CN107604670A

CN107604670A - A kind of gumming device and its technique of cellular amphiphilic non-woven fabrics

Info

Publication number: CN107604670A
Application number: CN201710827657.9A
Authority: CN
Inventors: 王栋; 牛应买; 赵青华; 李沐芳; 蒋海青; 郭启浩; 梅涛
Original assignee: Wuhan Textile University
Current assignee: Wuhan Textile University
Priority date: 2017-09-14
Filing date: 2017-09-14
Publication date: 2018-01-19
Anticipated expiration: 2037-09-14
Also published as: CN107604670B

Abstract

The invention discloses a kind of gumming device and its technique of cellular amphiphilic non-woven fabrics, the gumming device of the cellular amphiphilic non-woven fabrics includes the first yardage roll retractable frame and the second yardage roll retractable frame, in addition to first bath gumming device, the second bath gumming device, the 3rd bath gumming device and the drying device being successively set between the first yardage roll retractable frame and the second yardage roll retractable frame.It can be reacted using first bath impregnation and two-bath gum dipping in the gum dipping process of the present invention and produce CO₂Gas, in CO₂Micropore can be formed during release so that prepared impregnation non-woven fabrics has rough external surface, overall that the natural forms such as cellular or marine alga shape are presented, and increases contact area so that water suction oil absorption greatly improves, so as to reach more preferable clean effect.

Description

A kind of gumming device and its technique of cellular amphiphilic non-woven fabrics

Technical field

The present invention relates to the technical field of non-woven fabrics fabric, is filled in particular to a kind of impregnation of cellular amphiphilic non-woven fabrics Put and its technique.

Background technology

Non-woven fabrics is a kind of non-woven cloth, and it is that fiber directly is passed through into gas using high polymer section, chopped fiber or long filament Stream or mechanical networking, then reinforced by spun lacing, acupuncture, or hot rolling, the non-woven cloth finally formed by final finishing.Nothing Cloth new type of fibrous product with a soft, breathable and planar structure is spun, it is light, ventilative, nontoxic and convenient and practical.But with spinning Weave cotton cloth and compare, there is also following shortcoming for non-woven fabrics：Intensity and durability is poor, hydrophily is poor.

In the prior art, the Chinese invention patent of Application No. 201510475857.3 discloses a kind of degradable nonwoven fabrics Impregnation composite-making process and its material, the production technology are to be immersed in PVA colloidal solutions with least one side of PVA non-woven fabrics In, and be 10%-30% by controlling the mass fraction of PVA in colloidal solution, control the impregnation face quantity of non-woven fabrics different, Then PVA non-woven cloth glue impregnatings face and PVA non-woven fabrics are subjected to the step such as compound by the operation for rolling, drying, cooling down, however, Glue used in the invention takes blocking effect to liquid and solid, the deficiency that hydrophily is poor, can not clean be present, and easily from straight Split angular direction.

The content of the invention

Present invention aim to provide a kind of gumming device and its technique of cellular amphiphilic non-woven fabrics, the impregnation Impregnation non-woven fabrics obtained by technique has rough external surface, overall that the natural forms such as cellular or marine alga shape are presented, and increases Contact area so that water suction oil absorption greatly improves, so as to reach more preferable clean effect.

To achieve the above object, the invention provides a kind of gumming device of cellular amphiphilic non-woven fabrics, including first Yardage roll retractable frame and the second yardage roll retractable frame, it is characterized in that：Also include being successively set on the first yardage roll retractable frame and the First bath gumming device, the second bath gumming device, the 3rd bath gumming device and drying device between two yardage roll retractable frames；

The first bath gumming device includes the first pressure roller, the first home roll, the first deflector roll, the first belt supporting frame set gradually Pressure roller, the first steeping vat and the first scraper, first pressure roller are arranged on surface and its extrusion fit of the first home roll；

The second bath gumming device includes the second pressure roller, the second home roll, the second deflector roll, the second belt supporting frame set gradually Pressure roller, the second steeping vat and the second scraper, second pressure roller are arranged on surface and its extrusion fit of the second home roll；

The 3rd bath gumming device includes the 3rd pressure roller, the 3rd home roll, the 3rd deflector roll, the 3rd belt supporting frame set gradually Pressure roller, the 3rd steeping vat and the 3rd scraper；3rd pressure roller is arranged on surface and its extrusion fit of the 3rd home roll；

The drying device includes the 4th pressure roller, heating rod, the 5th pressure roller, the first chill roll, the Yi Ji set gradually Two chill rolls, the 4th pressure roller and the 5th pressure roller are symmetricly set on both sides and its extrusion fit of heating rod.

Present invention also offers the technique that a kind of gumming device using above-mentioned cellular amphiphilic non-woven fabrics carries out impregnation, Comprise the following steps：

1) nonwoven is arranged on the first yardage roll retractable frame, is passed sequentially through the first pressure roller, the first home roll and first Deflector roll, then enter the first steeping vat under the drawing-off of first band support pressure roller and be immersed in the first bath impregnation that temperature is 20-60 DEG C In, first bath impregnation unnecessary on non-woven fabrics is scraped back by the first steeping vat by the first scraper after dipping；

2) non-woven fabrics after step 1) processing is passed sequentially through into the second pressure roller, the second home roll and the second deflector roll, then the Enter the second steeping vat under the drawing-off of two belt supporting frame pressure rollers to be immersed in the two-bath gum dipping that temperature is 20-60 DEG C, lead to after dipping Cross the second scraper and two-bath gum dipping unnecessary on non-woven fabrics is scraped into back the second steeping vat；

3) non-woven fabrics after step 2) processing is passed sequentially through into the 3rd pressure roller, the 3rd home roll and the 3rd deflector roll, then the Enter the 3rd steeping vat under the drawing-off of three belt supporting frame pressure rollers to be immersed in the 3rd bath impregnation that temperature is 20-60 DEG C, lead to after dipping Cross the 3rd scraper and the 3rd bath impregnation unnecessary on non-woven fabrics is scraped into back the 3rd steeping vat；Last non-woven fabrics is successively by the 4th pressure After roller, heating rod, the 5th pressure roller, the first chill roll and the second chill roll, bunchy is wound on the second yardage roll retractable frame.

Further, in the step 1), non-woven fabrics be using polyamide fibre and polypropylene fibre blending into Nomex non-woven fabrics.

Further, in the step 1), first bath impregnation is counted in parts by weight to be made up of following component：Water 450- 490 parts, surfactant 10-50 parts.

Preferably, the first bath impregnation is counted in parts by weight is made up of following component：Water 470-480 parts, surface-active Agent 20-40 parts.

Most preferably, the first bath impregnation is counted in parts by weight is made up of following component：480 parts of water, surfactant 40 Part.

Further, the surfactant is selected from lauryl sodium sulfate, dodecyl sodium sulfate, odium stearate, oil One or more in acid, laurate, sulfonate of laurate sodium sulphate.

Preferably, the surfactant is in lauryl sodium sulfate, odium stearate, oleic acid, sulfonate of laurate sodium sulphate One or more.

Most preferably, the surfactant is that lauryl sodium sulfate, odium stearate, oleic acid, sulfonate of laurate sodium sulphate press matter Measure ratio 1:2:3:4 mix.

Further, the concocting method of the first bath impregnation comprises the following steps：Water, water temperature control are first added into container System is at 20-30 DEG C, then surfactant is added into container, stirs.

Further, in the step 2), two-bath gum dipping is counted in parts by weight to be made up of following component：PVA glues 400-600 parts, water 40-150 parts, adhesive 50-100 parts, hydrochloric acid 10-50 parts.

Preferably, the two-bath gum dipping is counted in parts by weight is made up of following component：PVA glue 500-550 parts, water 100-120 parts, adhesive 60-80 parts, hydrochloric acid 30-40 parts.

