CN107583313A - A kind of defoamer preparation method needed for porcelain idiosome sintering process - Google Patents
A kind of defoamer preparation method needed for porcelain idiosome sintering process Download PDFInfo
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Abstract
A kind of defoamer preparation method needed for porcelain idiosome sintering process, metal corrosion inhibitor, water are pressed 2：10 ratio is mixed and heated to 60 DEG C and stirred, it is cooled to normal temperature, again with mixture, supernatant liquor high temperature is added in high-pressure reactor, 30min is dehydrated under 120 140 DEG C of decompressions, period with nitrogen displacement for several times, then expoxy propane induced reaction is put into, inducing temperature is 140 DEG C, pressure≤0.3MPa, question response pressure substantially reduces, when temperature steeply rises, show that catalyst has activated, temperature control is at 140 160 DEG C, control reactor pressure≤0.3MPa, treat that pressure no longer reduces in kettle, continue insulation reaction 30min, the unreacted monomer of removed under reduced pressure, obtain defoamer.The metal corrosion inhibitor and dispersant contained in defoamer, the liquid with condensation effect is prepared, after high-temperature evaporation, be scattered in idiosome surface, cool down idiosome, cooling reduces blibbing.
Description
Technical field：
The present invention relates to ceramic field, and in particular to defoamer preparation side used in a kind of porcelain idiosome sintering process
Method.
Background technology：
Ceramics are the general names of pottery and porcelain.Chinese just send out early in about B.C. 8000-2000 (Neolithic Age)
Understand pottery.Ceramic material is oxide, nitride, boride and carbide etc. mostly.Common ceramic material has clay, oxygen
Change aluminium, kaolin etc..The general hardness of ceramic material is higher, but plasticity is poor.Except feeder, decoration use on, in section
Learn, also played an important role in the development of technology.Ceramic raw material is that the original ample resources clay of the earth forms by quenching to take.And
The property tool toughness of clay, normal temperature chance water is plastic, and micro- do can carve, absolutely dry to grind；Water can be filled into pottery by burning to 700 degree；Burn extremely
1230 degree of then porcelain, can not absorb water and corrosion-and high-temp-resistant completely.The elasticity of its usage, still have in culture today science and technology various
The application of intention.
Firing refers to by high-temperature process, makes base substrate that a series of physical chemical change, mineral composition expected from formation occur
And microstructure, so as to reach fixed profile and obtain required by effect process.It is the 3rd important procedure of ceramic process.
Sintering is that powdered compact is heated to be incubated below the melting temperature less than its basic constituent element, is then cooled to the heat of room temperature
Handling process.
The content of the invention：
The technical problems to be solved by the invention are the defects of part takes prior art, there is provided a kind of porcelain idiosome is sintered
Defoamer preparation method used in journey.
The technical problems to be solved by the invention are realized using following technical scheme.
Defoamer preparation method used in a kind of porcelain idiosome sintering process, it is characterised in that：Press down including metal erosion
Preparation 10-50 parts, deionized water 100-150 parts, diethylene glycol 1-5 parts, dispersant 2-5 parts, polyethylene glycol 10-20 parts, originally
Water 40-50 parts, sweet potato stem leaf 10-15 parts, deionized water 10-50 parts, forage 20-25 parts, pluck 10-13 parts, modification have
Machine silicon defoaming agent emulsion 6-9 parts, block polyether 1-3 parts, quaternary ammonium salt 2-10 parts, hydrophobic silica 1-5 parts, fluorine-containing poly- silica
Alkane 3-5 parts, expoxy propane 1-2 parts.
Further technology：Described defoaming liquid includes 10 parts of metal corrosion inhibitor, 100 parts of deionized water, diethylene glycol 1
Part, 2 parts of dispersant, 10 parts of polyethylene glycol, 40 parts of running water, 10 parts of sweet potato stem leaf, 10 parts of deionized water, 20 parts of forage, animal
It is 10 parts of internal organ, 6 parts of agent emulsion of modified organic silicon defoaming, 1 part of block polyether, 2 parts of quaternary ammonium salt, 1 part of hydrophobic silica, fluorine-containing poly-
3 parts of siloxanes, 1 part of expoxy propane.
