CN107586441B - Wine lees-based composite material and process for preparing 3D printing wire by using same - Google Patents
Wine lees-based composite material and process for preparing 3D printing wire by using same Download PDFInfo
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- CN107586441B CN107586441B CN201710971325.8A CN201710971325A CN107586441B CN 107586441 B CN107586441 B CN 107586441B CN 201710971325 A CN201710971325 A CN 201710971325A CN 107586441 B CN107586441 B CN 107586441B
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- 239000002131 composite material Substances 0.000 title claims abstract description 120
- 238000010146 3D printing Methods 0.000 title claims abstract description 33
- 238000004519 manufacturing process Methods 0.000 title claims description 12
- 239000000463 material Substances 0.000 claims abstract description 45
- 239000000843 powder Substances 0.000 claims abstract description 41
- 239000002994 raw material Substances 0.000 claims abstract description 34
- 238000002360 preparation method Methods 0.000 claims abstract description 18
- 239000000654 additive Substances 0.000 claims abstract description 15
- 230000000996 additive effect Effects 0.000 claims abstract description 13
- 238000000034 method Methods 0.000 claims abstract description 5
- 239000004626 polylactic acid Substances 0.000 claims description 43
- 229920000747 poly(lactic acid) Polymers 0.000 claims description 42
- 238000002156 mixing Methods 0.000 claims description 34
- 238000001035 drying Methods 0.000 claims description 33
- 150000001875 compounds Chemical class 0.000 claims description 30
- 239000002699 waste material Substances 0.000 claims description 27
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- 239000005014 poly(hydroxyalkanoate) Substances 0.000 claims description 18
- 229920000903 polyhydroxyalkanoate Polymers 0.000 claims description 17
- 238000004140 cleaning Methods 0.000 claims description 15
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- 229920001896 polybutyrate Polymers 0.000 claims description 14
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- 230000003078 antioxidant effect Effects 0.000 claims description 13
- 239000000314 lubricant Substances 0.000 claims description 12
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- -1 polybutylene terephthalate adipate Polymers 0.000 claims description 11
- 239000004632 polycaprolactone Substances 0.000 claims description 10
- 229920001610 polycaprolactone Polymers 0.000 claims description 10
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 9
- 240000007594 Oryza sativa Species 0.000 claims description 7
- 235000007164 Oryza sativa Nutrition 0.000 claims description 7
- 229920002521 macromolecule Polymers 0.000 claims description 7
- 238000005469 granulation Methods 0.000 claims description 5
- 230000003179 granulation Effects 0.000 claims description 5
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 claims description 4
- 239000004433 Thermoplastic polyurethane Substances 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
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- 238000000855 fermentation Methods 0.000 claims description 4
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- 239000004593 Epoxy Substances 0.000 claims description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical class CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 3
- 239000012188 paraffin wax Substances 0.000 claims description 3
- 229920002961 polybutylene succinate Polymers 0.000 claims description 3
- 239000004631 polybutylene succinate Substances 0.000 claims description 3
- 229920000098 polyolefin Polymers 0.000 claims description 3
- SPSPIUSUWPLVKD-UHFFFAOYSA-N 2,3-dibutyl-6-methylphenol Chemical compound CCCCC1=CC=C(C)C(O)=C1CCCC SPSPIUSUWPLVKD-UHFFFAOYSA-N 0.000 claims description 2
- IMSODMZESSGVBE-UHFFFAOYSA-N 2-Oxazoline Chemical compound C1CN=CO1 IMSODMZESSGVBE-UHFFFAOYSA-N 0.000 claims description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 2
- BGNXCDMCOKJUMV-UHFFFAOYSA-N Tert-Butylhydroquinone Chemical compound CC(C)(C)C1=CC(O)=CC=C1O BGNXCDMCOKJUMV-UHFFFAOYSA-N 0.000 claims description 2
- 150000008064 anhydrides Chemical class 0.000 claims description 2
- CZBZUDVBLSSABA-UHFFFAOYSA-N butylated hydroxyanisole Chemical compound COC1=CC=C(O)C(C(C)(C)C)=C1.COC1=CC=C(O)C=C1C(C)(C)C CZBZUDVBLSSABA-UHFFFAOYSA-N 0.000 claims description 2
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- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
