CN107629628A - A kind of preparation method of the anti-skidding floor paint of high-antistatic - Google Patents
A kind of preparation method of the anti-skidding floor paint of high-antistatic Download PDFInfo
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Abstract
The present invention relates to coating material preparing technical field, and in particular to a kind of preparation method of the anti-skidding floor paint of high-antistatic.The present invention is modified using polyethylene glycol to obtained bisphenol A type epoxy resin, bisphenol A type epoxy resin molecule with antistatic property and non-skid property is dispersed in filler surface, improve the antistatic property and non-skid property of floor paint, add organobentonite and gas-phase silica, promote the skidproof effect of floor paint splendid, quartz sand powder is modified with titanate coupling agent 201, and fermented with vegetable oil and Yoghourt blending, so as to improve non-skid property, it is subsequently added into mica powder and zinc oxide these antistatic materials, improve antistatic property, continuously add dispersant, defoamer and anti-settling agent, play the protection to floor paint moderate resistance electrostatic substance and non-slippery substance, the antistatic property and non-skid property of terrace after floor paint are smeared in raising, it is with a wide range of applications.
Description
Technical field
The present invention relates to coating material preparing technical field, and in particular to a kind of preparation side of the anti-skidding floor paint of high-antistatic
Method.
Background technology
Floor paint is to be invented by Germany in 1934 earliest, is mainly made up of oil plant, tree material, color, solvent etc., mainly
It is divided into ornamental floor paint, heavy antisepsis floor paint, resistance to heavily loaded floor paint etc..Floor paint by a variety of different materials it is blended, dissolving,
Many end production process such as scattered are manufactured and formed.Floor paint has the characteristics that beautiful, true, attractive in appearance, wear-resisting, waterproof, anti-corrosion.
At present, floor paint mainly has epoxide terrace paint, polyurethane floor paint, corrosion-resistant ground floor paint, elastic terrace paint, anti-quiet
Electric floor paint, anti-skidding floor paint, can 7 kinds of load-carrying floor paint, but based on epoxide terrace paint and polyurethane floor paint.Epoxy
Level ground can be divided into solvent-borne type and no-solvent type, no matter it is any, all more or less contain organic solvent, and indivedual solvent-free floor paints
Used in reactive diluent contain toxic component.And polyurethane floor can have free isocyanate in work progress,
These can all bring harm to environmental and human health impacts.Organic solvent in floor paint, exist to human body and environment different degrees of
Harm.1st, substantial amounts of VOC is contained in coating, it can outwards volatilize substantial amounts of toxic chemical substance in use, its
In, benzene, formaldehyde, dimethylbenzene be all poisonous and hazardous chemical gas；2nd, these organic solvents evaporateing into air while also make
Wasted into very serious petroleum resources；3rd, oil paint category combustible and explosive articles, exist in the production and use process very
Big potential safety hazard；4th, the worker of Long Term Contact oil paint, its life security are on the hazard.
In recent years, with national environmental protection and the reinforcement of worker's labour protection, with the floor coatings work of water substitution organic solvent
Skill has become the important directions of floor paint development.However, at this stage water-based floor paint antistatic other aspect of performances of grade without
Method is compared with the oiliness floor paint of maturation.Solvent-borne type floor coatings require higher in construction to base material humidity and ambient humidity；
Water-based terrace, without too big requirement, because of its non-ignitable not quick-fried property, in production, transport, is stored, construction to base material and ambient humidity
Etc. link more safety and environmental protection.But compared to solvent-borne type floor coatings, water-based terrace have compact in paint film is low, application property is poor,
Antistatic, the shortcomings of skidproof effect is poor, especially in the rainy day, clearly, the market share is smaller for potential safety hazard.
Therefore, developing a kind of floor paint that can solve the problem that above-mentioned performance issue is highly desirable.
The content of the invention
The technical problems to be solved by the invention：For current common floor paint although easy for construction, stain resistant, but paint film
Surface is smooth, coefficient of friction is low, not anti-skidding and antistatic effect is poor, is not suitable with the anti-skidding and anti-of the places such as parking lot or goods yard
Electrostatic requirement, especially in the rainy day, potential safety hazard clearly the defects of, there is provided a kind of preparation of the anti-skidding floor paint of high-antistatic
Method.
