CN107537313A - Except formaldehyde coating method and its obtained remove formaldehyde filter - Google Patents

Except formaldehyde coating method and its obtained remove formaldehyde filter Download PDF

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Publication number
CN107537313A
CN107537313A CN201610770932.3A CN201610770932A CN107537313A CN 107537313 A CN107537313 A CN 107537313A CN 201610770932 A CN201610770932 A CN 201610770932A CN 107537313 A CN107537313 A CN 107537313A
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China
Prior art keywords
catalyst
formaldehyde
coating
except
fixed bed
Prior art date
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Pending
Application number
CN201610770932.3A
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Chinese (zh)
Inventor
黎超明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangdong Sail Decoration Engineering Co Ltd
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Guangdong Sail Decoration Engineering Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by Guangdong Sail Decoration Engineering Co Ltd filed Critical Guangdong Sail Decoration Engineering Co Ltd
Priority to CN201610770932.3A priority Critical patent/CN107537313A/en
Publication of CN107537313A publication Critical patent/CN107537313A/en
Pending legal-status Critical Current

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  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)

Abstract

The invention discloses a kind of method except formaldehyde coating and its obtained remove formaldehyde filter, set on carrier and remove formaldehyde catalyst coating and catalyst fixed bed, catalyst fixed bed is arranged on catalyst coat outer layer, catalyst fixed bed will be fixed well except formaldehyde catalyst coating, prevent it from coming off, and avoid catalyst exposure and absorb moisture content in atmosphere, reduce the activity of catalyst;Catalyst fixed bed will not will remove formaldehyde catalyst coating covering parcel simultaneously, ensure that the effect except formaldehyde.

