CN1075506A - Solid detergent for tableware - Google Patents
Solid detergent for tableware Download PDFInfo
- Publication number
- CN1075506A CN1075506A CN 93110920 CN93110920A CN1075506A CN 1075506 A CN1075506 A CN 1075506A CN 93110920 CN93110920 CN 93110920 CN 93110920 A CN93110920 A CN 93110920A CN 1075506 A CN1075506 A CN 1075506A
- Authority
- CN
- China
- Prior art keywords
- detergent
- washing
- surface active
- composition
- active ingredient
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000013042 solid detergent Substances 0.000 title description 2
- 239000003599 detergent Substances 0.000 claims abstract description 21
- 150000004702 methyl esters Chemical class 0.000 claims abstract description 8
- 239000000344 soap Substances 0.000 claims abstract description 8
- 239000000843 powder Substances 0.000 claims abstract description 6
- 239000007787 solid Substances 0.000 claims abstract description 4
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910052806 inorganic carbonate Inorganic materials 0.000 claims abstract 2
- 238000005406 washing Methods 0.000 claims description 25
- 239000000203 mixture Substances 0.000 claims description 20
- 238000004851 dishwashing Methods 0.000 claims description 9
- 239000004480 active ingredient Substances 0.000 claims description 5
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 3
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 3
- 239000004615 ingredient Substances 0.000 claims description 3
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 2
- 239000008187 granular material Substances 0.000 claims 1
- 150000003016 phosphoric acids Chemical class 0.000 claims 1
- 230000001954 sterilising effect Effects 0.000 abstract description 10
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 2
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- 239000000654 additive Substances 0.000 abstract 1
- 229920003063 hydroxymethyl cellulose Polymers 0.000 abstract 1
- 229940031574 hydroxymethyl cellulose Drugs 0.000 abstract 1
- 239000002736 nonionic surfactant Substances 0.000 abstract 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract 1
- 239000010452 phosphate Substances 0.000 abstract 1
- 239000011780 sodium chloride Substances 0.000 abstract 1
- -1 Starso Chemical compound 0.000 description 9
- 238000004659 sterilization and disinfection Methods 0.000 description 9
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical class [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 239000013543 active substance Substances 0.000 description 5
- 230000002421 anti-septic effect Effects 0.000 description 5
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 230000015556 catabolic process Effects 0.000 description 4
- 238000006731 degradation reaction Methods 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 235000019832 sodium triphosphate Nutrition 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- 101710194948 Protein phosphatase PhpP Proteins 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 125000005907 alkyl ester group Chemical group 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 229910017053 inorganic salt Inorganic materials 0.000 description 2
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 2
- 235000019353 potassium silicate Nutrition 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 235000017550 sodium carbonate Nutrition 0.000 description 2
- 239000001488 sodium phosphate Substances 0.000 description 2
- 229910000162 sodium phosphate Inorganic materials 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 208000036142 Viral infection Diseases 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 239000004064 cosurfactant Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000004665 fatty acids Chemical group 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 235000012054 meals Nutrition 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 235000011008 sodium phosphates Nutrition 0.000 description 1
- 239000003206 sterilizing agent Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000271 synthetic detergent Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
The invention provides a solid tableware detergent, which is prepared from the conventional detergent assistants such as inorganic carbonate, phosphate, silicate, sulfuric acid and hydroxymethyl cellulose and other additives, wherein the surface active component is prepared by combining Methyl Ester Sulfonate (MES) and soap powder, and a small amount of nonionic surfactant is preferably added. The solid tableware detergent has excellent greasy and greasy dirt removing performance, and can raise the sterilizing activity of sodium chloride, etc.
Description
What the present invention relates to is a kind of washing composition of solid granular, particularly can be used for the washing composition of dishwashing detergent.
