CN107629459A - A kind of radiator shell - Google Patents

A kind of radiator shell Download PDF

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Publication number
CN107629459A
CN107629459A CN201710796730.0A CN201710796730A CN107629459A CN 107629459 A CN107629459 A CN 107629459A CN 201710796730 A CN201710796730 A CN 201710796730A CN 107629459 A CN107629459 A CN 107629459A
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CN
China
Prior art keywords
parts
freezing processing
radiator shell
freezing
rosin
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Application number
CN201710796730.0A
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Chinese (zh)
Inventor
倪明光
张红喜
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ANHUI CHENGYOU AUTO PARTS MANUFACTURING Co Ltd
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ANHUI CHENGYOU AUTO PARTS MANUFACTURING Co Ltd
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Priority to CN201710796730.0A priority Critical patent/CN107629459A/en
Publication of CN107629459A publication Critical patent/CN107629459A/en
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  • Processes Of Treating Macromolecular Substances (AREA)
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Abstract

A kind of radiator shell, it is related to automobile part production technique field, the present invention is using organic siliconresin, polyphenylene oxide resin, maleic anhydride inoculated polypropylene as primary raw material, add silica, rosin, cationic starch, polyethylene terephthalate, epoxidized soybean oil, various auxiliary agents are equipped with again, by heating, stirring, freezing processing three times, the molten step of reheating, the tank shell that the present invention makes can be made more resistant to high temperature, more resistant to low temperature, antiageing effect is more preferable, has flame retardant effect, service life is longer, it is not easy to damages.