Most preferably, the two-bath gum dipping is counted in parts by weight is made up of following component：550 parts of PVA glues, 120 parts of water, 60 parts of adhesive, 40 parts of hydrochloric acid.

Further, the adhesive is selected from polyvinyl alcohol Aqueous Adhesives, Aqueous Polyurethane Adhesives, vinyl acetate Esters Aqueous Adhesives, epoxy Aqueous Adhesives, phenolic aldehyde Aqueous Adhesives, organosilicon Aqueous Adhesives, the water-based gluing of rubber-like One or more in agent.

Preferably, adhesive is polyvinyl alcohol Aqueous Adhesives, organosilicon Aqueous Adhesives, rubber-like Aqueous Adhesives In mass ratio 1：2：1 mixes.

Further, the PVA glues are counted in parts by weight is made up of following component：Polyvinyl alcohol environmental protection glue 30-40 parts, Water 120-150 parts, thickener 9-18 parts, formaldehyde 11-22 parts.

Preferably, the PVA glues are counted in parts by weight is made up of following component：Polyvinyl alcohol environmental protection glue 32-35 parts, water 130-140 parts, thickener 12-15 parts, formaldehyde 16-20 parts.

Most preferably, the PVA glues are counted in parts by weight is made up of following component：32 parts of polyvinyl alcohol environmental protection glue, water 140 Part, 12 parts of thickener, 20 parts of formaldehyde.

Further, the thickener is in Arabic gum, polyurethane glue, xanthans, gelatine, donkey-hide gelatin, yellow rose glue One or more.

Preferably, the thickener is polyurethane adhesive, xanthans, gelatine, donkey-hide gelatin in mass ratio 1:2:3:1 mixes.

Preferably, thickener is Arabic gum, xanthans, gelatine, yellow rose glue in mass ratio 1:2:3:4 mix.

Further, the preparation method of the PVA glues is as follows：First polyvinyl alcohol environmental protection glue and water are added sequentially to instead Answer in container, heating water bath stirs 1-2h to 80-95 DEG C, with 1000-1200rad/min stir speed (S.S.), until polyvinyl alcohol Environment-friendlyadhesive adhesive is completely dissolved to obtain glue；Then glue is cooled to 70~72 DEG C, thickener is added, with 700-800rad/min's Stir speed (S.S.), which is stirred to thickener, to be completely dissolved to obtain sticky glue；The sticky glue of gained is finally cooled to 50-55 DEG C, added Formaldehyde is uniformly mixed, you can.

Further, the polyvinyl alcohol environmental protection glue is counted in parts by weight is made up of following component：Polyvinyl alcohol 5-10 parts, Modifying agent 2-5 parts, 0.1-0.4 parts preservative, water 60-88 parts, semi-hydrated gypsum 1-25 parts, retarder 1-25 parts.

Further, the modifying agent is selected from one in 1,2- ethylene glycol, Glycerin, xylit Kind is a variety of.

Preferably, modifying agent 1,2- ethylene glycol, Glycerin, xylit in mass ratio 1:2:3 Mix.

Further, the preservative is selected from boric acid and/or salicylic acid.

Preferably, preservative is boric acid and salicylic acid in mass ratio 1:2 mix.

Further, the retarder is selected from citric acid, sodium citrate, tartaric acid, potassium tartrate, acrylic acid, acrylic acid One or more in sodium, calgon, sodium polyphosphate.

Preferably, retarder is calgon, sodium polyphosphate in mass ratio 1:1 mixes.

Further, the mass concentration of the hydrochloric acid is 30.5-31.5%；The mass concentration of the formaldehyde is 36.5- 37.5%.

Further, the concocting method of the two-bath gum dipping comprises the following steps：First PVA glues and water are sequentially added Into reaction vessel, heating water bath stirs 1-2h to 80-95 DEG C, with 1000-1200rad/min stir speed (S.S.), until PVA glue Liquid is completely dissolved, and obtains the PVA aqueous solution；Then the PVA aqueous solution is cooled to 68~72 DEG C, adhesive is added, with 700- 800rad/min stir speed (S.S.), which is stirred to adhesive, to be completely dissolved；Hydrochloric acid is eventually adding, with 800-900rad/mind stirring Speed is stirred to solution and is well mixed, you can.

Further, in the step 3), the 3rd bath impregnation is counted in parts by weight to be made up of following component：Water 450- 490 parts, surfactant 10-50 parts.

The 3rd bath impregnation is counted in parts by weight to be made up of following component：Water 470-480 parts, surfactant 20-40 Part.

Most preferably, the 3rd bath impregnation is counted in parts by weight is made up of following component：480 parts of water, surfactant 40 Part.

Preferably, the water used in the first bath impregnation, two-bath gum dipping and two-bath gum dipping is deionized water.

Compared with prior art, the invention has the advantages that：

First, it is of the invention in blending Nomex nonwoven surface one layer of hydrophilic glue of dipping with parents' performance, and Activating agent is added when dipping, initiation reaction produces carbon dioxide, in CO₂Micropore can be formed during release, is made Obtaining prepared impregnation non-woven fabrics has rough external surface, overall that the natural forms such as cellular or marine alga shape are presented, and increases and connects Contacting surface is accumulated so that water suction oil absorption greatly improves, so as to reach more preferable clean effect.Meanwhile coarse surface, enhancing make Used time to the adsorption capacity of water, oil, reduces resistance when using, more laborsaving, light during use, prepared impregnation non-woven fabrics letter It is single practical, there are very good market prospects and prospects for commercial application.

Second, the non-woven fabrics of the present invention be using polyamide fibre and polypropylene fibre blending into Nomex non-woven fabrics, polypropylene fibre Nomex removes Outside some advantages with general acupuncture filter felt, also have the characteristics that good stability of the dimension, intensity are high, extend small, Er Qieyin Its surfacing is smooth, and has hole, gas permeability height, so it also has, vacuum resistance is small, saves the uniquenesses such as the energy, easy cleaning Advantage；Meanwhile the hygroscopicity very little of polypropylene fibre, almost non-hygroscopic, regain under the conditions of general atmosphere is close to zero.Polyamide fibre is by band It is made up of the linear macromolecule of amido link (- NHCO-), there is-CO- ,-NH- group in polyamide fibre molecule, can be in intermolecular or molecule Interior formation Hydrogenbond, can also be combined with other molecules, so polyamide moisture-absorption ability is preferable, and its have it is light, wrinkle resistant The features such as excellent, good permeability of property and good durability, dyeability and thermal finalization；The present invention uses polyamide fibre and polypropylene fibre blending Into Nomex non-woven fabrics so that made non-woven fabrics is the hydrophilic moisture absorption with polyamide fibre and the property with the non-hygroscopic oleophylic of polypropylene fibre Can, so as to parents' performance with hydrophilic and oleophilic, impregnation is carried out on this basis, while improving hydrophilicity, also improves it Intensity, it is set to keep preferable mechanical performance.

Brief description of the drawings

Fig. 1 is the structural representation of the gumming device of the cellular amphiphilic non-woven fabrics of the present invention；

In figure：The first yardage rolls of 1- retractable frame, the pressure rollers of 2- first, the home rolls of 3- first, the deflector rolls of 4- first, 5- first band support pressures Roller, the steeping vats of 6- first, the scrapers of 7- first, the pressure rollers of 8- second, the home rolls of 9- second, the deflector rolls of 10- second, 11- the second belt supporting frame pressures Roller, the steeping vats of 12- second, the scrapers of 13- second, the pressure rollers of 14- the 3rd, the home rolls of 15- the 3rd, the deflector rolls of 16- the 3rd, the band branch of 17- the 3rd Frame pressure roller, the steeping vats of 18- the 3rd, the scrapers of 19- the 3rd, the pressure rollers of 20- the 4th, 21- heating rod, the pressure rollers of 22- the 5th, 23- first are cold But roller, the chill rolls of 24- second, 25- the second yardage roll retractable frames.