Many kinds such as that though the proterties of washing composition has is solid-state, liquid, pastes, liquid a kind of as having only at present of using of the tool washing of can serving the meals, for storage, transportation waits all many inconvenience.And, be difficult to be used, so liquid tableware detergent has only washing more and does not have the sterilization effect because antiseptic sterilization agents such as chlorinated sodium phosphate easily decompose in liquid, and easy again crystallization was separated out after temperature reduced.
As washing composition, no matter how are its proterties or Application Areas, during it is formed, remove the yellow soda ash that all will use usually, sodium phosphate, tripoly phosphate sodium STPP, water glass, Starso, sodium sulfate, Tai-Ace S 150, washing auxiliary detergent and sterilizing agents (as chlorinated sodium phosphate) such as plurality of inorganic salt such as zeolite and carboxymethyl cellulose, float agent in vain, white dyes, outside the different added ingredientss such as enzyme, the surface active ingredient class important component that is absolutely necessary, wherein alkylbenzene sulfonate is to use the most extensively and the maximum a kind of anion surfactant of consumption, as documents such as Chinese patent 89101795.X and 90105835.1 related all be to use this kind tensio-active agent.But because the biological degradation of this tensio-active agent is incomplete, and has certain toxic action to human body, thereby it can not be applied in the dish washing detergent.
Alkyl ester sulfonate, for example methyl ester sulfonate does not then exist degradation rate problem and toxic action as a kind of tensio-active agent of natural origin composition.It as tensio-active agent by should be in washing composition, many because of the former of some aspect of performance thereby limited use.As just having pointed out it at cleaning performance in the Chinese patent 91109862.3, particularly unsatisfactory in the scope of removing greasy/oil, even when being used in combination with cosurfactant such as alkyl ethoxy compound, also be like this.The document and proposed for this reason a kind of with alkyl ester sulfonate with contain the detergent composition of polyhydrony fatty acid acyl by the combined form of derivative.From commercial angle, the polyhydrony fatty acid acyl all is disadvantageous by derivative at aspects such as preparation method and costs thereof.
The object of the present invention is to provide a kind of dishwashing detergent that can be used for, and be the washing composition of solid-state form.
With common washing composition, particularly dish washing detergent is the same, conventional washing auxiliary detergents such as inorganic salt compositions such as yellow soda ash, sodium phosphate, tripoly phosphate sodium STPP, water glass, Starso, sodium sulfate and carboxymethyl cellulose, and the conventional ingredients such as antiseptic sterilization agent such as chlorinated sodium phosphate that table-ware disinfection had special meaning, also be absolutely necessary in washing composition of the present invention, it selects assembly and consumption to handle routinely.Washing composition of the present invention special what propose is the selection of surface active ingredient and the array configuration that use should be methyl ester sulfonate (MES) and soap powder (alkali-metal higher fatty acid salt), its weight in washing composition is 5～20% respectively.On this basis, if think necessary, the nonionogenic tenside that can be used again as polyoxy ethyl ethers is desirable, and its consumption can be the 2-5% of washing composition weight.
Because the biological degradation rate height of methyl ester sulfonate (MES) replaces the not high and virose alkylbenzene sulfonate of biological degradation rate with it, be significant for dish washing detergent face speech, can guarantee safety to human body.It matches with the soap powder that is natural matter equally, has not only guaranteed security, has also improved scourability, particularly removes greasy and the smeary ability.Simultaneously, methyl ester sulfonate also has good dispersion of calcium soap, with soap powder behind the performance complement aspect some such as solvability, detersive power, dispersion of calcium soap, be favourable to the scourability that improves washing composition.The detersive power test-results of doing under the equal conditions with at present commercially available liquid dishwashing detergent (Chengdu Synthetic Detergent Plant production) sees Table 1.Thus test-results as can be seen the average detersive power of washing composition of the present invention improved about 2.6 times.