Further technology：Described defoaming liquid includes 50 parts of metal corrosion inhibitor, 150 parts of deionized water, diethylene glycol 5
Part, 5 parts of dispersant, 20 parts of polyethylene glycol, 50 parts of running water, 15 parts of sweet potato stem leaf, 50 parts of deionized water, 25 parts of forage, animal
It is 13 parts of internal organ, 9 parts of agent emulsion of modified organic silicon defoaming, 3 parts of block polyether, 10 parts of quaternary ammonium salt, 5 parts of hydrophobic silica, fluorine-containing
5 parts of polysiloxanes, 2 parts of expoxy propane.
Further technology：Described defoamer preparation method comprises the following steps, and in the tank of running water is filled, uses
Oxygen increasing pump carries out oxygenation to tank, then adds sweet potato stem leaf into tank every 24h, heats and is transferred to and fills deionization
In the fermentation tank of water, under the conditions of temperature is 30~35 DEG C, forage is added, 36~48h of sealed fermenting, is filtered, removes filter residue, is received
Collect filtrate；
Fluorinated polysiloxane is scattered in higher alcohols, is stirred 1~2 hour at 10~30 DEG C, then adds filtrate,
Stirring reaction 1~5 hour, obtains mixture at 100~150 DEG C after cooling；
Pluck is taken, internal organ are washed with deionized 3~5 times, then internal organ are placed in lucifuge ventilation and dried in the shade 2~4h,
Then be transferred in animal tissue's pulverizer, be ground into internal organ slurry, then by gained internal organ slurry and mass fraction be 18~
20% hydrochloric acid is 1 in mass ratio：2~1：4 are added in beakers, then beaker is placed in into digital display and tested the speed in constant temperature blender with magnetic force, in
Temperature is 40~45 DEG C, under the conditions of rotating speed is 400~480r/min, constant temperature 3~5h of stirring reaction, centrifuges, discards lower floor
Precipitation, collects to obtain supernatant liquor；
Metal corrosion inhibitor, water are pressed 2：10 ratio is mixed and heated to 60 DEG C and stirred, and is cooled to normal temperature, then with
Mixture, supernatant liquor high temperature are added in high-pressure reactor, are dehydrated 30min under 120-140 DEG C of decompression, are during which used nitrogen displacement
For several times, expoxy propane induced reaction is then put into, inducing temperature is 140 DEG C, pressure≤0.3MPa, and question response pressure substantially drops
It is low, when temperature steeply rises, show that catalyst has activated, temperature control at 140-160 DEG C, control reactor pressure≤
0.3MPa, treat that pressure no longer reduces in kettle, continue insulation reaction 30min, the unreacted monomer of removed under reduced pressure, obtain defoamer.
Further technology：The metal corrosion inhibitor be alcamines, phenol amine, carboxylic acid lipid, one kind of anhydrides or
Two or more mixing.
Further technology：The dispersant is acrylic acid, methacrylic acid, ethylacrylic acid, olefin sulfonic acid, maleic acid
One or both of acid anhydride, ethylene glycol, diethylene glycol, ethylene glycol monomethyl ether, ethylene glycol ethyl ether above monomeric unit are through homopolymerization or altogether
It is poly- to obtain one or both of material above material mixing.
Further technology：Increase anticracking additive in above-mentioned formula, including, p-aminobenzoic acid 25-100 parts, hydrogen-oxygen
Change sodium 4-16 parts, mannitol 2-8 parts, calcium nitrate 3-12 parts, water 50-60 parts, zinc oxide 10-12 parts, antistatic additive 6-9 parts.
Further technology：Described anticracking addictive preparation method is that water, p-aminophenyl first are sequentially added in agitator
Acid, sodium hydroxide, mannitol, stirring are to being completely dissolved；Then calcium nitrate, zinc oxide are added, is stirred standing, mistake after dissolving
Filter, gained filtrate add antistatic additive and are well mixed, gets product.
Further technology：Described part is parts by weight.
Further technology, sintering is kiln furnace used to be provided with support including body of heater, body of heater lower section, and body of heater side is provided with door, body of heater
Than provided with heater strip, some mounting tables are provided with body of heater, mounting table is provided with porcelain groove, and porcelain groove edge is provided with 2 layers of annular groove,
Mounting table is provided with cover body, and cover body is inserted in annular groove, and the outer annular groove cover body in 2 layers of annular groove covers on internal layer annular groove cover
On body, described cover body is provided with air-vent.
Further technology：The cover body of described internal layer annular groove passes through internal layer annular groove, and passes through bottom of furnace body.
Further technology：Described cover body is metal cover body.
Further technology：Described air-vent is provided with 800 mesh nets.
