CN107603418A - The graphene anticorrosive paint of application on low prepared surface grade steel construction - Google Patents
The graphene anticorrosive paint of application on low prepared surface grade steel construction Download PDFInfo
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Abstract
The invention discloses the graphene anticorrosive paint of the application on low prepared surface grade steel construction, mixed by coating A and coating B；Coating A main components and percentage by weight are epoxy resin 10~40%, graphene 0.5~2%, metal bleeding agent 0.2~2%, anti-settling agent 0.1~2%, color stuffing 40~70%, solvent 8~22%, and coating B component and percentage by weight are amine curing agent 10~100%, solvent 0~90%；Coating A is packed respectively with coating B, its mixed proportion according to construction it needs to be determined that.Coating of the present invention is in the steel structure surface that rusting grade is A levels, grade is on Sa2.5 base material, does not carry out application on the steel structure surface of sandblasting Shot Blasting for surface treatment, and film adhesive is in more than 10Mpa；In the steel structure surface application that rusting grade is B levels, film adhesive is in more than 7Mpa；With superpower salt spray resistance, meet various Painting Construction of Steel Structures requirements.
Description
Technical field
The present invention relates to painting technology and the graphene anticorrosive paint of application on steel construction in coating application field, specifically
It is related to a kind of graphene infiltration anticorrosive paint being made up of materials such as modified epoxy, graphene, metal bleeding agents, especially
Sandblasting Shot Blasting is not done for Sa1.0 levels, surface being surface-treated grade, and only on the steel of degreasing and rust removal and rusting grade is divided
Not Wei on the low prepared surface grade steel construction such as A levels, level-B steel material application graphene anticorrosive paint.
Background technology
In recent years, with the continuous development of heavy industry, requirement more and more higher of the heavy construction to anticorrosive paint.Traditional weight
Anticorrosive paint such as epoxy zinc-enriched paint increasingly can not meet the construction of modern anticorrosive coating because of the limitation in its construction
Technical requirements, it is obvious that its major technique short slab is embodied in coating layering, deposited phenomenon, is not easy to stir evenly during construction；Moreover, its is right
Base material treatment requires high, it is necessary to competence exertion coating property of being constructed under Sa2.5 surface treatment rating conditions, substantially can not be
Surface treatment grade is Sa1.0 levels, sandblasting Shot Blasting is not done on surface, and only on the steel of degreasing and rust removal and rusting grade is distinguished
To carry out application on A levels, level-B steel material；Further, because zinc content is too high in spraying process, " stifled rifle " phenomenon is easily produced；
Therefore existing anticorrosive paint such as can not meet at the application needs on low prepared surface grade steel construction.
The content of the invention
For above-mentioned the deficiencies in the prior art, present invention seek to address that traditional anticorrosive paint is to substrate to be coated processing requirement
Must be in the inconvenience of Sa2.5 grades or more requirement, there is provided a kind of suitable for application on low prepared surface grade steel construction
Graphene anticorrosive paint, suitable for various steel component surface anticorrosions, such as pylon, bridge, electric power facility, chemical industry equipment, storage tank,
Container, ship, fence etc., can the application under low prepared surface grade.