Because dish washing detergent of the present invention is a solid-state form, therefore provide favourable condition for the chlorinated sodium phosphate that adds as antiseptic sterilization agent.Test-results also demonstrates simultaneously, after in having adopted above-mentioned compositional system of the present invention, adding chlorinated sodium phosphate, its minimum sterilization concentration can be reduced to 10ppm by the 50ppm of independent use chlorinated sodium phosphate, and stability improves during also than independent use greatly, this compositional system that shows that the present invention washs also has the characteristics of obvious raising chlorinated sodium phosphate sterilizing activity, washing, sterilization are once finished simultaneously, and the usage quantity that can save antiseptic sterilization agent greatly, be superior to the liquid tableware detergent that only has washing function at present greatly.
In above-mentioned methyl ester sulfonate (MES),, there is no the influence of essence from actual environment for use and condition though the carbon number difference of its fatty acid chain has some cross one another otherness to aspects such as detersive power, foam height and anti-performance of hard water.And from the source difficulty or ease and the economic angle of natural matter, with the carbochain of C12～C18, especially the lipid acid with the most common C16～C18 that is easy to get is desirable.
The preparation of washing composition of the present invention after can be earlier the carbonate in MES and the washing auxiliary detergent and an amount of water being mixed, adds soap powder and other washing auxiliary detergent mixes again, adds added ingredientss such as antiseptic sterilization agent at last, promptly may be molded to the finished product behind the stirring reaction.
Below introduce some examples of the present invention, but scope of the present invention is not limited only to these examples.Methyl ester sulfonate in the example is C16～C18 fatty acid ester commonly used.Each example composition sees Table 2, and each amounts of components is weight % in the table.TX-10 in the table is the NONYL PHENOL POLYOXYETHYLENE tensio-active agent.
Claims (2)
1, a kind of dish washing detergent that includes surface active ingredient, reaches suitable added ingredients in case of necessity with inorganic carbonate, phosphoric acid salt, silicate, vitriol and carboxymethyl cellulose as washing auxiliary detergent, it is characterized in that the surface active ingredient in the composition is (weight %) methyl ester sulfonate (MES) 5～20%, soap powder 5～20%, all the other are conventional washing auxiliary detergent and added ingredients, and washing composition is the solid granulates shape.
2, dish washing detergent as claimed in claim 1 is characterized in that also being added with 2～5%(weight in the said surface active ingredient) nonionogenic tenside.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 93110920 CN1075506A (en) | 1993-03-25 | 1993-03-25 | Solid detergent for tableware |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 93110920 CN1075506A (en) | 1993-03-25 | 1993-03-25 | Solid detergent for tableware |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1075506A true CN1075506A (en) | 1993-08-25 |
Family
ID=4988736
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 93110920 Pending CN1075506A (en) | 1993-03-25 | 1993-03-25 | Solid detergent for tableware |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1075506A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1107111C (en) * | 1996-01-25 | 2003-04-30 | 尤尼利弗公司 | Detergent composition |
| CN105754769A (en) * | 2016-03-16 | 2016-07-13 | 丰益油脂科技有限公司 | Soap grain, preparation method thereof and laundry soap prepared by soap grain |
| CN106381247A (en) * | 2015-12-07 | 2017-02-08 | 蒋宏凯 | Cleaning agent and preparation method thereof |
-
1993
- 1993-03-25 CN CN 93110920 patent/CN1075506A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1107111C (en) * | 1996-01-25 | 2003-04-30 | 尤尼利弗公司 | Detergent composition |
| CN106381247A (en) * | 2015-12-07 | 2017-02-08 | 蒋宏凯 | Cleaning agent and preparation method thereof |
| CN105754769A (en) * | 2016-03-16 | 2016-07-13 | 丰益油脂科技有限公司 | Soap grain, preparation method thereof and laundry soap prepared by soap grain |
| CN105754769B (en) * | 2016-03-16 | 2017-11-10 | 丰益油脂科技有限公司 | A kind of neat soap and preparation method thereof and the laundry soap being prepared with it |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication |