight is added 1000-1500*105Polyacrylamide 3-5g, and using revolving speed 1000-1500r/min blender stirring 2-3min after water Change.
Beneficial effects of the present invention:
(1), the present invention in use, is adsorbed sweat using sweat adsorption layer, then utilizes the sodium of rotation Electrode and potassium electrode detect the sweat of sweat adsorption layer, and using sweat scavenger layer to the sweat on sodium electrode and potassium electrode Liquid is purged, and is realized real-time detection and monitoring to sporter's sweat, the dehydration of real time reaction sporter and fatigue conditions, is mentioned Awake sporter makes movement adjustment and supplement electrolyte in time, can be avoided sporter because largely sweat, machine cylinder electrolyte It is lost and leads to the injury to sporter's body;
(2), present invention material made of cation-exchange paper and the compacting of hydrophobic cloth, can be right as sweat adsorption layer The sweat of sporter carries out good absorption so that sweat it is opposite detection limit it is bigger, the error of detection is smaller, detection accuracy It is high;
(3), molecular weight 1000-1500*10 is added in mixed solution A in the present invention5Polyacrylamide 3-5g, can be with The intensity for increasing high-absorbent material, extends the service life of high-absorbent material;
(4), the present invention is using the high-absorbent material of chitosan and acrylic acid-grafted preparation as sodium electrode and potassium electrode Sweat scavenger layer, water suction Scavenging activity is strong, long using the time.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of sweat ion detection device in the present invention;
Fig. 2 is the circuit diagram of sweat ion detection device in the present invention;
Wherein, casing 1, electronic display 2, sweat adsorption layer 3, sodium electrode 4, potassium electrode 5, reference electrode 6, shaft 7, micro- Motor 8, information acquisition device 9, sweat collection box 10, sweat scavenger layer 11, power supply 12.
Specific embodiment
Below with reference to attached drawing, the present invention is described in detail:
It is as depicted in figs. 1 and 2:
Embodiment one:
A kind of detection method of quick detection sweat intermediate ion concentration, including a kind of sweat ion detection device, detection dress It sets including casing 1 and power supply 12, the surface of casing 1 is provided with electronic display 2 and sweat adsorption layer 3, and the one of sweat adsorption layer 3 Side is rotatably connected to shaft 7, and micro machine 8 is connected in shaft 7, and perspiration sensor, sweat sensing are equipped on the circumferential surface of shaft 7 Device is electrically connected with information acquisition device 9, and shaft 7 is far from being provided with sweat collection box 10, sweat on another circumferential surface of perspiration sensor Collection box 10 is provided with sweat scavenger layer 11, sweat scavenger layer 11 and perspiration sensor clearance fit;Sodium electrode 4, potassium electrode 5, Reference electrode 6, micro machine 8, information acquisition device 9 and electronic display 2 are electrically connected with power supply 12;Detection method is as follows:
A, before use, three times using deionized water cleaning sweat adsorption layer 3 first, drying, and in sweat collection box 10 Place sweat scavenger layer 11;
B, before movement, sweat adsorption layer 3 is covered on to the surface of skin, in motion process, after skin perspiration, is inhaled by sweat Sweat on 3 pairs of skin of attached layer is adsorbed and collected;
C, shaft 7 drives perspiration sensor rotation, when perspiration sensor is contacted with sweat adsorption layer 3, is sensed by sweat Device carries out ion detection to the sweat on sweat adsorption layer 3, and sweat simultaneously adheres on perspiration sensor, and the data of detection enter Then information acquisition device 9 shows detection ion concentration data by electronic display 2;
D, shaft 7 drives perspiration sensor to continue to rotate, when perspiration sensor, which is rotated to, to be contacted with sweat scavenger layer 11, Sweat scavenger layer 11 can absorb the sweat adhered on perspiration sensor, guarantee the cleaning of perspiration sensor;
E, shaft 7 continues to rotate, and perspiration sensor is contacted with sweat adsorption layer 3 again, again to the ion concentration of sweat It is detected.
