CN107552093A - A kind of supporting iridium catalyst and preparation method for Bisphenol F and esterification - Google Patents
A kind of supporting iridium catalyst and preparation method for Bisphenol F and esterification Download PDFInfo
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- CN107552093A CN107552093A CN201710764217.3A CN201710764217A CN107552093A CN 107552093 A CN107552093 A CN 107552093A CN 201710764217 A CN201710764217 A CN 201710764217A CN 107552093 A CN107552093 A CN 107552093A
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- catalyst
- iridium
- bisphenol
- bop
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- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 title claims abstract description 44
- 239000003054 catalyst Substances 0.000 title claims abstract description 42
- 229910052741 iridium Inorganic materials 0.000 title claims abstract description 33
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 title claims abstract description 32
- 238000005886 esterification reaction Methods 0.000 title claims abstract description 14
- 230000032050 esterification Effects 0.000 title claims abstract description 12
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 229960001545 hydrotalcite Drugs 0.000 claims abstract description 42
- 229910001701 hydrotalcite Inorganic materials 0.000 claims abstract description 42
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 claims abstract description 21
- 239000002131 composite material Substances 0.000 claims abstract description 16
- CMCIFSDUQWTRJV-UHFFFAOYSA-N [Ir].O1C=NC2=C1C=CC=C2 Chemical compound [Ir].O1C=NC2=C1C=CC=C2 CMCIFSDUQWTRJV-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000000203 mixture Substances 0.000 claims abstract description 3
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 claims description 36
- 239000000047 product Substances 0.000 claims description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 12
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 12
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 12
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 12
- 238000006243 chemical reaction Methods 0.000 claims description 12
- 238000001035 drying Methods 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 11
- 239000008367 deionised water Substances 0.000 claims description 8
- 229910021641 deionized water Inorganic materials 0.000 claims description 8
- 239000007789 gas Substances 0.000 claims description 8
- 235000011187 glycerol Nutrition 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 7
- 239000011259 mixed solution Substances 0.000 claims description 7
- 239000012046 mixed solvent Substances 0.000 claims description 7
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 6
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 6
- 239000012043 crude product Substances 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 5
- 239000002904 solvent Substances 0.000 claims description 5
- 125000000355 1,3-benzoxazolyl group Chemical group O1C(=NC2=C1C=CC=C2)* 0.000 claims description 4
- KMZHZAAOEWVPSE-UHFFFAOYSA-N 2,3-dihydroxypropyl acetate Chemical compound CC(=O)OCC(O)CO KMZHZAAOEWVPSE-UHFFFAOYSA-N 0.000 claims description 4
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 claims description 4
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 238000004064 recycling Methods 0.000 claims description 4
- 238000003786 synthesis reaction Methods 0.000 claims description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 238000013461 design Methods 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 229910052786 argon Inorganic materials 0.000 claims description 2
- 235000019441 ethanol Nutrition 0.000 claims description 2
- 150000002314 glycerols Chemical class 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- 238000001953 recrystallisation Methods 0.000 claims description 2
- 238000000967 suction filtration Methods 0.000 claims description 2
- 238000011027 product recovery Methods 0.000 claims 1
- 230000003197 catalytic effect Effects 0.000 abstract description 3
- 238000004925 denaturation Methods 0.000 abstract description 3
- 230000036425 denaturation Effects 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 238000011084 recovery Methods 0.000 abstract description 2
- 238000004140 cleaning Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract 1
- URAYPUMNDPQOKB-UHFFFAOYSA-N glycerine triacetate Natural products CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 description 7
- 239000001087 glyceryl triacetate Substances 0.000 description 4
- 235000013773 glyceryl triacetate Nutrition 0.000 description 4
- 229960002622 triacetin Drugs 0.000 description 4
- 150000002500 ions Chemical group 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000004587 chromatography analysis Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- AEDZKIACDBYJLQ-UHFFFAOYSA-N ethane-1,2-diol;hydrate Chemical compound O.OCCO AEDZKIACDBYJLQ-UHFFFAOYSA-N 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 230000002194 synthesizing effect Effects 0.000 description 2
- 239000004367 Lipase Substances 0.000 description 1
- 102000004882 Lipase Human genes 0.000 description 1
- 108090001060 Lipase Proteins 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000002389 environmental scanning electron microscopy Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 150000002504 iridium compounds Chemical class 0.000 description 1
- 235000019421 lipase Nutrition 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000011973 solid acid Substances 0.000 description 1
- -1 triacetin ester compounds Chemical class 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
This hair discloses a kind of supporting iridium catalyst and preparation method for Bisphenol F and esterification, and prepared composite load benzoxazole iridium hydrotalcite catalyst is synthesized by following two classes iridium complex.Wherein hydrotalcite supports (layer dihydroxy complex hydroxide) have the characteristics that the adjustable denaturation of the Modulatory character of the Nomenclature Composition and Structure of Complexes, acid-base property and the adjustable denaturation that interacts, it is considered as the splendid carrier of nanometer iridium, this catalyst has very high heat endurance and catalytic activity, is advantageous to catalyze and synthesize Bisphenol F and esterification.And convenient recovery, reduce production cost, it is expected to as the cleaning procedure route of great competitiveness.