In order to solve the above technical problems, the present invention is using technical scheme as described below：
A kind of preparation method of the anti-skidding floor paint of high-antistatic, it is characterised in that specifically preparation process is：
（1）20~30g bisphenol-As and 45~55mL epoxychloropropane are mixed be placed in equipped with agitator, separatory funnel, thermometer and
Stirred in the four-hole boiling flask of reflux condensing tube, 20~30mL sodium hydroxide solutions, and heat temperature raising are added dropwise into separatory funnel, after
Continuous stirring, then 25~35mL deionized waters and 40~60mL toluene are added into four-hole boiling flask, continue insulated and stirred, taken advantage of after stirring
Heat pours into separatory funnel, stratification, after removing aqueous phase, is transferred in vacuum distillation plant and is evaporated in vacuo, and removes toluene and not anti-
The epoxychloropropane answered, room temperature is naturally cooled to, discharged, obtain making bisphenol A type epoxy resin by oneself；
（2）Self-control bisphenol A type epoxy resin, polyethylene glycol and hydrochloric acid solution are mixed to be placed in beaker and stirred, is naturally cooled to
Room temperature, discharging, obtain modified self-control bisphenol A type epoxy resin；
（3）Weigh after 20~35g quartzite sand grinds crush and cross 200 mesh sieves, collect sieving powder, sieving powder and titanate esters is even
Connection agent 201 mixes, and obtains mixture, continues to add the sesame oil and mixture quality of mixture quality 7% into mixture
0.6% Yoghourt, is fitted into fermentation tank, is sealed by fermentation, and after fermentation ends, takes out tunning, as Modified Quartz Sand powder；
（4）Organobentonite, gas-phase silica, mica powder and zinc oxide and peach gum and biogas slurry are fitted into fermentation tank, sealed
Fermentation, after fermentation ends, obtain tunning, then with deionized water rinsing tunning, dried after flushing, obtain being modified self-control
Mixture；
（5）Count in parts by weight, weigh modified self-control bisphenol A type epoxy resin, adjacent diamines methyl cyclopentane, modified quartz respectively
Emery dust end, modified self-control mixture, glyceryl monostearate and deionized water mixing are placed in mixer and stirred, then add talcum
Powder, sodium carboxymethylcellulose, dimethyl silicone polymer and titanium dioxide, continue to stir, naturally cool to room temperature, discharge, you can system
Obtain the anti-skidding floor paint of high-antistatic.
Step（1）Described whipping temp is 45~65 DEG C, and mixing time is 12~16min, sodium hydroxide solution quality
Fraction is 30%, rate of addition 1mL/min, and heat temperature raising temperature is 55~75 DEG C, and continuation mixing time is 1~3h, and insulation is stirred
It is 1~2h to mix the time, and vapo(u)rizing temperature is 110~120 DEG C.
Step（2）Described self-control bisphenol A type epoxy resin, polyethylene glycol and mass fraction is 15% hydrochloric acid solution
Mass ratio is 3：2：1, whipping temp is 100~110 DEG C, and mixing time is 1~3h.
Step（3）Described grinding time is 7~9min, and the mass ratio of sieving powder and titanate coupling agent 201 is 5：
1, mixing time is 12~18min, and fermentation temperature is 32~42 DEG C, and fermentation time is 9~11 days.
Step（4）The mass ratio of described organobentonite, gas-phase silica, mica powder and zinc oxide, peach gum and biogas slurry
For 2：1：3：2：1：1, fermentation temperature is 30~40 DEG C, and fermentation time is 6~8 days.
Step（5）Described meter in parts by weight, weigh respectively 25~35 parts of modified self-control bisphenol A type epoxy resins, 6~
8 parts of adjacent diamines methyl cyclopentanes, 12~16 parts of Modified Quartz Sand powder, 8~10 parts of modified self-control mixtures, 4~6 parts of stearic acid
Monoglyceride and 10~12 parts of deionized waters, 3~5 parts of talcum powder, 2~4 parts of sodium carboxymethylcelluloses, 3~5 parts of poly dimethyl silicon
Oxygen alkane and 1~3 part of titanium dioxide, whipping temp are 55~65 DEG C, and mixing time be 35~45min, continue whipping temp for 75~