In order to solve the above-mentioned technical problem, present invention employs following technical scheme：
The graphene anticorrosive paint of application on low prepared surface grade steel construction, it is characterised in that：By coating A and coating
B is mixed；
Coating A main components and percentage by weight are：
Coating B component and percentage by weight are：
| Composition | Percentage by weight (%) |
| Amine curing agent | 10~100 |
| Solvent | 0~90 |
Its epoxy resin is modified epoxy, modified E20, any of the E44 of modification；
Wherein graphene is lamellar structure, and its number of molecule layers is any one in 1-10 layers, and the piece footpath of graphene is 3-
10um；
Wherein metal bleeding agent is：Polyethenoxy ether class bleeding agent；
Wherein anti-settling agent is：Any of rheology modified wax liquor, polyamide wax powder, organobentonite；Or wherein wantonly two
Kind, or three kinds, mixed with the ratio for being each greater than 0 percent；
Its color stuffing is：Any of titanium dioxide, carbon black, blanc fixe, micaceous iron oxide gray, ferrophosphorus powder etc., or
Wherein any two, or wherein wantonly three kinds or wherein wantonly four kinds, or five kinds, mixed with the ratio for being each greater than 0 percent；
Wherein solvent is：Any of cyclohexanone, methyl iso-butyl ketone (MIBK), dimethylbenzene, n-butanol, or wherein any two,
Or it is wherein wantonly three kinds, or four kinds, mixed with the ratio for being each greater than 0 percent；
Coating B amine curing agent is：Any in polyamide curing agent, phenolic aldehyde amine amine hardener, fatty amine curing agent
Kind, or any two, or three kinds be each greater than 0 percent ratio mix；
Coating B solvent is：Any of cyclohexanone, methyl iso-butyl ketone (MIBK), dimethylbenzene, n-butanol, or wherein wantonly two
Kind, or it is wherein wantonly three kinds, or four kinds, mixed with the ratio for being each greater than 0 percent；
Further feature is：Wherein coating A also includes non-ionic dispersing agent, and its percentage by weight is 0.1~1%.
Wherein coating A also includes adhesion promoter, and adhesion promoter is：Methylsiloxane class, its percentage by weight
For 0.3~3%.
Wherein coating A also includes fluorine richness organosiloxane class wetting agent, and its percentage by weight is 0.1~1%.
Wherein coating A also includes levelling agent, and levelling agent is any in silicone levelling agent, or fluorinated levelling agent
Plant, or two kinds are mixed with the ratio for being each greater than 0 percent；Its percentage by weight is 0.2~1%.
Wherein coating A also includes levelling agent, and levelling agent is any in silicone levelling agent, or fluorinated levelling agent
Plant, or two kinds are mixed with the ratio for being each greater than 0 percent；Its percentage by weight is 0.2~1%.
The graphene molecules number of plies is any one in 1-10 layers, and the piece footpath of graphene is 3-10um.
The specific surface area of the graphene is any one in 100-300m2/g, and the water content of graphene is less than 1%.
Coating A is packed respectively with coating B, its mixed proportion according to construction it needs to be determined that, usual extemporaneous preparation.
The graphene anticorrosive paint of application on low prepared surface grade steel construction of the present invention, mainly by the epoxy of special modification
Resin, various amine curing agents, graphene, metal bleeding agent, functional aid, solvent, color stuffing etc. form.Graphite of the present invention
Alkene anticorrosive paint has the characteristics that：
(1) steel structure surface application of this coating in rusting grade for A levels, film adhesive is in more than 10Mpa；In corrosion
Grade is the steel structure surface application of B levels, and film adhesive is in more than 7Mpa.
(2) this coating steel structure surface processing grade be Sa2.5 base material on application, film adhesive 10Mpa with
On；It is application on Sa1.0 base material in steel structure surface processing grade, film adhesive is in more than 8Mpa；In steel structure surface
Sandblasting Shot Blasting, only application on the base material of degreasing and rust removal are not carried out, and film adhesive is in more than 7Mpa.
(3) this coating has superpower salt spray resistance.
(4) this coating application performance is good, meets various Painting Construction of Steel Structures requirements.
(5) this coating can solidify under cryogenic.
(6) this coating applicable period is grown.
Embodiment
With reference to specific embodiment, the present invention is described in further detail.Wherein, for description using it is all as above,
Under, the exemplary term such as left and right, it is therefore intended that help reader to understand, without being intended for limiting.