Description
Technical field
The present invention relates to a kind of supporting iridium catalyst and preparation method for Bisphenol F and esterification, this catalyst
With very high heat endurance and catalytic activity, be advantageous to catalyze and synthesize Bisphenol F and convenient recovery, simultaneously for Bisphenol F
Synthetic reaction and esterification also show good property.
Background technology
Hydrotalcite is ion functional's clay that a kind of interlayer ion has interchangeability.Due to hydrotalcite layered structure
Particularity, show the special properties such as adjustable denaturation and interchangeability, the alkalescence of ion.These unique structures of hydrotalcite
Property, a kind of supported materials for having and there is very big application potential are become, it is of increased attention with applying.Mesh
Before, hydrotalcite material has in catalysis, biology, environmental protection, additive, medicine and functional high molecule material etc. widely should
With., can be by some metal iridiums using the interchangeability of hydrotalcite layers anion and the high activity of metal iridium complex catalyst
Complex catalyst is inserted into hydrotalcite layers, and the iridium supported catalyst being prepared not only has higher catalytic activity, and
Catalyst is easily isolated after completion of the reaction, avoids such iridium catalyst and product purity is impacted, it also avoid simultaneously
Heavy metal pollution is caused to environment.The eka-iridium supported catalyst also has very high heat endurance, still has after recycled for multiple times
There is very high activity.
Bisphenol F and triacetin ester compounds are all high added value products, their synthesis mainly using strong acid or
Solid acid catalyst, the problems such as environmental pollution cost is high be present.Also bring along serious equipment corrosion problem.Therefore, find
Catalyst can be replaced to have become current research and the focus of exploitation.
In order to solve the above problems, based on the present invention is using hydrotalcite and two metal iridium compounds, it is prepared for compound
Benzoxazole iridium hydrotalcite catalyst is loaded, for catalyzing and synthesizing Bisphenol F and acetin, the method has not yet to see report.
The content of the invention
The invention discloses a kind of supporting iridium catalyst and preparation method for Bisphenol F and esterification.Ours
Found in research, this composite catalyst is advantageous to catalyzing and synthesizing for Bisphenol F and acetin.
The technical scheme provided according to invention, prepared composite load benzoxazole iridium hydrotalcite catalyst is by following
The synthesis of two class iridium complexs：
The invention provides a kind of supporting iridium catalyst and preparation method for Bisphenol F and esterification, specific and conjunction
It is as follows into step:
(1) solvent-thermal method is first used, by benzoxazole part and iridous chloride with 1:1~30:1 ratio is dissolved in 1:1
~30:In the ethylene glycol ethyl ether of 1 ratio and the mixed solution of water, 25~500 DEG C are stirred and heated under special gas protection, stirring
After 1~48h, suction filtration obtains iridium complex BO.By BO and PEt3With 1:1~1:20 ratio is blended in absolute ethyl alcohol and the tert-butyl alcohol
In the mixed solvent, stir 4~12h at room temperature, heat 2~12h with reactor at 50~110 DEG C, centrifugal drying produced
Thing BOP.
(2) by BO and hydrotalcite (HT) 1:1~1:20 ratio is blended in deionized water, absolute ethyl alcohol and the tert-butyl alcohol it is mixed
In bonding solvent, 1~48h is stirred at room temperature, 1~72h is heated with reactor at 20~500 DEG C, and centrifugal drying obtains product BO@
HT。
(3) by BOP and BO@HT with 1:1~1:30 ratio is blended in deionized water, the mixing of absolute ethyl alcohol and the tert-butyl alcohol
In solvent, 1~48h is stirred at room temperature, 1~72h is heated with reactor at 20~600 DEG C, and centrifugal drying obtains product BO@
BOP@HT。
Further, the special gas in above-mentioned steps (1) are carried out under the protection of such as nitrogen, argon gas etc..
Further, in above-mentioned steps, programming rate is 0.1~10 DEG C/min.
Above-mentioned composite load iridium catalyst BO@BOP@HT Bisphenol F applications, it is characterised in that：By 4g phenol, 1g NEW TYPE OF COMPOSITEs
Iridium catalyst is added in 10mL dimethylbenzene, is stirred at room temperature, then be slowly added dropwise 1：1 10% HCl and 37% formalin 4mL
Mixed solution, 100 DEG C are heated to, react 2h.Then by resulting reacting liquid filtering, catalyst is reclaimed.The liquid being filtrated to get
Body is crude product.Gained crude product by rotating recycling design, being evaporated under reduced pressure and reclaim remaining phenol, remaining product is used back
The solvent recrystallization of receipts once, obtains Bisphenol F.