Description

A kind of radiator shell
Technical field:
The present invention relates to automobile part production technique field, and in particular to a kind of radiator shell.
Background technology:
Radiator is also known as radiator, is critical part in automobile cooling system;Function is to distribute heat, and cooling water is in water Heat is absorbed in set, heat disperses after flowing to radiator, returns in water jacket and circulates, reaches temperature adjustment.It is the group of automobile engine Into part.Because water temperature is usually too high in water tank, the material of water tank needs have resistant to elevated temperatures performance, and in winter, automobile is not When starting, water tank temperature is too low, it is possible to can freeze, water tank will also have low temperature resistant performance.Water tank is commonly used, it is necessary to have There are anti-aging other performances of grade.
The content of the invention:
The technical problems to be solved by the invention are to provide a kind of radiator shell.
The technical problems to be solved by the invention are realized using following technical scheme:
A kind of radiator shell, is made up of the component of following parts by weight:Organic siliconresin 40-50 parts, polyphenylene oxide tree Fat 10-20 parts, maleic anhydride inoculated polypropylene 8-12 parts, silica 4-6 parts, rosin 3-5 parts, cationic starch 2-4 parts, It is macromolecule resin emulsion 1-2 parts, polyethylene terephthalate 4-6 parts, epoxidized soybean oil 6-8 parts, aromatic hydrocarbon 1-3 parts, anti- Oxygen agent 0.5-1 parts, glass fibre 2-4 parts, sepiolite fibre 1-3 parts, emulsifying agent 0.6-0.8 parts, nano zine oxide 1-3 parts, electricity Sub- level silicon powder 1-3 parts.
Further, the component of the preferably following parts by weight of the radiator shell is made:45 parts of organic siliconresin, gather 15 parts of phenylene ether resins, 10 parts of maleic anhydride inoculated polypropylene, 5 parts of silica, 4 parts of rosin, 3 parts of cationic starch, macromolecule 1.5 parts of resin emulsion, 5 parts of polyethylene terephthalate, 7 parts of epoxidized soybean oil, 2 parts of aromatic hydrocarbon, 0.8 part of antioxidant, glass 3 parts of glass fiber, 2 parts of sepiolite fibre, 0.7 part of emulsifying agent, 2 parts of nano zine oxide, 2 parts of electronic-grade silicon micro mist.
The preparation method of above-mentioned radiator shell is as follows:
1) raw material is claimed by above-mentioned weight proportion;
2) by organic siliconresin, polyphenylene oxide resin, maleic anhydride inoculated polypropylene, silica, poly terephthalic acid second Diol ester, epoxidized soybean oil, sepiolite fibre are heated to molten condition, are stirred mixing;
3) macromolecule resin emulsion, aromatic hydrocarbon, nano zine oxide are added in the mixture in step 2) to continue to stir, stir It is 600-800r/min to mix speed;
4) it is micro- that rosin, cationic starch, antioxidant, glass fibre, emulsifying agent, electronic-grade silicon are added in step 3) Powder, after being thoroughly mixed, 60-80 degree is kept the temperature at, is quickly stirred, mixing speed 800-1000r/min, made Material fully reacts emulsification;
5) material handled well in step 4) is sent into freezing equipment, carries out freezing processing;
6) material after step 5) is freezed melts through granulator heating, is expressed into mould molding, obtains outside radiator Shell.
Further, the freezing processing of the step 5) is divided into first time freezing processing, second of freezing processing, and the 3rd Secondary freezing processing, after first time freezing processing, after material is recovered into room temperature 1 hour, then second of freezing processing is carried out, second After freezing processing, after material equally is recovered into room temperature 1 hour, then third time freezing processing is carried out.
Further, first time freezing processing is that 2-3 hours are continuously freezed in the environment of subzero 5-10 DEG C, and second cold Jelly processing is that 3-5 hours are continuously freezed in the environment of subzero 10-20 DEG C, and second of freezing processing is at subzero 20-25 DEG C 2-3 hours are continuously freezed under environment.
The beneficial effects of the invention are as follows:The present invention using organic siliconresin, polyphenylene oxide resin, maleic anhydride inoculated polypropylene as Primary raw material, silica, rosin, cationic starch, polyethylene terephthalate, epoxidized soybean oil are added, then matched somebody with somebody With various auxiliary agents, by heating, stirring, freezing processing three times, the molten step of reheating, the tank shell that can make the present invention More resistant to high temperature, more resistant to low temperature, antiageing effect is more preferable, has a flame retardant effect, and service life is longer, it is not easy to damages.
Embodiment:
In order that the technical means, the inventive features, the objects and the advantages of the present invention are easy to understand, tie below Specific embodiment is closed, the present invention is expanded on further.
Embodiment 1
A kind of radiator shell, is made up of the component of following parts by weight:40 parts of organic siliconresin, polyphenylene oxide resin 10 Part, 8 parts of maleic anhydride inoculated polypropylene, 4 parts of silica, 3 parts of rosin, 2 parts of cationic starch, 1 part of macromolecule resin emulsion, 4 parts of polyethylene terephthalate, 6 parts of epoxidized soybean oil, 1 part of aromatic hydrocarbon, 0.5 part of antioxidant, 2 parts of glass fibre, Hai Pao 1 part of mineral wool, 0.6 part of emulsifying agent, 1 part of nano zine oxide, 1 part of electronic-grade silicon micro mist.
The preparation method of above-mentioned radiator shell is as follows:
1) raw material is claimed by above-mentioned weight proportion;
2) by organic siliconresin, polyphenylene oxide resin, maleic anhydride inoculated polypropylene, silica, poly terephthalic acid second Diol ester, epoxidized soybean oil, sepiolite fibre are heated to molten condition, are stirred mixing;
3) macromolecule resin emulsion, aromatic hydrocarbon, nano zine oxide are added in the mixture in step 2) to continue to stir, stir It is 600r/min to mix speed;
4) it is micro- that rosin, cationic starch, antioxidant, glass fibre, emulsifying agent, electronic-grade silicon are added in step 3) Powder, after being thoroughly mixed, 60 degree are kept the temperature at, is quickly stirred, mixing speed 800r/min, make material abundant Reaction emulsification;
5) material handled well in step 4) is sent into freezing equipment, carries out freezing processing;
6) material after step 5) is freezed melts through granulator heating, is expressed into mould molding, obtains outside radiator Shell.
