CN107573863A - A kind of adhesive sticker and preparation method thereof - Google Patents

A kind of adhesive sticker and preparation method thereof Download PDF

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Publication number
CN107573863A
CN107573863A CN201710781272.3A CN201710781272A CN107573863A CN 107573863 A CN107573863 A CN 107573863A CN 201710781272 A CN201710781272 A CN 201710781272A CN 107573863 A CN107573863 A CN 107573863A
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CN
China
Prior art keywords
polyethylene
layer
polypropylene
extrusion
adhesive sticker
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710781272.3A
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Chinese (zh)
Inventor
钱昇阳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wuxi Huanyu Packaging Material Ltd By Share Ltd
Original Assignee
Wuxi Huanyu Packaging Material Ltd By Share Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wuxi Huanyu Packaging Material Ltd By Share Ltd filed Critical Wuxi Huanyu Packaging Material Ltd By Share Ltd
Priority to CN201710781272.3A priority Critical patent/CN107573863A/en
Publication of CN107573863A publication Critical patent/CN107573863A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a kind of adhesive sticker and preparation method thereof, the adhesive sticker is characterized in that, plane materiel is used as using polypropylene-polyethylene co-extrusion calendered film, relief printing plate flexographic ink prints adhesive and is bonded release base stock on plane materiel, the polypropylene-polyethylene co-extrusion calendered film is will to be extruded after polyethylene, polypropylene, polyethylene difference co-extrusion through three layers of T-shaped mould head, and then calendering formation is top layer polyethylene layer, intermediate layer polypropylene layer, the laminate of bottom polyethylene layer;The polyethylene is acrylic graft-modified LLDPE.The adhesive sticker of the present invention had both had the high property endured of polypropylene material or the flexibility for possessing polyethylene material.