95 DEG C, continuation mixing time is 1~3h.
Compared with other method, advantageous effects are the present invention：
（1）Bisphenol A type epoxy resin is prepared using bisphenol-A and epoxychloropropane in the present invention under catalysts conditions, then uses
Polyethylene glycol is modified to bisphenol A type epoxy resin, by the epoxy bond in bisphenol A type epoxy resin molecule, by poly- second two
Alcohol polar groups are introduced into bisphenol A type epoxy resin molecular skeleton, and these hydrophilic polar groups can help bisphenol type epoxy tree
Fat disperses in water, and the bisphenol A type epoxy resin molecule for making to have antistatic property and non-skid property is dispersed in other fill out
Expect surface, so as to improve smear floor paint after terrace antistatic property and non-skid property, add organobentonite and gas phase
White carbon, because during epoxy hardener is added, epoxy resin and epoxy hardener in paint solution start reaction and forms hydroxyl
Base, hydroxyl are highly polar groups, raise the polarity of system, because gas-phase silica is to Polarity comparision sensitivity, its silica
Between Hydrogen bonding forces can be reduced with the rise of system polarity, so as to reduce the thixotropy triggered by silica,
And as the polarity of mixing paint solution improves constantly, bentonite increased activity, hydroxyl also contributes to bentonite lamella structure
Between key between adsorb so that the thixotropy triggered by organobentonite is improved, in gas-phase silica and have in addition
When the bentonitic ratio of machine reaches certain condition, both thixotropy changes reach a relative equilibrium, so that whole system
Thixotropy extension over time without obvious change, the skidproof effect for promoting to smear terrace after floor paint obtains
Improve；
（2）The present invention is modified using titanate coupling agent 201 to quartz sand powder, and itself and vegetable oil and Yoghourt blending are sent out
Ferment, plant oil decomposition is produced into lipophile ester group using microorganism in Yoghourt, and cause ester under the self-crosslinking of microorganism
Base is grafted to part resin surface, enhances the compatibility of quartz sand powder and high polymer, promotes the non-skid property of resin to improve,
So as to improve the non-skid property for smearing terrace after floor paint, mica powder and zinc oxide these antistatic materials are added, by peach gum
The sticking macromolecular carbohydrate of tool is resolved under microorganism, these antistatic materials is dispersed in inside floor paint, from
And the antistatic property of terrace after smearing floor paint is improved, continuously add dispersant, defoamer and anti-settling agent, wherein dispersant energy
Promote the compatibility between filler and filler, defoamer can eliminate in addition easily forms asking for foam under surface-active action
Topic, does not interfere with compact in paint film degree, and will not produce micropore, so as to play to floor paint moderate resistance electrostatic substance and non-slippery substance
Protection, finally because anti-settling agent can be such that conducting medium and other components are evenly distributed in system, it is steady to not only increase storage
It is qualitative, the uniformity of coating resistance value is also helped, further improves and smears after floor paint the antistatic property of terrace and anti-skidding
Performance, it is with a wide range of applications.
Embodiment
20~30g bisphenol-As and 45~55mL epoxychloropropane are mixed and are placed in equipped with agitator, separatory funnel, thermometer
In the four-hole boiling flask of reflux condensing tube, 12~16min is stirred at 45~65 DEG C, into separatory funnel with 1mL/min speed
Degree is added dropwise 20~30mL mass fractions and is 30% sodium hydroxide solution, and is heated to 55~75 DEG C, continues 1~3h of stirring,
25~35mL deionized waters and 40~60mL toluene are added into four-hole boiling flask again, continues 1~2h of insulated and stirred, after stirring while hot
Separatory funnel is poured into, stratification, after removing aqueous phase, is transferred in vacuum distillation plant, vacuum at being 110~120 DEG C in temperature
Distillation, toluene and unreacted epoxychloropropane are removed, naturally cools to room temperature, discharged, obtain making bisphenol type epoxy tree by oneself
Fat, it is in mass ratio 3：2：1 mixes the hydrochloric acid solution that bisphenol A type epoxy resin, polyethylene glycol and mass fraction are 15% is made by oneself
Conjunction is placed in beaker, and 1~3h is stirred at 100~110 DEG C, naturally cools to room temperature, is discharged, and obtains modified self-control bisphenol A-type
Epoxy resin, weigh 20~35g quartzite sand grinds crush 7~9min after cross 200 mesh sieves, collect sieving powder, in mass ratio for
5：Sieving powder and titanate coupling agent 201 are mixed 12~18min by 1, are obtained mixture, are continued to add into mixture
The sesame oil of mixture quality 7% and the Yoghourt of mixture quality 0.6%, are fitted into fermentation tank, are 32~42 DEG C of conditions in temperature
It is lower to be sealed by fermentation 9~11 days, after fermentation ends, tunning, as Modified Quartz Sand powder are taken out, is in mass ratio 2：1：3：
2：1：1 is fitted into organobentonite, gas-phase silica, mica powder and zinc oxide and peach gum and biogas slurry in fermentation tank, 30~
It is sealed by fermentation 6~8 days at 40 DEG C, after fermentation ends, obtains tunning, then with deionized water rinsing tunning, after flushing
Dry, obtain modified self-control mixture, count in parts by weight, weigh respectively 25~35 parts of modified self-control bisphenol A type epoxy resins,
6~8 parts of adjacent diamines methyl cyclopentanes, 12~16 parts of Modified Quartz Sand powder, 8~10 parts of modified self-control mixtures, 4~6 parts it is hard
Resin acid monoglyceride and 10~12 parts of deionized water mixing are placed in mixer, 35~45min are stirred at 55~65 DEG C, then add
Add 3~5 parts of talcum powder, 2~4 parts of sodium carboxymethylcelluloses, 3~5 parts of dimethyl silicone polymers and 1~3 part of titanium dioxide, 75~
Continue 1~3h of stirring at 95 DEG C, naturally cool to room temperature, discharge, you can the anti-skidding floor paint of high-antistatic is made.