Further technology：Described mounting table is hollow, and mounting table upper surface is provided with hole, and shower nozzle is provided with mounting table,
Shower nozzle is stuck in mounting table, and the hole of shower nozzle corresponds to the hole on mounting table, shower nozzle connecting pipe, and pipeline is lived through bottom of furnace body connection
Plug, piston are built-in with defoaming liquid.
Further technology：The cover body inwall of described outer annular groove is provided with sponge, and for sponge by immersion, soak is increasing
Tough liquid.
Beneficial effect：Idiosome after pugging is placed in porcelain groove, cover upper outlet body, closed the door, heating, heat is out of cover body
Hole and cover body penetrate into itself, cover body internal heat is uniform, while heat-agglomerating, the sponge of cover body inwall, evaporates steam, leads to
Via enters in the cover body of internal layer, under high temperature, vaporization, but the composition of air is remained in, constantly penetrate into idiosome, increase at high temperature
The attachment structure of bonus point, the bulk strength that is becomes big, and while toughness reinforcing, idiosome produces a small amount of bubble due to beating reason,
Now, defoamer is sprayed into by piston, quick defoaming, reduces stomata；
The metal corrosion inhibitor and dispersant contained in defoamer, the liquid with condensation effect is prepared, passes through high temperature
After vaporization, idiosome surface is scattered in, cools down idiosome, cooling reduces blibbing, meanwhile, a kind of protection is formed on surface, it is modified
Organic silicon defoamer emulsion constantly suppresses bubble generation so that idiosome sintering is more perfect.
Brief description of the drawings：
Fig. 1 is the structural representation of the present invention；
Fig. 2 is the double-deck cover body structural representation of the present invention.
Embodiment：
In order that the technical means, the inventive features, the objects and the advantages of the present invention are easy to understand, tie below
Drawings and the specific embodiments are closed, the present invention is expanded on further.
Specific embodiment 1：Defoamer preparation method used in a kind of porcelain idiosome sintering process, including metal erosion suppression
10 parts of preparation, 100 parts of deionized water, 1 part of diethylene glycol, 2 parts of dispersant, 10 parts of polyethylene glycol, 40 parts of running water, sweet potato stem
10 parts of leaf, 10 parts of deionized water, 20 parts of forage, 10 parts of pluck, 6 parts of agent emulsion of modified organic silicon defoaming, block polyether 1
Part, 2 parts of quaternary ammonium salt, 1 part of hydrophobic silica, 3 parts of fluorinated polysiloxane, 1 part of expoxy propane.
Defoamer preparation method comprises the following steps, and in the tank of running water is filled, tank is carried out using oxygen increasing pump
Oxygenation, sweet potato stem leaf is then added into tank every 24h, heat and be transferred in the fermentation tank for filling deionized water, in
Under the conditions of temperature is 30~35 DEG C, forage is added, 36~48h of sealed fermenting, is filtered, removes filter residue, collects filtrate；
Fluorinated polysiloxane is scattered in higher alcohols, is stirred 1~2 hour at 10~30 DEG C, then adds filtrate,
Stirring reaction 1~5 hour, obtains mixture at 100~150 DEG C after cooling；
Pluck is taken, internal organ are washed with deionized 3~5 times, then internal organ are placed in lucifuge ventilation and dried in the shade 2~4h,
Then be transferred in animal tissue's pulverizer, be ground into internal organ slurry, then by gained internal organ slurry and mass fraction be 18~
20% hydrochloric acid is 1 in mass ratio：2~1：4 are added in beakers, then beaker is placed in into digital display and tested the speed in constant temperature blender with magnetic force, in
Temperature is 40~45 DEG C, under the conditions of rotating speed is 400~480r/min, constant temperature 3~5h of stirring reaction, centrifuges, discards lower floor
Precipitation, collects to obtain supernatant liquor；
Metal corrosion inhibitor, water are pressed 2：10 ratio is mixed and heated to 60 DEG C and stirred, and is cooled to normal temperature, then with
Mixture, supernatant liquor high temperature are added in high-pressure reactor, are dehydrated 30min under 120-140 DEG C of decompression, are during which used nitrogen displacement
For several times, expoxy propane induced reaction is then put into, inducing temperature is 140 DEG C, pressure≤0.3MPa, and question response pressure substantially drops
It is low, when temperature steeply rises, show that catalyst has activated, temperature control at 140-160 DEG C, control reactor pressure≤
0.3MPa, treat that pressure no longer reduces in kettle, continue insulation reaction 30min, the unreacted monomer of removed under reduced pressure, obtain defoamer.