Embodiment

With reference to specific embodiment, the present invention is described in further detail.

As shown in figure 1, the gumming device of the cellular amphiphilic non-woven fabrics of the present invention, including the He of the first yardage roll retractable frame 1 Second yardage roll retractable frame 25, in addition to first be successively set between the first yardage roll retractable frame 1 and the second yardage roll retractable frame 25 Bathe gumming device, the second bath gumming device, the 3rd bath gumming device and drying device；First bath gumming device is included successively The first pressure roller 2, the first home roll 3, the first deflector roll 4, first band support pressure roller 5, the first steeping vat 6 and the first scraper set 7, the first pressure roller 2 is arranged on surface and its extrusion fit of the first home roll 3；Second bath gumming device includes the set gradually Two pressure rollers 8, the second home roll 9, the second deflector roll 10, the second belt supporting frame pressure roller 11, the second steeping vat 12 and the second scraper 13, the Two pressure rollers 8 are arranged on surface and its extrusion fit of the second home roll 9；3rd bath gumming device includes the 3rd pressure set gradually Roller 14, the 3rd home roll 15, the 3rd deflector roll 16, the 3rd belt supporting frame pressure roller 17, the 3rd steeping vat 18 and the 3rd scraper 19；3rd Pressure roller 14 is arranged on surface and its extrusion fit of the 3rd home roll 15；Drying device include set gradually the 4th pressure roller 20, It is symmetrical to heat rod 21, the 5th pressure roller 22, the first chill roll 23 and the second chill roll 24, the 4th pressure roller 20 and the 5th pressure roller 22 It is arranged on both sides and its extrusion fit of heating rod 21.

Embodiment 1：

The present invention carries out the technique of impregnation, including following step using the gumming device of above-mentioned cellular amphiphilic non-woven fabrics Suddenly：

1) by non-woven fabrics (non-woven fabrics of the invention be using polyamide fibre and polypropylene fibre blending into Nomex non-woven fabrics) be placed in the On one yardage roll retractable frame 1, the first pressure roller 2, the first home roll 3 and the first deflector roll 4 are passed sequentially through, then in the first belt supporting frame Enter the first steeping vat 6 under the drawing-off of pressure roller 5 to be immersed in the first bath impregnation that temperature is 20 DEG C, infiltrate the surface of non-woven fabrics, Nonwoven surface is set to adhere to layer of surface activating agent, by the first scraper 7 by first bath impregnation unnecessary on non-woven fabrics after dipping Scrape back the first steeping vat 6；

2) non-woven fabrics after step 1) processing is passed sequentially through into the second pressure roller 8, the second home roll 9 and the second deflector roll 10, then Enter the second steeping vat 12 under the drawing-off of the second belt supporting frame pressure roller 11 to be immersed in the two-bath gum dipping that temperature is 60 DEG C, second The first bath impregnation that bath impregnation adheres to nonwoven surface reacts, and discharges carbon dioxide, so as to form one on non-woven fabrics Layer has the rough surface of microcellular structure, and two-bath gum dipping unnecessary on non-woven fabrics is scraped back into the by the second scraper 13 after dipping Two steeping vats 12；

3) non-woven fabrics after step 2) processing is passed sequentially through into the 3rd pressure roller 14, the 3rd home roll 15 and the 3rd deflector roll 16, Enter the 3rd steeping vat 18 under the drawing-off of the 3rd belt supporting frame pressure roller 17 again to be immersed in the 3rd bath impregnation that temperature is 20 DEG C, it is complete Into the roughening of nonwoven surface, nonwoven surface is set to be in cellular, marine alga shape, by the 3rd scraper 19 by non-woven fabrics after dipping The 3rd unnecessary bath impregnation scrapes back the 3rd steeping vat 18；Last non-woven fabrics is pressed by the 4th pressure roller 20, heating rod the 21, the 5th successively After roller 22, the first chill roll 23 and the second chill roll 24, bunchy is wound on the second yardage roll retractable frame 25.

First bath impregnation, the formula of two-bath gum dipping and the 3rd bath impregnation and concocting method are as follows in the present embodiment：

First bath impregnation is counted in parts by weight to be made up of following component：450 parts of water, 50 parts of surfactant, wherein, it is described Surfactant is lauryl sodium sulfate, dodecyl sodium sulfate, odium stearate in mass ratio 1：2：3 mix；

The concocting method of first bath impregnation is as follows：

(1) first add water in retort, water temperature is controlled at 20 DEG C；

(2) Surfactant SDS is launched into retort, stirring 15min is well mixed.

Two-bath gum dipping is counted in parts by weight to be made up of following component：400 parts of PVA glues, 40 parts of water, adhesive (gluing Agent is polyvinyl alcohol Aqueous Adhesives, Aqueous Polyurethane Adhesives, vinyl acetate esters Aqueous Adhesives in mass ratio 1：2：3 Mix) 50 parts, 10 parts of hydrochloric acid (mass concentration 30.5%)；

Wherein, the PVA glues are counted in parts by weight is made up of following component：30 parts of polyvinyl alcohol environmental protection glue, water 120 (thickener is Arabic gum, polyurethane adhesive, xanthans in mass ratio 1 for part, thickener:2:1 mixes) 9 parts, formaldehyde (formaldehyde Mass concentration be 36.5%) 11 parts；

The preparation method of PVA glues is as follows：

(1) polyvinyl alcohol environmental protection glue and water are added sequentially in reaction vessel, open stirring, heating water bath to 80 DEG C, 1h is stirred with 1000rad/min stir speed (S.S.), until polyvinyl alcohol environmental protection glue is completely dissolved to obtain glue；

(2) glue obtained by step (1) is cooled to 70 DEG C, thickener is added, with 700rad/min stir speed (S.S.) Stirring is completely dissolved to thickener, obtains sticky glue；

(3) the sticky glue of gained is cooled to 55 DEG C, adding formaldehyde stirring is well mixed glue, produces thick PVA glues.

Polyvinyl alcohol environmental protection glue is counted in parts by weight to be made up of following component：5 parts of polyvinyl alcohol, modifying agent (1,2- second two Alcohol) 2 parts, 0.1 part of preservative (boric acid), 60 parts of water, 1 part of semi-hydrated gypsum, (retarder is citric acid, sodium citrate, wine to retarder Stone acid in mass ratio 1:2:3 mix) 1 part.

The preparation method of polyvinyl alcohol environmental protection glue is as follows：

(1) polyethylene alcohol and water is added in hot pot, 90 DEG C is heated with stirring to, with 1000rad/min's under heat-retaining condition Stir speed (S.S.) stirs 25min and is completely dissolved to polyvinyl alcohol,

(2) add modifying agent and preservative stirs, sealed storage is standby；

(3) semi-hydrated gypsum and retarder are added when to be used, stirs and can be used.

The concocting method of two-bath gum dipping is as follows：

(1) PVA glues and water are added sequentially in reaction vessel, open stirring, heating water bath to 80 DEG C, with 1000rad/min stir speed (S.S.) stirring 1h, until PVA glues are completely dissolved, obtains the PVA aqueous solution；

(2) the PVA aqueous solution obtained by step (1) is cooled to 70 DEG C, adhesive is added, with 700rad/min stirring Speed is stirred to adhesive and is completely dissolved；

(3) hydrochloric acid is added, is stirred to solution and is well mixed with 800rad/mind speed, required viscous fluid is just made Body, you can be added in cement dipping machine and use.

The formula of 3rd bath impregnation is with concocting method with first bath impregnation.

Embodiment 2：The gum dipping process of the cellular amphiphilic non-woven fabrics of the present invention is in addition to following difference, remaining same embodiment 1：

First bath impregnation is counted in parts by weight to be made up of following component：490 parts of water, 10 parts of surfactant, wherein, it is described Surfactant is oleic acid, laurate, sulfonate of laurate sodium sulphate in mass ratio 1：2：3 mix；

The concocting method of first bath impregnation is as follows：

(1) first add water in retort, water temperature is controlled at 30 DEG C；

(2) Surfactant SDS is launched into retort, stirring 25min is well mixed.

