CN107629395A - A kind of POM and PTFE copolymers and preparation method thereof - Google Patents

A kind of POM and PTFE copolymers and preparation method thereof Download PDF

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Publication number
CN107629395A
CN107629395A CN201610563249.2A CN201610563249A CN107629395A CN 107629395 A CN107629395 A CN 107629395A CN 201610563249 A CN201610563249 A CN 201610563249A CN 107629395 A CN107629395 A CN 107629395A
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CN
China
Prior art keywords
pom
ptfe
subsidiary engine
main frame
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610563249.2A
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Chinese (zh)
Inventor
高道峰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kunshan Tai Yi Alwayseal Technology Ltd
Original Assignee
Kunshan Tai Yi Alwayseal Technology Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
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Application filed by Kunshan Tai Yi Alwayseal Technology Ltd filed Critical Kunshan Tai Yi Alwayseal Technology Ltd
Priority to CN201610563249.2A priority Critical patent/CN107629395A/en
Publication of CN107629395A publication Critical patent/CN107629395A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a kind of POM and PTFE copolymers and preparation method thereof, its each component and its content are:POM:50%;PTFE:50%.Its preparation method is:1st, prepare two firing equipments, a main frame, a subsidiary engine, and be separately heated to 280 ~ 380 DEG C and 165 ~ 195 DEG C;2nd, PTFE plastic grains are added into main frame, POM plastic particle is added into subsidiary engine, and debug the rotating speed and feeding rotating speed of main and auxiliaries, make satisfaction feed proportioning;3rd, subsidiary engine is connected with main frame, the material heat that subsidiary engine discharges to main frame is melted section;4th, the extruded machine of compound after hot melt is extruded.Simple production process of the present invention, low-quality product can be changed over premium quality product, low-value product is converted into high-value product, greatly reduces use cost, and product more high temperature resistant, chemical resistance, sliding can be made, and improve its hardness and thermal change type temperature.

Description

A kind of POM and PTFE copolymers and preparation method thereof
Technical field
The present invention relates to high performance plastics technical field of modification, more particularly to a kind of high temperature resistant for improving product, chemically-resistant Property, sliding, and POM and the PTFE copolymer of its hardness and thermal change type temperature can be improved and preparation method thereof.
Background technology
POM(Acetal resin)Definition:Polyformaldehyde be it is a kind of without side chain, high density, high crystalline linear polymer, It is the one kind for belonging to engineering plastics, it is firm also to turn into match by people.It is the engineering plastics with excellent combination property.Have good Physics, mechanically and chemically performance, especially have excellent crocking resistance.
But POM plastic unlike other engineering plastics can high temperature resistant, and also intolerant to bright and new irradiation, acid resistance Difference, and impact strength is not high.
Therefore, generally use and the method for other materials copolymerization change its characteristic, still, the method being copolymerized in the prior art Complexity, and be required to professional equipment and could carry out, otherwise it can not synthesize.Its complex process, cost are high, and the intensity of copolymerization product It is unable to reach demand.
The content of the invention
In order to solve the problems of the prior art, it is an object of the invention to provide a kind of POM and PTFE copolymers and its system Preparation Method, it can make product more high temperature resistant, chemical resistance, sliding, and can improve its hardness and thermal change type temperature.
To achieve these goals, the technical solution adopted by the present invention is:
The percentage by weight of a kind of POM and PTFE copolymers, its each component included and each component is respectively:
POM 50%
PTFE 50%。
Present invention also offers a kind of POM and PTFE copolymers preparation method, it comprises the following steps:
S1, prepare two firing equipments, one be main frame, one be subsidiary engine, and main and auxiliaries be separately heated to required temperature Degree;
S2, PTFE plastic grains are added into main frame, POM plastic particle is added into subsidiary engine, and debug turning for main and auxiliaries Speed and feeding rotating speed, it is allowed to meet feed proportioning;
S3, subsidiary engine is connected with main frame, the material heat that subsidiary engine discharges to main frame is melted section;
S4, by the extruded comminutor of compound after hot melt.
Preferably, the heating-up temperature of main frame is 280 ~ 380 DEG C in step S1, and the heating-up temperature of subsidiary engine is 165 DEG C ~ 195 DEG C.
It is further preferred that the feed proportioning of POM plastic particle, PTFE plastic grains is:50%: 50%.
Still more preferably, the extruder is single screw extrusion machine or double screw extruder.
By using above technical scheme, a kind of POM of the present invention and PTFE copolymers and preparation method thereof and prior art Compare, its advantage is:
1st, the present invention can make product more high temperature resistant, chemical resistance, sliding, and can improve its hardness and thermal change type temperature.
2nd, it maintains the original characteristics of cryogenic material POM, while can make original material property and usability scope more Widen general.
3rd, low-quality product is changed over premium quality product by the present invention, low-value product is converted into high-value product, significantly Reduce use cost.
4th, simple production process of the present invention, production cost are low.
Embodiment
To make the object, technical solutions and advantages of the present invention of greater clarity, with reference to instantiation, to the present invention It is further described.It should be understood that these descriptions are merely illustrative, and it is not intended to limit the scope of the present invention.In addition, In illustrating below, the description to known features and technology is eliminated, to avoid unnecessarily obscuring idea of the invention.
A kind of POM of the present invention can use formula as below to prepare with PTFE copolymers:
Formula one:
Weight percentages of components(%)
POM 50
PTFE 50
Formula two:
Weight percentages of components(%)
POM 70
PTFE 30
Formula three:
Weight percentages of components(%)
POM 80
PTFE 20
It is formulated more than, its preparation process is:
1st, prepare two firing equipments, one be main frame, one be subsidiary engine, and main and auxiliaries be separately heated to required temperature Degree;
2nd, PTFE plastic grains are added into main frame, POM plastic particle are added into subsidiary engine, and debug the rotating speed of main and auxiliaries And feeding rotating speed, it is allowed to meet above-mentioned feed proportioning;
4th, subsidiary engine is connected with main frame, the material heat that subsidiary engine discharges to main frame is melted section;
5th, by the extruded comminutor of compound after hot melt.
Above-mentioned embodiment is exemplary, is to preferably make skilled artisans appreciate that originally Patent, it is impossible to be not understood as the limitation for including scope to this patent;As long as times made of spirit according to disclosed in this patent How with change or modification, the scope that this patent includes is each fallen within.