Example 1
20g bisphenol-As and 45mL epoxychloropropane are mixed and are placed in equipped with agitator, separatory funnel, thermometer and reflux condensing tube
Four-hole boiling flask in, stir 12min at 45 DEG C, into separatory funnel using 1mL/min speed be added dropwise 20mL mass fractions as
30% sodium hydroxide solution, and 55 DEG C are heated to, continue to stir 1h, then add 25mL deionized waters into four-hole boiling flask
With 40mL toluene, continue insulated and stirred 1h, pour into separatory funnel after stirring while hot, stratification, after removing aqueous phase, be transferred to vacuum
In distillation equipment, it is evaporated in vacuo at being 110 DEG C in temperature, removes toluene and unreacted epoxychloropropane, naturally cool to room
Temperature, discharging, obtain making bisphenol A type epoxy resin by oneself, be in mass ratio 3：2：1 will self-control bisphenol A type epoxy resin, polyethylene glycol
It is placed in mass fraction for 15% hydrochloric acid solution mixing in beaker, stirs 1h at 100 DEG C, naturally cool to room temperature, discharge,
Modified self-control bisphenol A type epoxy resin is obtained, weighs after 20g quartzite sand grinds crush 7min and crosses 200 mesh sieves, collect sieving powder
End, it is in mass ratio 5：Sieving powder and titanate coupling agent 201 are mixed 12min by 1, obtain mixture, are continued to mixed
The sesame oil of mixture quality 7% and the Yoghourt of mixture quality 0.6% are added in compound, is fitted into fermentation tank, is 32 in temperature
It is sealed by fermentation 9 days under the conditions of DEG C, after fermentation ends, takes out tunning, as Modified Quartz Sand powder, be in mass ratio 2：1：
3：2：1：1 is fitted into organobentonite, gas-phase silica, mica powder and zinc oxide and peach gum and biogas slurry in fermentation tank, 30
It is sealed by fermentation 6 days at DEG C, after fermentation ends, obtains tunning, then with deionized water rinsing tunning, drying after flushing,
Modified self-control mixture is obtained, is counted in parts by weight, weighs 25 parts of modified self-control bisphenol A type epoxy resins, 6 parts of adjacent diamines respectively
Methyl cyclopentane, 12 parts of Modified Quartz Sand powder, 8 parts of modified self-control mixture, 4 parts of glyceryl monostearates and 10 parts of deionizations
Water mixing is placed in mixer, and 35min is stirred at 55 DEG C, then add 3 parts of talcum powder, 2 parts of sodium carboxymethylcelluloses, 3 parts it is poly-
Dimethyl siloxane and 1 part of titanium dioxide, continue to stir 1h at 75 DEG C, naturally cool to room temperature, discharge, you can Gao Kangjing is made
The anti-skidding floor paint of electricity.
