CN107556942A - A kind of corrugated paper quick-drying MR adhesive and preparation method thereof - Google Patents
A kind of corrugated paper quick-drying MR adhesive and preparation method thereof Download PDFInfo
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- CN107556942A CN107556942A CN201710732361.9A CN201710732361A CN107556942A CN 107556942 A CN107556942 A CN 107556942A CN 201710732361 A CN201710732361 A CN 201710732361A CN 107556942 A CN107556942 A CN 107556942A
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Abstract
The invention provides a kind of corrugated paper quick-drying MR adhesive and preparation method thereof.Preparation method is as follows：（1）It is standby NaOH solution will to be configured；（2）Starch is added to the water, configures amidin, adjusts pH to 13, then adds monoxone stirring reaction；（3）Hydrogen peroxide is added after etherificate, is heated up, sodium thiosulfate stirring is added after reaction, then NaOH solution is slowly added dropwise, continues to heat up, makes to be gelatinized completely, be then down to room temperature, adjust pH to 78；（4）Calgon is continuously added, adds lauryl sodium sulfate, blast-furnace cinder, alum, the collateralization carbon fatty alcohol APEO of isomery 13 while stirring；（5）It is to be mixed uniformly after sequentially add thiocarbamide, wood ash, red clay and continue to stir, be eventually adding tributyl phosphate defoaming.The corrugated paper of the present invention is fast with quick-drying MR adhesive rate of drying, and water resistance is good.
Description
Technical field
The present invention relates to paper products paint field, and in particular to a kind of corrugated paper quick-drying MR adhesive and its preparation side
Method.
Background technology
It is well known that corrugated board is a kind of using extremely wide important packaging material, and produce the master of corrugated board
It is exactly adhesive to want auxiliary material, and main binder used in China's corrugated board manufacturing industry is bubble before the 1980s
Flower alkali
Glue, it the shortcomings that be to have stronger corrosivity, require coating weight is higher, humidity resistance is poor etc..Chinese packaging enters within 1984
Key popularized project of the export firm using amylum adhesive as national carton industry production, forbade making from 1 day January in 1993
By the use of sodium silicate as corrugated case production adhesive, and provide that export packing carton and packaging for foodstuff carton use corn without exception
Amylum adhesive.Amylum adhesive has advantages below：(1) production equipment is simple, easy to make, goes into operation fast, the cycle is short；(2)
Adhesive strength is higher than sodium silicate, and production cost is low；(3) there is preferable moisture resistance, coating weight is less than sodium silicate;(4) safe nothing
Poison, it is environment-friendly products.The main method for producing amylum adhesive is oxidizing process, and conventional oxidant has sodium hypochlorite, dioxygen
Water, potassium permanganate etc..Due to H2O2Low in the pollution of the environment compared with other oxidants, the adhesive color of preparation is good, mobility and
Stability is good, thus now through frequently with.But amylum adhesive is in itself there is also some shortcomings, for example, it is slow from dry speed, just
Viscous force is low, poor water resistance etc., and this to preparation and brings the problem of certain using amylum adhesive.
The content of the invention
Technical problems to be solved：It is an object of the invention to provide a kind of corrugated paper quick-drying MR adhesive, Ke Yiyou
The problem of rate of drying and water resistance of the improvement adhesive of effect.
Technical scheme：A kind of corrugated paper quick-drying MR adhesive, it is prepared by weight by following component：Corn forms sediment
Powder 40-60 parts, water 120-160 parts, hydrogen peroxide 3.4-5.5 parts, monoxone 2.4-6.5 parts, sodium thiosulfate 0.2-0.8 parts, hydrogen
Sodium oxide molybdena 8-12 parts, tributyl phosphate 0.06-0.1 parts, lauryl sodium sulfate 0.3-0.6 parts, calgon 0.5-1 parts,
Blast-furnace cinder 1.5-5 parts, alum 1.5-2.5 parts, collateralization isomery 13 carbon fatty alcohol APEO 5-8 parts, thiocarbamide 0.5-
1.2 parts, wood ash 0.3-0.5 parts, red clay 4-6 parts.
