CN107587384A - It is a kind of to improve colored parchment vividness and effectively prevent the method to fade - Google Patents

It is a kind of to improve colored parchment vividness and effectively prevent the method to fade Download PDF

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Publication number
CN107587384A
CN107587384A CN201710932909.4A CN201710932909A CN107587384A CN 107587384 A CN107587384 A CN 107587384A CN 201710932909 A CN201710932909 A CN 201710932909A CN 107587384 A CN107587384 A CN 107587384A
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China
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addition
parts
mixing
wood pulp
parchment
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CN201710932909.4A
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Chinese (zh)
Inventor
宋夫建
贺永
栗先武
赵敬军
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Zaozhuang Hengyu Paper Co Ltd
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Zaozhuang Hengyu Paper Co Ltd
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Priority to CN201710932909.4A priority Critical patent/CN107587384A/en
Publication of CN107587384A publication Critical patent/CN107587384A/en
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Abstract

The method to fade is prevented the invention discloses a kind of colored parchment vividness of raising and effectively, comprised the following steps:(1)80 120 parts of the mixing wood pulp accomplished fluently is added in mixing pit;(2)Organic pigment after dilution, chitosan, acrylic emulsion, zinc gluconate, poly-aspartic-acid, vitamin A powder, addition are mixed in wood pulp, and be sufficiently mixed with mixing wood pulp;(3)Then quaternary ammonium salt aldehyde-free colour stabilizer, Tea Polyphenols, the pulullan polysaccharide of dilution are added;(4)Upper step gains feeding paper machine is copied into paper, the paper after being copied into first is allowed to parchmentizing through sulfuric acid dipping, then handles, is finally batched as parchment through depickling, washing, neutralization, plasticizing etc..It is bright in colour using the colored parchment for preparing of the present invention, it is not easy to fade, thoroughly solves the problems, such as that domestic parchment color and luster is gloomy, easily faded during use;And preparation method is simple, raw material is easy to get, and is advantageous to industrialized production.