Description

A kind of adhesive sticker and preparation method thereof
Technical field
The present invention relates to polymer film forming field, and in particular to a kind of adhesive sticker and preparation method thereof.
Background technology
In the past, adhesive material was used for TAG field, and generally it is for fabric with paper, plastic sheeting etc., and the back side applies There is adhesive, to apply a kind of composite of the silicon bottom as release base stock, be made after the processing such as printing, being die cut.Due to making Plane materiel is mostly paper or single composition plastic sheeting, and the former is non-watertight, and crease easily folding, and the latter is confined to plastic sheeting Functional limitation, deflection is poor, intensity difference, cost are high.
The content of the invention
In view of the above-mentioned state of the art, the present invention provides a kind of adhesive sticker and preparation method thereof, and of the invention does not do Glue is a kind of adhesive sticker of polypropylene-polyethylene material, and such a adhesive sticker had both had the high property endured of polypropylene material or possessed poly- second The flexibility of alkene material.There is good ink adhesion in its surface, possess excellent processing characteristics so that back of the body patch thing possesses good Good expressive force.
Specifically, the present invention provides a kind of adhesive sticker, using polypropylene-polyethylene co-extrusion calendered film as plane materiel, one on plane materiel Face carries out relief printing plate flexographic ink printing, and another side coating adhesive is simultaneously bonded release base stock,
The polypropylene-polyethylene co-extrusion calendered film is will be T-shaped through three layers after polyethylene, polypropylene, polyethylene difference co-extrusion Die head is extruded, and then calendering formation is top layer polyethylene layer, intermediate layer polypropylene layer, the laminate of bottom polyethylene layer;It is described Polyethylene is LLDPE.
Wherein, the top layer polyethylene layer, intermediate layer polypropylene layer, the thickness of bottom polyethylene layer are respectively 17 μm, 50- 450μm、17μm;The thickness of gluing oxidant layer is 10 μm.
Release base stock can be for example conventional Ge Laxin base stocks.
Polyethylene layer uses the LLDPE of special modification, and adhesive material can be made to be applied without follow-up Under conditions of cloth and directly carry out relief printing plate flexographic ink printing.It is strong to possess good combination simultaneously for adhesive sticker adhesive Degree, is allowed to be bonded after PET not cull.
In addition, the intermediate layer polypropylene layer is using weight ratio as 5:It is prepared by 1 polypropylene and the mixture of colour masterbatch Form.
The present invention also provides a kind of preparation method of adhesive sticker as described above, and it comprises the steps:
(1) by each raw material according to top layer polyethylene layer, intermediate layer polypropylene layer, bottom polyethylene layer the extruded machine of order Go out respectively after melting extrusion through three layers of T-shaped mould coextrusion head;
(2) roll through 40 DEG C of stretcher rolls, cooling, corona;
(3) polyethylene layers carry out relief printing plate flexographic ink printings, be bonded after another polyethylene layer coating adhesive from Type base stock.
Wherein, in step (1), 17 μm of 220 DEG C of extrusion temperature, the thickness of top layer polyethylene;
Middle 250 DEG C of layer polypropylene extrusion temperature, 50-450;
220 DEG C of bottom polyethylene extrusion temperature, 17 μm of thickness.
In addition, the extrusion temperature of three layers of T-shaped mould head is 250 DEG C.
For the adhesive sticker of the present invention compared with traditional adhesive sticker, the plane materiel that adhesive sticker of the present invention uses is to use the poly- second of polypropylene Alkene co-extrusion calendered film, such a material makes polypropylene be layered co-extrusion calendering formation after die head is extruded with polyethylene, post-treated to add Work is made, and has both possessed polyethylene flexibility, excellent processing characteristics it is hereby achieved that a kind of, but also with polyacrylic intensity and The adhesive sticker product of deflection;And the present invention can make adhesive material under conditions of without follow-up coating and directly enter Row relief printing plate flexographic ink prints.Possess good bond strength simultaneously for adhesive sticker adhesive, be allowed to be bonded not residual after PET Glue..
Brief description of the drawings
Fig. 1 is the structural representation of the new adhesive sticker of the present invention.
Description of reference numerals
1. top layer polyethylene layer;2. intermediate layer polypropylene layer;3. bottom polyethylene layer;4. plane materiel;5. adhesive;It is 6. release Base stock.
Embodiment
Technical solution of the present invention is discussed in detail below in conjunction with the accompanying drawings, but the present invention is not limited to this.
Fig. 1 is the structural representation of adhesive sticker of the present invention.As shown in figure 1, the adhesive sticker of the present invention, possesses plane materiel 4, gluing Agent 5, release base stock 6.
Plane materiel 4 includes:Top layer polyethylene layer 1, intermediate layer polypropylene layer 2, bottom polyethylene layer 3.
The preparation method of the adhesive sticker of the present invention, is respectively to gather top layer polyethylene layer 1, intermediate layer polypropylene layer 2, bottom The respective raw material of pvdf layer 3 is melted and then made after being extruded in the lump in three layers of T-shaped mould head after calendering respectively by extruder Polypropylene-polyethylene calendered film is obtained, and relief printing plate flexographic ink is carried out as plane materiel 4 and then through cooling, corona, a face Printing, another face coating adhesive 5 are simultaneously bonded release base stock 6 and are made.
Specifically, it is 5 by film level polyethylene, weight ratio:1 polypropylene and colour masterbatch, the extruded machine of film level polyethylene Extrusion, wherein 220 DEG C of the extrusion temperature of the polyethylene of top layer polyethylene layer, 17 μm of thickness, weight ratio are 5:1 polypropylene and face 250 DEG C of the extrusion temperature of color masterbatch, 50-400 μm of thickness;220 DEG C of extrusion temperature, the thickness of the polyethylene of layer polyethylene layer 17μm.Extruded by three layers of T-shaped mould head, extrusion temperature is 250 DEG C, 40 degree of stretcher roll, is cooled down through calendering, corona, winding etc. Plane materiel is made in technical process.Then facestock is cut again, a face relief printing plate flexographic ink printing, another main coating glue Glutinous agent thickness is 10 μm, is bonded the adhesive sticker that the present invention is made in release base stock.
Adhesive sticker can directly carry out the printing of UV relief printing plates and soft version without coating, using 3M600 adhesive tape tests without falling Black phenomenon.Specific method of testing is that 3M600 adhesive tapes pull out to 20cm is smooth to be affixed on tested new label printing face, and finger comes energetically Go back to 180 degree directions before rolling 5 times backward and quickly tear adhesive tape, it is desirable to which printing-ink is intact, and oil-free Motuo falls, noresidue on adhesive tape Ink.