It is further preferred that a kind of described corrugated paper quick-drying MR adhesive, is prepared by weight by following component
Form：Cornstarch 45-55 parts, water 130-150 parts, hydrogen peroxide 4-5 parts, monoxone 3-5.5 parts, sodium thiosulfate 0.4-0.6
Part, sodium hydroxide 9-10 parts, tributyl phosphate 0.06-0.08 parts, lauryl sodium sulfate 0.4-0.5 parts, calgon
0.6-0.8 parts, blast-furnace cinder 2.5-3.5 parts, alum 1.8-2.2 parts, collateralization isomery 13 carbon fatty alcohol APEO 6-7
Part, thiocarbamide 0.7-1 parts, wood ash 0.3-0.4 parts, red clay 4.5-5.5 parts.
The above-mentioned corrugated paper preparation method of quick-drying MR adhesive, comprises the following steps：
（1）Sodium hydroxide is dissolved in the water of 2 times of parts by weight stir to clarify it is standby；
（2）Starch is added in remaining water, configures amidin, emulsifies 20-60min, pH to 13 is adjusted, then adds chlorine
Acetic acid stirring reaction 30min；
（3）Hydrogen peroxide is added after etherificate, is heated up 40-50 DEG C, reacts 40-80min, adds sodium thiosulfate, stirs 10min,
NaOH solution is slowly added dropwise again, is warming up to 80-90 DEG C, makes to be gelatinized completely, is then down to room temperature, adjusts pH to 7-8；
（4）Continuously add calgon, stir 5-10min, add lauryl sodium sulfate, blast-furnace cinder, bright while stirring
Alum, the collateralization carbon fatty alcohol APEO of isomery 13；
（5）It is to be mixed uniformly after sequentially add thiocarbamide, wood ash, red clay continue stir 20-40min, be eventually adding tricresyl phosphate fourth
Ester defoams.
Further, the preparation method of described a kind of corrugated paper quick-drying MR adhesive, the step（2）Middle emulsification
Time is 30-50min.
Further, the preparation method of described a kind of corrugated paper quick-drying MR adhesive, the step（3）Middle dioxygen
The concentration of water is 30wt%, and hydrogen peroxide oxidation temperature is 45 DEG C, and oxidization time 50-70min, NaOH gelatinization point are 85 DEG C.
Further, the preparation method of described a kind of corrugated paper quick-drying MR adhesive, the step（4）Middle stirring
Time is 8min.
Further, the preparation method of described a kind of corrugated paper quick-drying MR adhesive, the step（5）Middle stirring
Time is 25-35min.
Beneficial effect：The corrugated paper of present invention water resistance after thiocarbamide, wood ash, red clay is added with quick-drying MR adhesive
It can be greatly improved, 75h is soaked in water and just falls off phenomenon；Adding blast-furnace cinder, alum, collateralization isomery ten
After three carbon fatty alcohol APEOs, adhesive rate of drying is improved, is measured and is can be seen that after 120min by percentage of water loss,
Percentage of water loss reaches 43.4%, far above the 32.7% of comparative example.
Embodiment
Embodiment 1
A kind of corrugated paper quick-drying MR adhesive, it is prepared by weight by following component：40 parts of cornstarch, water 120
Part, 3.4 parts of hydrogen peroxide, 2.4 parts of monoxone, 0.8 part of sodium thiosulfate, 8 parts of sodium hydroxide, 0.1 part of tributyl phosphate, dodecane
0.6 part of base sodium sulphate, 0.5 part of calgon, 1.5 parts of blast-furnace cinder, 2.5 parts of alum, the collateralization carbon fatty alcohol of isomery 13
5 parts of APEO, 0.5 part of thiocarbamide, 0.3 part of wood ash, 6 parts of red clay.
Above-mentioned corrugated paper is with the preparation method of quick-drying MR adhesive：（1）Sodium hydroxide is dissolved in the water of 2 times of parts by weight
In stir to clarify it is standby；（2）Starch is added in remaining water, configures amidin, emulsifies 20min, adjusts pH to 13,
Then monoxone stirring reaction 30min is added；（3）Hydrogen peroxide is added after etherificate, is heated up 50 DEG C, reacts 40min, is added thio
Sodium sulphate, 10min is stirred, then NaOH solution is slowly added dropwise, be warming up to 90 DEG C, make to be gelatinized completely, be then down to room temperature, adjust pH
To 7；（4）Continuously add calgon, stir 5min, add while stirring lauryl sodium sulfate, blast-furnace cinder, alum,
It is branched the carbon fatty alcohol APEO of isomery 13；（5）It is to be mixed uniformly after sequentially add thiocarbamide, wood ash, red clay continue
40min is stirred, is eventually adding tributyl phosphate defoaming.