Description

It is a kind of to improve colored parchment vividness and effectively prevent the method to fade
Technical field
It is specifically a kind of to improve colored parchment vividness and effectively prevent what is faded the present invention relates to pulp technology for making paper Method.
Background technology
Parchment, template is also, it is usually that body paper first passes through after being copied into body paper as raw material using chemical wood pulp and rag stock Sulfuric acid dipping is allowed to parchmentizing, then handles, is finally batched as parchment through depickling, washing, neutralization, plasticizing etc..
Color plant parchment belongs to high-grade special paper, is characterized in:Product technology content is high, and added value is high, enters to enter the market The technology barriers of field are high, have a extensive future.At present, domestic manufacturer is few, and produces colored parchment and use always Direct dyes dyes to fiber, starches the salt of interior addition 5%(NaCl)Make wood pulp cellulose obtain darker to adjust.Using this dye The body paper that color method obtains is again through persulfuric acid impregnation processability(I.e. parchmentizing is handled)Afterwards, paper color and luster is gloomy and in use Extremely easily fade, contaminate on contactant.For many years, color is gloomy, this serious two big technology of the phenomenon that faded during use is asked Topic annoyings the development of domestic colored sheepskin paper product, the lifting of limit product class always.Therefore, the present invention provides one kind and carried High color parchment vividness simultaneously effectively prevents the method to fade.
The content of the invention
The method to fade is prevented it is an object of the invention to provide a kind of colored parchment vividness of raising and effectively, with solution The problem of being proposed in certainly above-mentioned background technology.
To achieve the above object, the present invention provides following technical scheme:
It is a kind of to improve colored parchment vividness and effectively prevent the method to fade, comprise the following steps:
(1)The mixing wood pulp 80-120 parts accomplished fluently are added in mixing pit, the beating degree of the mixing wood pulp is 33-36 ° of SR, dense Spend for 4-6%, alpha-cellulose content 95-98%;
(2)By the organic pigment after dilution, chitosan, acrylic emulsion, zinc gluconate, poly-aspartic-acid, vitamin A Powder, add in mixing wood pulp, and 1-3h, mixing speed 300-500r/min are sufficiently mixed with mixing wood pulp;The organic pigment Addition be 0.1-1 parts;Organic pigment uses the stainless steel dissolving tank with stirring to be diluted with water 40-50 times and used;Shell gathers The addition of sugar is 1-2 parts, and the addition of acrylic emulsion is 2-3 parts, and the addition of zinc gluconate is 3-5 parts, poly- Tianmen The addition of winter propylhomoserin is 2-4 parts, and the addition of vitamin A powder is 0.1-1 parts;
(3)Then quaternary ammonium salt aldehyde-free colour stabilizer, Tea Polyphenols, the pulullan polysaccharide of dilution are added, is sufficiently stirred 1-2h, mixing is equal It is even, mixing speed 250-300r/min;The addition of the quaternary ammonium salt aldehyde-free colour stabilizer is 2-5 parts;The addition of Tea Polyphenols is 1-3 parts;The addition of pulullan polysaccharide is 1-5 parts;Make after being diluted with water 30-40 times using the stainless steel dissolving tank with stirring With;
(4)Upper step gains feeding paper machine is copied into paper, the paper after being copied into first is allowed to parchmentizing through sulfuric acid dipping, then Handle, finally batched as parchment through depickling, washing, neutralization, plasticizing etc..
As the further scheme of the present invention:The mixing wood pulp is using 30-50% Korean pine wood Time of Fluff Slurry, 40-60% The hardwood pulp of bamboo pulp, 30-40%.
As the further scheme of the present invention:The organic pigment uses triaryl methane pigment, AZOpigments or phthalein mountain valley with clumps of trees and bamboo face Material.
As the further scheme of the present invention:The quaternary ammonium salt aldehyde-free colour stabilizer is using the Eccofix for liking Ball Corp. FD-3。
As the further scheme of the present invention:Step(1)100 parts of the mixing wood pulp accomplished fluently is added in mixing pit, it is described The beating degree of mixing wood pulp is 34 ° of SR, concentration 5%, alpha-cellulose content 97%.
As the further scheme of the present invention:Step(2)By the organic pigment after dilution, chitosan, acrylic emulsion, Portugal In grape saccharic acid zinc, poly-aspartic-acid, vitamin A powder, addition mixing wood pulp, and 2h, stirring speed are sufficiently mixed with mixing wood pulp Spend 400r/min;The addition of the organic pigment is 0.5 part;Organic pigment uses the stainless steel dissolving tank with stirring to add water 45 times of uses of dilution;The addition of chitosan is 1.6 parts, and the addition of acrylic emulsion is 2.6 parts, the addition of zinc gluconate Measure as 4 parts, the addition of poly-aspartic-acid is 3 parts, and the addition of vitamin A powder is 0.5 part;
As the further scheme of the present invention:Step(3)Then quaternary ammonium salt aldehyde-free colour stabilizer, Tea Polyphenols, the Pu Lu of dilution are added Blue polysaccharide, is sufficiently stirred 1.6h, is well mixed, mixing speed 270r/min;The addition of the quaternary ammonium salt aldehyde-free colour stabilizer is 4 Part;The addition of Tea Polyphenols is 2 parts;The addition of pulullan polysaccharide is 3 parts;Water is added using the stainless steel dissolving tank with stirring Used after 35 times of dilution.
Compared with prior art, the beneficial effects of the invention are as follows:
It is bright in colour using the colored parchment for preparing of the present invention, be not easy to fade, thoroughly solve domestic parchment color and luster it is gloomy, The problem of easily being faded during use, be advantageous to marketing;And preparation method is simple, raw material is easy to get, and is advantageous to industrialize Production.
Embodiment
The technical scheme of this patent is described in more detail with reference to embodiment.
Embodiment 1