The application of above-mentioned composite load iridium catalyst BO@BOP@HT catalyzing glycerols and acid esterification reaction, it is characterised in that：
By glycerine and acetic acid according to molar ratio of alcohol to acid 1:2~1:7 add in reactor, and it is anti-to add 30~50mL toluene and quality
The composite load iridium catalyst BO@BOP@HT of the 0.6~5% of thing gross mass are answered, are 100 DEG C~140 DEG C in reaction temperature, backflow
Divide water, 2~8h of stirring reaction, obtain the mixture containing acetin.
Brief description of the drawings
Composite load iridium catalyst BO BOP HT prepared by Fig. 1 present invention ESEM collection of illustrative plates.
Embodiment
The composite of this modification provided by the invention can significantly improving Bisphenol F and triacetin Lipase absobed production
Rate, and the preparation technology of catalyst is simple, it is green.
Hereinafter, applicant has done specific experiment to the present invention.These are only used for elaborating the present invention, not with any side
The scope of formula limitation invention.
Embodiment one：A kind of supporting iridium catalyst and preparation method for Bisphenol F and esterification, including following technique
Step：
(1) solvent-thermal method is first used, by benzoxazole part and iridous chloride with 1:1 ratio is dissolved in 1:1 ratio
In the mixed solution of ethylene glycol ethyl ether and water, 25~500 DEG C are stirred and heated under special gas protection, after stirring 48h, is filtered
To iridium complex BO.By BO and PEt3With 1:1 ratio is blended in the in the mixed solvent of absolute ethyl alcohol and the tert-butyl alcohol, stirs at room temperature
4h is mixed, 12h is heated with reactor at 110 DEG C, centrifugal drying obtains product BOP.
(2) by BO and hydrotalcite (HT) 1:20 ratio is blended in deionized water, and the mixing of absolute ethyl alcohol and the tert-butyl alcohol is molten
In agent, 24h is stirred at room temperature, 48h is heated with reactor at 400 DEG C, and centrifugal drying obtains product BO@HT.
(3) by BOP and BO@HT with 1:30 ratio is blended in the mixed solvent of deionized water, absolute ethyl alcohol and the tert-butyl alcohol
In, 48h is stirred at room temperature, 12h is heated with reactor at 400 DEG C, and centrifugal drying obtains product BO@BOP@HT.
Embodiment two：A kind of supporting iridium catalyst and preparation method for Bisphenol F and esterification, including following technique
Step：
(1) solvent-thermal method is first used, by benzoxazole part and iridous chloride with 1:2 ratio is dissolved in 1:2 ratios
In the mixed solution of ethylene glycol ethyl ether and water, 25~500 DEG C are stirred and heated under special gas protection, after stirring 36h, is filtered
To iridium complex BO.By BO and PEt3With 1:1 ratio is blended in the in the mixed solvent of absolute ethyl alcohol and the tert-butyl alcohol, stirs at room temperature
4h is mixed, 12h is heated with reactor at 110 DEG C, centrifugal drying obtains product BOP.
(2) by BO and hydrotalcite (HT) 1:20 ratio is blended in deionized water, and the mixing of absolute ethyl alcohol and the tert-butyl alcohol is molten
In agent, 24h is stirred at room temperature, 36h is heated with reactor at 300 DEG C, and centrifugal drying obtains product BO@HT.
(3) by BOP and BO@HT with 1:20 ratio is blended in the mixed solvent of deionized water, absolute ethyl alcohol and the tert-butyl alcohol
In, 36h is stirred at room temperature, 12h is heated with reactor at 300 DEG C, and centrifugal drying obtains product BO@BOP@HT.
Embodiment three：4g phenol, 1g NEW TYPE OF COMPOSITEs iridium catalyst are added in 10mL dimethylbenzene, stirred at room temperature, then delay
It is slow to be added dropwise 1：1 10% HCl and 37% formalin 4mL mixed solutions, 100 DEG C are heated to, react 2h.Then by obtained by
Reacting liquid filtering, reclaim catalyst.The liquid being filtrated to get is crude product.Gained crude product by rotate recycling design,
It is evaporated under reduced pressure and reclaims remaining phenol, remaining product is recrystallized once with recovered solvent, obtains Bisphenol F.Yield is 86%
Example IV：In 250mL round-bottomed flasks, 0.1mol glycerine, 0.6mol acetic acid and 40mL toluene are added, is added
0.3g catalyst BO@BOP@HT, it is 110 DEG C in reaction temperature, reflux water-dividing, stirring reaction 2h, through chromatography, glycerine turns
Rate is 99%, and the selectivity of diacetine is 83%, and the selectivity of glyceryl triacetate is 14%.