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- 239000012948 isocyanate Substances 0.000 claims description 2
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- 239000004250 tert-Butylhydroquinone Substances 0.000 claims description 2
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- 229910019142 PO4 Inorganic materials 0.000 claims 1
- 150000001735 carboxylic acids Chemical class 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- 239000010452 phosphate Substances 0.000 claims 1
- 238000012545 processing Methods 0.000 abstract description 27
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- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 18
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- 229920001903 high density polyethylene Polymers 0.000 description 8
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- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 3
- 238000006065 biodegradation reaction Methods 0.000 description 3
- 230000003013 cytotoxicity Effects 0.000 description 3
- 231100000135 cytotoxicity Toxicity 0.000 description 3
- ZJIPHXXDPROMEF-UHFFFAOYSA-N dihydroxyphosphanyl dihydrogen phosphite Chemical class OP(O)OP(O)O ZJIPHXXDPROMEF-UHFFFAOYSA-N 0.000 description 3
- 238000000338 in vitro Methods 0.000 description 3
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- 239000002689 soil Substances 0.000 description 3
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- 239000002023 wood Substances 0.000 description 3
- QZCLKYGREBVARF-UHFFFAOYSA-N Acetyl tributyl citrate Chemical compound CCCCOC(=O)CC(C(=O)OCCCC)(OC(C)=O)CC(=O)OCCCC QZCLKYGREBVARF-UHFFFAOYSA-N 0.000 description 2
- 241000282414 Homo sapiens Species 0.000 description 2
- 239000004594 Masterbatch (MB) Substances 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- 238000003556 assay Methods 0.000 description 2
- RYYVLZVUVIJVGH-UHFFFAOYSA-N caffeine Chemical compound CN1C(=O)N(C)C(=O)C2=C1N=CN2C RYYVLZVUVIJVGH-UHFFFAOYSA-N 0.000 description 2
- 230000004663 cell proliferation Effects 0.000 description 2
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- 235000013312 flour Nutrition 0.000 description 2
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
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- 235000015097 nutrients Nutrition 0.000 description 2
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- 239000000243 solution Substances 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- 238000010792 warming Methods 0.000 description 2
- 244000301850 Cupressus sempervirens Species 0.000 description 1
- LPHGQDQBBGAPDZ-UHFFFAOYSA-N Isocaffeine Natural products CN1C(=O)N(C)C(=O)C2=C1N(C)C=N2 LPHGQDQBBGAPDZ-UHFFFAOYSA-N 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 1
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- 229960000892 attapulgite Drugs 0.000 description 1
- 229960001948 caffeine Drugs 0.000 description 1
- VJEONQKOZGKCAK-UHFFFAOYSA-N caffeine Natural products CN1C(=O)N(C)C(=O)C2=C1C=CN2C VJEONQKOZGKCAK-UHFFFAOYSA-N 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
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- 238000011161 development Methods 0.000 description 1
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- 210000002950 fibroblast Anatomy 0.000 description 1
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- 229920001912 maleic anhydride grafted polyethylene Polymers 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 238000000643 oven drying Methods 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical class OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000011846 petroleum-based material Substances 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920002215 polytrimethylene terephthalate Polymers 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
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Images
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Biological Depolymerization Polymers (AREA)
Abstract
Description
Sample (I) | Tensile Strength (MPa) | Weight loss after 90 days in soil (%) |
PHA | 20.1 | 2.3 |
Compound material 1 (20%) | 21.7 | 3.1 |
Compound material 2 (40%) | 22.5 | 6.8 |
Compound material 3 (60%) | 20.3 | 24.3 |
PBAT | 18.6 | 2.2 |
Compound material 1' (20%) | 21.5 | 2.9 |
Compound material 2' (40%) | 20.8 | 5.7 |
Composite material 3' (60%) | 18.2 | 20.6 |
Sample (I) | Tensile Strength (MPa) | Relative cell proliferation Rate (%) |
ABS | 38.4 | 78.9 |
Compound material 4 (20%) | 42.2 | 126.9 |
Compound material 5 (40%) | 42.6 | 177.6 |
Compound material 6 (60%) | 38.5 | 242.8 |