Graphene infiltration anticorrosive paint of the present invention is bi-component normal temperature self-drying paint, is mixed by coating A and coating B；
Coating A main components and percentage by weight are：
Coating B component and percentage by weight are：
| Composition | Percentage by weight (%) |
| Amine curing agent | 10~100 |
| Solvent | 0~90 |
Its epoxy resin is modified epoxy, such as any of modified E20, modification E44；
Wherein graphene is lamellar structure, and its number of molecule layers is any one in 1-10 layers, such as 3 layers, 5 layers；Wherein
The piece footpath of graphene is 3-10um；The specific surface area of wherein graphene is any one in 100-300m2/g, such as 180m2/g,
230m2/g etc.；Wherein the water content of graphene is less than 1%, such as 0.2,0.5；Wherein the oxygen content of graphene is less than 3%, such as
1%th, 2.5% etc.；Wherein the oil factor of graphene is 450-750mL/100g；
Wherein metal bleeding agent is：Polyethenoxy ether class bleeding agent, such as one or both of OE-35, E-1006 with appoint
Meaning ratio mixes.
Wherein anti-settling agent is：Any of rheology modified wax liquor, polyamide wax powder, organobentonite；Or wherein wantonly two
Kind, or three kinds, mixed with the ratio for being each greater than 0 percent；
Its color stuffing is：Any of titanium dioxide, carbon black, blanc fixe, micaceous iron oxide gray, ferrophosphorus powder etc., or
Wherein any two, or wherein wantonly three kinds or wherein wantonly four kinds, or five kinds, mixed with the ratio for being each greater than 0 percent；
Wherein solvent is：Any of cyclohexanone, methyl iso-butyl ketone (MIBK), dimethylbenzene, n-butanol, or wherein any two,
Or it is wherein wantonly three kinds, or four kinds, mixed with the ratio for being each greater than 0 percent；
Wherein dispersing aid is：Non-ionic dispersing agent.
The graphene of the present invention permeates needs of the anticorrosive paint according to actual use occasion, can also add following component,
Such as adhesion promoter, substrate wetting agents or levelling agent, to obtain more excellent performance：
Wherein adhesion promoter is：Methylsiloxane class, such as z-6040, BFK-D；Its percentage by weight be 0.3~
3%；
Wherein substrate wetting agents are：Fluorine richness organosiloxane class wetting agent, such as wet245, byk345；Its weight hundred
Divide than being 0.1~1%；
Wherein levelling agent is：Silicone levelling agent, such as Tego450, fluorinated levelling agent, as EFKA3600,
EFKA3777's etc. is any, or two kinds are mixed with the ratio for being each greater than 0 percent；Its percentage by weight is 0.2~1%.
Coating B amine curing agent is：Any in polyamide curing agent, phenolic aldehyde amine amine hardener, fatty amine curing agent
Kind, or any two, or three kinds be each greater than 0 percent ratio mix；
Coating B solvent is：More than one or both of dimethylbenzene, n-butanol, cyclohexanone, methyl iso-butyl ketone (MIBK) to appoint
Meaning ratio mixes.Its percentage by weight is 0~90%, represents not having to solvent in the proportioning during zero content, coating B only includes amine
Curing agent.
Coating A is packed respectively with coating B, is well mixed at the construction field (site), its mixed proportion according to construction it needs to be determined that, lead to
Often prepared, it is substantially unrestricted；The mass ratio A of preferably two components of the invention:B=M:N, M, N are natural number, such as 8:1、
10:1、20:3 etc..