Embodiment 2
A kind of corrugated paper quick-drying MR adhesive, it is prepared by weight by following component：60 parts of cornstarch, water 160
Part, 5.5 parts of hydrogen peroxide, 6.5 parts of monoxone, 0.2 part of sodium thiosulfate, 12 parts of sodium hydroxide, 0.06 part of tributyl phosphate, ten
0.3 part of sodium dialkyl sulfate, 1 part of calgon, 15 parts of blast-furnace cinder, 1.5 parts of alum, the collateralization carbon fatty alcohol of isomery 13
8 parts of APEO, 1.2 parts of thiocarbamide, 0.5 part of wood ash, 4 parts of red clay.
Above-mentioned corrugated paper is with the preparation method of quick-drying MR adhesive：（1）Sodium hydroxide is dissolved in the water of 2 times of parts by weight
In stir to clarify it is standby；（2）Starch is added in remaining water, configures amidin, emulsifies 60min, adjusts pH to 13,
Then monoxone stirring reaction 30min is added；（3）Hydrogen peroxide is added after etherificate, is heated up 40 DEG C, reacts 80min, is added thio
Sodium sulphate, 10min is stirred, then NaOH solution is slowly added dropwise, be warming up to 80 DEG C, make to be gelatinized completely, be then down to room temperature, adjust pH
To 8；（4）Continuously add calgon, stir 10min, add while stirring lauryl sodium sulfate, blast-furnace cinder, alum,
It is branched the carbon fatty alcohol APEO of isomery 13；（5）It is to be mixed uniformly after sequentially add thiocarbamide, wood ash, red clay continue
20min is stirred, is eventually adding tributyl phosphate defoaming.
Embodiment 3
A kind of corrugated paper quick-drying MR adhesive, it is prepared by weight by following component：45 parts of cornstarch, water 130
Part, 5 parts of hydrogen peroxide, 3 parts of monoxone, 0.6 part of sodium thiosulfate, 10 parts of sodium hydroxide, 0.08 part of tributyl phosphate, dodecane
0.5 part of base sodium sulphate, 0.6 part of calgon, 3.5 parts of blast-furnace cinder, 1.8 parts of alum, the collateralization carbon fatty alcohol of isomery 13
6 parts of APEO, 1 part of thiocarbamide, 0.4 part of wood ash, 4.5 parts of red clay.
Above-mentioned corrugated paper is with the preparation method of quick-drying MR adhesive：（1）Sodium hydroxide is dissolved in the water of 2 times of parts by weight
In stir to clarify it is standby；（2）Starch is added in remaining water, configures amidin, emulsifies 30min, adjusts pH to 13,
Then monoxone stirring reaction 30min is added；（3）Hydrogen peroxide is added after etherificate, is heated up 45 DEG C, reacts 70min, is added thio
Sodium sulphate, 10min is stirred, then NaOH solution is slowly added dropwise, be warming up to 85 DEG C, make to be gelatinized completely, be then down to room temperature, adjust pH
To 7；（4）Continuously add calgon, stir 8min, add while stirring lauryl sodium sulfate, blast-furnace cinder, alum,
It is branched the carbon fatty alcohol APEO of isomery 13；（5）It is to be mixed uniformly after sequentially add thiocarbamide, wood ash, red clay continue
25min is stirred, is eventually adding tributyl phosphate defoaming.
Embodiment 4
A kind of corrugated paper quick-drying MR adhesive, it is prepared by weight by following component：55 parts of cornstarch, water 150
Part, 4 parts of hydrogen peroxide, 5.5 parts of monoxone, 0.4 part of sodium thiosulfate, 9 parts of sodium hydroxide, 0.06 part of tributyl phosphate, dodecane
0.4 part of base sodium sulphate, 0.8 part of calgon, 2.5 parts of blast-furnace cinder, 2.2 parts of alum, the collateralization carbon fatty alcohol of isomery 13
7 parts of APEO, 0.7 part of thiocarbamide, 0.3 part of wood ash, 5.5 parts of red clay.
