CN107631290A - A kind of flue gas waste heat recovery system absorbed based on film - Google Patents

A kind of flue gas waste heat recovery system absorbed based on film Download PDF

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Publication number
CN107631290A
CN107631290A CN201710825968.1A CN201710825968A CN107631290A CN 107631290 A CN107631290 A CN 107631290A CN 201710825968 A CN201710825968 A CN 201710825968A CN 107631290 A CN107631290 A CN 107631290A
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flue gas
heat exchanger
water
boiler
heat
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CN201710825968.1A
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CN107631290B (en
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张群力
王明爽
张琳
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Beijing University of Civil Engineering and Architecture
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Beijing University of Civil Engineering and Architecture
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/34Indirect CO2mitigation, i.e. by acting on non CO2directly related matters of the process, e.g. pre-heating or heat recovery

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Abstract

The invention belongs to gas fired-boiler flue gas heat recovery and film absorption technique field, is related to a kind of flue gas waste heat recovery system absorbed based on film.The system includes gas fired-boiler, vacuum diaphragm moisture recover, perineurium heat exchanger, indirect heat exchanger, air preheater, heating network, chimney etc.;Flue gas passes through the vacuum hollow fiber membrane bundle in vacuum diaphragm moisture recover, vapor in wet flue gas is separated with dry flue gas, dry flue gas after separation passes sequentially through indirect heat exchanger and air preheater, water and air will be returned by waste heat to heat, the water vapour of separation enters perineurium heat exchanger simultaneously, and the once heating backwater in water preventing ability hollow fiber membrane bundle is further heated, feeding boiler or secondary pipe network user nearby, vapor after heat exchange is condensed, can directly boiler of feeding moisturizing.The system can realize the separating dry space from moist space of flue gas, and the water vapour and dry flue gas institute band heat energy after separation are efficiently utilized, and have been saved water resource and have been reduced the phenomenon that chimney emits white cigarette.