The present invention coating A, its epoxy resin, the content that can be chosen be 10%, 15%, 20%, 25%, 30%,
45%th, 50% etc., the needs of the present invention can be met；Graphene, the content that can be chosen be 0.5%, 0.6%, 0.7%,
0.8%th, 0.9%, 1.0%, 1.1%, 1.2%, 1.3%, 1.4%, 1.5%, 1.6%, 1.7%, 1.8%, 1.9%, 2.0%
Deng, can meet the present invention needs；Metal bleeding agent, the content that can be chosen be 0.2%, 0.3%, 0.4%, 0.5%,
0.6%th, 0.7%, 0.8%, 0.9%, 1.0%, 1.1%, 1.2%, 1.3%, 1.4%, 1.5%, 1.6%, 1.7%,
1.8%th, 1.9%, 2.0% etc., the needs of the present invention can be met；Anti-settling agent, the content that can be chosen be 0.1%, 0.2%,
0.3%th, 0.4%, 0.5%, 0.6%, 0.7%, 0.8%, 0.9%, 1.0%, 1.1%, 1.2%, 1.3%, 1.4%,
1.5%th, 1.6%, 1.7%, 1.8%, 1.9%, 2.0% etc., the needs of the present invention can be met；Color stuffing, it can choose
Content is 40%, 45%, 50%, 55%, 60%, 65%, 70% etc., can meet the needs of the present invention；Dispersing aid, can be with
The content of selection is 0.1%, 0.2%, 0.3%, 0.4%, 0.5%, 0.6%, 0.7%, 0.8%, 0.9%, 1.0% etc., all
The needs of the present invention can be met；Solvent, the content that can be chosen be 8%, 9%, 10%, 11%, 12%, 13%, 14%,
15%th, 16%, 17%, 18%, 19%, 20%, 21%, 22% etc., the needs of the present invention can be met.
The present invention coating B, its amine curing agent, the content that can be chosen be 20%, 25%, 30%, 35%, 40%,
45%th, 50%, 55%, 60%, 65%, 70%, 75%, 80%, 85%, 90%, 95%, 100% etc., the present invention can be met
Needs；Solvent, the content that can be chosen be 0%, 5%, 10%, 15%, 20%, 25%, 30%, 35%, 40%, 45%,
50%th, 55%, 60%, 65%, 70%, 75%, 80% etc., the needs of the present invention can be met.
Specific embodiment 1：
Graphene permeates the preparation of anticorrosive paint
Component A：
Step 1：Weigh the modified epoxy liquid 267Kg as modified epoxy, the high-efficient graphite as graphene
Alkene 2kg, as the non-ionic dispersing agent 0.5kg of dispersant, as the organobentonite 1.2kg of anti-settling agent, as solvent
Dimethylbenzene 54kg, the n-butanol 36g as solvent are mixed and stirred for uniformly, being dispersed with stirring 10 minutes, being ground.In rotating speed
1372 revs/min, grind 45 minutes under conditions of 28-42 DEG C of temperature, ground slurry fineness to 25um, sampling detection solids content
For 49%, discharging is stand-by.
Step 2：Slurry 153kg made from step 1 is weighed, the modified epoxy liquid as modified epoxy
52kg, as the non-ionic dispersing agent 0.4kg of dispersant, as the titanium dioxide 105kg of color stuffing, the mica as color stuffing
Iron oxide ash 367kg is mixed and stirred for uniformly, being dispersed with stirring 10 minutes, being ground.In 1500 revs/min of rotating speed, temperature 31-
Ground 50 minutes under conditions of 54 DEG C, ground slurry fineness to 50um, sampling detection solids content is 75%, and discharging is stand-by.
Step 3：Weigh the slurry 464kg of step 2 preparation, the methylsiloxane class adhesive force as adhesion promoter
Accelerator 3kg, as the fluorine richness organosiloxane class wetting agent 2.5kg of substrate wetting agents, the organic silicon as levelling agent
Levelling agent 2.5kg is mixed and stirred for uniformly, is stirred 10 minutes under the conditions of 1500 revs/min of rotating speed, is filtered after inspection by sampling is qualified
Packaging.
B component, the polyamide curing agent 80kg of amine curing agent, packages spare.