Two-bath gum dipping is counted in parts by weight to be made up of following component：600 parts of PVA glues, 150 parts of water, adhesive (gluing Agent is epoxy Aqueous Adhesives, phenolic aldehyde Aqueous Adhesives, organosilicon Aqueous Adhesives, rubber-like Aqueous Adhesives in mass ratio 1： 2：3：4 mix) 100 parts, 50 parts of hydrochloric acid (mass concentration 31.5%)；

Wherein, the PVA glues are counted in parts by weight is made up of following component：40 parts of polyvinyl alcohol environmental protection glue, water 150 (thickener is gelatine, donkey-hide gelatin, yellow rose glue in mass ratio 1 for part, thickener:2:3 mix) 18 parts, the formaldehyde (quality of formaldehyde Concentration is 36.5%) 22 parts；

The preparation method of PVA glues is as follows：

(1) polyvinyl alcohol environmental protection glue and water are added sequentially in reaction vessel, open stirring, heating water bath to 95 DEG C, 2h is stirred with 1200rad/min stir speed (S.S.), until polyvinyl alcohol environmental protection glue is completely dissolved to obtain glue；

(2) glue obtained by step (1) is cooled to 72 DEG C, thickener is added, with 800rad/min stir speed (S.S.) Stirring is completely dissolved to thickener, obtains sticky glue；

(3) the sticky glue of gained is cooled to 50 DEG C, adding formaldehyde stirring is well mixed glue, produces thick PVA glues.

Polyvinyl alcohol environmental protection glue is counted in parts by weight to be made up of following component：10 parts of polyvinyl alcohol, modifying agent (1,2- second two Alcohol) 5 parts, 0.4 part of preservative (salicylic acid), 88 parts of water, 24 parts of semi-hydrated gypsum, (retarder is potassium tartrate, propylene to retarder Acid, PAA in mass ratio 1:2:3 mix) 1 part.

(1) polyethylene alcohol and water is added in hot pot, 100 DEG C is heated with stirring to, with 1200rad/min's under heat-retaining condition Stir speed (S.S.) stirs 30min and is completely dissolved to polyvinyl alcohol,

(2) add modifying agent and preservative stirs, sealed storage is standby；

The concocting method of two-bath gum dipping is as follows：

(1) PVA glues and water are added sequentially in reaction vessel, open stirring, heating water bath to 95 DEG C, with 1200rad/min stir speed (S.S.) stirring 2h, until PVA glues are completely dissolved, obtains the PVA aqueous solution；

(2) the PVA aqueous solution obtained by step (1) is cooled to 72 DEG C, adhesive is added, with 800rad/min stirring Speed is stirred to adhesive and is completely dissolved；

(3) hydrochloric acid is added, is stirred to solution and is well mixed with 900rad/mind speed, required viscous fluid is just made Body, you can be added in cement dipping machine and use.

Embodiment 3：The gum dipping process of the cellular amphiphilic non-woven fabrics of the present invention is in addition to following difference, remaining same embodiment 1：

First bath impregnation is counted in parts by weight to be made up of following component：470 parts of water, 30 parts of surfactant, wherein, it is described Surfactant is dodecyl sodium sulfate, odium stearate, oleic acid, laurate in mass ratio 1：2：3：4 mix；

The concocting method of first bath impregnation is as follows：

(1) first add water in retort, water temperature is controlled at 25 DEG C；

(2) Surfactant SDS is launched into retort, stirring 20min is well mixed.

Two-bath gum dipping is counted in parts by weight to be made up of following component：500 parts of PVA glues, 100 parts of water, adhesive (gluing Agent is Aqueous Polyurethane Adhesives, vinyl acetate esters Aqueous Adhesives, epoxy Aqueous Adhesives, phenolic aldehyde Aqueous Adhesives press matter Measure ratio 1：1：1：1 mixes) 80 parts, 30 parts of hydrochloric acid (mass concentration 31.5%)；

Wherein, the PVA glues are counted in parts by weight is made up of following component：35 parts of polyvinyl alcohol environmental protection glue, water 130 (thickener is polyurethane adhesive, xanthans, gelatine, donkey-hide gelatin in mass ratio 1 for part, thickener:2:3:1 mixes) 15 parts, formaldehyde 16 parts of (mass concentration of formaldehyde is 36.5%)；

The preparation method of PVA glues is as follows：

(1) polyvinyl alcohol environmental protection glue and water are added sequentially in reaction vessel, open stirring, heating water bath to 90 DEG C, 1.5h is stirred with 1100rad/min stir speed (S.S.), until polyvinyl alcohol environmental protection glue is completely dissolved to obtain glue；

(2) glue obtained by step (1) is cooled to 70 DEG C, thickener is added, with 750rad/min stir speed (S.S.) Stirring is completely dissolved to thickener, obtains sticky glue；

(3) the sticky glue of gained is cooled to 52 DEG C, adding formaldehyde stirring is well mixed glue, produces thick PVA glues.

Polyvinyl alcohol environmental protection glue is counted in parts by weight to be made up of following component：(modifying agent is for 8 parts of polyvinyl alcohol, modifying agent 1,2- ethylene glycol, 1,2,3- glycerine, 1,2,3,4,5- pentitols in mass ratio 1:1:3 mix) 3 parts, preservative (anti-corrosion Agent is boric acid and salicylic acid in mass ratio 1:1 mixes) 0.2 part, 78 parts of water, 2 parts of semi-hydrated gypsum, (retarder is retarder Calgon, sodium polyphosphate in mass ratio 1:1 mixes) 3 parts.

(1) polyethylene alcohol and water is added in hot pot, 95 DEG C is heated with stirring to, with 1100rad/min's under heat-retaining condition Stir speed (S.S.) stirs 28min and is completely dissolved to polyvinyl alcohol,

(2) add modifying agent and preservative stirs, sealed storage is standby；

The concocting method of two-bath gum dipping is as follows：

(1) PVA glues and water are added sequentially in reaction vessel, open stirring, heating water bath to 90 DEG C, with 1200rad/min stir speed (S.S.) stirring 1.5h, until PVA glues are completely dissolved, obtains the PVA aqueous solution；

(2) the PVA aqueous solution obtained by step (1) is cooled to 70 DEG C, adhesive is added, with 750rad/min stirring Speed is stirred to adhesive and is completely dissolved；

(3) hydrochloric acid is added, is stirred to solution and is well mixed with 850rad/mind speed, required viscous fluid is just made Body, you can be added in cement dipping machine and use.

Embodiment 4：The gum dipping process of the cellular amphiphilic non-woven fabrics of the present invention is in addition to following difference, remaining same embodiment 1：

First bath impregnation is counted in parts by weight to be made up of following component：480 parts of water, 40 parts of surfactant, wherein, it is described Surfactant is lauryl sodium sulfate, odium stearate, oleic acid, sulfonate of laurate sodium sulphate in mass ratio 1:2:3:4 mix；

The concocting method of first bath impregnation is as follows：

(1) first add water in retort, water temperature is controlled at 25 DEG C；

(2) Surfactant SDS is launched into retort, stirring 20min is well mixed.