It is a kind of to improve colored parchment vividness and effectively prevent the method to fade, comprise the following steps:(1)Add in mixing pit Enter 80 parts of the mixing wood pulp accomplished fluently, the beating degree of the mixing wood pulp is 33 ° of SR, concentration 4%, alpha-cellulose content 95%;(2) Organic pigment after dilution, chitosan, acrylic emulsion, zinc gluconate, poly-aspartic-acid, vitamin A powder, addition is mixed Close in wood pulp, and 1h, mixing speed 300r/min are sufficiently mixed with mixing wood pulp;The addition of the organic pigment is 0.1 part; Organic pigment uses the stainless steel dissolving tank with stirring to be diluted with water 40 times of uses;The addition of chitosan is 1 part, acrylic acid The addition of emulsion is 2 parts, and the addition of zinc gluconate is 3 parts, and the addition of poly-aspartic-acid is 2 parts, vitamin A powder Addition be 0.1 part;(3)Then quaternary ammonium salt aldehyde-free colour stabilizer, Tea Polyphenols, the pulullan polysaccharide of dilution are added, is sufficiently stirred 1h, it is well mixed, mixing speed 250r/min;The addition of the quaternary ammonium salt aldehyde-free colour stabilizer is 2 parts;The addition of Tea Polyphenols For 1 part;The addition of pulullan polysaccharide is 1 part;Used after being diluted with water 30 times using the stainless steel dissolving tank with stirring; (4)Upper step gains feeding paper machine is copied into paper, the paper after being copied into first is allowed to parchmentizing through sulfuric acid dipping, then through de- The processing such as acid, washing, neutralization, plasticizing, are finally batched as parchment.It is described mixing wood pulp using 30% Korean pine wood Time of Fluff Slurry, 40% bamboo pulp, 30% hardwood pulp.The organic pigment uses triaryl methane pigment.The quaternary ammonium salt aldehyde-free colour stabilizer uses Like the Eccofix FD-3 of Ball Corp..
Embodiment 2
It is a kind of to improve colored parchment vividness and effectively prevent the method to fade, comprise the following steps:(1)Add in mixing pit Enter 120 parts of the mixing wood pulp accomplished fluently, the beating degree of the mixing wood pulp is 36 ° of SR, concentration 6%, alpha-cellulose content 98%; (2)By the organic pigment after dilution, chitosan, acrylic emulsion, zinc gluconate, poly-aspartic-acid, vitamin A powder, plus Enter to mix in wood pulp, and 3h, mixing speed 500r/min are sufficiently mixed with mixing wood pulp;The addition of the organic pigment is 1 Part;Organic pigment uses the stainless steel dissolving tank with stirring to be diluted with water 50 times of uses;The addition of chitosan be 2 parts, third The addition of olefin(e) acid emulsion is 3 parts, and the addition of zinc gluconate is 5 parts, and the addition of poly-aspartic-acid is 4 parts, dimension life The addition of plain A powder is 1 part;(3)Then quaternary ammonium salt aldehyde-free colour stabilizer, Tea Polyphenols, the pulullan polysaccharide of dilution are added, is fully stirred 2h is mixed, is well mixed, mixing speed 300r/min;The addition of the quaternary ammonium salt aldehyde-free colour stabilizer is 5 parts;The addition of Tea Polyphenols Measure as 3 parts;The addition of pulullan polysaccharide is 5 parts;Used after being diluted with water 40 times using the stainless steel dissolving tank with stirring; (4)Upper step gains feeding paper machine is copied into paper, the paper after being copied into first is allowed to parchmentizing through sulfuric acid dipping, then through de- The processing such as acid, washing, neutralization, plasticizing, are finally batched as parchment.It is described mixing wood pulp using 50% Korean pine wood Time of Fluff Slurry, 60% bamboo pulp, 40% hardwood pulp.The organic pigment uses AZOpigments.The quaternary ammonium salt aldehyde-free colour stabilizer is rich using love The Eccofix FD-3 of your company.
Embodiment 3
It is a kind of to improve colored parchment vividness and effectively prevent the method to fade, comprise the following steps:(1)Add in mixing pit Enter 100 parts of the mixing wood pulp accomplished fluently, the beating degree of the mixing wood pulp is 34 ° of SR, concentration 5%, alpha-cellulose content 97%. (2)By the organic pigment after dilution, chitosan, acrylic emulsion, zinc gluconate, poly-aspartic-acid, vitamin A powder, plus Enter to mix in wood pulp, and 2h, mixing speed 400r/min are sufficiently mixed with mixing wood pulp;The addition of the organic pigment is 0.5 part;Organic pigment uses the stainless steel dissolving tank with stirring to be diluted with water 45 times of uses;The addition of chitosan is 1.6 Part, the addition of acrylic emulsion is 2.6 parts, and the addition of zinc gluconate is 4 parts, and the addition of poly-aspartic-acid is 3 Part, the addition of vitamin A powder is 0.5 part;(3)Then quaternary ammonium salt aldehyde-free colour stabilizer, Tea Polyphenols, the Propiram for adding dilution are more Sugar, 1.6h is sufficiently stirred, be well mixed, mixing speed 270r/min;The addition of the quaternary ammonium salt aldehyde-free colour stabilizer is 4 parts; The addition of Tea Polyphenols is 2 parts;The addition of pulullan polysaccharide is 3 parts;Add water dilute using the stainless steel dissolving tank with stirring Used after releasing 35 times.(4)Upper step gains feeding paper machine is copied into paper, the paper after being copied into first is allowed to sheep through sulfuric acid dipping Pi Hua, then handle, finally batched as parchment through depickling, washing, neutralization, plasticizing etc..The mixing wood pulp uses 30- 50% Korean pine wood Time of Fluff Slurry, 40-60% bamboo pulp, 30-40% hardwood pulp.The organic pigment uses phthalein mountain valley with clumps of trees and bamboo pigment.It is described Quaternary ammonium salt aldehyde-free colour stabilizer is using the Eccofix FD-3 for liking Ball Corp..
Experimental example
The parchment of production is bright in luster, the like product with domestic production(Direct dyeing method)It is real to carry out boiling contrast Test, experimental result is as follows.Boiling experiment is to examine a kind of method whether to be faded during paper use, is specially:Weigh 5 grams Over dry pattern, the 2-3cm scraps of paper are torn into, are put into small beaker, added 100ml distilled water, surface plate is stamped above, in electric furnace Or heated in water-bath, keep micro-boiling 15 minutes, pull the scraps of paper out after cooling, observe the color in water.
Experimental result:Parchment prepared by embodiment 3 does not fade, bright in colour;And direct dyeing method is used to prepare Parchment fade seriously, color and luster is gloomy.
From experimental result as can be seen that the present invention thoroughly solves, domestic parchment color and luster is gloomy, during use easily The problem of fading.
The colored parchment prepared using the present invention is bright in colour, is not easy to fade, thoroughly solves domestic parchment color and luster The problem of easily being faded during gloomy, use, is advantageous to marketing;And preparation method is simple, raw material is easy to get, and is advantageous to work Industry metaplasia is produced.
The better embodiment of this patent is explained in detail above, but this patent is not limited to above-mentioned embodiment party Formula, can also be on the premise of this patent objective not be departed from one skilled in the relevant art's possessed knowledge Make a variety of changes.