Embodiment 2：
Graphene permeates the preparation of anticorrosive paint
Component A：
Step 1：Weigh the modified epoxy liquid 189.5Kg as modified epoxy, the efficient stone as graphene
Black alkene 1.4kg, as the non-ionic dispersing agent 0.4kg of dispersant, as the organobentonite 0.9kg of anti-settling agent, as molten
The dimethylbenzene 38.3kg of agent, the n-butanol 25.5g as solvent are mixed and stirred for uniformly；, it is dispersed with stirring 10 minutes, is ground
Mill.Ground 45 minutes under conditions of 1384 revs/min of rotating speed, 28-42 DEG C of temperature, ground slurry fineness to 25um, sampling inspection
It is 50% to survey solids content, and discharging is stand-by.
Step 2：Slurry 108.6kg made from step 1 is weighed, the modified epoxy liquid as modified epoxy
36.9g, as the non-ionic dispersing agent 0.3kg of dispersant, as the titanium dioxide 74.5kg of color stuffing, the cloud as color stuffing
Female iron oxide ash 260.5kg is mixed and stirred for uniformly；, it is dispersed with stirring 10 minutes, is ground.In 1500 revs/min of rotating speed, temperature
Ground 50 minutes under conditions of 30-52 DEG C of degree, ground slurry fineness to 50um, sampling detection solids content is 76%, and discharging is treated
With.
Step 3：The slurry 329.4kg of step 2 preparation is weighed, the methylsiloxane class as adhesion promoter is adhered to
Power accelerator 2.1kg, as the fluorine richness organosiloxane class wetting agent 1.8kg of substrate wetting agents, as the organic of levelling agent
Silicon class levelling agent 1.8kg is mixed and stirred for uniformly, is stirred 10 minutes under the conditions of 1500 revs/min of rotating speed, after inspection by sampling is qualified
Filter and package.
B component, the phenolic aldehyde amine amine hardener 80kg of amine curing agent, solvent 50kg, is uniformly mixed, packages spare.
Graphene of the present invention permeates anti-corrosion primer, and product is sampled by GB/T3186 regulation, drawn II in HG/T3668-2009
Type I class organic zinc-rich primers standard (except Zn content project) such as table 1, is detected to paint vehicle
II type I class technical indicators in table 1HG/T3668-2009
The example 1 of table 2, the sample survey result of example 2
The present invention is not zinc rich primer, so without Zn content examination criteria.Other standards meet or exceed HG/T3668-
II type I class standards in 2009.
Graphene infiltration anticorrosive paint example 1 of the present invention, example 2 are that Sa1.0 levels and surface are not done and sprayed in processing grade
The base material (rear to claim base material of not polishing) of sand Shot Blasting, only degreasing and rust removal does adhesive force test according to GB/T5210-2006.
The example 1 of table 3, the sample adhesive force test result of example 2.
| Example 1 | Example 2 | |
| Sa1.0 level base materials | 8.5MPa | 9.4MPa |
| Do not polish base material | 7.6MPa | 8.1MPa |
As can be seen from Table 3, graphene infiltration anti-corrosion paint of the present invention is adhered on surface treatment Sa1.0 level base materials
Power reaches more than 8MPa, reaches more than 7MPa coated in adhesive force on base material of not polishing.
Graphene infiltration anticorrosive paint example 1 of the present invention, example 2 is according to standard GB8923-88《Steel surface before application
Rusting grade and derusting grade》Middle steel corrosion ranking is attached to be done on the base material of A levels and B levels according to GB/T5210-2006
Put forth effort to test.
The example 1 of table 4, the sample adhesive force test result of example 2.
| Example 1 | Example 2 | |
| A level steel | 11.2MPa | 10.5MPa |
| Level-B steel material | 7.3MPa | 7.7MPa |
As can be seen from Table 4, graphene infiltration anti-corrosion paint of the present invention is adhesive force on A level base materials in rusting grade
Reach more than 10MPa, be that adhesive force reaches more than 7MPa on B level base materials coated in rusting grade.
Graphene infiltration anticorrosive paint construction reference of the present invention：
(1) before spraying, the pretreatment procedures such as workpiece cleaning do be carried out, to keep that workpiece oil-free is rustless, clean drying.