Embodiment five：Composite load iridium catalyst BO@BOP@HT recycling：
In 250mL round-bottomed flasks, 0.1mol glycerine, 0.6mol acetic acid and 40mL toluene are added, adds returning for 0.3g
The catalyst BO@BOP@HT of receipts, it is 110 DEG C in reaction temperature, reflux water-dividing, stirring reaction 2h, through chromatography, glycerine conversion
Rate is 99%, and the selectivity of diacetine is 83%, and the selectivity of glyceryl triacetate is 13%.
Claims (3)
1. the invention discloses a kind of supporting iridium catalyst and preparation method for Bisphenol F and esterification；
The technical scheme provided according to invention, prepared composite load benzoxazole iridium hydrotalcite catalyst is by following two class
Iridium complex synthesis：
The invention provides a kind of supporting iridium catalyst and preparation method for Bisphenol F and esterification, specific and synthesis step
It is rapid as follows:
(1) solvent-thermal method is first used, by benzoxazole part and iridous chloride with 1:1~30:1 ratio is dissolved in 1:1~30:
In the ethylene glycol ethyl ether of 1 ratio and the mixed solution of water, 25~500 DEG C are stirred and heated under special gas protection, stirring 1~
After 48h, suction filtration obtains iridium complex BO；By BO and PEt3With 1:1~1:20 ratio is blended in absolute ethyl alcohol and the tert-butyl alcohol
In the mixed solvent, 4~12h being stirred at room temperature, 2~12h being heated with reactor at 50~110 DEG C, centrifugal drying obtains product
BOP。
(2) by BO and hydrotalcite (HT) 1:1~1:20 ratio is blended in deionized water, and the mixing of absolute ethyl alcohol and the tert-butyl alcohol is molten
In agent, 1~48h is stirred at room temperature, 1~72h is heated with reactor at 20~500 DEG C, and centrifugal drying obtains product BO@HT.
(3) by BOP and BO@HT with 1:1~1:30 ratio is blended in the mixed solvent of deionized water, absolute ethyl alcohol and the tert-butyl alcohol
In, 1~48h is stirred at room temperature, 1~72h is heated with reactor at 20~600 DEG C, and centrifugal drying obtains product BO@BOP@
HT；
Further, the special gas in above-mentioned steps (1) are carried out under the protection of such as nitrogen, argon gas etc.；
Further, in above-mentioned steps, programming rate is 0.1~10 DEG C/min.
2. above-mentioned composite load iridium catalyst BO@BOP@HT Bisphenol F applications, it is characterised in that：By 4g phenol, 1g NEW TYPE OF COMPOSITE iridium
Catalyst is added in 10mL dimethylbenzene, is stirred at room temperature, then be slowly added dropwise 1：1 10% HCl and 37% formalin 4mL is mixed
Solution is closed, is heated to 100 DEG C, reacts 2h.Then by resulting reacting liquid filtering, catalyst is reclaimed；The liquid being filtrated to get
For crude product；Gained crude product by rotating recycling design, being evaporated under reduced pressure and reclaim remaining phenol, remaining product recovery
Solvent recrystallization once, obtain Bisphenol F.
3. above-mentioned composite load iridium catalyst BO@BOP@HT catalyzing glycerols and the application of acid esterification reaction, it is characterised in that：Will
Glycerine and acetic acid are according to molar ratio of alcohol to acid 1:2~1:7 add in reactor, and toluene and the quality for adding 30~50mL are reaction
The composite load iridium catalyst BO@BOP@HT of the 0.6~5% of thing gross mass, it is 100 DEG C~140 DEG C in reaction temperature, backflow point
Water, 2~8h of stirring reaction, obtain the mixture containing acetin.
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Cited By (3)
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|---|---|---|---|---|
| CN111974457A (en) * | 2020-08-31 | 2020-11-24 | 江南大学 | Catalyst for synthesizing substituted ketone compound and preparation method thereof |
| CN112169842A (en) * | 2020-10-27 | 2021-01-05 | 江南大学 | Novel efficient supported Au/GO catalyst and preparation method and application thereof |
| CN115193479A (en) * | 2021-04-27 | 2022-10-18 | 江南大学 | PBS microsphere loaded metal iridium catalyst, preparation method and application |
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| CN112169842A (en) * | 2020-10-27 | 2021-01-05 | 江南大学 | Novel efficient supported Au/GO catalyst and preparation method and application thereof |
| CN115193479A (en) * | 2021-04-27 | 2022-10-18 | 江南大学 | PBS microsphere loaded metal iridium catalyst, preparation method and application |
| CN115193479B (en) * | 2021-04-27 | 2023-10-27 | 江南大学 | PBS microsphere supported metal iridium catalyst and preparation method and application thereof |
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