Sweat adsorption layer 3 includes cation-exchange paper and hydrophobic cloth, and is suppressed by cation-exchange paper and hydrophobic cloth, Hydrophilic micro-fluidic grid is woven on hydrophobic cloth.Cation-exchange paper is used for sodium ion and potassium ion, and hydrophobic cloth is used In the collection of sweat, so, it is possible to carry out good absorption to the sweat of sporter so that sweat it is opposite detection limit it is bigger, The error of detection is smaller, and detection accuracy is high.
Shaft 7, micro machine 8, perspiration sensor, collection box and sweat scavenger layer 11 are respectively positioned on inside casing 1.By shaft 7, Micro machine 8, perspiration sensor, collection box and sweat scavenger layer 11 are arranged in casing 1, so that the structure of detection device is more It is compact, it is more convenient for wearing.
Perspiration sensor includes sodium electrode 4, potassium electrode 5 and reference electrode 6, sodium electrode 4, potassium electrode 5 and reference electrode 6 with Information acquisition device 9 is electrically connected, and sodium electrode 4 is the carbon nanotube of kayexalate cladding, and potassium electrode 5 is polystyrolsulfon acid The carbon nanotube of potassium cladding, reference electrode 6 are the carbon nanotube of polyvinyl butyral cladding.Wherein sodium electrode 5, potassium electrode 5 Electrode potential signal Es is generated according to sodium ion, potassium concentration variation in sweat between reference electrode 6, information is transmitted to and adopts Then storage 9 shows detection ion concentration data by electronic display 2.
In stepb, sweat adsorption layer is covered on the skin at forehead.
High-absorbent material made of sweat scavenger layer 11 is chitosan and is acrylic acid-grafted.
Embodiment two:
A kind of detection method of quick detection sweat intermediate ion concentration, including a kind of sweat ion detection device, detection dress It sets including casing 1 and power supply 12, the surface of casing 1 is provided with electronic display 2 and sweat adsorption layer 3, and the one of sweat adsorption layer 3 Side is rotatably connected to shaft 7, and micro machine 8 is connected in shaft 7, and perspiration sensor, sweat sensing are equipped on the circumferential surface of shaft 7 Device is electrically connected with information acquisition device 9, and shaft 7 is far from being provided with sweat collection box 10, sweat on another circumferential surface of perspiration sensor Collection box 10 is provided with sweat scavenger layer 11, sweat scavenger layer 11 and perspiration sensor clearance fit;Sodium electrode 4, potassium electrode 5, Reference electrode 6, micro machine 8, information acquisition device 9 and electronic display 2 are electrically connected with power supply 12;Detection method is as follows:
A, before use, three times using deionized water cleaning sweat adsorption layer 3 first, drying, and in sweat collection box 10 Place sweat scavenger layer 11;
B, before movement, sweat adsorption layer 3 is covered on to the surface of skin, in motion process, after skin perspiration, is inhaled by sweat Sweat on 3 pairs of skin of attached layer is adsorbed and collected;
C, shaft 7 drives perspiration sensor rotation, when perspiration sensor is contacted with sweat adsorption layer 3, is sensed by sweat Device carries out ion detection to the sweat on sweat adsorption layer 3, and sweat simultaneously adheres on perspiration sensor, and the data of detection enter Then information acquisition device 9 shows detection ion concentration data by electronic display 2;
D, shaft 7 drives perspiration sensor to continue to rotate, when perspiration sensor, which is rotated to, to be contacted with sweat scavenger layer 11, Sweat scavenger layer 11 can absorb the sweat adhered on perspiration sensor, guarantee the cleaning of perspiration sensor;
E, shaft 7 continues to rotate, and perspiration sensor is contacted with sweat adsorption layer 3 again, again to the ion concentration of sweat It is detected.
Sweat adsorption layer 3 includes cation-exchange paper and hydrophobic cloth, and is suppressed by cation-exchange paper and hydrophobic cloth, Hydrophilic micro-fluidic grid is woven on hydrophobic cloth.Cation-exchange paper is used for sodium ion and potassium ion, and hydrophobic cloth is used In the collection of sweat, so, it is possible to carry out good absorption to the sweat of sporter so that sweat it is opposite detection limit it is bigger, The error of detection is smaller, and detection accuracy is high.