Metal corrosion inhibitor is one or more kinds of mixing of alcamines, phenol amine, carboxylic acid lipid, anhydrides.
Dispersant is acrylic acid, methacrylic acid, ethylacrylic acid, olefin sulfonic acid, maleic anhydride, ethylene glycol, diethyl two
One or both of alcohol, ethylene glycol monomethyl ether, ethylene glycol ethyl ether above monomeric unit obtain one in material through homopolymerization or copolymerization
Kind or two or more material mixings.
Increase anticracking additive in above-mentioned formula, including, p-aminobenzoic acid 25-100 parts, sodium hydroxide 4-16 parts,
Mannitol 2-8 parts, calcium nitrate 3-12 parts, water 50-60 parts, zinc oxide 10-12 parts, antistatic additive 6-9 parts.
Anticracking addictive preparation method is that water, p-aminobenzoic acid, sodium hydroxide, sweet dew are sequentially added in agitator
Alcohol, stirring are to being completely dissolved；Then calcium nitrate, zinc oxide are added, is stirred standing, filtering after dissolving, gained filtrate adds
Antistatic additive is well mixed, and is got product.
Part is parts by weight.
As depicted in figs. 1 and 2, sintering is kiln furnace used is provided with support 2 including body of heater 1, body of heater lower section, and body of heater side is provided with door
3, body of heater ratio is provided with heater strip 14, is provided with some mounting tables 4 in body of heater, mounting table is provided with porcelain groove 5, and porcelain groove edge is provided with
2 layers of annular groove 6, mounting table are provided with cover body 7, and cover body is inserted in annular groove, and the outer annular groove cover body in 2 layers of annular groove covers on
On internal layer annular groove cover body, described cover body is provided with air-vent 8.
The cover body of internal layer annular groove passes through internal layer annular groove, and passes through bottom of furnace body.
Cover body is metal cover body.
Air-vent is provided with 800 mesh nets 15.
Mounting table is hollow, and mounting table upper surface is provided with hole 9, is provided with shower nozzle 10 in mounting table, shower nozzle is stuck in mounting table
Interior, the hole of shower nozzle corresponds to the hole on mounting table, shower nozzle connecting pipe 11, and pipeline is through bottom of furnace body connection piston 12, in piston
It is equipped with defoaming liquid.
The cover body inwall of outer annular groove is provided with sponge 13, and for sponge by immersion, soak is toughness reinforcing liquid.
Through overtesting, the china bowl for adding the china bowl and common defoamer and earth kiln sintering of this law defoamer is contrasted：
Data above can be obtained, and the idiosome after pugging is placed in porcelain groove, cover upper outlet body, be closed the door, and heating, heat is from cover
Internal hole and cover body is penetrated into itself, and cover body internal heat is uniform, while heat-agglomerating, the sponge of cover body inwall, and evaporation water
Vapour, entered by hole in the cover body of internal layer, under high temperature, vaporization, but the composition of air is remained in, idiosome is constantly penetrated at high temperature
It is interior, increase the attachment structure of molecule, the bulk strength for being becomes big, and while toughness reinforcing, idiosome produces a small amount of due to beating reason
Bubble, now, defoamer is sprayed into by piston, quick defoaming, reduce stomata；
The metal corrosion inhibitor and dispersant contained in defoamer, the liquid with condensation effect is prepared, passes through high temperature
After vaporization, idiosome surface is scattered in, cools down idiosome, cooling reduces blibbing, meanwhile, a kind of protection is formed on surface, it is modified
Organic silicon defoamer emulsion constantly suppresses bubble generation so that idiosome sintering is more perfect.
Specific embodiment 2：Defoamer preparation method used in a kind of porcelain idiosome sintering process, including metal erosion suppression
50 parts of preparation, 150 parts of deionized water, 5 parts of diethylene glycol, 5 parts of dispersant, 20 parts of polyethylene glycol, 50 parts of running water, sweet potato stem
15 parts of leaf, 50 parts of deionized water, 25 parts of forage, 13 parts of pluck, 9 parts of agent emulsion of modified organic silicon defoaming, block polyether 3
Part, 10 parts of quaternary ammonium salt, 5 parts of hydrophobic silica, 5 parts of fluorinated polysiloxane, 2 parts of expoxy propane.