Description

A kind of flue gas waste heat recovery system absorbed based on film
Technical field
It is more particularly to a kind of to be based on film the invention belongs to gas fired-boiler flue gas heat recovery and film absorption technique field The flue gas waste heat recovery system of absorption.
Background technology
The main component of natural gas is methane, and substantial amounts of vapor can be produced after burning, because exhaust gas temperature is typically 180 ~250 DEG C, part sensible heat and whole latent heat in vapor can be discharged into air together with smoke evacuation, cause heat losses and Water resource waste, in order to reduce energy waste and saving water resource, it is ten to carry out depth recuperation of heat and Water Sproading to fume afterheat Divide necessary.
Current waste heat recovery mode has direct contact heat transfer and indirect type heat exchange, and indirect type exchanges heat due to floor space Greatly, heat exchanged thermoresistance is larger, and heat exchange is insufficient, and requires that heat exchanger will have higher antiseptic power.Although direct contact heat transfer The sufficient sensible heat of recovered flue gas of energy and the condensation heat of most of flue gas, but flue gas is in acid with the water after water heat exchange, it is impossible to Directly use, cause great lot of water resources to waste.
The content of the invention
It is an object of the invention to provide a kind of flue gas waste heat recovery system absorbed based on film, by gas fired-boiler 1, vacuum diaphragm Moisture recover 3, perineurium heat exchanger 4, indirect heat exchanger 5, once air preheater 6, net backwater 7, once net water supply 9, chimney 18 and some attached water pumps, blower fan composition;
Wherein, gas fired-boiler 1, vacuum diaphragm moisture recover 3, indirect heat exchanger 5, air preheater 6, chimney 18 connect successively Connect, vacuum diaphragm moisture recover 3 and perineurium heat exchanger 4 are integrated connection, and the water penetration vacuum of vertical distribution is hollow in recover 3 Fiber-film bundle 19 is communicated with the cavity of heat exchanger 4, and water preventing ability hollow fiber membrane bundle 20 is horizontally distributed in the cavity of heat exchanger 4 simultaneously And both sides connect boiler 1 and the once pipeline of net backwater respectively, the preheating of the condensed water and air preheater of perineurium heat exchanger is empty Gas enters boiler by pipeline.
The gas fired-boiler 1 is general Medium and small gas boiler, using combustion gas 14 as fuel, transfers heat to boiler and enters After water 8, form once net water supply 9 and carry out heat supplies.
The vacuum diaphragm moisture recover 3 employs doughnut, and inside hollow fibre is vacuum, utilizes hollow-fibre membrane The pressure difference of both sides, the wet flue gas 2 of boiler export is subjected to separating dry space from moist space, the flue gas after dehumidification enters indirect heat exchanger 5, isolates High-temperature vapor enter perineurium heat exchanger 4.
The perineurium heat exchanger 4 is made up of a kind of hollow fiber membrane bundle with water preventing ability, using hollow fiber membrane bundle outside Once heating backwater 17 of the water vapor condensation liberated heat heating of side after indirect heat exchanger 5 tentatively heating, by entering Become boiler feed water 8 after the heating of one step, and the condensed water 12 that water vapor condensation is formed can use as boiler replenishing water.
The indirect heat exchanger 5 is a flue gas and the indirect heat exchanger of water heat exchange, from vacuum diaphragm moisture recover 3 Dry flue gas 15 carries out heat exchange with once net backwater 7, and once net backwater 7 becomes once to heat backwater 17 by heating, with Enter perineurium heat exchanger 4 afterwards, and dry flue gas becomes the relatively low flue gas 16 of temperature after heat exchange cools, and subsequently enters air preheat Device 6.
The air preheater 6 is the indirect heat exchanger that is exchanged with atmospheric heat of in general flue gas, heat quilt in flue gas 16 It is delivered in air 10, the air 11 after preheating is burnt into boiler, and the flue gas after heat exchange is then arranged into chimney 18 It is put into air.
The present invention has the advantages that compared with prior art:
1. vacuum diaphragm moisture recover has the characteristics of wet flue gas is carried out into separating dry space from moist space, the dry flue gas dew point temperature after dehumidification Degree reduces, and when subsequently being exchanged heat, can ensure not condense at a lower temperature, and efficiently solving flue gas waste heat recovery will The problem of seeking anti-corrosion.
2. the high-temperature vapor isolated condenses after being exchanged heat in perineurium heat exchanger with once net backwater, due to vacuum film water It is divided to the characteristic of two kinds of films in recover and perineurium heat exchanger, pure condensed water is formed after vapor heat exchange, boiler can be used as to mend Water uses, and efficiently solves water resource waste problem.
3. it is provided by the invention based on film absorb flue gas waste heat recovery system can not only high efficiente callback fume afterheat, and And can moisture effectively in recovered flue gas, have and improve boiler thermal output, the advantages that saving water resource.
Brief description of the drawings
Fig. 1 is the schematic diagram of the flue gas waste heat recovery system absorbed based on film.
Fig. 2 is vacuum diaphragm moisture recover and perineurium heat exchanger schematic diagram