Above-mentioned corrugated paper is with the preparation method of quick-drying MR adhesive：（1）Sodium hydroxide is dissolved in the water of 2 times of parts by weight
In stir to clarify it is standby；（2）Starch is added in remaining water, configures amidin, emulsifies 50min, adjusts pH to 13,
Then monoxone stirring reaction 30min is added；（3）Hydrogen peroxide is added after etherificate, is heated up 45 DEG C, reacts 50min, is added thio
Sodium sulphate, 10min is stirred, then NaOH solution is slowly added dropwise, be warming up to 85 DEG C, make to be gelatinized completely, be then down to room temperature, adjust pH
To 8；（4）Continuously add calgon, stir 8min, add while stirring lauryl sodium sulfate, blast-furnace cinder, alum,
It is branched the carbon fatty alcohol APEO of isomery 13；（5）It is to be mixed uniformly after sequentially add thiocarbamide, wood ash, red clay continue
25min is stirred, is eventually adding tributyl phosphate defoaming.
Embodiment 5
A kind of corrugated paper quick-drying MR adhesive, it is prepared by weight by following component：50 parts of cornstarch, water 140
Part, 4.5 parts of hydrogen peroxide, 4.5 parts of monoxone, 0.5 part of sodium thiosulfate, 9.5 parts of sodium hydroxide, 0.07 part of tributyl phosphate, ten
0.45 part of sodium dialkyl sulfate, 0.7 part of calgon, 3 parts of blast-furnace cinder, 2 parts of alum, the collateralization carbon fatty alcohol of isomery 13
6.5 parts of APEO, 0.9 part of thiocarbamide, 0.35 part of wood ash, 5 parts of red clay.
Above-mentioned corrugated paper is with the preparation method of quick-drying MR adhesive：（1）Sodium hydroxide is dissolved in the water of 2 times of parts by weight
In stir to clarify it is standby；（2）Starch is added in remaining water, configures amidin, emulsifies 40min, adjusts pH to 13,
Then monoxone stirring reaction 30min is added；（3）Hydrogen peroxide is added after etherificate, is heated up 45 DEG C, reacts 60min, is added thio
Sodium sulphate, 10min is stirred, then NaOH solution is slowly added dropwise, be warming up to 85 DEG C, make to be gelatinized completely, be then down to room temperature, adjust pH
To 7；（4）Continuously add calgon, stir 8min, add while stirring lauryl sodium sulfate, blast-furnace cinder, alum,
It is branched the carbon fatty alcohol APEO of isomery 13；（5）It is to be mixed uniformly after sequentially add thiocarbamide, wood ash, red clay continue
30min is stirred, is eventually adding tributyl phosphate defoaming.
Comparative example 1
A kind of corrugated paper quick-drying MR adhesive, it is prepared by weight by following component：40 parts of cornstarch, water 120
Part, 3.4 parts of hydrogen peroxide, 2.4 parts of monoxone, 0.8 part of sodium thiosulfate, 8 parts of sodium hydroxide, 0.1 part of tributyl phosphate, dodecane
0.6 part of base sodium sulphate, 0.5 part of calgon, 0.5 part of thiocarbamide, 0.3 part of wood ash, 6 parts of red clay.
Above-mentioned corrugated paper is with the preparation method of quick-drying MR adhesive：（1）Sodium hydroxide is dissolved in the water of 2 times of parts by weight
In stir to clarify it is standby；（2）Starch is added in remaining water, configures amidin, emulsifies 20min, adjusts pH to 13,
Then monoxone stirring reaction 30min is added；（3）Hydrogen peroxide is added after etherificate, is heated up 50 DEG C, reacts 40min, is added thio
Sodium sulphate, 10min is stirred, then NaOH solution is slowly added dropwise, be warming up to 90 DEG C, make to be gelatinized completely, be then down to room temperature, adjust pH
To 7；（4）Calgon is continuously added, 5min is stirred, adds lauryl sodium sulfate while stirring；（5）It is to be mixed uniformly after
Sequentially add thiocarbamide, wood ash, red clay to continue to stir 40min, be eventually adding tributyl phosphate defoaming.