Defoamer preparation method comprises the following steps, and in the tank of running water is filled, tank is carried out using oxygen increasing pump
Oxygenation, sweet potato stem leaf is then added into tank every 24h, heat and be transferred in the fermentation tank for filling deionized water, in
Under the conditions of temperature is 30~35 DEG C, forage is added, 36~48h of sealed fermenting, is filtered, removes filter residue, collects filtrate；
Fluorinated polysiloxane is scattered in higher alcohols, is stirred 1~2 hour at 10~30 DEG C, then adds filtrate,
Stirring reaction 1~5 hour, obtains mixture at 100~150 DEG C after cooling；
Pluck is taken, internal organ are washed with deionized 3~5 times, then internal organ are placed in lucifuge ventilation and dried in the shade 2~4h,
Then be transferred in animal tissue's pulverizer, be ground into internal organ slurry, then by gained internal organ slurry and mass fraction be 18~
20% hydrochloric acid is 1 in mass ratio：2~1：4 are added in beakers, then beaker is placed in into digital display and tested the speed in constant temperature blender with magnetic force, in
Temperature is 40~45 DEG C, under the conditions of rotating speed is 400~480r/min, constant temperature 3~5h of stirring reaction, centrifuges, discards lower floor
Precipitation, collects to obtain supernatant liquor；
Metal corrosion inhibitor, water are pressed 2：10 ratio is mixed and heated to 60 DEG C and stirred, and is cooled to normal temperature, then with
Mixture, supernatant liquor high temperature are added in high-pressure reactor, are dehydrated 30min under 120-140 DEG C of decompression, are during which used nitrogen displacement
For several times, expoxy propane induced reaction is then put into, inducing temperature is 140 DEG C, pressure≤0.3MPa, and question response pressure substantially drops
It is low, when temperature steeply rises, show that catalyst has activated, temperature control at 140-160 DEG C, control reactor pressure≤
0.3MPa, treat that pressure no longer reduces in kettle, continue insulation reaction 30min, the unreacted monomer of removed under reduced pressure, obtain defoamer.
Metal corrosion inhibitor is one or more kinds of mixing of alcamines, phenol amine, carboxylic acid lipid, anhydrides.
Dispersant is acrylic acid, methacrylic acid, ethylacrylic acid, olefin sulfonic acid, maleic anhydride, ethylene glycol, diethyl two
One or both of alcohol, ethylene glycol monomethyl ether, ethylene glycol ethyl ether above monomeric unit obtain one in material through homopolymerization or copolymerization
Kind or two or more material mixings.
Increase anticracking additive in above-mentioned formula, including, p-aminobenzoic acid 25-100 parts, sodium hydroxide 4-16 parts,
Mannitol 2-8 parts, calcium nitrate 3-12 parts, water 50-60 parts, zinc oxide 10-12 parts, antistatic additive 6-9 parts.
Anticracking addictive preparation method is that water, p-aminobenzoic acid, sodium hydroxide, sweet dew are sequentially added in agitator
Alcohol, stirring are to being completely dissolved；Then calcium nitrate, zinc oxide are added, is stirred standing, filtering after dissolving, gained filtrate adds
Antistatic additive is well mixed, and is got product.
Part is parts by weight.
As depicted in figs. 1 and 2, sintering is kiln furnace used is provided with support 2 including body of heater 1, body of heater lower section, and body of heater side is provided with door
3, body of heater ratio is provided with heater strip 14, is provided with some mounting tables 4 in body of heater, mounting table is provided with porcelain groove 5, and porcelain groove edge is provided with
2 layers of annular groove 6, mounting table are provided with cover body 7, and cover body is inserted in annular groove, and the outer annular groove cover body in 2 layers of annular groove covers on
On internal layer annular groove cover body, described cover body is provided with air-vent 8.
The cover body of internal layer annular groove passes through internal layer annular groove, and passes through bottom of furnace body.
Cover body is metal cover body.
Air-vent is provided with 800 mesh nets 15.
Mounting table is hollow, and mounting table upper surface is provided with hole 9, is provided with shower nozzle 10 in mounting table, shower nozzle is stuck in mounting table
Interior, the hole of shower nozzle corresponds to the hole on mounting table, shower nozzle connecting pipe 11, and pipeline is through bottom of furnace body connection piston 12, in piston
It is equipped with defoaming liquid.
The cover body inwall of outer annular groove is provided with sponge 13, and for sponge by immersion, soak is toughness reinforcing liquid.