Corresponding relation wherein in figure between reference and component names is:1- gas fired-boilers, 2- high temperature wet flue gas, 3- Vacuum diaphragm moisture recover, 4- perineurium heat exchangers, 5- indirect heat exchangers, 6- air preheaters, once net backwater, 8- boilers enter 7- Water, 9- once net water supply, 10- air, air after 11- preheatings, 12- condensed waters/boiler replenishing water, 13- discharge flue gases, 14- combustion gas, High-temperature flue gas after 15- dehumidifications, low-temperature flue gas after 16- dehumidifications, 17- once heat backwater, 18- chimneys, and 19- water penetration vacuum is hollow Fiber-film bundle, 20- water preventing ability hollow fiber membrane bundles.
Embodiment
The invention provides it is a kind of based on film absorb flue gas waste heat recovery system, the present invention is made below in conjunction with the accompanying drawings into One step explanation.
Fig. 1 show the schematic diagram of the flue gas waste heat recovery system absorbed based on film.More than the flue gas absorbed based on film Heat recovery system, it is mainly pre- by gas fired-boiler 1, vacuum diaphragm moisture recover 3, perineurium heat exchanger 4 and indirect heat exchanger 5, air Hot device 6, once net backwater 7 form with once net water supply 9, chimney 18 and some attached water pumps, blower fan;
Wherein, gas fired-boiler 1, vacuum diaphragm moisture recover 3, indirect heat exchanger 5, air preheater 6, chimney 18 connect successively Connect, vacuum diaphragm moisture recover 3 and perineurium heat exchanger 4 are integrated connection (as shown in Figure 2), and vertical distribution is saturating in recover 3 Water-based vacuum hollow fiber membrane bundle 19 is communicated with the cavity of perineurium heat exchanger 4, and water preventing ability hollow fiber membrane bundle 20 is horizontally distributed in In the cavity of heat exchanger 4 and both sides connect boiler 1 and the once pipeline of net backwater, the condensed water and sky of perineurium heat exchanger respectively The preheated air of air preheater enters boiler by pipeline.
Vacuum diaphragm moisture recover 3 and perineurium heat exchanger 4 of the present invention, it make use of hollow fiber hydrophobic membrane and hollow The characteristic of fiber hydrophilic film, gas fired-boiler 1 burn caused by high temperature wet flue gas 2 initially enter in vacuum diaphragm moisture recover, will High temperature wet flue gas carries out separating dry space from moist space, and the high-temperature flue gas 15 after dehumidification enters indirect heat exchanger 5, and high-temperature vapor enters water penetration Vacuum hollow fiber membrane bundle 19, subsequently enter perineurium heat exchanger 4.The water vapour content of dehumidification high-temperature flue gas 15 is less, dew point temperature Degree is very low, and basis is provided for follow-up waste heat recovery.
In indirect heat exchanger 5, heat is recovered further the high-temperature flue gas 15 of dehumidification in flue gas, is delivered to and is once netted back In water 7, temperature is relatively low in indirect heat exchanger once net recovery 7 and flue gas carry out indirect heat exchange, and the overwhelming majority is aobvious in flue gas Heat is recovered, and because the water vapour content of dehumidification high-temperature flue gas 15 is less, dew-point temperature is very low, therefore even in sensible heat only occurs In the case of recovery, most heats in dehumidification high-temperature flue gas can be also recovered.
In the air inlet preheater 6 of low-temperature flue gas 16 after heat exchange, heat is recovered further utilization, for preheated air 10, air 11 enters boiler after preheating, further improves boiler thermal output.
In perineurium heat exchanger, high-temperature vapor and once adding in hollow-fibre membrane beam tube on the outside of hollow-fibre membrane beam tube Hot backwater 17 carries out heat exchange, and high-temperature vapor condensation gives off heat to be delivered to and once heated in backwater 17, once nets back here Coolant-temperature gage further improves, and can not only be used for boiler feed water 8, can also be sent into secondary network water supply line nearby, direct heating user Use.
Caused condensed water after high-temperature vapor heat exchange, because it is not all contacted in whole process with other media, because This is regarded as pure water, while high efficiente callback waste heat, and effectively can reclaim flue gas directly as boiler replenishing water 12 In moisture, saved water resource.
Vacuum diaphragm moisture recover as shown in Figure 2 and the operation principle of perineurium heat exchanger, in vacuum diaphragm moisture recover 3 In, the vapor in high temperature wet flue gas 2 quickly can be entered in perineurium pipe by fiber-film bundle 19 in water penetration vacuum, and cigarette Other components can not then pass through hollow-fibre membrane and enter in perineurium pipe in gas.Therefore, it is achieved that the dry and wet point of high temperature wet flue gas From.High-temperature vapor in perineurium pipe is subsequently entered in perineurium heat exchange 4, and the film in perineurium heat exchanger is water preventing ability hollow-fibre membrane Beam 20, is high-temperature vapor on the outside of water preventing ability hollow fiber membrane bundle, and inner side is once to heat backwater 17 by preliminarily heated, two Person carries out indirect heat exchange, and high-temperature vapor condensation gives off heat to be delivered to and once heated in backwater 17.
In summary, the flue gas waste heat recovery system of the present invention absorbed based on film, can be in high efficiente callback flue gas While waste heat, the moisture in recovered flue gas, and moisture is not required to subsequent treatment after recovery, can make directly as boiler replenishing water With.Not only depth has reclaimed fume afterheat and a large amount of condensed waters, also avoids the etching problem of flue gas heat exchange to a certain extent.Have Boiler thermal output is improved, the advantages that saving water resource.