Claims (7)

1. a kind of improve colored parchment vividness and effectively prevent the method to fade, it is characterised in that comprises the following steps:
(1)The mixing wood pulp 80-120 parts accomplished fluently are added in mixing pit, the beating degree of the mixing wood pulp is 33-36 ° of SR, dense Spend for 4-6%, alpha-cellulose content 95-98%;
(2)By the organic pigment after dilution, chitosan, acrylic emulsion, zinc gluconate, poly-aspartic-acid, vitamin A Powder, add in mixing wood pulp, and 1-3h, mixing speed 300-500r/min are sufficiently mixed with mixing wood pulp;The organic pigment Addition be 0.1-1 parts;Organic pigment uses the stainless steel dissolving tank with stirring to be diluted with water 40-50 times and used;Shell gathers The addition of sugar is 1-2 parts, and the addition of acrylic emulsion is 2-3 parts, and the addition of zinc gluconate is 3-5 parts, poly- Tianmen The addition of winter propylhomoserin is 2-4 parts, and the addition of vitamin A powder is 0.1-1 parts;
(3)Then quaternary ammonium salt aldehyde-free colour stabilizer, Tea Polyphenols, the pulullan polysaccharide of dilution are added, is sufficiently stirred 1-2h, mixing is equal It is even, mixing speed 250-300r/min;The addition of the quaternary ammonium salt aldehyde-free colour stabilizer is 2-5 parts;The addition of Tea Polyphenols is 1-3 parts;The addition of pulullan polysaccharide is 1-5 parts;Make after being diluted with water 30-40 times using the stainless steel dissolving tank with stirring With;
(4)Upper step gains feeding paper machine is copied into paper, the paper after being copied into first is allowed to parchmentizing through sulfuric acid dipping, then Handle, finally batched as parchment through depickling, washing, neutralization, plasticizing etc..
2. according to claim 1 improve colored parchment vividness and effectively prevent the method to fade, it is characterised in that The mixing wood pulp uses 30-50% Korean pine wood Time of Fluff Slurry, 40-60% bamboo pulp, 30-40% hardwood pulp.
3. according to claim 1 improve colored parchment vividness and effectively prevent the method to fade, it is characterised in that The organic pigment uses triaryl methane pigment, AZOpigments or phthalein mountain valley with clumps of trees and bamboo pigment.
4. according to claim 1 improve colored parchment vividness and effectively prevent the method to fade, it is characterised in that The quaternary ammonium salt aldehyde-free colour stabilizer is using the Eccofix FD-3 for liking Ball Corp..
5. according to claim 1 improve colored parchment vividness and effectively prevent the method to fade, it is characterised in that Step(1)100 parts of the mixing wood pulp accomplished fluently is added in mixing pit, the beating degree of the mixing wood pulp is 34 ° of SR, and concentration is 5%, alpha-cellulose content 97%.
6. according to claim 1 improve colored parchment vividness and effectively prevent the method to fade, it is characterised in that Step(2)By the organic pigment after dilution, chitosan, acrylic emulsion, zinc gluconate, poly-aspartic-acid, vitamin A Powder, add in mixing wood pulp, and 2h, mixing speed 400r/min are sufficiently mixed with mixing wood pulp;The addition of the organic pigment Measure as 0.5 part;Organic pigment uses the stainless steel dissolving tank with stirring to be diluted with water 45 times of uses;The addition of chitosan is 1.6 parts, the addition of acrylic emulsion is 2.6 parts, and the addition of zinc gluconate is 4 parts, the addition of poly-aspartic-acid For 3 parts, the addition of vitamin A powder is 0.5 part.
7. according to claim 1 improve colored parchment vividness and effectively prevent the method to fade, it is characterised in that Step(3)Then quaternary ammonium salt aldehyde-free colour stabilizer, Tea Polyphenols, the pulullan polysaccharide of dilution are added, is sufficiently stirred 1.6h, mixing is equal It is even, mixing speed 270r/min;The addition of the quaternary ammonium salt aldehyde-free colour stabilizer is 4 parts;The addition of Tea Polyphenols is 2 parts;It is general The addition of Shandong orchid polysaccharide is 3 parts;Used after being diluted with water 35 times using the stainless steel dissolving tank with stirring.
CN201710932909.4A 2017-10-10 2017-10-10 It is a kind of to improve colored parchment vividness and effectively prevent the method to fade Pending CN107587384A (en)