Example 2
25g bisphenol-As and 50mL epoxychloropropane are mixed and are placed in equipped with agitator, separatory funnel, thermometer and reflux condensing tube
Four-hole boiling flask in, stir 14min at 55 DEG C, into separatory funnel using 1mL/min speed be added dropwise 25mL mass fractions as
30% sodium hydroxide solution, and 65 DEG C are heated to, continue to stir 2h, then add 30mL deionized waters into four-hole boiling flask
With 50mL toluene, continue insulated and stirred 1.5h, pour into separatory funnel after stirring while hot, stratification, after removing aqueous phase, be transferred to true
In empty distillation equipment, it is evaporated in vacuo at being 115 DEG C in temperature, removes toluene and unreacted epoxychloropropane, naturally cool to
Room temperature, discharging, obtain making bisphenol A type epoxy resin by oneself, be in mass ratio 3：2：1 will self-control bisphenol A type epoxy resin, poly- second two
Alcohol and the hydrochloric acid solution mixing that mass fraction is 15% are placed in beaker, are stirred 2h at 105 DEG C, are naturally cooled to room temperature, go out
Material, modified self-control bisphenol A type epoxy resin is obtained, weigh after 27g quartzite sand grinds crush 8min and cross 200 mesh sieves, collect sieving
Powder, it is in mass ratio 5：1 will sieving powder and titanate coupling agent 201 mix 15min, obtain mixture, continue to
The sesame oil of mixture quality 7% and the Yoghourt of mixture quality 0.6% are added in mixture, is fitted into fermentation tank, is in temperature
Be sealed by fermentation 10 days under the conditions of 37 DEG C, after fermentation ends, take out tunning, as Modified Quartz Sand powder, in mass ratio for
2：1：3：2：1：1 is fitted into organobentonite, gas-phase silica, mica powder and zinc oxide and peach gum and biogas slurry in fermentation tank,
It is sealed by fermentation 7 days at 35 DEG C, after fermentation ends, obtains tunning, then with deionized water rinsing tunning, is done after flushing
It is dry, modified self-control mixture is obtained, is counted in parts by weight, weighs 30 parts of modified self-control bisphenol A type epoxy resins, 7 parts of neighbours respectively
Diamines methyl cyclopentane, 14 parts of Modified Quartz Sand powder, 9 parts of modified self-control mixtures, 5 parts of glyceryl monostearates and 11 parts are gone
Ionized water mixing is placed in mixer, 40min is stirred at 60 DEG C, then add 4 parts of talcum powder, 3 parts of sodium carboxymethylcelluloses, 4
Part dimethyl silicone polymer and 2 parts of titanium dioxides, continue to stir 2h at 85 DEG C, naturally cool to room temperature, discharge, you can height is made
Antistatic antiskid floor paint.
Example 3
30g bisphenol-As and 55mL epoxychloropropane are mixed and are placed in equipped with agitator, separatory funnel, thermometer and reflux condensing tube
Four-hole boiling flask in, stir 16min at 65 DEG C, into separatory funnel using 1mL/min speed be added dropwise 30mL mass fractions as
30% sodium hydroxide solution, and 75 DEG C are heated to, continue to stir 3h, then add 35mL deionized waters into four-hole boiling flask
With 60mL toluene, continue insulated and stirred 2h, pour into separatory funnel after stirring while hot, stratification, after removing aqueous phase, be transferred to vacuum
In distillation equipment, it is evaporated in vacuo at being 120 DEG C in temperature, removes toluene and unreacted epoxychloropropane, naturally cool to room
Temperature, discharging, obtain making bisphenol A type epoxy resin by oneself, be in mass ratio 3：2：1 will self-control bisphenol A type epoxy resin, polyethylene glycol
It is placed in mass fraction for 15% hydrochloric acid solution mixing in beaker, stirs 3h at 110 DEG C, naturally cool to room temperature, discharge,
Modified self-control bisphenol A type epoxy resin is obtained, weighs after 35g quartzite sand grinds crush 9min and crosses 200 mesh sieves, collect sieving powder
End, it is in mass ratio 5：Sieving powder and titanate coupling agent 201 are mixed 18min by 1, obtain mixture, are continued to mixed
The sesame oil of mixture quality 7% and the Yoghourt of mixture quality 0.6% are added in compound, is fitted into fermentation tank, is 42 in temperature
It is sealed by fermentation 11 days under the conditions of DEG C, after fermentation ends, takes out tunning, as Modified Quartz Sand powder, be in mass ratio 2：
1：3：2：1：1 is fitted into organobentonite, gas-phase silica, mica powder and zinc oxide and peach gum and biogas slurry in fermentation tank,
It is sealed by fermentation 8 days at 40 DEG C, after fermentation ends, obtains tunning, then with deionized water rinsing tunning, is done after flushing
It is dry, modified self-control mixture is obtained, is counted in parts by weight, weighs 35 parts of modified self-control bisphenol A type epoxy resins, 8 parts of neighbours respectively
Diamines methyl cyclopentane, 16 parts of Modified Quartz Sand powder, 10 parts of modified self-control mixtures, 6 parts of glyceryl monostearates and 12 parts
Deionized water mixing be placed in mixer, 45min is stirred at 65 DEG C, then add 5 parts of talcum powder, 4 parts of sodium carboxymethylcelluloses,
5 parts of dimethyl silicone polymers and 3 parts of titanium dioxides, continue to stir 3h at 95 DEG C, naturally cool to room temperature, discharge, you can be made
The anti-skidding floor paint of high-antistatic.