Comparative example 2
A kind of corrugated paper quick-drying MR adhesive, it is prepared by weight by following component：60 parts of cornstarch, water 160
Part, 5.5 parts of hydrogen peroxide, 6.5 parts of monoxone, 0.2 part of sodium thiosulfate, 12 parts of sodium hydroxide, 0.06 part of tributyl phosphate, ten
0.3 part of sodium dialkyl sulfate, 1 part of calgon, 15 parts of blast-furnace cinder, 1.5 parts of alum, the collateralization carbon fatty alcohol of isomery 13
8 parts of APEO.
Above-mentioned corrugated paper is with the preparation method of quick-drying MR adhesive：（1）Sodium hydroxide is dissolved in the water of 2 times of parts by weight
In stir to clarify it is standby；（2）Starch is added in remaining water, configures amidin, emulsifies 60min, adjusts pH to 13,
Then monoxone stirring reaction 30min is added；（3）Hydrogen peroxide is added after etherificate, is heated up 40 DEG C, reacts 80min, is added thio
Sodium sulphate, 10min is stirred, then NaOH solution is slowly added dropwise, be warming up to 80 DEG C, make to be gelatinized completely, be then down to room temperature, adjust pH
To 8；（4）Continuously add calgon, stir 10min, add while stirring lauryl sodium sulfate, blast-furnace cinder, alum,
It is branched the carbon fatty alcohol APEO of isomery 13；（5）It is to be mixed uniformly after, add tributyl phosphate defoaming.
Embodiment 1-5 and comparative example 1,2 are subjected to properties test.
Water resisting time：The amylum adhesive of equivalent is coated in two corrugated papers by hand（2cm×2cm）On, then through 80
DEG C dry 1d, room temperature place 1d after, time when being dipped to Automatic-falling in 25 DEG C of water using it is used as measurement index.
Rate of drying：Rate of drying is tested by weighing method, under the conditions of 25 DEG C of environment temperature, humidity are 73%, in the face of grade
The amylum adhesive of equivalent is coated with long-pending corrugated board, is weighed at once as W1, weighed according to the percentage of water loss of different time
Its rate of drying, period are respectively 40min, 80min, 120min, and separated in time claims to obtain cardboard weight W respectively2, until
Claim cardboard room temperature constant weight weight W0, then percentage of water loss be calculated as follows：Percentage of water loss %=(W1-W2)/(W1 -W0)×100%。
The property indices of material of the present invention see the table below, it may be seen that this corrugated paper is existed with quick-drying MR adhesive
Water resistance is greatly improved after adding thiocarbamide, wood ash, red clay, and 75h is soaked in water and just falls off phenomenon；Adding
After entering blast-furnace cinder, alum, the collateralization carbon fatty alcohol APEO of isomery 13, adhesive rate of drying is improved, is passed through
Percentage of water loss measurement is it can be seen that after 120min, and percentage of water loss reaches 43.4%, far above the 32.7% of comparative example.
The property indices of the corrugated paper of table 1 quick-drying MR adhesive
。
Claims (7)
1. a kind of corrugated paper quick-drying MR adhesive, it is characterised in that be prepared by weight by following component：Corn forms sediment
Powder 40-60 parts, water 120-160 parts, hydrogen peroxide 3.4-5.5 parts, monoxone 2.4-6.5 parts, sodium thiosulfate 0.2-0.8 parts, hydrogen
Sodium oxide molybdena 8-12 parts, tributyl phosphate 0.06-0.1 parts, lauryl sodium sulfate 0.3-0.6 parts, calgon 0.5-1 parts,
Blast-furnace cinder 1.5-5 parts, alum 1.5-2.5 parts, collateralization isomery 13 carbon fatty alcohol APEO 5-8 parts, thiocarbamide 0.5-
1.2 parts, wood ash 0.3-0.5 parts, red clay 4-6 parts.
2. a kind of corrugated paper quick-drying MR adhesive according to claim 1, it is characterised in that by following component by weight
Amount part is prepared：Cornstarch 45-55 parts, water 130-150 parts, hydrogen peroxide 4-5 parts, monoxone 3-5.5 parts, thiosulfuric acid
It is sodium 0.4-0.6 parts, sodium hydroxide 9-10 parts, tributyl phosphate 0.06-0.08 parts, lauryl sodium sulfate 0.4-0.5 parts, six inclined
Sodium phosphate 0.6-0.8 parts, blast-furnace cinder 2.5-3.5 parts, alum 1.8-2.2 parts, the collateralization carbon fatty alcohol polyoxy second of isomery 13
Alkene ether 6-7 parts, thiocarbamide 0.7-1 parts, wood ash 0.3-0.4 parts, red clay 4.5-5.5 parts.