Shaft 7, micro machine 8, perspiration sensor, collection box and sweat scavenger layer 11 are respectively positioned on inside casing 1.By shaft 7, Micro machine 8, perspiration sensor, collection box and sweat scavenger layer 11 are arranged in casing 1, so that the structure of detection device is more It is compact, it is more convenient for wearing.
Perspiration sensor includes sodium electrode 4, potassium electrode 5 and reference electrode 6, sodium electrode 4, potassium electrode 5 and reference electrode 6 with Information acquisition device 9 is electrically connected, and sodium electrode 4 is the carbon nanotube of kayexalate cladding, and potassium electrode 5 is polystyrolsulfon acid The carbon nanotube of potassium cladding, reference electrode 6 are the carbon nanotube of polyvinyl butyral cladding.Wherein sodium electrode 5, potassium electrode 5 Electrode potential signal Es is generated according to sodium ion, potassium concentration variation in sweat between reference electrode 6, information is transmitted to and adopts Then storage 9 shows detection ion concentration data by electronic display 2.
In stepb, sweat adsorption layer is covered on the skin at forehead.
High-absorbent material made of sweat scavenger layer 11 is chitosan and is acrylic acid-grafted.
The method of high-absorbent material:
A: molecular mass 5.5*10 is selected5Chitosan 100g, be dissolved in 250ml acrylic acid solution, stir, keep shell poly- Sugared sufficiently dissolution, obtains mixed solution A;
B: after dissolution, nitrogen is filled with into solution A, and initiator is added in stirring, and initiator is 4 concentration The Mn of 0.006mol/L3+, obtain solution B;
C, 90 DEG C is heated to B solution, after reacting 90min, using in sodium hydroxide solution and B solution, so that B solution pH Value 7 obtains C solution after neutralization;
D, C solution is dehydrated, obtains high-absorbent material after crushing drying.
Embodiment three:
A kind of detection method of quick detection sweat intermediate ion concentration, including a kind of sweat ion detection device, detection dress It sets including casing 1 and power supply 12, the surface of casing 1 is provided with electronic display 2 and sweat adsorption layer 3, and the one of sweat adsorption layer 3 Side is rotatably connected to shaft 7, and micro machine 8 is connected in shaft 7, and perspiration sensor, sweat sensing are equipped on the circumferential surface of shaft 7 Device is electrically connected with information acquisition device 9, and shaft 7 is far from being provided with sweat collection box 10, sweat on another circumferential surface of perspiration sensor Collection box 10 is provided with sweat scavenger layer 11, sweat scavenger layer 11 and perspiration sensor clearance fit;Sodium electrode 4, potassium electrode 5, Reference electrode 6, micro machine 8, information acquisition device 9 and electronic display 2 are electrically connected with power supply 12;Detection method is as follows:
A, before use, three times using deionized water cleaning sweat adsorption layer 3 first, drying, and in sweat collection box 10 Place sweat scavenger layer 11;
B, before movement, sweat adsorption layer 3 is covered on to the surface of skin, in motion process, after skin perspiration, is inhaled by sweat Sweat on 3 pairs of skin of attached layer is adsorbed and collected;
C, shaft 7 drives perspiration sensor rotation, when perspiration sensor is contacted with sweat adsorption layer 3, is sensed by sweat Device carries out ion detection to the sweat on sweat adsorption layer 3, and sweat simultaneously adheres on perspiration sensor, and the data of detection enter Then information acquisition device 9 shows detection ion concentration data by electronic display 2;
D, shaft 7 drives perspiration sensor to continue to rotate, when perspiration sensor, which is rotated to, to be contacted with sweat scavenger layer 11, Sweat scavenger layer 11 can absorb the sweat adhered on perspiration sensor, guarantee the cleaning of perspiration sensor;
E, shaft 7 continues to rotate, and perspiration sensor is contacted with sweat adsorption layer 3 again, again to the ion concentration of sweat It is detected.