Claims (6)

1. a kind of flue gas waste heat recovery system absorbed based on film, it is characterised in that system is mainly by gas fired-boiler (1), vacuum Film water divides recover (3), perineurium heat exchanger (4) and indirect heat exchanger (5), once air preheater (6), net backwater (7), once Net supplies water (9), chimney (18) and some attached water pumps, blower fan form;
Wherein, gas fired-boiler (1), vacuum diaphragm moisture recover (3), indirect heat exchanger (5), air preheater (6), chimney (18) It is sequentially connected, vacuum diaphragm moisture recover (3) and perineurium heat exchanger (4) are integrated connection, are hung down in vacuum diaphragm moisture recover (3) The water penetration vacuum hollow fiber membrane bundle (19) being directly distributed communicates with the cavity of perineurium heat exchanger (4), water preventing ability hollow-fibre membrane Beam (20) is horizontally distributed in the cavity of perineurium heat exchanger (4) and both sides connect gas fired-boiler (1) and once net backwater respectively (7) pipeline, condensed water/boiler replenishing water (12) of perineurium heat exchanger (4) and the air after the preheating of air preheater (6) (11) boiler is entered by pipeline.
2. the flue gas waste heat recovery system according to claim 1 absorbed based on film, it is characterised in that the gas fired-boiler (1) it is Medium and small gas boiler, using combustion gas (14) as fuel, after transferring heat to boiler feed water (8), forms once net and supply Water (9) carries out heat supply.
3. the flue gas waste heat recovery system according to claim 1 absorbed based on film, it is characterised in that the vacuum film water Divide recover (3) to employ the hollow fiber membrane bundle composition with hydrone selective coating, be true inside hollow fiber membrane bundle Sky, using the pressure difference inside and outside perineurium, the high temperature wet flue gas (2) of boiler flue gas outlet is subjected to separating dry space from moist space, after subsequent dehumidification Flue gas enters indirect heat exchanger (5), and the high-temperature vapor isolated enters perineurium heat exchanger (4).
4. the flue gas waste heat recovery system absorbed based on film according to claim 1 or 3, it is characterised in that the perineurium Heat exchanger (4) by a kind of there is the hollow fiber membrane bundle for hindering hydrone to pass through to form, and utilize the water vapor condensation on the outside of perineurium Liberated heat heating flows through and once heats backwater (17) by preliminarily heated after indirect heat exchanger (5), by further heating After become boiler feed water (8), and the condensed water (12) that water vapor condensation is formed uses as boiler replenishing water.
5. the flue gas waste heat recovery system absorbed based on film according to claim 1 or 3, it is characterised in that described indirect Heat exchanger (5) is a flue gas and the indirect heat exchanger of water heat exchange, the dry flue gas (15) from vacuum diaphragm moisture recover (3) Heat exchange is carried out with once net backwater (7), once net backwater (7) becomes once to heat backwater (17) by heating, with laggard Enter perineurium heat exchanger (4), and dry flue gas becomes the relatively low flue gas of temperature (16) after heat exchange cools, and subsequently enters air preheat Device (6).
6. the flue gas waste heat recovery system absorbed according to claim 1 or 5 based on film, it is characterised in that the air Preheater (6) is the indirect heat exchanger that is exchanged with atmospheric heat of flue gas, and heat is passed in air (10) in flue gas (16), in advance Air (11) after heat is burnt into boiler, and the flue gas after heat exchange is then discharged in air into chimney (18).
CN201710825968.1A 2017-09-14 2017-09-14 A kind of flue gas waste heat recovery system absorbed based on film Active CN107631290B (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108443904A (en) * 2018-04-19 2018-08-24 北京中矿赛力贝特节能科技有限公司 A kind of power-plant flue gas based on heat pipe heat exchanging technology disappears white system
CN109268861A (en) * 2018-09-20 2019-01-25 北京建筑大学 Based on the latent waste heat recycling of the flue gas condensing humidified in mixed gas and burner hearth and purification system
CN109331614A (en) * 2018-11-12 2019-02-15 中国华电科工集团有限公司 The recovery system and method for Combined cycle gas-steam turbine unit fume afterheat and moisture
CN110410816A (en) * 2018-07-24 2019-11-05 青岛科技大学 A kind of station boiler afterheat utilizing system of intelligence communication control fan operation
CN112212728A (en) * 2020-09-28 2021-01-12 巢湖云海镁业有限公司 Flue gas treatment device and flue gas waste heat recovery device for magnesium alloy processing
CN113091082A (en) * 2019-12-23 2021-07-09 大唐环境产业集团股份有限公司 Flue gas waste heat and moisture recycle's system

