CN107537695A - A kind of method for improving complex lead zinc ores metal recovery rate - Google Patents
A kind of method for improving complex lead zinc ores metal recovery rate Download PDFInfo
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- CN107537695A CN107537695A CN201710689693.3A CN201710689693A CN107537695A CN 107537695 A CN107537695 A CN 107537695A CN 201710689693 A CN201710689693 A CN 201710689693A CN 107537695 A CN107537695 A CN 107537695A
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Abstract
Provide a kind of lead-zinc ore floating flow and regime of agent, it is therefore an objective to solve the low problem of the Pb-Zn deposits rate of recovery.The raising Pb-Zn deposits rate of recovery refers to that raw ore is complicated, granularity is uneven, the high Pb-Zn deposits of oxygenation efficiency.Choosing, administering drug combinations etc. are mixed to reclaim mineral by stage grinding, the fast choosing of substep and oxygen sulphur.The fast choosing of stage grinding, substep, had both reclaimed particulate lead in lead is selected, and reduced coarse grain lead internal circulating load again;Thick first groove of zinc is directly gone out into product, other foams enter essence 2, and former essence 1 had not only ensured concentrate grade but also improved the rate of recovery as cleaner scavenger;Oxidating chemicals recovery oxide ore is added scanning.The invention provides a whole set of lead-zinc ore floating flow and regime of agent, can effectively improve containing mud height, high oxidation, the unequal Pb-Zn deposits metal recovery rate of granularity thickness.
Description
Technical field
The present invention relates to a kind of method for floating, more particularly to a kind of method for improving the complex lead zinc ores rate of recovery.
Background technology
According to statistics, Mineral Resources in China overall recovery only has 50% or so, altogether the comprehensive utilization ratio of (companion) raw mineral resources
Less than 40%, mineral resources overall recovery has differed 20 to 30 percentage points with foreign countries.China is developing country, and population is many
More, the per capita ownership of many important mineral resources and water resource is far below world's per capita share, and imbalance between supply and demand protrudes, severe
Situation be impermissible for China's mining industry and continue to walk the experienced road of waste of resource adverse condition, and sustainable development path must be walked, this
Key therein is exactly to improve the comprehensive utilization ratio of mineral resources and water resource, reduces destruction of the Mining Development to ecological environment,
This is also the needs of national economy sustainable development.
Lead for China, Zn Cr coating pass through the construction and development of more than 60 years, have been formed than more complete industrial system, have had phase
When the material base of scale.According to statistics, Chinese lead and zinc concentrate yield in 2016 reaches 7,000,000 tons, accounts for global total output
More than 40%.China turns into International Lead, zinc major producing country and country of consumption.At the same time, industry is thrown in technological progress, industry
The diversification of money main body, enterprise implement go-global strategy etc. all achieve prominent achievement, in recent years, due to lead, zinc smelting
Enterprise's production capacity overdistension is refined, causes raw materials requirement amount to surge.China is changed into net importer from lead, zinc raw material net exporter.
Particularly large-scale key smelting enterprise is to the interdependency more and more higher of external lead, zinc concentrate, and there is lack of raw materials has become system for lead zinc
The about bottleneck of Lead for China Zn Cr coating sustainable development.
From the point of view of the consumption in China, Lead for China, the zinc deficiency and excess coming years will appear from the situation that supply falls short of demand.
With lasting increase of the China to the demand of non-ferrous metal, it is available for the high-quality Pb-Zn deposits of exploitation fewer and fewer, only
The complicated mine of recovery lean ore, oxide ore, structure construction can progressively be exploited.Traditional beneficiation method is difficult processing to such raw ore
And recovery, the wasting of resources is caused, is badly in need of handling such ore using the flow and regime of agent of optimization.