Through overtesting, the china bowl for adding the china bowl and common defoamer and earth kiln sintering of this law defoamer is contrasted：
Data above can be obtained, and the idiosome after pugging is placed in porcelain groove, cover upper outlet body, be closed the door, and heating, heat is from cover
Internal hole and cover body is penetrated into itself, and cover body internal heat is uniform, while heat-agglomerating, the sponge of cover body inwall, and evaporation water
Vapour, entered by hole in the cover body of internal layer, under high temperature, vaporization, but the composition of air is remained in, idiosome is constantly penetrated at high temperature
It is interior, increase the attachment structure of molecule, the bulk strength for being becomes big, and while toughness reinforcing, idiosome produces a small amount of due to beating reason
Bubble, now, defoamer is sprayed into by piston, quick defoaming, reduce stomata；
The metal corrosion inhibitor and dispersant contained in defoamer, the liquid with condensation effect is prepared, passes through high temperature
After vaporization, idiosome surface is scattered in, cools down idiosome, cooling reduces blibbing, meanwhile, a kind of protection is formed on surface, it is modified
Organic silicon defoamer emulsion constantly suppresses bubble generation so that idiosome sintering is more perfect.
Specific embodiment 3：Defoamer preparation method used in a kind of porcelain idiosome sintering process, including metal erosion suppression
30 parts of preparation, 120 parts of deionized water, 3 parts of diethylene glycol, 3 parts of dispersant, 15 parts of polyethylene glycol, 45 parts of running water, sweet potato stem
13 parts of leaf, 30 parts of deionized water, 22 parts of forage, 11 parts of pluck, 7 parts of agent emulsion of modified organic silicon defoaming, block polyether 2
Part, 5 parts of quaternary ammonium salt, 3 parts of hydrophobic silica, 4 parts of fluorinated polysiloxane, 2 parts of expoxy propane.
Defoamer preparation method comprises the following steps, and in the tank of running water is filled, tank is carried out using oxygen increasing pump
Oxygenation, sweet potato stem leaf is then added into tank every 24h, heat and be transferred in the fermentation tank for filling deionized water, in
Under the conditions of temperature is 30~35 DEG C, forage is added, 36~48h of sealed fermenting, is filtered, removes filter residue, collects filtrate；
Fluorinated polysiloxane is scattered in higher alcohols, is stirred 1~2 hour at 10~30 DEG C, then adds filtrate,
Stirring reaction 1~5 hour, obtains mixture at 100~150 DEG C after cooling；
Pluck is taken, internal organ are washed with deionized 3~5 times, then internal organ are placed in lucifuge ventilation and dried in the shade 2~4h,
Then be transferred in animal tissue's pulverizer, be ground into internal organ slurry, then by gained internal organ slurry and mass fraction be 18~
20% hydrochloric acid is 1 in mass ratio：2~1：4 are added in beakers, then beaker is placed in into digital display and tested the speed in constant temperature blender with magnetic force, in
Temperature is 40~45 DEG C, under the conditions of rotating speed is 400~480r/min, constant temperature 3~5h of stirring reaction, centrifuges, discards lower floor
Precipitation, collects to obtain supernatant liquor；
Metal corrosion inhibitor, water are pressed 2：10 ratio is mixed and heated to 60 DEG C and stirred, and is cooled to normal temperature, then with
Mixture, supernatant liquor high temperature are added in high-pressure reactor, are dehydrated 30min under 120-140 DEG C of decompression, are during which used nitrogen displacement
For several times, expoxy propane induced reaction is then put into, inducing temperature is 140 DEG C, pressure≤0.3MPa, and question response pressure substantially drops
It is low, when temperature steeply rises, show that catalyst has activated, temperature control at 140-160 DEG C, control reactor pressure≤
0.3MPa, treat that pressure no longer reduces in kettle, continue insulation reaction 30min, the unreacted monomer of removed under reduced pressure, obtain defoamer.
Metal corrosion inhibitor is one or more kinds of mixing of alcamines, phenol amine, carboxylic acid lipid, anhydrides.
Dispersant is acrylic acid, methacrylic acid, ethylacrylic acid, olefin sulfonic acid, maleic anhydride, ethylene glycol, diethyl two
One or both of alcohol, ethylene glycol monomethyl ether, ethylene glycol ethyl ether above monomeric unit obtain one in material through homopolymerization or copolymerization
Kind or two or more material mixings.