Stirred after please mixing component A and B component to scale, permeate priming paint special diluting agent as dilution by the use of graphene
Agent, dilution ratio are about the 10-20% of former paint, and adjustment working viscosity is 25-35s, places application after 10min.
(2) coating process uses high pressure airless spray equipment spraying application, spray pressure：0.4-0.8MPa rifles away from：0.2-
More coating thickness of 0.4m are 70-100 μm.
(3) in work progress, if paint solution has coarse grain to enter filtering with 120 mesh filter clothes.
The paint solidification condition of the present invention is normal temperature spontaneous curing, and solidification temperature can meet to be actually needed more than 5 DEG C,
Realize the object of the invention.
Finally it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention rather than restriction technologies side
Case, although the present invention is described in detail with reference to preferred embodiment by applicant, one of ordinary skill in the art should manage
Solution, technical scheme is modified for those or equivalent substitution, without departing from the objective and scope of the technical program,
It all should cover among scope of the presently claimed invention.
Claims (9)
1. the graphene anticorrosive paint of application on low prepared surface grade steel construction, it is characterised in that：By coating A and coating B
Mix；
Coating A main components and percentage by weight are：
Coating B component and percentage by weight are：
Its epoxy resin is modified epoxy, modified E20, any of the E44 of modification；
Wherein graphene is lamellar structure, and its number of molecule layers is any one in 1-10 layers, and the piece footpath of graphene is 3-10um；
Wherein metal bleeding agent is：Polyethenoxy ether class bleeding agent；
Wherein anti-settling agent is：Any of rheology modified wax liquor, polyamide wax powder, organobentonite；Or wherein any two, or
Three kinds, mixed with the ratio for being each greater than 0 percent；
Its color stuffing is：Any of titanium dioxide, carbon black, blanc fixe, micaceous iron oxide gray, ferrophosphorus powder etc., or wherein
Any two, or it is wherein wantonly three kinds or wherein wantonly four kinds, or five kinds, mixed with the ratio for being each greater than 0 percent；
Wherein solvent is：Any of cyclohexanone, methyl iso-butyl ketone (MIBK), dimethylbenzene, n-butanol, or wherein any two, or its
In wantonly three kinds, or four kinds, mixed with the ratio for being each greater than 0 percent；
Coating B amine curing agent is：Any of polyamide curing agent, phenolic aldehyde amine amine hardener, fatty amine curing agent, or
Any two, or three kinds be each greater than 0 percent ratio mix；
Coating B solvent is：Any of cyclohexanone, methyl iso-butyl ketone (MIBK), dimethylbenzene, n-butanol, or wherein any two, or
It is wherein wantonly three kinds, or four kinds, mixed with the ratio for being each greater than 0 percent.
2. according to claim 1 on low prepared surface grade steel construction application graphene anticorrosive paint, its feature exists
In：Wherein coating A also includes non-ionic dispersing agent, and its percentage by weight is 0.1~1%.
3. the graphene anticorrosive paint of the application according to claim 1 or claim 2 on low prepared surface grade steel construction, its feature
It is：Wherein coating A also includes adhesion promoter, and adhesion promoter is：Methylsiloxane class, its percentage by weight are
0.3~3%.
4. according to claim 1-3 is any on low prepared surface grade steel construction application graphene anticorrosive paint, its
It is characterised by：Wherein coating A also includes fluorine richness organosiloxane class wetting agent, and its percentage by weight is 0.1~1%.
5. the graphene anticorrosive paint of the application according to claim 1 or claim 2 on low prepared surface grade steel construction, its feature
It is：Wherein coating A also includes levelling agent, and levelling agent is silicone levelling agent, or any of fluorinated levelling agent, or
Two kinds are mixed with the ratio for being each greater than 0 percent；Its percentage by weight is 0.2~1%.