Two-bath gum dipping is counted in parts by weight to be made up of following component：550 parts of PVA glues, 120 parts of water, adhesive (gluing Agent is polyvinyl alcohol Aqueous Adhesives, organosilicon Aqueous Adhesives, rubber-like Aqueous Adhesives in mass ratio 1：2：1 mixing and Into) 60 parts, 40 parts of hydrochloric acid (mass concentration 31.5%)；

Wherein, the PVA glues are counted in parts by weight is made up of following component：32 parts of polyvinyl alcohol environmental protection glue, water 140 (thickener is Arabic gum, xanthans, gelatine, yellow rose glue in mass ratio 1 for part, thickener:2:3:4 mix) 12 parts, first 20 parts of aldehyde (mass concentration of formaldehyde is 36.5%)；

The preparation method of PVA glues is as follows：

(1) polyvinyl alcohol environmental protection glue and water are added sequentially in reaction vessel, open stirring, heating water bath to 90 DEG C, 2h is stirred with 1000rad/min stir speed (S.S.), until polyvinyl alcohol environmental protection glue is completely dissolved to obtain glue；

Polyvinyl alcohol environmental protection glue is counted in parts by weight to be made up of following component：(modifying agent is for 6 parts of polyvinyl alcohol, modifying agent 1,2- ethylene glycol, 1,2,3- glycerine, 1,2,3,4,5- pentitols in mass ratio 1:2:3 mix) 4 parts, preservative (anti-corrosion Agent is boric acid and salicylic acid in mass ratio 1:2 mix) 0.1 part, 68 parts of water, 10 parts of semi-hydrated gypsum, (retarder is retarder Calgon, sodium polyphosphate in mass ratio 1:1 mixes) 10 parts.

(1) polyethylene alcohol and water is added in hot pot, 100 DEG C is heated with stirring to, with 1000rad/min's under heat-retaining condition Stir speed (S.S.) stirs 30min and is completely dissolved to polyvinyl alcohol,

(2) add modifying agent and preservative stirs, sealed storage is standby；

The concocting method of two-bath gum dipping is as follows：

(1) PVA glues and water are added sequentially in reaction vessel, open stirring, heating water bath to 95 DEG C, with 1000rad/min stir speed (S.S.) stirring 2h, until PVA glues are completely dissolved, obtains the PVA aqueous solution；

3rd bath impregnation is counted in parts by weight to be made up of following component：475 parts of water, 25 parts of surfactant, wherein, it is described Surfactant is lauryl sodium sulfate, odium stearate, oleic acid, sulfonate of laurate sodium sulphate in mass ratio 1:2:3:4 mix. Concocting method of the concocting method of 3rd bath impregnation with the first bath impregnation of the present embodiment.

Embodiment 5：The gum dipping process of the cellular amphiphilic non-woven fabrics of the present invention is in addition to following difference, remaining same embodiment 1：

First bath impregnation is counted in parts by weight to be made up of following component：470 parts of water, 30 parts of surfactant, wherein, it is described Surfactant is lauryl sodium sulfate；

The concocting method of first bath impregnation is as follows：

(1) first add water in retort, water temperature is controlled at 25 DEG C；

(2) Surfactant SDS is launched into retort, stirring 20min is well mixed.

Two-bath gum dipping is counted in parts by weight to be made up of following component：550 parts of PVA glues, 120 parts of water, adhesive (gluing Agent is polyvinyl alcohol Aqueous Adhesives) 60 parts, 40 parts of hydrochloric acid (mass concentration 31.5%)；

Wherein, the PVA glues are counted in parts by weight is made up of following component：32 parts of polyvinyl alcohol environmental protection glue, water 140 Part, 12 parts of thickener (thickener is Arabic gum), 20 parts of formaldehyde (mass concentration of formaldehyde is 36.5%)；The system of PVA glues Preparation Method is the same as embodiment 4.

Polyvinyl alcohol environmental protection glue is counted in parts by weight to be made up of following component：(modifying agent is for 6 parts of polyvinyl alcohol, modifying agent 1,2,3- glycerine) 4 parts, 0.1 part of preservative (preservative is salicylic acid), 68 parts of water, 10 parts of semi-hydrated gypsum, retarder (slow setting Agent is citric acid, sodium citrate in mass ratio 1:1 mixes) 10 parts；The same embodiment of preparation method of polyvinyl alcohol environmental protection glue 4。

The concocting method of two-bath gum dipping is as follows：

Embodiment 6：The gum dipping process of the cellular amphiphilic non-woven fabrics of the present invention is in addition to following difference, remaining same embodiment 1：

First bath impregnation is counted in parts by weight to be made up of following component：470 parts of water, 30 parts of surfactant, wherein, it is described Surfactant is dodecyl sodium sulfate；

The concocting method of first bath impregnation is as follows：

(1) first add water in retort, water temperature is controlled at 25 DEG C；

(2) Surfactant SDS is launched into retort, stirring 20min is well mixed.

Two-bath gum dipping is counted in parts by weight to be made up of following component：550 parts of PVA glues, 120 parts of water, adhesive (gluing Agent is Aqueous Polyurethane Adhesives) 60 parts, 40 parts of hydrochloric acid (mass concentration 31.5%)；

Wherein, the PVA glues are counted in parts by weight is made up of following component：32 parts of polyvinyl alcohol environmental protection glue, water 140 Part, 12 parts of thickener (thickener is polyurethane adhesive), 20 parts of formaldehyde (mass concentration of formaldehyde is 36.5%)；The system of PVA glues Preparation Method is the same as embodiment 4.

Polyvinyl alcohol environmental protection glue is counted in parts by weight to be made up of following component：(modifying agent is for 6 parts of polyvinyl alcohol, modifying agent 1,2,3,4,5- pentitols) 4 parts, 0.1 part of preservative (preservative is boric acid), 68 parts of water, 10 parts of semi-hydrated gypsum, retarder it is (slow Solidifying agent is tartaric acid, potassium tartrate in mass ratio 1:1 mixes) 10 parts；The preparation method of polyvinyl alcohol environmental protection glue is the same as implementation Example 4.

The concocting method of two-bath gum dipping is as follows：

Embodiment 7：The gum dipping process of the cellular amphiphilic non-woven fabrics of the present invention is in addition to following difference, remaining same embodiment 1：

First bath impregnation is counted in parts by weight to be made up of following component：470 parts of water, 30 parts of surfactant, wherein, it is described Surfactant is odium stearate；

The concocting method of first bath impregnation is as follows：

(1) first add water in retort, water temperature is controlled at 25 DEG C；

(2) Surfactant SDS is launched into retort, stirring 20min is well mixed.

Two-bath gum dipping is counted in parts by weight to be made up of following component：550 parts of PVA glues, 120 parts of water, adhesive (gluing Agent is vinyl acetate esters Aqueous Adhesives) 60 parts, 40 parts of hydrochloric acid (mass concentration 31.5%)；

Wherein, the PVA glues are counted in parts by weight is made up of following component：32 parts of polyvinyl alcohol environmental protection glue, water 140 Part, 12 parts of thickener (thickener is xanthans), 20 parts of formaldehyde (mass concentration of formaldehyde is 36.5%)；The preparation of PVA glues Method is the same as embodiment 4.

Polyvinyl alcohol environmental protection glue is counted in parts by weight to be made up of following component：(modifying agent is for 6 parts of polyvinyl alcohol, modifying agent 1,2,3,4,5- pentitols) 4 parts, 0.1 part of preservative (preservative is boric acid), 68 parts of water, 10 parts of semi-hydrated gypsum, retarder it is (slow Solidifying agent is acrylic acid, PAA in mass ratio 1:1 mixes) 10 parts；The preparation method of polyvinyl alcohol environmental protection glue is the same as implementation Example 4.

The concocting method of two-bath gum dipping is as follows：

Embodiment 8：The gum dipping process of the cellular amphiphilic non-woven fabrics of the present invention is in addition to following difference, remaining same embodiment 1：

First bath impregnation is counted in parts by weight to be made up of following component：450 parts of water, 50 parts of surfactant, wherein, it is described Surfactant is oleic acid；

The concocting method of first bath impregnation is as follows：

(1) first add water in retort, water temperature is controlled at 20 DEG C；

(2) Surfactant SDS is launched into retort, stirring 15min is well mixed.