Increase anticracking additive in above-mentioned formula, including, p-aminobenzoic acid 25-100 parts, sodium hydroxide 4-16 parts,
Mannitol 2-8 parts, calcium nitrate 3-12 parts, water 50-60 parts, zinc oxide 10-12 parts, antistatic additive 6-9 parts.
Anticracking addictive preparation method is that water, p-aminobenzoic acid, sodium hydroxide, sweet dew are sequentially added in agitator
Alcohol, stirring are to being completely dissolved；Then calcium nitrate, zinc oxide are added, is stirred standing, filtering after dissolving, gained filtrate adds
Antistatic additive is well mixed, and is got product.
Part is parts by weight.
As depicted in figs. 1 and 2, sintering is kiln furnace used is provided with support 2 including body of heater 1, body of heater lower section, and body of heater side is provided with door
3, body of heater ratio is provided with heater strip 14, is provided with some mounting tables 4 in body of heater, mounting table is provided with porcelain groove 5, and porcelain groove edge is provided with
2 layers of annular groove 6, mounting table are provided with cover body 7, and cover body is inserted in annular groove, and the outer annular groove cover body in 2 layers of annular groove covers on
On internal layer annular groove cover body, described cover body is provided with air-vent 8.
The cover body of internal layer annular groove passes through internal layer annular groove, and passes through bottom of furnace body.
Cover body is metal cover body.
Air-vent is provided with 800 mesh nets 15.
Mounting table is hollow, and mounting table upper surface is provided with hole 9, is provided with shower nozzle 10 in mounting table, shower nozzle is stuck in mounting table
Interior, the hole of shower nozzle corresponds to the hole on mounting table, shower nozzle connecting pipe 11, and pipeline is through bottom of furnace body connection piston 12, in piston
It is equipped with defoaming liquid.
The cover body inwall of outer annular groove is provided with sponge 13, and for sponge by immersion, soak is toughness reinforcing liquid.
Through overtesting, the china bowl for adding the china bowl and common defoamer and earth kiln sintering of this law defoamer is contrasted：
Data above can be obtained, and the idiosome after pugging is placed in porcelain groove, cover upper outlet body, be closed the door, and heating, heat is from cover
Internal hole and cover body is penetrated into itself, and cover body internal heat is uniform, while heat-agglomerating, the sponge of cover body inwall, and evaporation water
Vapour, entered by hole in the cover body of internal layer, under high temperature, vaporization, but the composition of air is remained in, idiosome is constantly penetrated at high temperature
It is interior, increase the attachment structure of molecule, the bulk strength for being becomes big, and while toughness reinforcing, idiosome produces a small amount of due to beating reason
Bubble, now, defoamer is sprayed into by piston, quick defoaming, reduce stomata；
The metal corrosion inhibitor and dispersant contained in defoamer, the liquid with condensation effect is prepared, passes through high temperature
After vaporization, idiosome surface is scattered in, cools down idiosome, cooling reduces blibbing, meanwhile, a kind of protection is formed on surface, it is modified
Organic silicon defoamer emulsion constantly suppresses bubble generation so that idiosome sintering is more perfect.
General principle, principal character and the advantages of the present invention of the present invention has been shown and described above.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the simply explanation described in above-described embodiment and specification is originally
The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes
Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its
Equivalent thereof.
Claims (7)
1. defoamer preparation method used, comprises the following steps, is filling running water in a kind of porcelain idiosome sintering process
In tank, oxygenation is carried out to tank using oxygen increasing pump, then adds sweet potato stem leaf into tank every 24h, heated and by its turn
In the fermentation tank for entering to fill deionized water, under the conditions of temperature is 30~35 DEG C, forage is added, 36~48h of sealed fermenting, is taken out
Filter, filter residue is removed, collect filtrate；
Fluorinated polysiloxane is scattered in higher alcohols, is stirred 1~2 hour at 10~30 DEG C, filtrate is then added, 100
Stirring reaction 1~5 hour, obtains mixture at~150 DEG C after cooling；
Pluck is taken, internal organ are washed with deionized 3~5 times, then internal organ are placed in lucifuge ventilation and dried in the shade 2~4h, then
It is transferred in animal tissue's pulverizer, is ground into internal organ slurry, then by gained internal organ slurry and mass fraction is 18~20%
Hydrochloric acid is 1 in mass ratio：2~1：4 are added in beakers, then beaker is placed in into digital display and tested the speed in constant temperature blender with magnetic force, in temperature
For 40~45 DEG C, under the conditions of rotating speed is 400~480r/min, constant temperature 3~5h of stirring reaction, centrifuges, discard lower sediment,
Collect to obtain supernatant liquor；
Metal corrosion inhibitor, water are pressed 2：10 ratio is mixed and heated to 60 DEG C and stirred, and is cooled to normal temperature, then with mixing
Thing, supernatant liquor high temperature are added in high-pressure reactor, 30min are dehydrated under 120-140 DEG C of decompression, during which with nitrogen displacement number
It is secondary, expoxy propane induced reaction is then put into, inducing temperature is 140 DEG C, pressure≤0.3MPa, and question response pressure substantially reduces,
When temperature steeply rises, showing that catalyst has activated, temperature control controls reactor pressure≤0.3MPa at 140-160 DEG C,
Treat that pressure no longer reduces in kettle, continue insulation reaction 30min, the unreacted monomer of removed under reduced pressure, obtain defoamer.