6. according to claim 4 on low prepared surface grade steel construction application graphene anticorrosive paint, its feature exists
In：Wherein coating A also includes levelling agent, and levelling agent is silicone levelling agent, or any of fluorinated levelling agent, or two
Kind is mixed with the ratio for being each greater than 0 percent；Its percentage by weight is 0.2~1%.
7. the graphene anticorrosive paint of the application according to claim 1 or claim 2 on low prepared surface grade steel construction, its feature
It is：The graphene molecules number of plies is any one in 1-10 layers, and the piece footpath of graphene is 3-10um.
8. according to claim 7 on low prepared surface grade steel construction application graphene anticorrosive paint, its feature exists
In：The specific surface area of graphene is any one in 100-300m2/g, and the water content of graphene is less than 1%.
9. the graphene anticorrosive paint of the application according to claim 1 or claim 2 on low prepared surface grade steel construction, its feature
It is：Coating A is packed respectively with coating B, its mixed proportion according to construction it needs to be determined that.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108654950A (en) * | 2018-03-30 | 2018-10-16 | 青岛正为能源科技有限公司 | The Anticorrosion measure of steel construction under saline-alkali environment |
| CN109486342A (en) * | 2018-09-05 | 2019-03-19 | 广西大学 | A kind of anticorrosive paint of D structure graphene reinforced epoxy |
| CN110408309A (en) * | 2019-08-19 | 2019-11-05 | 武汉钢铁有限公司 | Play the inorganic agent and application method of provisional protection to rail |
| WO2020118468A1 (en) * | 2018-12-09 | 2020-06-18 | 张维维 | Novel protective antirust agent for petroleum research instruments |
| CN112266703A (en) * | 2020-11-09 | 2021-01-26 | 三棵树(上海)新材料研究有限公司 | Graphene low-surface-treatment epoxy thick paste coating and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101457116A (en) * | 2007-12-12 | 2009-06-17 | 上海海悦涂料有限公司 | Long acting low surface treatment epoxy coating priming lacquer |
| CN105733405A (en) * | 2016-03-18 | 2016-07-06 | 信和新材料股份有限公司 | Graphene-based enhanced high-solid epoxy anticorrosive coating and method for preparing same |
-
2017
- 2017-10-27 CN CN201711056932.8A patent/CN107603418A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101457116A (en) * | 2007-12-12 | 2009-06-17 | 上海海悦涂料有限公司 | Long acting low surface treatment epoxy coating priming lacquer |
| CN105733405A (en) * | 2016-03-18 | 2016-07-06 | 信和新材料股份有限公司 | Graphene-based enhanced high-solid epoxy anticorrosive coating and method for preparing same |
Non-Patent Citations (4)
| Title |
|---|
| 唐玉林等: "《圣泉铸工手册》", 31 March 2006, 东北大学出版社 * |
| 曾晓鹰等: "《电子束固化涂料及应用》", 30 June 2014, 天津大学出版社 * |
| 李肇强: "《现代涂料的生产与应用》", 28 February 1996, 上海科学技术文献出版社 * |
| 秦国治等: "《防腐技术及应用实例》", 30 April 2002, 化学工业出版社 工业装备与信息工程出版中心 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108654950A (en) * | 2018-03-30 | 2018-10-16 | 青岛正为能源科技有限公司 | The Anticorrosion measure of steel construction under saline-alkali environment |
| CN109486342A (en) * | 2018-09-05 | 2019-03-19 | 广西大学 | A kind of anticorrosive paint of D structure graphene reinforced epoxy |
| WO2020118468A1 (en) * | 2018-12-09 | 2020-06-18 | 张维维 | Novel protective antirust agent for petroleum research instruments |
| CN110408309A (en) * | 2019-08-19 | 2019-11-05 | 武汉钢铁有限公司 | Play the inorganic agent and application method of provisional protection to rail |
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Application publication date: 20180119 |