The content of the invention
The deficiency of actual and existing flotation technology is exploited for complex lead zinc ores, the present invention is mainly just to provide one kind and carried
The method of high complex lead zinc ores flotation recovery rate.Mainly following methods and the step taken:
(1) by raw ore ore, the target mineral monomer cleavage of the embedding cloth of coarse grain is ground to by primary grinding;
(2) by cleavage and the lead-zinc sulfide ore thing of the fast embedding cloth of coarse grain of ascent rate, according to roughing froth pulp
Grade and flexibly determine directly to go out concentrate product containing miscellaneous situation, be also into and selected a certain sort section;
(3) the slow lead-zinc sulfide ore of ascent rate and part and the oxide ore order of sulphide ore adhesion are entered into selected stream
Journey;
(4) the thin and traditional sulfide flotation medicament of those disseminated grain sizes effectively the oxygen of flotation recovery, sulphur can not be mixed
Ore deposit is reclaimed by the method for administering drug combinations (adding oxide ore and sulfide flotation medicament simultaneously in proportion);
(5) froth pulp of step (4) is entered into cleaning technological flowasheet after secondary grinding;
(6) secondary grinding of step (5) is divided according to difference of the raw ore fine-grained disseminated grain partial target mineral between individual grade
Regrinded for open circuit and regrind two kinds with closed circuit.
The floatation process method of the present invention, compared to existing traditional handicraft, has following major advantage:
(1) ore different to disseminated grain size in same ore, by ore grinding twice, progressively cleavage can both reduce ore grinding energy
Consumption, and can prevent overground and argillization;
(2) concentration times of different foam product are determined according to the difference of flotation speed, middling cycle amount can be reduced, carried
High-recovery;
(3) by scanning combine add oxide ore flotation medicament, can partially recycled oxide ore, can synthetical recovery oxidation
Sulphide ore and oxide ore of the rate in 15% or so lead zine ores.
(4) lead zinc recovery can be greatly improved 5-10 percentage points by the method for floating of this technique, produce good economy
Benefit.
Brief description of the drawings
Fig. 1 show conventional process flow.
Fig. 2 show the technological process that the present invention uses.
Embodiment
The present invention enters in places such as the gloomy Mining Limited Company lead zinc-silver polymetallic ores of Inner Mongol Zalantun City state
Implementation is gone, specific embodiment is as follows.
Embodiment 1:
The gloomy Mining Limited Company lead zinc-silver polymetallic ore of Inner Mongol Zalantun City state, raw ore primary grinding to -200 mesh
55% or so is accounted for, after lead roughing is by adding sulphide ore beneficiation reagent under the conditions of basicity in, the froth pulp of the first groove contains
Lead more than 40%, containing zinc 15% or so, they are directly entered selected 3 flow;The froth pulp of its excess-three groove of roughing enters
Selected 1 flow.The Floatation Concentrate Grade of galena had so both been ensure that, has improved the rate of recovery again.
Embodiment 2:
Inner Mongol Zalantun City state gloomy Mining Limited Company lead zinc-silver polymetallic ore is thick in lead in lead Beneficiation flowsheet
Select and (scan 1) in mine tailing gate case while add sulphide ore and efficient oxidation ore deposit collecting agent, what is obtained scans 1 froth pulp warp
Enter selected 1 flow after regrinding;Scan 2 and scan 3 and also add chats product order after sulphide ore and efficient oxidation ore deposit collecting agent
Return.So, the vulcanized lead of thin had not only been reclaimed but also partially recycled lead oxide.
Embodiment 3:
Flow is regrinded in embodiment 2, according to raw ore situation of change:Regrinded when scanning when clay content is more in 1 froth pulp
Use open circuit flow;Otherwise regrind and use closed circuit flow.Can so solve clay content it is more when it is selected fall groove, concentrate product grade
The problems such as relatively low.
Embodiment 4:
The gloomy Mining Limited Company mine of Inner Mongol Zalantun City state is has an opencast mining of, and poor under richness on ore body, zinc supplies ore deposit
Grade is high, and zinc roughing the first groove froth pulp is best in quality, better than the zinc concentrate and other initial separatory cell foams of selected operation output
Product.Again because the disseminated grain size of zinc mineral is thick, ascent rate is fast, selected can reach production marketing quality through 3 times and (is designed as
4 times are selected), for case above, carry out following transformation:The groove of zinc roughing first directly goes out product;The foam of the other grooves of roughing
Product enters selected 2, and original selected 1 scans use as selected.By above method, solves zinc in high-grade Pb-Zn-Ag ore
In the case of head grade 8-14%, problem is altered after the zinc flotation flowsheet amount of suppressing, mine tailing.Under the premise of concentrate grade is ensured, improve
Zinc metal recovery rate and ore dressing treating capacity.