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CN206463745U (en) * 2016-12-14 2017-09-05 华北电力大学 A kind of device based on hollow ceramic membranes recovered flue gas moisture and waste heat
CN107149865A (en) * 2017-05-24 2017-09-12 华中农业大学 CO based on vapor mass transfer enhancement waste heat recovery2Chemical absorbing System and method for

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CN103120886A (en) * 2013-01-25 2013-05-29 重庆大学 Method for efficiently removing CO2 from flue gas with utilization of hollow fiber hydrophobic membrane
CN203501818U (en) * 2013-09-05 2014-03-26 山东金升有色集团有限公司 Recycling device for afterheat and dust in reclaimed copper refining smoke
CN104014243A (en) * 2013-12-13 2014-09-03 南京工业大学 Ceramic membrane condensation treatment recycling method for smoke waste heat and water of power plant
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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108443904A (en) * 2018-04-19 2018-08-24 北京中矿赛力贝特节能科技有限公司 A kind of power-plant flue gas based on heat pipe heat exchanging technology disappears white system
CN110410816A (en) * 2018-07-24 2019-11-05 青岛科技大学 A kind of station boiler afterheat utilizing system of intelligence communication control fan operation
CN109268861A (en) * 2018-09-20 2019-01-25 北京建筑大学 Based on the latent waste heat recycling of the flue gas condensing humidified in mixed gas and burner hearth and purification system
CN109331614A (en) * 2018-11-12 2019-02-15 中国华电科工集团有限公司 The recovery system and method for Combined cycle gas-steam turbine unit fume afterheat and moisture
CN113091082A (en) * 2019-12-23 2021-07-09 大唐环境产业集团股份有限公司 Flue gas waste heat and moisture recycle's system
CN112212728A (en) * 2020-09-28 2021-01-12 巢湖云海镁业有限公司 Flue gas treatment device and flue gas waste heat recovery device for magnesium alloy processing
CN112212728B (en) * 2020-09-28 2022-03-22 巢湖云海镁业有限公司 Flue gas treatment device and flue gas waste heat recovery device for magnesium alloy processing

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