Further, the freezing processing of step 5) is divided into first time freezing processing, second of freezing processing, and cold for the third time Jelly is handled, and after first time freezing processing, after material is recovered into room temperature 1 hour, then carries out second of freezing processing, second of freezing After processing, after material equally is recovered into room temperature 1 hour, then third time freezing processing is carried out.
Further, first time freezing processing is continuously freezed 2 hours in the environment of subzero 5 DEG C, at second of freezing Reason is continuous freezing 3 hours in the environment of subzero 10 DEG C, and second of freezing processing is the continuous cold in the environment of subzero 20 DEG C Freeze 2 hours.
Implement 2
A kind of radiator shell, is made up of the component of following parts by weight:50 parts of organic siliconresin, polyphenylene oxide resin 20 Part, 12 parts of maleic anhydride inoculated polypropylene, 6 parts of silica, 5 parts of rosin, 4 parts of cationic starch, macromolecule resin emulsion 2 Part, 6 parts of polyethylene terephthalate, 8 parts of epoxidized soybean oil, 3 parts of aromatic hydrocarbon, 1 part of antioxidant, 4 parts of glass fibre, Hai Pao 3 parts of mineral wool, 0.8 part of emulsifying agent, 3 parts of nano zine oxide, 3 parts of electronic-grade silicon micro mist.
The preparation method of above-mentioned radiator shell is as follows:
1) raw material is claimed by above-mentioned weight proportion;
2) by organic siliconresin, polyphenylene oxide resin, maleic anhydride inoculated polypropylene, silica, poly terephthalic acid second Diol ester, epoxidized soybean oil, sepiolite fibre are heated to molten condition, are stirred mixing;
3) macromolecule resin emulsion, aromatic hydrocarbon, nano zine oxide are added in the mixture in step 2) to continue to stir, stir It is 800r/min to mix speed;
4) it is micro- that rosin, cationic starch, antioxidant, glass fibre, emulsifying agent, electronic-grade silicon are added in step 3) Powder, after being thoroughly mixed, 80 degree are kept the temperature at, is quickly stirred, mixing speed 800r/min, make material abundant Reaction emulsification;
5) material handled well in step 4) is sent into freezing equipment, carries out freezing processing;
6) material after step 5) is freezed melts through granulator heating, is expressed into mould molding, obtains outside radiator Shell.
Further, the freezing processing of step 5) is divided into first time freezing processing, second of freezing processing, and cold for the third time Jelly is handled, and after first time freezing processing, after material is recovered into room temperature 1 hour, then carries out second of freezing processing, second of freezing After processing, after material equally is recovered into room temperature 1 hour, then third time freezing processing is carried out.
Further, first time freezing processing is continuously freezed 3 hours in the environment of subzero 10 DEG C, at second of freezing Reason is continuous freezing 5 hours in the environment of subzero 20 DEG C, and second of freezing processing is the continuous cold in the environment of subzero 25 DEG C Freeze 3 hours.
Control group 1
A kind of radiator shell, is made up of the component of following parts by weight:40 parts of organic siliconresin, polyphenylene oxide resin 10 Part, 8 parts of maleic anhydride inoculated polypropylene, 4 parts of silica, 3 parts of rosin, 2 parts of cationic starch, 1 part of macromolecule resin emulsion, 4 parts of polyethylene terephthalate, 6 parts of epoxidized soybean oil, 1 part of aromatic hydrocarbon, 0.5 part of antioxidant, 2 parts of glass fibre, Hai Pao 1 part of mineral wool, 0.6 part of emulsifying agent, 1 part of nano zine oxide, 1 part of electronic-grade silicon micro mist.
The preparation method of above-mentioned radiator shell is as follows:
1) raw material is claimed by above-mentioned weight proportion;
2) by organic siliconresin, polyphenylene oxide resin, maleic anhydride inoculated polypropylene, silica, poly terephthalic acid second Diol ester, epoxidized soybean oil, sepiolite fibre are heated to molten condition, are stirred mixing;
3) macromolecule resin emulsion, aromatic hydrocarbon, nano zine oxide is added in the mixture in step 2) to continue to stir;
4) it is micro- that rosin, cationic starch, antioxidant, glass fibre, emulsifying agent, electronic-grade silicon are added in step 3) Powder, after being thoroughly mixed, 60 degree are kept the temperature at, is sufficiently stirred;
5) material handled well in step 4) is sent into freezing equipment, carries out freezing processing, connect in the environment of subzero 5 DEG C Continuous freezing 2 hours;
6) material after step 5) is freezed melts through granulator heating, is expressed into mould molding, obtains outside radiator Shell.
Control group 2
A kind of radiator shell, is made up of the component of following parts by weight:50 parts of organic siliconresin, polyphenylene oxide resin 20 Part, 12 parts of maleic anhydride inoculated polypropylene, 6 parts of silica, 5 parts of rosin, 4 parts of cationic starch, macromolecule resin emulsion 2 Part, 6 parts of polyethylene terephthalate, 8 parts of epoxidized soybean oil, 3 parts of aromatic hydrocarbon, 1 part of antioxidant, 4 parts of glass fibre, Hai Pao 3 parts of mineral wool, 0.8 part of emulsifying agent, 3 parts of nano zine oxide, 3 parts of electronic-grade silicon micro mist.
The preparation method of above-mentioned radiator shell is as follows:
1) raw material is claimed by above-mentioned weight proportion;
2) by organic siliconresin, polyphenylene oxide resin, maleic anhydride inoculated polypropylene, silica, poly terephthalic acid second Diol ester, epoxidized soybean oil, sepiolite fibre are heated to molten condition, are stirred mixing;
3) macromolecule resin emulsion, aromatic hydrocarbon, nano zine oxide is added in the mixture in step 2) to continue to stir;
4) it is micro- that rosin, cationic starch, antioxidant, glass fibre, emulsifying agent, electronic-grade silicon are added in step 3) Powder, after being thoroughly mixed, 80 degree are kept the temperature at, is sufficiently stirred;
5) material handled well in step 4) is sent into freezing equipment, freezing processing is carried out, in the environment of subzero 10 DEG C Continuous freezing 3 hours;
6) material after step 5) is freezed melts through granulator heating, is expressed into mould molding, obtains outside radiator Shell.
Table 1 is the present invention and control group performance test
The general principle and principal character and advantages of the present invention of the present invention has been shown and described above.The technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the simply explanation described in above-described embodiment and specification is originally The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its Equivalent thereof.