Sweat adsorption layer 3 includes cation-exchange paper and hydrophobic cloth, and is suppressed by cation-exchange paper and hydrophobic cloth, Hydrophilic micro-fluidic grid is woven on hydrophobic cloth.Cation-exchange paper is used for sodium ion and potassium ion, and hydrophobic cloth is used In the collection of sweat, so, it is possible to carry out good absorption to the sweat of sporter so that sweat it is opposite detection limit it is bigger, The error of detection is smaller, and detection accuracy is high.
Shaft 7, micro machine 8, perspiration sensor, collection box and sweat scavenger layer 11 are respectively positioned on inside casing 1.By shaft 7, Micro machine 8, perspiration sensor, collection box and sweat scavenger layer 11 are arranged in casing 1, so that the structure of detection device is more It is compact, it is more convenient for wearing.
Perspiration sensor includes sodium electrode 4, potassium electrode 5 and reference electrode 6, sodium electrode 4, potassium electrode 5 and reference electrode 6 with Information acquisition device 9 is electrically connected, and sodium electrode 4 is the carbon nanotube of kayexalate cladding, and potassium electrode 5 is polystyrolsulfon acid The carbon nanotube of potassium cladding, reference electrode 6 are the carbon nanotube of polyvinyl butyral cladding.Wherein sodium electrode 5, potassium electrode 5 Electrode potential signal Es is generated according to sodium ion, potassium concentration variation in sweat between reference electrode 6, information is transmitted to and adopts Then storage 9 shows detection ion concentration data by electronic display 2.
In stepb, sweat adsorption layer is covered on the skin at forehead.
High-absorbent material made of sweat scavenger layer 11 is chitosan and is acrylic acid-grafted.
The method of high-absorbent material:
A: molecular mass 5.5*10 is selected5Chitosan 100g, be dissolved in 250ml acrylic acid solution, stir, keep shell poly- Sugared sufficiently dissolution, obtains mixed solution A, and after stirring finishes to obtain mixed liquor A, into mixed solution A, molecular weight is added 1000-1500*105Polyacrylamide 4g, and using revolving speed 1000-1500r/min stirring 3min after aquation;
B: after dissolution, nitrogen is filled with into solution A, and initiator is added in stirring, and initiator is 4 concentration The Mn of 0.006mol/L3+, obtain solution B;
C, 90 DEG C is heated to B solution, after reacting 90min, using in sodium hydroxide solution and B solution, so that B solution pH Value 7 obtains C solution after neutralization;
D, C solution is dehydrated, obtains high-absorbent material after crushing drying.
In use, sweat is adsorbed using sweat adsorption layer, then utilizes sodium electrode and the potassium electricity of rotation Extremely the sweat of sweat adsorption layer is detected, and the sweat on sodium electrode and potassium electrode is carried out clearly using sweat scavenger layer It removes, realizes the real-time detection and monitoring to sporter's sweat, the dehydration of real time reaction sporter and fatigue conditions, remind sporter Movement adjustment and supplement electrolyte are made in time, can be avoided sporter because largely sweating, body Inner electrolysis mass flow is lost and led It causes the injury to sporter's body that alarm can also be set in casing in utilization, the fatigue strength of sporter is reported It is alert.
By embodiment one, embodiment two and embodiment three, can to the sodium in sporter during the motion sweat from Son and potassium ion are detected, and the high-absorbent material in embodiment three is improved than the service life of embodiment one and embodiment two 30%.
The above examples are only used to illustrate the technical scheme of the present invention and are not limiting, although referring to preferred embodiment to this hair It is bright to be described in detail, those skilled in the art should understand that, it can modify to technical solution of the present invention Or equivalent replacement should all cover without departing from the objective and range of technical solution of the present invention in claim of the invention In range.Technology not described in detail in the present invention, shape, construction portion are well-known technique.