Claims (6)

1. a kind of adhesive sticker, it is characterised in that simultaneously carried out using polypropylene-polyethylene co-extrusion calendered film as plane materiel, on plane materiel convex Version flexographic ink printing, another side coating adhesive are simultaneously bonded release base stock,
The polypropylene-polyethylene co-extrusion calendered film be by polyethylene, polypropylene, polyethylene difference co-extrusion after through three layers of T-shaped mould head Extrusion, then calendering formation is top layer polyethylene layer, intermediate layer polypropylene layer, the laminate of bottom polyethylene layer;The poly- second Alkene is acrylic graft-modified LLDPE.
2. adhesive sticker according to claim 1, it is characterised in that the top layer polyethylene layer, intermediate layer polypropylene layer, bottom The thickness of strata pvdf layer is respectively 17 μm, 50-450 μm, 17 μm;The thickness of gluing oxidant layer is 10 μm.
3. adhesive sticker according to claim 1, it is characterised in that the intermediate layer polypropylene layer is using weight ratio as 5:1 Polypropylene and the mixture of colour masterbatch be prepared.
4. the preparation method of the adhesive sticker in a kind of 1-3 such as claim as described in any one, it is characterised in that including following steps Suddenly:
(1) each raw material is distinguished according to the extruded machine of order of top layer polyethylene layer, intermediate layer polypropylene layer, bottom polyethylene layer Go out after melting extrusion through three layers of T-shaped mould coextrusion head;
(2) roll through 40 DEG C of stretcher rolls, cooling, corona;
(3) polyethylene layers carry out relief printing plate flexographic ink printing, and release bottom is bonded after another polyethylene layer coating adhesive Paper.
5. preparation method according to claim 4, it is characterised in that in step (1), the extrusion temperature of top layer polyethylene 220 DEG C, 17 μm of thickness;
Middle 250 DEG C of layer polypropylene extrusion temperature, 50-450 μm of thickness;
220 DEG C of bottom polyethylene extrusion temperature, 17 μm of thickness.
6. preparation method according to claim 4, it is characterised in that the extrusion temperature of three layers of T-shaped mould head is 250 DEG C.
CN201710781272.3A 2017-09-01 2017-09-01 A kind of adhesive sticker and preparation method thereof Pending CN107573863A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710781272.3A CN107573863A (en) 2017-09-01 2017-09-01 A kind of adhesive sticker and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710781272.3A CN107573863A (en) 2017-09-01 2017-09-01 A kind of adhesive sticker and preparation method thereof

Publications (1)

Publication Number Publication Date
CN107573863A true CN107573863A (en) 2018-01-12

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CN (1) CN107573863A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109955580A (en) * 2019-04-01 2019-07-02 阜阳市尤美合成纸有限公司 A kind of preparation method of multilayer synthetic paper
CN110815884A (en) * 2019-11-18 2020-02-21 许锦才 Production method of environment-friendly cloth-based adhesive tape

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002127332A (en) * 2000-10-23 2002-05-08 Tamapori Kk Film for stretch label
US20030008082A1 (en) * 2001-06-22 2003-01-09 Dronzek Peter J. Labels with removable section for in-mold production of in-mold labeled molded containers
US20030148132A1 (en) * 1998-12-23 2003-08-07 Georg Schwinn Recyclable label foil

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030148132A1 (en) * 1998-12-23 2003-08-07 Georg Schwinn Recyclable label foil
JP2002127332A (en) * 2000-10-23 2002-05-08 Tamapori Kk Film for stretch label
US20030008082A1 (en) * 2001-06-22 2003-01-09 Dronzek Peter J. Labels with removable section for in-mold production of in-mold labeled molded containers

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
赵秀萍 等: "《柔性版印刷技术》", 30 April 2003, 中国轻工业出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109955580A (en) * 2019-04-01 2019-07-02 阜阳市尤美合成纸有限公司 A kind of preparation method of multilayer synthetic paper
CN110815884A (en) * 2019-11-18 2020-02-21 许锦才 Production method of environment-friendly cloth-based adhesive tape

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