Claims (5)

1. a kind of radiator shell, it is characterised in that be made up of the component of following parts by weight:Organic siliconresin 40-50 parts, Polyphenylene oxide resin 10-20 parts, maleic anhydride inoculated polypropylene 8-12 parts, silica 4-6 parts, rosin 3-5 parts, cationic starch 2-4 parts, macromolecule resin emulsion 1-2 parts, polyethylene terephthalate 4-6 parts, epoxidized soybean oil 6-8 parts, aromatic hydrocarbon 1-3 Part, antioxidant 0.5-1 parts, glass fibre 2-4 parts, sepiolite fibre 1-3 parts, emulsifying agent 0.6-0.8 parts, nano zine oxide 1-3 Part, electronic-grade silicon micro mist 1-3 parts.
A kind of 2. radiator shell according to claim 1, it is characterised in that:It is preferred that the component system of following parts by weight Into:45 parts of organic siliconresin, 15 parts of polyphenylene oxide resin, 10 parts of maleic anhydride inoculated polypropylene, 5 parts of silica, 4 parts of rosin, 3 parts of cationic starch, 1.5 parts of macromolecule resin emulsion, 5 parts of polyethylene terephthalate, 7 parts of epoxidized soybean oil, fragrance 2 parts of hydrocarbon, 0.8 part of antioxidant, 3 parts of glass fibre, 2 parts of sepiolite fibre, 0.7 part of emulsifying agent, 2 parts of nano zine oxide, electron level 2 parts of silicon powder.
A kind of 3. radiator shell according to claim 1 or 2, it is characterised in that:The system of above-mentioned radiator shell Preparation Method is as follows:
1) raw material is claimed by above-mentioned weight proportion;
2) by organic siliconresin, polyphenylene oxide resin, maleic anhydride inoculated polypropylene, silica, polyethylene terephthalate Ester, epoxidized soybean oil, sepiolite fibre are heated to molten condition, are stirred mixing;
3) add macromolecule resin emulsion, aromatic hydrocarbon, nano zine oxide in the mixture in step 2) to continue to stir, stirring speed Spend for 600-800r/min;
4) rosin, cationic starch, antioxidant, glass fibre, emulsifying agent, electronic-grade silicon micro mist are added in step 3), is filled Divide after being stirred, keep the temperature at 60-80 degree, quickly stirred, mixing speed 800-1000r/min, make material Fully reaction emulsification;
5) material handled well in step 4) is sent into freezing equipment, carries out freezing processing;
6) material after step 5) is freezed melts through granulator heating, is expressed into mould molding, obtains radiator shell.
A kind of 4. radiator shell according to claim 3, it is characterised in that:The freezing processing of the step 5) is divided into First time freezing processing, second of freezing processing, and third time freezing processing, after first time freezing processing, by material recovery room Temperature is after 1 hour, then carries out second of freezing processing, after second of freezing processing, after material equally is recovered into room temperature 1 hour, then Carry out third time freezing processing.
A kind of 5. radiator shell according to claim 4, it is characterised in that:First time freezing processing is in subzero 5- Continuously freezing 2-3 hours, second of freezing processing are that 3-5 is continuously freezed in the environment of subzero 10-20 DEG C in the environment of 10 DEG C Hour, second of freezing processing is that 2-3 hours are continuously freezed in the environment of subzero 20-25 DEG C.
CN201710796730.0A 2017-09-06 2017-09-06 A kind of radiator shell Withdrawn CN107629459A (en)

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Application Number Priority Date Filing Date Title
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108485270A (en) * 2018-03-28 2018-09-04 天长市蓝天复合材料有限公司 A kind of anti-flammability glass-fiber reinforced plastic grille and preparation method
CN108825351A (en) * 2018-06-05 2018-11-16 山东东都新材料科技有限公司 A kind of pressure-bearing type expansion tank

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104292623A (en) * 2014-09-26 2015-01-21 苏州博利迈新材料科技有限公司 Automobile water tank fabric and preparation method thereof
CN106009689A (en) * 2016-05-18 2016-10-12 许五妮 Upper cover vulcanization assembly of hydraulic damping support of automobile engine

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104292623A (en) * 2014-09-26 2015-01-21 苏州博利迈新材料科技有限公司 Automobile water tank fabric and preparation method thereof
CN106009689A (en) * 2016-05-18 2016-10-12 许五妮 Upper cover vulcanization assembly of hydraulic damping support of automobile engine

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108485270A (en) * 2018-03-28 2018-09-04 天长市蓝天复合材料有限公司 A kind of anti-flammability glass-fiber reinforced plastic grille and preparation method
CN108825351A (en) * 2018-06-05 2018-11-16 山东东都新材料科技有限公司 A kind of pressure-bearing type expansion tank

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Application publication date: 20180126