Claims (8)

1. a kind of detection method of quickly detection sweat intermediate ion concentration, it is characterised in that: filled including a kind of sweat ion detection It sets, the detection device includes casing and power supply, and the power supply is mounted on casing internal, and the surface of the casing is provided with information Display system and sweat adsorption layer, the side of the sweat adsorption layer are rotatably connected to shaft, micro- electricity are connected in the shaft Machine, is equipped with perspiration sensor on the circumferential surface of the shaft, and the perspiration sensor is electrically connected with information acquisition system, and described turn Axis is provided with sweat scavenger layer far from sweat collection box, the sweat collection box is provided on another circumferential surface of perspiration sensor, The sweat scavenger layer and perspiration sensor clearance fit, the perspiration sensor, micro machine, information acquisition system and information are aobvious Show that system is electrically connected to a power source;Detection method is as follows:
A, before use, being dried, and place sweat in sweat collection box first using deionized water cleaning sweat adsorption layer 2-3 times Liquid scavenger layer;
B, before movement, sweat adsorption layer is covered on to the surface of skin, in motion process, after skin perspiration, by sweat adsorption layer Sweat on skin is adsorbed and collected;
C, shaft drives perspiration sensor rotation, when perspiration sensor is contacted with sweat adsorption layer, by perspiration sensor to sweat Sweat on liquid adsorption layer carries out ion detection, and sweat simultaneously adheres on perspiration sensor, and the data of detection enter information and adopt Then collecting system shows detection ion concentration data by information display system;
D, shaft drives perspiration sensor to continue to rotate, and when perspiration sensor, which is rotated to, to be contacted with sweat scavenger layer, sweat is clear Except layer absorbs the sweat adhered on perspiration sensor, guarantee the cleaning of perspiration sensor;
E, shaft continues to rotate, and perspiration sensor is contacted with sweat adsorption layer again, examines again to the ion concentration of sweat It surveys.
2. a kind of detection method of quickly detection sweat intermediate ion concentration according to claim 1, it is characterised in that: described Sweat adsorption layer includes cation-exchange paper and hydrophobic cloth, and is suppressed by cation-exchange paper and hydrophobic cloth, described hydrophobic Hydrophilic micro-fluidic grid is woven on cloth.
3. a kind of detection method of quickly detection sweat intermediate ion concentration according to claim 2, it is characterised in that: described Shaft, micro machine, perspiration sensor, collection box and sweat scavenger layer are respectively positioned on casing internal.
4. a kind of detection method of quickly detection sweat intermediate ion concentration according to claim 3, it is characterised in that: described Perspiration sensor includes sodium electrode, potassium electrode and reference electrode, the sodium electrode, potassium electrode and reference electrode and information collection system System is electrically connected, and the sodium electrode is the carbon nanotube of kayexalate cladding, and the potassium electrode is polystyrolsulfon acid The carbon nanotube of potassium cladding, the reference electrode are the carbon nanotube of polyvinyl butyral cladding.
5. a kind of detection method of quickly detection sweat intermediate ion concentration according to claim 4, it is characterised in that: step In b, sweat adsorption layer is covered on the wherein skin at one of forehead, neck, trunk front and back, waist, the back of the hand or forearm.
6. a kind of detection method of quickly detection sweat intermediate ion concentration according to claim 5, it is characterised in that: described High-absorbent material made of sweat scavenger layer is chitosan and is acrylic acid-grafted.
7. a kind of detection method of quickly detection sweat intermediate ion concentration according to claim 6, it is characterised in that: described The preparation method of high-absorbent material, includes the following steps,
A: molecular mass 5.1-6.0*10 is selected5Chitosan 100g, be dissolved in acrylic acid solution, stir, keep chitosan abundant Dissolution, obtains mixed solution A;
B: after dissolution, nitrogen is filled with into solution A, and initiator is added in stirring, and initiator is concentration 0.006mol/ The Mn of L3+, obtain solution B;
C, 85-95 DEG C is heated to B solution, after reacting 80-100min, using in sodium hydroxide solution and B solution, so that B is molten Liquid pH value 6.5-7.5, obtains C solution after neutralization;
D, C solution is dehydrated, obtains high-absorbent material after crushing drying.
8. a kind of detection method of quickly detection sweat intermediate ion concentration according to claim 7, it is characterised in that: described In step a, after stirring finishes to obtain mixed liquor A, into mixed solution A, molecular weight 1000-1500*10 is added5Polypropylene Amide 3-5g, and use aquation after the blender of revolving speed 1000-1500r/min stirring 2-3min.
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