The floor paint that comparative example is produced with company of Suzhou City is prevented high-antistatic produced by the present invention as a comparison case
Floor paint in sliding floor paint and comparative example is detected, and testing result is as shown in table 1：1st, method of testing
According to national standard《Terrace coating material》（GB/T22374-2008）To the example 1~3 obtained by the present invention and contrast
Example carries out experiment test.
Table 1
It can be seen from data in table 1, the anti-skidding floor paint hardness of high-antistatic produced by the present invention is high, antistatic effect is strong, anti-skidding
Effect is good, wear resistance is strong, green, has good market value.
Claims (6)
1. a kind of preparation method of the anti-skidding floor paint of high-antistatic, it is characterised in that specifically preparation process is：
（1）20~30g bisphenol-As and 45~55mL epoxychloropropane are mixed be placed in equipped with agitator, separatory funnel, thermometer and
Stirred in the four-hole boiling flask of reflux condensing tube, 20~30mL sodium hydroxide solutions, and heat temperature raising are added dropwise into separatory funnel, after
Continuous stirring, then 25~35mL deionized waters and 40~60mL toluene are added into four-hole boiling flask, continue insulated and stirred, taken advantage of after stirring
Heat pours into separatory funnel, stratification, after removing aqueous phase, is transferred in vacuum distillation plant and is evaporated in vacuo, and removes toluene and not anti-
The epoxychloropropane answered, room temperature is naturally cooled to, discharged, obtain making bisphenol A type epoxy resin by oneself；
（2）Self-control bisphenol A type epoxy resin, polyethylene glycol and hydrochloric acid solution are mixed to be placed in beaker and stirred, is naturally cooled to
Room temperature, discharging, obtain modified self-control bisphenol A type epoxy resin；
（3）Weigh after 20~35g quartzite sand grinds crush and cross 200 mesh sieves, collect sieving powder, sieving powder and titanate esters is even
Connection agent 201 mixes, and obtains mixture, continues to add the sesame oil and mixture quality of mixture quality 7% into mixture
0.6% Yoghourt, is fitted into fermentation tank, is sealed by fermentation, and after fermentation ends, takes out tunning, as Modified Quartz Sand powder；
（4）Organobentonite, gas-phase silica, mica powder and zinc oxide and peach gum and biogas slurry are fitted into fermentation tank, sealed
Fermentation, after fermentation ends, obtain tunning, then with deionized water rinsing tunning, dried after flushing, obtain being modified self-control
Mixture；
（5）Count in parts by weight, weigh modified self-control bisphenol A type epoxy resin, adjacent diamines methyl cyclopentane, modified quartz respectively
Emery dust end, modified self-control mixture, glyceryl monostearate and deionized water mixing are placed in mixer and stirred, then add talcum
Powder, sodium carboxymethylcellulose, dimethyl silicone polymer and titanium dioxide, continue to stir, naturally cool to room temperature, discharge, you can system
Obtain the anti-skidding floor paint of high-antistatic.
A kind of 2. preparation method of the anti-skidding floor paint of high-antistatic according to claim 1, it is characterised in that：Step（1）
Described whipping temp is 45~65 DEG C, and mixing time is 12~16min, and sodium hydroxide solution mass fraction is 30%, and speed is added dropwise
It is 55~75 DEG C to spend for 1mL/min, heat temperature raising temperature, and continuation mixing time is 1~3h, and the insulated and stirred time is 1~2h, is steamed
Temperature is evaporated for 110~120 DEG C.