2. according to defoamer preparation method used in a kind of porcelain idiosome sintering process described in claim 1, its feature
It is：The metal corrosion inhibitor is one or more kinds of mixing of alcamines, phenol amine, carboxylic acid lipid, anhydrides.
3. according to defoamer preparation method used in a kind of porcelain idiosome sintering process described in claim 1, its feature
It is：The dispersant is acrylic acid, methacrylic acid, ethylacrylic acid, olefin sulfonic acid, maleic anhydride, ethylene glycol, diethyl two
One or both of alcohol, ethylene glycol monomethyl ether, ethylene glycol ethyl ether above monomeric unit obtain one in material through homopolymerization or copolymerization
Kind or two or more material mixings.
4. according to defoamer preparation method used in a kind of porcelain idiosome sintering process described in claim 1, its feature
It is：Increase anticracking additive in above-mentioned formula, including, p-aminobenzoic acid 25-100 parts, sodium hydroxide 4-16 parts, sweet dew
Alcohol 2-8 parts, calcium nitrate 3-12 parts, water 50-60 parts, zinc oxide 10-12 parts, antistatic additive 6-9 parts.
5. according to defoamer preparation method used in a kind of porcelain idiosome sintering process described in claim 4, its feature
It is：Described anticracking addictive preparation method is that water, p-aminobenzoic acid, sodium hydroxide, sweet is sequentially added in agitator
Dew alcohol, stirring are to being completely dissolved；Then calcium nitrate, zinc oxide are added, is stirred standing, filtering after dissolving, gained filtrate adds
Enter antistatic additive to be well mixed, get product.
6. according to defoamer preparation method used in a kind of porcelain idiosome sintering process described in claim 1, its feature
It is：Described part is parts by weight.
7. according to defoamer preparation method used in a kind of porcelain idiosome sintering process described in claim 1, its feature
It is：Sinter kiln furnace used including body of heater, mounting table is provided with body of heater, the hole of shower nozzle corresponds to the hole on mounting table, and shower nozzle connects
Pipeline, pipeline are built-in with defoaming liquid through bottom of furnace body connection piston, piston.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114111157A (en) * | 2021-11-30 | 2022-03-01 | 重庆医药高等专科学校 | Safe and reliable's bacterin storage device |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02198603A (en) * | 1989-01-27 | 1990-08-07 | Shin Etsu Chem Co Ltd | Defoaming agent composition |
| EP0596049B1 (en) * | 1991-12-12 | 2006-03-08 | Advanced Technology Pharmaceuticals Corp. | Defoaming composition |
| CN105214349A (en) * | 2015-11-17 | 2016-01-06 | 雷春生 | A kind of method utilizing waste oil to prepare defoamer |
-
2017
- 2017-08-31 CN CN201710771503.2A patent/CN107583313B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02198603A (en) * | 1989-01-27 | 1990-08-07 | Shin Etsu Chem Co Ltd | Defoaming agent composition |
| EP0596049B1 (en) * | 1991-12-12 | 2006-03-08 | Advanced Technology Pharmaceuticals Corp. | Defoaming composition |
| CN105214349A (en) * | 2015-11-17 | 2016-01-06 | 雷春生 | A kind of method utilizing waste oil to prepare defoamer |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114111157A (en) * | 2021-11-30 | 2022-03-01 | 重庆医药高等专科学校 | Safe and reliable's bacterin storage device |
| CN114111157B (en) * | 2021-11-30 | 2023-10-13 | 重庆医药高等专科学校 | Safe and reliable's vaccine storage device |
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| Publication number | Publication date |
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| CN107583313B (en) | 2020-06-12 |
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