Sample (I) | Tensile Strength (MPa) | Impact strength (J/m) |
PLA/PHA(8:2) | 36.2 | 47.8 |
Compound material 11 (20%) | 47.9 | 202.5 |
Compound material 12 (40%) | 48.5 | 208.1 |
Compound material 13 (60%) | 44.3 | 212.4 |
Sample (I) | Impact strength (J/m) | Elongation at Break (%) |
PLA | 20.4 | 3.9 |
Compound material 14 (20%) | 376.9 | 280.6 |
Compound material 15 (40%) | 342.1 | 225.7 |
Compound material 16 (60%) | 294.8 | 190.5 |
Sample (I) | Tensile Strength (MPa) | Degree of crystallinity (%) | Relative cell proliferation Rate (%) |
HDPE | 28.5 | 76.4 | 113.4 |
Compound material 17 (20%) | 32.8 | 79.6 | 198.3 |
Compound material 18 (40%) | 29.3 | 81.2 | 267.9 |
Compound material 19 (60%) | 26.1 | 80.5 | 313.5 |
Sample (I) | Tensile Strength (MPa) | Degree of crystallinity (%) |
PET | 32.1 | 12.7 |
Compound material 20 (15%) | 34.3 | 34.1 |
Compound material 21 (35%) | 33.5 | 37.8 |
Compound material 22 (55%) | 32.2 | 38.4 |
Claims (2)
Priority Applications (1)
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CN201710971325.8A CN107586441B (en) | 2017-10-18 | 2017-10-18 | Wine lees-based composite material and process for preparing 3D printing wire by using same |
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CN201710971325.8A CN107586441B (en) | 2017-10-18 | 2017-10-18 | Wine lees-based composite material and process for preparing 3D printing wire by using same |
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CN107586441A CN107586441A (en) | 2018-01-16 |
CN107586441B true CN107586441B (en) | 2021-02-26 |
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Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
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CN109129970A (en) * | 2018-07-09 | 2019-01-04 | 福建师范大学 | One kind wire rod of 3D printing containing algae-residue and preparation method thereof |
CN109575540A (en) * | 2018-11-30 | 2019-04-05 | 深圳市裕同包装科技股份有限公司 | A kind of vinasse polylactic acid biodegradable composites, preparation method and application |
IT201900022884A1 (en) * | 2019-12-03 | 2020-03-03 | Univ Degli Studi Di Modena E Reggio Emilia | Composite material consisting of a biofiller and a thermoplastic matrix and process for making an article with such a composite material |
US20220380592A1 (en) * | 2021-06-01 | 2022-12-01 | Xerox Corporation | Polymer filaments for additive manufacturing having reduced emissions |
CN113831704A (en) * | 2021-08-10 | 2021-12-24 | 珠海市三绿实业有限公司 | Biodegradable PHA composite material for 3D printer consumable and preparation method thereof |
CN113861710B (en) * | 2021-09-01 | 2023-06-02 | 四川轻化工大学 | Antibacterial raw material powder, antibacterial wood-plastic composite material and preparation method thereof |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102746681A (en) * | 2012-05-17 | 2012-10-24 | 北京化工大学 | Wood-plastic material with distiller's grain as reinforcing phase, and manufacturing method thereof |
CN106317809A (en) * | 2015-07-03 | 2017-01-11 | 南京理工大学 | Bio-based degradable flame-retardant polylactic acid engineering material and preparation method thereof |
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CN101712805B (en) * | 2009-11-06 | 2011-06-08 | 北京化工大学 | Method for preparing degradable mulch by reusing organic waste residues of biomass |
KR20120116127A (en) * | 2011-04-12 | 2012-10-22 | 송승원 | Manufacture method of sikhye makgeolli and sikhye makgeolli |
CN103044702A (en) * | 2011-10-11 | 2013-04-17 | 成都泰宜鑫建材有限公司 | Method of producing foaming plastic from plant materials |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN102746681A (en) * | 2012-05-17 | 2012-10-24 | 北京化工大学 | Wood-plastic material with distiller's grain as reinforcing phase, and manufacturing method thereof |
CN106317809A (en) * | 2015-07-03 | 2017-01-11 | 南京理工大学 | Bio-based degradable flame-retardant polylactic acid engineering material and preparation method thereof |
Non-Patent Citations (1)
Title |
---|
"酒糟增强聚丙烯复合材料的制备与性能研究";戚方伟等;《中国塑料》;20140126;第28卷(第1期);第43-48页 * |
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Effective date of registration: 20230302 Address after: No. 430 Xingneng Road, East Industrial Zone, Xindu District, Chengdu, Sichuan 610000 Patentee after: Sichuan Bozhiduo Technology Co.,Ltd. Patentee after: Sichuan zhixiangyi Technology Co.,Ltd. Patentee after: Zigong Zhisheng Core Technology Co.,Ltd. Address before: Gw1101, 11 / F, building 9-2, 75 cuijiadian Road, Chenghua District, Chengdu, Sichuan 610000 Patentee before: Sichuan zhixiangyi Technology Co.,Ltd. Patentee before: Zigong Zhisheng Core Technology Co.,Ltd. |