A kind of 3. preparation method of the anti-skidding floor paint of high-antistatic according to claim 1, it is characterised in that：Step（2）
The mass ratio for the hydrochloric acid solution that described self-control bisphenol A type epoxy resin, polyethylene glycol and mass fraction is 15% is 3：2：1,
Whipping temp is 100~110 DEG C, and mixing time is 1~3h.
A kind of 4. preparation method of the anti-skidding floor paint of high-antistatic according to claim 1, it is characterised in that：Step（3）
Described grinding time is 7~9min, and the mass ratio of sieving powder and titanate coupling agent 201 is 5：1, mixing time be 12~
18min, fermentation temperature are 32~42 DEG C, and fermentation time is 9~11 days.
A kind of 5. preparation method of the anti-skidding floor paint of high-antistatic according to claim 1, it is characterised in that：Step（4）
The mass ratio of described organobentonite, gas-phase silica, mica powder and zinc oxide, peach gum and biogas slurry is 2：1：3：2：1：1, hair
Ferment temperature is 30~40 DEG C, and fermentation time is 6~8 days.
A kind of 6. preparation method of the anti-skidding floor paint of high-antistatic according to claim 1, it is characterised in that：Step（5）
Described meter in parts by weight, 25~35 parts of modified self-control bisphenol A type epoxy resins, 6~8 parts of adjacent diamines methyl rings are weighed respectively
Pentane, 12~16 parts of Modified Quartz Sand powder, 8~10 parts of modified self-control mixtures, 4~6 parts of glyceryl monostearates and 10~
12 parts of deionized waters, 3~5 parts of talcum powder, 2~4 parts of sodium carboxymethylcelluloses, 3~5 parts of dimethyl silicone polymers and 1~3 part of titanium
White powder, whipping temp are 55~65 DEG C, and mixing time is 35~45min, and it is 75~95 DEG C to continue whipping temp, when continuing stirring
Between be 1~3h.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108977073A (en) * | 2018-08-10 | 2018-12-11 | 安徽信达家居有限公司 | A kind of coating improving outdoor furniture ageing-resistant performance |
| WO2021237556A1 (en) * | 2020-05-28 | 2021-12-02 | 江苏扬农锦湖化工有限公司 | Waterborne epoxy floor paint and preparation method therefor |
| CN114196284A (en) * | 2021-11-28 | 2022-03-18 | 安徽朗凯奇建材有限公司 | Antiskid water-based epoxy floor paint and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1239557C (en) * | 2003-11-11 | 2006-02-01 | 中国石化集团巴陵石油化工有限责任公司 | Method for producing epoxy resin by using bisphenol A and epoxy chloropropane |
| CN101886336A (en) * | 2010-06-23 | 2010-11-17 | 北京航空航天大学 | Polyalcohol modified epoxy resin carbon fiber emulsion sizing agent component and preparation method thereof |
| CN103122194A (en) * | 2012-12-26 | 2013-05-29 | 王娟 | Epoxy laminate floor paint |
| CN106967330A (en) * | 2017-04-21 | 2017-07-21 | 吴迪 | A kind of preparation method of liquid photosensitive welding resistant printing ink |
-
2017
- 2017-10-16 CN CN201710956851.7A patent/CN107629628A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1239557C (en) * | 2003-11-11 | 2006-02-01 | 中国石化集团巴陵石油化工有限责任公司 | Method for producing epoxy resin by using bisphenol A and epoxy chloropropane |
| CN101886336A (en) * | 2010-06-23 | 2010-11-17 | 北京航空航天大学 | Polyalcohol modified epoxy resin carbon fiber emulsion sizing agent component and preparation method thereof |
| CN103122194A (en) * | 2012-12-26 | 2013-05-29 | 王娟 | Epoxy laminate floor paint |
| CN106967330A (en) * | 2017-04-21 | 2017-07-21 | 吴迪 | A kind of preparation method of liquid photosensitive welding resistant printing ink |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108977073A (en) * | 2018-08-10 | 2018-12-11 | 安徽信达家居有限公司 | A kind of coating improving outdoor furniture ageing-resistant performance |
| WO2021237556A1 (en) * | 2020-05-28 | 2021-12-02 | 江苏扬农锦湖化工有限公司 | Waterborne epoxy floor paint and preparation method therefor |
| CN114196284A (en) * | 2021-11-28 | 2022-03-18 | 安徽朗凯奇建材有限公司 | Antiskid water-based epoxy floor paint and preparation method thereof |
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