Description

Except formaldehyde coating method and its obtained remove formaldehyde filter
Technical field
The present invention relates to be made except formaldehyde process, especially a kind of method and application this method except formaldehyde coating Remove formaldehyde filter.
Background technology
Current air-conditioning, the performance of air purifier have strict antibacterial, purification to require that air conditioner filter has certain Can stamp the mark of " purification air-conditioning " except the function of formaldehyde, air-conditioning;After standard appearance, the State Bureau of Quality Supervision is in the market " purification " electrical equipment is spot-check, and testing result shows that " purification air-conditioning " of multiple brands is unable to reach the requirement of national standard, has Functional circuit be that the filter of prestowage has certain function of removing formaldehyde, but the performance of functional circuit complete machine is joined with Standard Number greatly differs from each other, or even the functional circuit having has no function of removing formaldehyde and can sayed, it is necessary to develop new purification techniques to make complete machine Purification function meets the requirement of national standard.
In addition, prior art removes formaldehyde catalyst coating, when making in order to play the effect of catalyst to greatest extent, The adhesive ratio of addition is less, and catalyst coat can come off in use, filter is reduced except formaldehyde performance, and urge Agent exposes in atmosphere the moisture content in easily absorption air, greatly reduces the activity of catalyst;But if add excessively Adhesive, or selection adhesive are improper, and catalyst can be completely wrapped again, can not play the effect of it removes formaldehyde.
The content of the invention
In order to overcome prior art easily to be come off except formaldehyde coating, and moisture content in meeting absorption air, influence remove effect of formaldehyde Deficiency, the invention provides one kind to prevent catalyst coat from coming off, and what catalyst performance can give full play to removes formaldehyde coating Method.
The technical solution adopted for the present invention to solve the technical problems is:
It is a kind of except the method for formaldehyde coating,
One carrier is provided first;
Mixing will be configured in proportion except formaldehyde catalyst coating each component, and be sufficiently stirred;
Except formaldehyde catalyst coating any of spraying, immersion, coating mode will be used to be added to carrier;
It is dried by the way of the one or more combination in natural drying, pneumatic conveying drying, microwave drying or vacuum drying;
Catalyst fixed bed each component is configured into mixing in proportion, and is sufficiently stirred;
Catalyst fixed bed is added to except formaldehyde catalyst coating surface using any of spraying, immersion, coating mode;
Carried out again by the way of the one or more combination in natural drying, pneumatic conveying drying, microwave drying or vacuum drying Dry.
Except formaldehyde catalyst coating by mass percent be 5%-50% except formaldehyde catalyst, 10%-70% adhesive, 0- 2% thickener and water is made, and above-mentioned prescription quality percentage total amount is 100%.
Except formaldehyde catalyst be metal oxide catalyst, noble metal catalyst, one kind in rare-earth metal catalyst or Several combinations.
In order to which what is be optimal removes formaldehyde performance, except formaldehyde catalyst is nm-class catalyst, granularity is 5-100 nanometers.
Adhesive is Aqueous Adhesives and/or inorganic adhesive, in order to be fixedly secured catalyst, and plays urge to greatest extent Agent removes formaldehyde performance, the preferred vinyl acetate class adhesive of Aqueous Adhesives, polyacrylic adhesive, water-based polyurethane Adhesive or neoprene type of latex type adhesive;The preferred Ludox of inorganic adhesive or titanium colloidal sol.
In order to avoid catalyst coat comes off and prevents that catalyst from absorbing the moisture content in excessive air and causes active reduction, Catalyst fixed bed by mass percent be 10%-70% Aqueous Adhesives, 0.1%-1% thickener, 0-1% defoamer, 0- 5% pigment and water is made, and above-mentioned prescription quality percentage total amount is 100%.
In order to allow catalyst surface to be higher than 800mPas by uniform fold, the viscosity of catalyst fixed bed.
The preferred vinyl acetate class adhesive of above-mentioned Aqueous Adhesives, polyacrylic adhesive, water-based polyurethane gluing Agent or neoprene type of latex type adhesive, above-mentioned thickener preferred cellulose class thickener, subtract swelling type catalyst or association type catalysis Agent.
In order to which catalyst coat surface is completely covered, while the performance of catalyst coat is not influenceed again, the catalyst is consolidated The one side addition weight of given layer is 30-200g/m2
A kind of to remove formaldehyde filter except formaldehyde coating process using above-mentioned, filter surfaces are provided with except formaldehyde catalyst Coating, described removing are provided with catalyst fixed bed above formaldehyde catalyst coating.
Described filter is the structure of cellular, tabular, rugosity, one or more combination in corrugated.
The beneficial effects of the invention are as follows:Catalyst fixed bed will be fixed well except formaldehyde catalyst coating, prevent it Come off, and avoid catalyst exposure and absorb moisture content in atmosphere, reduce the activity of catalyst;While catalyst fixed bed is not Formaldehyde catalyst coating covering parcel can will be removed, ensure that the effect except formaldehyde.
Embodiment
Embodiment 1, one kind of the invention remove formaldehyde filter, are set on carrier and remove formaldehyde catalyst coating and catalyst Fixed bed, catalyst fixed bed are arranged on catalyst coat outer layer.
Except formaldehyde catalyst coating composition is:Manganese dioxide 30% that granularity is 50 nanometers, the Platinum Nanoparticles that granularity is 10 nanometers Gold 0.1%, acrylic acid adhesive 20%, the water with 49.9% mixes, and stirring makes it well mixed for 60 minutes.
Catalyst fixed bed forms:Aqueous Polyurethane Adhesives 25%, cellulose thickener 0.2%, brown powder 2%, with Stirred after 72.8% water mixing, viscosity 1200mPas.
The above-mentioned catalyst coat prepared is added on ceramic honeycomb carrier by way of spraying, then by true Empty drying box drying, roller is reused by the above-mentioned catalyst fixed bed even spread prepared to catalyst coat, is coated with Measure as one side 1.5g/ ㎡, dried finally by hot air type drier.
The ceramic honeycomb of the present embodiment is processed as to 300 × 170 × 5mm specification, on air-conditioning(Air conditioner load wind Measure 325m3/h), with reference to GB/T 18801-2008《Air purifier》With GB 21551.6-2010《Family expenses and similar applications electricity The antibacterial of device, degerming, purification function air conditioner particular/special requirement》The Clean air delivery rate and purification efficiency of testing air conditioner.Do simultaneously Common air-conditioning removes formaldehyde filter(Equivalent specifications)Contrast test, as a result such as following table:
Filter name Pure air output rating(m³/h) Purifying formaldehyde rate(%)
The present embodiment 91 28
Common air-conditioning removes formaldehyde net 13 4%
Embodiment 2, one kind of the invention remove formaldehyde filter, are set on carrier except formaldehyde catalyst coating and catalyst are fixed Layer, catalyst fixed bed are arranged on catalyst coat outer layer.
Except formaldehyde catalyst coating composition is:Titanium dioxide 10% that granularity is 30 nanometers, the Technique of Nano Pd that granularity is 20 nanometers 2%th, cerium oxide 5%, the EVA adhesives 31% that granularity is 30 nanometers, the water with 52% mix, and stirring makes it well mixed for 60 minutes.
Catalyst fixed bed forms:Acrylic acid adhesive 30%, cellulose thickener 0.1%, after being mixed with 69.9% water Stir, viscosity 1500mPas.
The above-mentioned catalyst coat prepared is added to by way of immersion on rugosity gum sprayed cotton carrier, Ran Houtong The drying of hot air type drying box is crossed, the above-mentioned catalyst fixed bed prepared is uniformly added to catalyst by the mode for reusing spraying On coating, coating weight is one side 1g/ ㎡, last naturally dry.
Certainly, the present invention can also have the deformation in other steps, these equivalent technologies in addition to above-mentioned embodiment Scheme should also be as within its protection domain.