Embodiment 5:
The gloomy Mining Limited Company lead zinc-silver polymetallic ore of Inner Mongol Zalantun City state, in zinc Beneficiation flowsheet, swept in zinc
Choose at the same add sulphide ore and efficient oxidation ore deposit collecting agent after chats product order return.So, not only reclaimed zinc sulphide but also
Partially recycled zinc oxide.
Finally, gloomy Mining Limited Company lead zinc-silver ore-dressing of polymetallic ore factory of Inner Mongol Zalantun City state is invented using this
The rate of recovery improves 10% or so after method.
Claims (4)
- A kind of 1. method for improving complex lead zinc ores metal recovery rate, it is characterised in that flotation flowsheet structure and regime of agent bag Include:(1) by raw ore ore, the target mineral monomer cleavage of the embedding cloth of coarse grain is ground to by primary grinding;(2) by cleavage and the lead-zinc sulfide ore thing of the fast embedding cloth of coarse grain of ascent rate, according to the grade of roughing froth pulp Flexibly determine directly to go out concentrate product with containing miscellaneous situation, be also into and selected a certain sort section;(3) the slow lead-zinc sulfide ore of ascent rate and part and the oxide ore order of sulphide ore adhesion are entered into cleaning technological flowasheet;(4) by the thin and traditional sulfide flotation medicament of those disseminated grain sizes can not effectively the oxygen of flotation recovery, sulphur composite ore leads to Cross the method recovery of administering drug combinations (in proportion while add oxide ore and sulfide flotation medicament);(5) froth pulp of step (4) is entered into cleaning technological flowasheet after secondary grinding;(6) secondary grinding of step (5) is divided into out according to difference of the raw ore fine-grained disseminated grain partial target mineral between individual grade Road is regrinded regrinds two kinds with closed circuit.
- 2. a kind of method for improving complex lead zinc ores metal recovery rate according to claim 1, it is characterised in that lead is thick First groove bubble washes one's hair the pulp-absorbing pipe that concentrate is directly entered lead essence 2 (or essence 3) flotation device;Other roughing froth pulps enter selected 1;Sweep 1 middling ore regrinding, and flow targetedly using open circuit or closed circuit is regrinded according to the difference of raw ore clay content;Scan while add Oxide ore and sulfide flotation medicament.
- 3. a kind of method for improving complex lead zinc ores metal recovery rate according to claim 1, it is characterised in that zinc is thick The first groove is selected directly to go out product;Other 4 groove froth concentrates enter selected 2 or selected 3 flotation devices according to the change of head grade Pulp-absorbing pipe;In scanning while add the floating agent of sulphide ore and oxide ore.
- 4. a kind of method for improving complex lead zinc ores metal recovery rate according to claim 1, it is characterised in that lead zinc is former Ore deposit is that structure construction is complicated, disseminated grain size thickness is uneven, head grade is high, the Pb-Zn deposits that clay content is big, oxygenation efficiency is high.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109482361A (en) * | 2018-12-12 | 2019-03-19 | 北京矿冶科技集团有限公司 | A kind of method that lead-zinc sulphur oxygen synchronizes flotation |
CN113304888A (en) * | 2021-05-26 | 2021-08-27 | 广西中金岭南矿业有限责任公司 | Speed-division flotation process for sphalerite |
CN113731638A (en) * | 2021-07-27 | 2021-12-03 | 甘肃省合作早子沟金矿有限责任公司 | Method for improving gold separation recovery rate of ore by regrinding middling |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109482361A (en) * | 2018-12-12 | 2019-03-19 | 北京矿冶科技集团有限公司 | A kind of method that lead-zinc sulphur oxygen synchronizes flotation |
CN113304888A (en) * | 2021-05-26 | 2021-08-27 | 广西中金岭南矿业有限责任公司 | Speed-division flotation process for sphalerite |
CN113731638A (en) * | 2021-07-27 | 2021-12-03 | 甘肃省合作早子沟金矿有限责任公司 | Method for improving gold separation recovery rate of ore by regrinding middling |
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Application publication date: 20180105 |