Two-bath gum dipping is counted in parts by weight to be made up of following component：400 parts of PVA glues, 40 parts of water, adhesive (gluing Agent is epoxy Aqueous Adhesives) 50 parts, 10 parts of hydrochloric acid (mass concentration 30.5%)；

Wherein, the PVA glues are counted in parts by weight is made up of following component：30 parts of polyvinyl alcohol environmental protection glue, water 120 Part, 9 parts of thickener (thickener is gelatine), 11 parts of formaldehyde (mass concentration of formaldehyde is 36.5%)；The preparation method of PVA glues With embodiment 1.

Polyvinyl alcohol environmental protection glue is counted in parts by weight to be made up of following component：(modifying agent is for 5 parts of polyvinyl alcohol, modifying agent 1,2- ethylene glycol, 1,2,3- glycerine in mass ratio 1:2 mix) 2 parts, 0.1 part of preservative (salicylic acid), 60 parts of water, half (retarder is calgon, sodium polyphosphate in mass ratio 1 for 1 part of water gypsum, retarder:2 mix) 1 part；Polyethylene The preparation method of alcohol environment-friendlyadhesive adhesive is the same as embodiment 1.

The concocting method of two-bath gum dipping is as follows：

3rd bath impregnation is counted in parts by weight to be made up of following component：475 parts of water, 25 parts of surfactant, wherein, it is described Surfactant is oleic acid.Concocting method of the concocting method of 3rd bath impregnation with the first bath impregnation of the present embodiment.

Embodiment 9：The gum dipping process of the cellular amphiphilic non-woven fabrics of the present invention is in addition to following difference, remaining same embodiment 1：

First bath impregnation is counted in parts by weight to be made up of following component：490 parts of water, 10 parts of surfactant, wherein, it is described Surfactant is laurate；

The concocting method of first bath impregnation is as follows：

(1) first add water in retort, water temperature is controlled at 30 DEG C；

(2) Surfactant SDS is launched into retort, stirring 25min is well mixed.

Two-bath gum dipping is counted in parts by weight to be made up of following component：600 parts of PVA glues, 150 parts of water, adhesive (gluing Agent is that phenolic aldehyde Aqueous Adhesives, organosilicon Aqueous Adhesives in mass ratio 11 mix) 100 parts, (mass concentration is hydrochloric acid 31.5%) 50 parts；

Wherein, the PVA glues are counted in parts by weight is made up of following component：40 parts of polyvinyl alcohol environmental protection glue, water 150 Part, 18 parts of thickener (thickener is donkey-hide gelatin), 22 parts of formaldehyde (mass concentration of formaldehyde is 36.5%)；The preparation side of PVA glues Method is the same as embodiment 2.

Polyvinyl alcohol environmental protection glue is counted in parts by weight to be made up of following component：(modifying agent is for 10 parts of polyvinyl alcohol, modifying agent 1,2- ethylene glycol, 1,2,3,4,5- pentitols are according to mass ratio 1:1 mixes) 5 parts, 0.4 part of preservative (boric acid), water 88 (retarder is calgon, sodium polyphosphate in mass ratio 1 for part, 24 parts of semi-hydrated gypsum, retarder:1 mixes) 1 part； The preparation method of polyvinyl alcohol environmental protection glue is the same as embodiment 2.

The concocting method of two-bath gum dipping is as follows：

Embodiment 10：The gum dipping process of the cellular amphiphilic non-woven fabrics of the present invention is in addition to following difference, and remaining is the same as implementation Example 1：

First bath impregnation is counted in parts by weight to be made up of following component：470 parts of water, 30 parts of surfactant, wherein, it is described Surfactant is sulfonate of laurate sodium sulphate；

The concocting method of first bath impregnation is as follows：

(1) first add water in retort, water temperature is controlled at 25 DEG C；

(2) Surfactant SDS is launched into retort, stirring 20min is well mixed.

Two-bath gum dipping is counted in parts by weight to be made up of following component：500 parts of PVA glues, 100 parts of water, adhesive (gluing Agent is rubber-like Aqueous Adhesives) 80 parts, 30 parts of hydrochloric acid (mass concentration 31.5%)；

Wherein, the PVA glues are counted in parts by weight is made up of following component：35 parts of polyvinyl alcohol environmental protection glue, water 130 Part, 15 parts of thickener (thickener is yellow rose glue), 16 parts of formaldehyde (mass concentration of formaldehyde is 36.5%)；The preparation of PVA glues Method is the same as embodiment 3.

Polyvinyl alcohol environmental protection glue is counted in parts by weight to be made up of following component：(modifying agent is for 8 parts of polyvinyl alcohol, modifying agent 1,2,3,4,5- pentitols) 3 parts, (preservative is boric acid and salicylic acid in mass ratio 1 to preservative:1 mixes) 0.2 part, water 78 parts, 2 parts of semi-hydrated gypsum, 3 parts of retarder (retarder is calgon)；The preparation method of polyvinyl alcohol environmental protection glue is the same as implementation Example 3.

The concocting method of two-bath gum dipping is as follows：

3rd bath impregnation is counted in parts by weight to be made up of following component：475 parts of water, 25 parts of surfactant, wherein, it is described Surfactant is sulfonate of laurate sodium sulphate.Allotment side of the concocting method of 3rd bath impregnation with the first bath impregnation of the present embodiment Method.

Embodiment 11：The gum dipping process of the cellular amphiphilic non-woven fabrics of the present invention is in addition to following difference, and remaining is the same as implementation Example 1：

First bath impregnation is counted in parts by weight to be made up of following component：470 parts of water, 30 parts of surfactant, wherein, it is described Surfactant is laurate, sulfonate of laurate sodium sulphate in mass ratio 1:1 mixes；

The concocting method of first bath impregnation is as follows：

(1) first add water in retort, water temperature is controlled at 20 DEG C；

(2) Surfactant SDS is launched into retort, stirring 20min is well mixed.

Two-bath gum dipping is counted in parts by weight to be made up of following component：550 parts of PVA glues, 100 parts of water, adhesive (gluing Agent is vinyl acetate esters Aqueous Adhesives) 80 parts, 30 parts of hydrochloric acid (mass concentration 31.5%)；

Wherein, the PVA glues are counted in parts by weight is made up of following component：35 parts of polyvinyl alcohol environmental protection glue, water 130 (thickener is Arabic gum, polyurethane adhesive according to mass ratio 1 for part, thickener:1 mixes) 15 parts, the formaldehyde (quality of formaldehyde Concentration is 36.5%) 16 parts；The preparation method of PVA glues is the same as embodiment 4.

Polyvinyl alcohol environmental protection glue is counted in parts by weight to be made up of following component：(modifying agent is for 8 parts of polyvinyl alcohol, modifying agent 1,2,3- glycerine) 3 parts, (preservative is boric acid and salicylic acid in mass ratio 1 to preservative:1 mixes) 0.2 part, 78 parts of water, 2 parts of semi-hydrated gypsum, 3 parts of retarder (retarder is tartaric acid)；The preparation method of polyvinyl alcohol environmental protection glue is the same as embodiment 4.

The concocting method of two-bath gum dipping is as follows：

Embodiment 12：The gum dipping process of the cellular amphiphilic non-woven fabrics of the present invention is in addition to following difference, and remaining is the same as implementation Example 1：

First bath impregnation is counted in parts by weight to be made up of following component：470 parts of water, 30 parts of surfactant, wherein, it is described Surfactant is odium stearate, oleic acid in mass ratio 1:1 mixes；

The concocting method of first bath impregnation is as follows：

(1) first add water in retort, water temperature is controlled at 25 DEG C；

(2) Surfactant SDS is launched into retort, stirring 20min is well mixed.

Two-bath gum dipping is counted in parts by weight to be made up of following component：580 parts of PVA glues, 80 parts of water, adhesive (gluing Agent is phenolic aldehyde Aqueous Adhesives) 60 parts, 20 parts of hydrochloric acid (mass concentration 31.5%)；

Wherein, the PVA glues are counted in parts by weight is made up of following component：35 parts of polyvinyl alcohol environmental protection glue, water 130 (thickener is xanthans, gelatine, donkey-hide gelatin in mass ratio 1 for part, thickener:1:1 mixes) 10 parts, the formaldehyde (quality of formaldehyde Concentration is 36.5%) 17 parts；The preparation method of PVA glues is the same as embodiment 3.

Polyvinyl alcohol environmental protection glue is counted in parts by weight to be made up of following component：(modifying agent is for 8 parts of polyvinyl alcohol, modifying agent 1,2- ethylene glycol) 3 parts, 0.2 part of preservative (preservative is boric acid 1,2- ethylene glycol), 78 parts of water, 2 parts of semi-hydrated gypsum, retarder 3 parts of (retarder is sodium citrate)；The preparation method of polyvinyl alcohol environmental protection glue is the same as embodiment 3.

The concocting method of two-bath gum dipping is as follows：

3rd bath impregnation is counted in parts by weight to be made up of following component：475 parts of water, 25 parts of surfactant, wherein, it is described Surfactant is odium stearate, oleic acid in mass ratio 1:1 mixes.The concocting method of 3rd bath impregnation is the same as the present embodiment The concocting method of first bath impregnation.

Embodiment 13：The gum dipping process of the cellular amphiphilic non-woven fabrics of the present invention is in addition to following difference, and remaining is the same as implementation Example 1：

First bath impregnation is counted in parts by weight to be made up of following component：450 parts of water, 50 parts of surfactant, wherein, it is described Surfactant is lauryl sodium sulfate；

The concocting method of first bath impregnation is as follows：

(1) first add water in retort, water temperature is controlled at 20 DEG C；

(2) Surfactant SDS is launched into retort, stirring 20min is well mixed.

Two-bath gum dipping is counted in parts by weight to be made up of following component：406 parts of PVA glues, 150 parts of water, adhesive (gluing Agent is polyvinyl alcohol Aqueous Adhesives) 95 parts, 49 parts of hydrochloric acid (mass concentration 31.5%)；

Wherein, the PVA glues are counted in parts by weight is made up of following component：30 parts of polyvinyl alcohol environmental protection glue, water 150 Part, 9 parts of thickener (thickener is Arabic gum), 11 parts of formaldehyde (mass concentration of formaldehyde is 36.5%)；The preparation of PVA glues Method is the same as embodiment 4.

Polyvinyl alcohol environmental protection glue is counted in parts by weight to be made up of following component：(modifying agent is for 5 parts of polyvinyl alcohol, modifying agent 1,2- ethylene glycol) 2 parts, 0.1 part of preservative (preservative is boric acid), 88 parts of water, 1 part of semi-hydrated gypsum, (retarder is lemon to retarder Lemon acid) 4 parts；The preparation method of polyvinyl alcohol environmental protection glue is the same as embodiment 4.

The concocting method of two-bath gum dipping is as follows：

3rd bath impregnation is counted in parts by weight to be made up of following component：475 parts of water, 25 parts of surfactant, wherein, it is described Surfactant is lauryl sodium sulfate.Allotment side of the concocting method of 3rd bath impregnation with the first bath impregnation of the present embodiment Method.

Embodiment 14：The gum dipping process of the cellular amphiphilic non-woven fabrics of the present invention is in addition to following difference, and remaining is the same as implementation Example 1：

First bath impregnation is counted in parts by weight to be made up of following component：450 parts of water, 50 parts of surfactant, wherein, it is described Surfactant is odium stearate；

The concocting method of first bath impregnation is as follows：

(1) first add water in retort, water temperature is controlled at 20 DEG C；

(2) Surfactant SDS is launched into retort, stirring 20min is well mixed.

Two-bath gum dipping is counted in parts by weight to be made up of following component：406 parts of PVA glues, 150 parts of water, adhesive (gluing Agent is Aqueous Polyurethane Adhesives) 95 parts, 49 parts of hydrochloric acid (mass concentration 31.5%)；

Wherein, the PVA glues are counted in parts by weight is made up of following component：30 parts of polyvinyl alcohol environmental protection glue, water 150 Part, 9 parts of thickener (thickener is xanthans), 11 parts of formaldehyde (mass concentration of formaldehyde is 36.5%)；The preparation side of PVA glues Method is the same as embodiment 4.

The concocting method of two-bath gum dipping is as follows：

3rd bath impregnation is counted in parts by weight to be made up of following component：475 parts of water, 25 parts of surfactant, wherein, it is described Surfactant is odium stearate.Concocting method of the concocting method of 3rd bath impregnation with the first bath impregnation of the present embodiment.

Embodiment 15：The gum dipping process of the cellular amphiphilic non-woven fabrics of the present invention is in addition to following difference, and remaining is the same as implementation Example 1：

First bath impregnation is counted in parts by weight to be made up of following component：450 parts of water, 50 parts of surfactant, wherein, it is described Surfactant is laurate；

The concocting method of first bath impregnation is as follows：

(1) first add water in retort, water temperature is controlled at 25 DEG C；

(2) Surfactant SDS is launched into retort, stirring 20min is well mixed.

Two-bath gum dipping is counted in parts by weight to be made up of following component：406 parts of PVA glues, 150 parts of water, adhesive (gluing Agent is epoxy Aqueous Adhesives) 98 parts, 46 parts of hydrochloric acid (mass concentration 31.5%)；

The concocting method of two-bath gum dipping is as follows：

3rd bath impregnation is counted in parts by weight to be made up of following component：475 parts of water, 25 parts of surfactant, wherein, it is described Surfactant is laurate.Concocting method of the concocting method of 3rd bath impregnation with the first bath impregnation of the present embodiment.

Embodiment 16：The gum dipping process of the cellular amphiphilic non-woven fabrics of the present invention is in addition to following difference, and remaining is the same as implementation Example 1：

First bath impregnation is counted in parts by weight to be made up of following component：450 parts of water, 50 parts of surfactant, wherein, it is described Surfactant is sulfonate of laurate sodium sulphate；

The concocting method of first bath impregnation is as follows：

(1) first add water in retort, water temperature is controlled at 25 DEG C；

(2) Surfactant SDS is launched into retort, stirring 20min is well mixed.

Two-bath gum dipping is counted in parts by weight to be made up of following component：406 parts of PVA glues, 150 parts of water, adhesive (gluing Agent is rubber-like Aqueous Adhesives) 98 parts, 46 parts of hydrochloric acid (mass concentration 31.5%)；

The concocting method of two-bath gum dipping is as follows：

To cellular amphiphilic non-woven fabrics and undressed non-woven fabrics made from above-described embodiment 1-16 as a comparison Example 1 carries out quantitative measurement, gained test result such as table 1 below：

Table 1

Embodiment	Water absorption rate (%)	Tensile strength (KN)	Elongation at break (%)	Porosity (%)
					Embodiment 1	1211	10.25	135	77
Embodiment 2	1219	10.16	132	78
					Embodiment 3	1228	10.19	123	79
Embodiment 4	1237	10.42	137	80
					Embodiment 5	1110	10.20	126	76
Embodiment 6	1179	10.26	131	77
					Embodiment 7	1111	10.12	120	76
Embodiment 8	1011	10.20	126	74
					Embodiment 9	1179	10.26	131	79
Embodiment 10	1112	10.12	123	73
					Embodiment 11	1018	10.23	116	74
Embodiment 12	1139	10.14	126	76
					Embodiment 13	1180	10.15	120	75
Embodiment 14	1070	10.13	130	74
					Embodiment 15	1050	10.17	110	77
Embodiment 16	1110	10.12	120	73
					Comparative example 1	862	6.25	96	32

The foregoing is only a specific embodiment of the invention, it is noted that any those skilled in the art exist Disclosed herein technical scope in, the change or replacement that can readily occur in, should all cover protection scope of the present invention it It is interior.

Claims

1. a kind of gumming device of cellular amphiphilic non-woven fabrics, including the first yardage roll retractable frame (1) and the second yardage roll retractable frame (25), it is characterised in that also include the be successively set between the first yardage roll retractable frame (1) and the second yardage roll retractable frame (25) One bath gumming device, the second bath gumming device, the 3rd bath gumming device and drying device；

The first bath gumming device include set gradually the first pressure roller (2), the first home roll (3), the first deflector roll (4), first Belt supporting frame pressure roller (5), the first steeping vat (6) and the first scraper (7), first pressure roller (2) are arranged on the first home roll (3) Surface and its extrusion fit；

It is described second bath gumming device include set gradually the second pressure roller (8), the second home roll (9), the second deflector roll (10), second Belt supporting frame pressure roller (11), the second steeping vat (12) and the second scraper (13), second pressure roller (8) are arranged on the second home roll (9) surface and its extrusion fit；

The 3rd pressure roller (14) that the 3rd bath gumming device includes setting gradually, the 3rd home roll (15), the 3rd deflector roll (16), the Three belt supporting frame pressure rollers (17), the 3rd steeping vat (18) and the 3rd scraper (19)；3rd pressure roller (14) is arranged on the 3rd master The surface of roller (15) and its extrusion fit；

The drying device includes the 4th pressure roller (20), heating rod (21), the 5th pressure roller (22), the first chill roll set gradually (23) and the second chill roll (24), the 4th pressure roller (20) are symmetricly set on heating rod (21) with the 5th pressure roller (22) Both sides and its extrusion fit.

2. a kind of gumming device using cellular amphiphilic non-woven fabrics described in claim 1 carries out the technique of impregnation, its feature It is, comprises the following steps：

1) nonwoven is arranged on the first yardage roll retractable frame (1), passed sequentially through the first pressure roller (2), the first home roll (3), with And first deflector roll (4), then it is 20-60 to be immersed in temperature into the first steeping vat (6) under the drawing-off of first band support pressure roller (5) DEG C first bath impregnation in, first bath impregnation unnecessary on non-woven fabrics is scraped back by the first impregnation by the first scraper (7) after dipping Groove (6)；

2) non-woven fabrics after step 1) processing is passed sequentially through into the second pressure roller (8), the second home roll (9) and the second deflector roll (10), Enter the second steeping vat (12) under the drawing-off of the second belt supporting frame pressure roller (11) again and be immersed in the second bath leaching that temperature is 20-60 DEG C In glue, two-bath gum dipping unnecessary on non-woven fabrics is scraped back by the second steeping vat (12) by the second scraper (13) after dipping；

3) non-woven fabrics after step 2) processing is passed sequentially through into the 3rd pressure roller (14), the 3rd home roll (15) and the 3rd deflector roll (16) the 3rd steeping vat (18) is immersed in that temperature is 20-60 DEG C the is entered, then under the drawing-off of the 3rd belt supporting frame pressure roller (17) In three bath impregnations, the 3rd bath impregnation unnecessary on non-woven fabrics is scraped back by the 3rd steeping vat by the 3rd scraper (19) after dipping (18)；Last non-woven fabrics successively by the 4th pressure roller (20), heating rod (21), the 5th pressure roller (22), the first chill roll (23), with And second after chill roll (24), bunchy is wound on the second yardage roll retractable frame (25).

3. the gum dipping process of cellular amphiphilic non-woven fabrics according to claim 2, it is characterised in that in the step 1) In, first bath impregnation is counted in parts by weight to be made up of following component：Water 450-490 parts, surfactant 10-50 parts；The table Face activating agent is in lauryl sodium sulfate, dodecyl sodium sulfate, odium stearate, oleic acid, laurate, sulfonate of laurate sodium sulphate One or more；The non-woven fabrics be using polyamide fibre and polypropylene fibre blending into Nomex non-woven fabrics.

4. the gum dipping process of cellular amphiphilic non-woven fabrics according to claim 3, it is characterised in that：The first bath impregnation Concocting method comprise the following steps：Water is first added into container, water temperature is controlled at 20-30 DEG C, then surface is added into container Activating agent, stir.

5. the gum dipping process of cellular amphiphilic non-woven fabrics according to claim 2, it is characterised in that in the step 2) In, two-bath gum dipping is counted in parts by weight to be made up of following component：PVA glue 400-600 parts, water 40-150 parts, adhesive 50- 100 parts, hydrochloric acid 10-50 parts；Wherein, the adhesive is selected from polyvinyl alcohol Aqueous Adhesives, Aqueous Polyurethane Adhesives, second Alkene acetate esters Aqueous Adhesives, epoxy Aqueous Adhesives, phenolic aldehyde Aqueous Adhesives, organosilicon Aqueous Adhesives, rubber-like water One or more in property adhesive.

6. the gum dipping process of cellular amphiphilic non-woven fabrics according to claim 5, it is characterised in that：The PVA glues Count and be made up of following component in parts by weight：Polyvinyl alcohol environmental protection glue 30-40 parts, water 120-150 parts, thickener 9-18 parts, first Aldehyde 11-22 parts, wherein, the thickener is in Arabic gum, polyurethane glue, xanthans, gelatine, donkey-hide gelatin, yellow rose glue It is one or more.

7. the gum dipping process of cellular amphiphilic non-woven fabrics according to claim 6, it is characterised in that：The PVA glues Preparation method it is as follows：First polyvinyl alcohol environmental protection glue and water are added sequentially in reaction vessel, heating water bath to 80-95 DEG C, 1-2h is stirred with 1000-1200rad/min stir speed (S.S.), until polyvinyl alcohol environmental protection glue is completely dissolved to obtain glue；Then Glue is cooled to 70~72 DEG C, thickener is added, is stirred with 700-800rad/min stir speed (S.S.) completely molten to thickener Solution obtains sticky glue；The sticky glue of gained is finally cooled to 50-55 DEG C, formaldehyde is added and is uniformly mixed, you can.

8. the gum dipping process of cellular amphiphilic non-woven fabrics according to claim 6, it is characterised in that：The polyvinyl alcohol Environment-friendlyadhesive adhesive is counted in parts by weight to be made up of following component：Polyvinyl alcohol 5-10 parts, modifying agent 2-5 parts, 0.1-0.4 parts preservative, Water 60-88 parts, semi-hydrated gypsum 1-25 parts, retarder 1-25 parts；Wherein, the modifying agent is selected from 1,2- ethylene glycol, 1,2,3- third One or more in triol, 1,2,3,4,5- pentitols；The preservative is selected from boric acid and/or salicylic acid；The retarder In citric acid, sodium citrate, tartaric acid, potassium tartrate, acrylic acid, PAA, calgon, sodium polyphosphate It is one or more.

9. the gum dipping process of cellular amphiphilic non-woven fabrics according to claim 5, it is characterised in that the second bath leaching The concocting method of glue comprises the following steps：First PVA glues and water are added sequentially in reaction vessel, heating water bath to 80-95 DEG C, 1-2h is stirred with 1000-1200rad/min stir speed (S.S.), until PVA glues are completely dissolved, obtains the PVA aqueous solution；So The PVA aqueous solution is cooled to 68~72 DEG C afterwards, adhesive is added, is stirred with 700-800rad/min stir speed (S.S.) to adhesive It is completely dissolved；Hydrochloric acid is eventually adding, is stirred to solution and is well mixed with 800-900rad/mind stir speed (S.S.), you can.

10. the gum dipping process of cellular amphiphilic non-woven fabrics according to claim 2, it is characterised in that in the step 3) in, the 3rd bath impregnation is counted in parts by weight to be made up of following component：Water 450-490 parts, surfactant 10-50 parts；It is described Surfactant is selected from lauryl sodium sulfate, dodecyl sodium sulfate, odium stearate, oleic acid, laurate, sulfonate of laurate sodium sulphate In one or more.