Claims (5)

1. a kind of POM and PTFE copolymers, it is characterised in that the percentage by weight of its each component included and each component is distinguished For:
POM 50%
PTFE 50%。
2. a kind of POM and PTFE copolymers preparation method, it is characterised in that it comprises the following steps:
S1, prepare two firing equipments, one be main frame, one be subsidiary engine, and main and auxiliaries be separately heated to required temperature Degree;
S2, PTFE plastic grains are added into main frame, POM plastic particle is added into subsidiary engine, and debug turning for main and auxiliaries Speed and feeding rotating speed, it is allowed to meet feed proportioning;
S3, subsidiary engine is connected with main frame, the material heat that subsidiary engine discharges to main frame is melted section;
S4, by the extruded comminutor of compound after hot melt.
3. a kind of POM according to claim 2 and PTFE copolymers preparation method, it is characterised in that main in step S1 The heating-up temperature of machine is 280 ~ 380 DEG C, and the heating-up temperature of subsidiary engine is 165 ~ 195 DEG C.
4. a kind of POM according to claim 2 and PTFE copolymers preparation method, it is characterised in that POM plastic Grain, the feed proportioning of PTFE plastic grains are:50%:50%.
5. a kind of POM according to claim 2 and PTFE copolymers preparation method, it is characterised in that the extruder For single screw extrusion machine or double screw extruder.
CN201610563249.2A 2016-07-18 2016-07-18 A kind of POM and PTFE copolymers and preparation method thereof Pending CN107629395A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610563249.2A CN107629395A (en) 2016-07-18 2016-07-18 A kind of POM and PTFE copolymers and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610563249.2A CN107629395A (en) 2016-07-18 2016-07-18 A kind of POM and PTFE copolymers and preparation method thereof

Publications (1)

Publication Number Publication Date
CN107629395A true CN107629395A (en) 2018-01-26

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610563249.2A Pending CN107629395A (en) 2016-07-18 2016-07-18 A kind of POM and PTFE copolymers and preparation method thereof

Country Status (1)

Country Link
CN (1) CN107629395A (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3387447A (en) * 1965-12-27 1968-06-11 Celanese Corp Traveler rings
JPS63213546A (en) * 1987-02-28 1988-09-06 Sanko Shoji Kk Resin composition
CN103992615A (en) * 2014-06-17 2014-08-20 四川大学 Novel wear-resistant anti-static polyformaldehyde material and preparation method thereof
CN104045965A (en) * 2014-06-17 2014-09-17 合肥杰事杰新材料股份有限公司 Micronized polytetrafluoroethylene wax modified polyformaldehyde composite material and preparation method thereof
CN105462160A (en) * 2014-09-05 2016-04-06 青岛颐世保塑料有限公司 Wear-resistant polyoxymethylene material

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3387447A (en) * 1965-12-27 1968-06-11 Celanese Corp Traveler rings
JPS63213546A (en) * 1987-02-28 1988-09-06 Sanko Shoji Kk Resin composition
CN103992615A (en) * 2014-06-17 2014-08-20 四川大学 Novel wear-resistant anti-static polyformaldehyde material and preparation method thereof
CN104045965A (en) * 2014-06-17 2014-09-17 合肥杰事杰新材料股份有限公司 Micronized polytetrafluoroethylene wax modified polyformaldehyde composite material and preparation method thereof
CN105462160A (en) * 2014-09-05 2016-04-06 青岛颐世保塑料有限公司 Wear-resistant polyoxymethylene material

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
刘西文: "《塑料注射成型技术实用教程》", 31 October 2013, 印刷工业出版社 *

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Application publication date: 20180126