Claims (10)

  1. It is 1. a kind of except the method for formaldehyde coating, it is characterised in that:
    One carrier is provided first;
    Mixing will be configured in proportion except formaldehyde catalyst coating each component, and be sufficiently stirred;
    Except formaldehyde catalyst coating any of spraying, immersion, coating mode will be used to be added to carrier;
    It is dried by the way of the one or more combination in natural drying, pneumatic conveying drying, microwave drying or vacuum drying;
    Catalyst fixed bed each component is configured into mixing in proportion, and is sufficiently stirred;
    Catalyst fixed bed is added to except formaldehyde catalyst coating surface using any of spraying, immersion, coating mode;
    Carried out again by the way of the one or more combination in natural drying, pneumatic conveying drying, microwave drying or vacuum drying Dry.
  2. It is 2. according to claim 1 a kind of except the method for formaldehyde coating, it is characterised in that:Except formaldehyde catalyst coating is by matter Percentage is measured by 5%-50% except formaldehyde catalyst, 10%-70% adhesive, 0-2% thickener and water are made, it is above-mentioned to match somebody with somebody Square mass percent total amount is 100%.
  3. It is 3. according to claim 2 a kind of except the method for formaldehyde coating, it is characterised in that:Except formaldehyde catalyst is metal oxygen One or more combination in compound catalyst, noble metal catalyst, rare-earth metal catalyst.
  4. It is 4. according to claim 2 a kind of except the method for formaldehyde coating, it is characterised in that:Except formaldehyde catalyst is nanoscale Catalyst, granularity are 5-100 nanometers.
  5. It is 5. according to claim 2 a kind of except the method for formaldehyde coating, it is characterised in that:Adhesive is Aqueous Adhesives And/or inorganic adhesive.
  6. It is 6. according to claim 1 a kind of except the method for formaldehyde coating, it is characterised in that:Catalyst fixed bed is by quality hundred Ratio is divided to be made up of 10%-70% Aqueous Adhesives, 0.1%-1% thickener, 0-1% defoamer, 0-5% pigment and water, Above-mentioned prescription quality percentage total amount is 100%.
  7. It is 7. according to claim 1 a kind of except the method for formaldehyde coating, it is characterised in that:The catalyst fixed bed glues Degree is higher than 800mPas.
  8. It is 8. according to claim 1 a kind of except the method for formaldehyde coating, it is characterised in that:The list of the catalyst fixed bed Face addition weight is 30-200g/m2
  9. 9. one kind application is above-mentioned to remove formaldehyde filter except formaldehyde coating process is obtained, it is characterised in that:Filter surfaces are set Have and remove formaldehyde catalyst coating, described removing is provided with catalyst fixed bed above formaldehyde catalyst coating.
  10. 10. according to claim 9 remove formaldehyde filter, it is characterised in that:Described filter is cellular, flat board The structure of one or more combination in shape, rugosity, corrugated.
CN201610770932.3A 2016-08-31 2016-08-31 Except formaldehyde coating method and its obtained remove formaldehyde filter Pending CN107537313A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610770932.3A CN107537313A (en) 2016-08-31 2016-08-31 Except formaldehyde coating method and its obtained remove formaldehyde filter

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610770932.3A CN107537313A (en) 2016-08-31 2016-08-31 Except formaldehyde coating method and its obtained remove formaldehyde filter

Publications (1)

Publication Number Publication Date
CN107537313A true CN107537313A (en) 2018-01-05

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113058423A (en) * 2021-03-24 2021-07-02 海信(广东)空调有限公司 Formaldehyde removal filter screen and preparation method and application thereof
CN114272958A (en) * 2022-01-13 2022-04-05 广州天与地投资服务有限公司 Platinum catalyst for quickly removing formaldehyde
CN114452726A (en) * 2020-11-06 2022-05-10 佛山市顺德区美的电热电器制造有限公司 Air purification filter screen, air purification device and method for preparing air purification filter screen

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102872715A (en) * 2012-09-11 2013-01-16 佛山市顺德区阿波罗环保器材有限公司 Filter for removing methanal and manufacturing method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102872715A (en) * 2012-09-11 2013-01-16 佛山市顺德区阿波罗环保器材有限公司 Filter for removing methanal and manufacturing method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114452726A (en) * 2020-11-06 2022-05-10 佛山市顺德区美的电热电器制造有限公司 Air purification filter screen, air purification device and method for preparing air purification filter screen
CN114452726B (en) * 2020-11-06 2023-06-27 佛山市顺德区美的电热电器制造有限公司 Air purification filter screen, air purification device and method for preparing air purification filter screen
CN113058423A (en) * 2021-03-24 2021-07-02 海信(广东)空调有限公司 Formaldehyde removal filter screen and preparation method and application thereof
CN114272958A (en) * 2022-01-13 2022-04-05 广州天与地投资服务有限公司 Platinum catalyst for quickly removing formaldehyde

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Application publication date: 20180105

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