3. a kind of corrugated paper preparation method of quick-drying MR adhesive, it is characterised in that comprise the following steps：
（1）Sodium hydroxide is dissolved in the water of 2 times of parts by weight stir to clarify it is standby；
（2）Starch is added in remaining water, configures amidin, emulsifies 20-60min, pH to 13 is adjusted, then adds chlorine
Acetic acid stirring reaction 30min；
（3）Hydrogen peroxide is added after etherificate, is heated up 40-50 DEG C, reacts 40-80min, adds sodium thiosulfate, stirs 10min,
NaOH solution is slowly added dropwise again, is warming up to 80-90 DEG C, makes to be gelatinized completely, is then down to room temperature, adjusts pH to 7-8；
（4）Continuously add calgon, stir 5-10min, add lauryl sodium sulfate, blast-furnace cinder, bright while stirring
Alum, the collateralization carbon fatty alcohol APEO of isomery 13；
（5）It is to be mixed uniformly after sequentially add thiocarbamide, wood ash, red clay continue stir 20-40min, be eventually adding tricresyl phosphate fourth
Ester defoams.
A kind of 4. preparation method of corrugated paper quick-drying MR adhesive according to claim 3, it is characterised in that：It is described
Step（2）Middle emulsification times are 30-50min.
A kind of 5. preparation method of corrugated paper quick-drying MR adhesive according to claim 3, it is characterised in that：It is described
Step（3）The concentration of middle hydrogen peroxide is 30wt%, and hydrogen peroxide oxidation temperature is 45 DEG C, oxidization time 50-70min, NaOH paste
It is 85 DEG C to change temperature.
A kind of 6. preparation method of corrugated paper quick-drying MR adhesive according to claim 3, it is characterised in that：It is described
Step（4）Middle mixing time is 8min.
A kind of 7. preparation method of corrugated paper quick-drying MR adhesive according to claim 3, it is characterised in that：It is described
Step（5）Middle mixing time is 25-35min.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110561828A (en) * | 2019-09-15 | 2019-12-13 | 安徽佰特包装制品有限公司 | Pressure-resistant corrugated carton and production process thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103087653A (en) * | 2012-11-13 | 2013-05-08 | 陈晓 | Fast-curing adhesive |
| CN106433512A (en) * | 2016-09-29 | 2017-02-22 | 江南大学 | Wallpaper adhesive prepared through starch oxidative coupling pasting |
| CN106753120A (en) * | 2016-12-01 | 2017-05-31 | 刘德玉 | Acoustic mastic and preparation method thereof is built in a kind of ageing-resistant one-component epoxy resin capital construction |
| CN106753035A (en) * | 2016-12-08 | 2017-05-31 | 苏州纳贝通环境科技有限公司 | A kind of starch base corrugation adhesive for paper and preparation method thereof |
-
2017
- 2017-08-24 CN CN201710732361.9A patent/CN107556942A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103087653A (en) * | 2012-11-13 | 2013-05-08 | 陈晓 | Fast-curing adhesive |
| CN106433512A (en) * | 2016-09-29 | 2017-02-22 | 江南大学 | Wallpaper adhesive prepared through starch oxidative coupling pasting |
| CN106753120A (en) * | 2016-12-01 | 2017-05-31 | 刘德玉 | Acoustic mastic and preparation method thereof is built in a kind of ageing-resistant one-component epoxy resin capital construction |
| CN106753035A (en) * | 2016-12-08 | 2017-05-31 | 苏州纳贝通环境科技有限公司 | A kind of starch base corrugation adhesive for paper and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 张亚梅: "《土木工程材料》", 31 January 2013, 东南大学出版社 * |
| 张玉龙: "《环境友好胶黏剂制备与应用技术》", 31 January 2008, 中国石化出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110561828A (en) * | 2019-09-15 | 2019-12-13 | 安徽佰特包装制品有限公司 | Pressure-resistant corrugated carton and production process thereof |
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Application publication date: 20180109 |