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CN201710932909.4A CN107587384A (en) 2017-10-10 2017-10-10 It is a kind of to improve colored parchment vividness and effectively prevent the method to fade

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102852038A (en) * 2012-09-24 2013-01-02 济南晨光纸业有限公司 Method for improving vividness of colorized parchment and effectively preventing fading
CN103061181A (en) * 2012-12-31 2013-04-24 黄河三角洲京博化工研究院有限公司 Complex enzyme preparation and technique for preparing dissolving pulp by using same
CN103556541A (en) * 2013-10-18 2014-02-05 湖南中烟工业有限责任公司 Cigarette paper with variable diffusion rate and pore structure and application thereof
CN103850149A (en) * 2012-11-30 2014-06-11 周青标 Dermal-fiber regenerated leather and preparation method thereof
CN106012684A (en) * 2016-05-20 2016-10-12 苏州倍力特物流设备有限公司 Pricking-resistant mildew-proof corrugated paper material and method for preparing same
CN106758539A (en) * 2016-11-14 2017-05-31 蚌埠市风驰滤清器有限公司 A kind of cold-resistant filter paper of filter

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102852038A (en) * 2012-09-24 2013-01-02 济南晨光纸业有限公司 Method for improving vividness of colorized parchment and effectively preventing fading
CN103850149A (en) * 2012-11-30 2014-06-11 周青标 Dermal-fiber regenerated leather and preparation method thereof
CN103061181A (en) * 2012-12-31 2013-04-24 黄河三角洲京博化工研究院有限公司 Complex enzyme preparation and technique for preparing dissolving pulp by using same
CN103556541A (en) * 2013-10-18 2014-02-05 湖南中烟工业有限责任公司 Cigarette paper with variable diffusion rate and pore structure and application thereof
CN106012684A (en) * 2016-05-20 2016-10-12 苏州倍力特物流设备有限公司 Pricking-resistant mildew-proof corrugated paper material and method for preparing same
CN106758539A (en) * 2016-11-14 2017-05-31 蚌埠市风驰滤清器有限公司 A kind of cold-resistant filter paper of filter

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