CN107524044A - A kind of damp-prrof packing paper - Google Patents

A kind of damp-prrof packing paper Download PDF

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Publication number
CN107524044A
CN107524044A CN201710634482.XA CN201710634482A CN107524044A CN 107524044 A CN107524044 A CN 107524044A CN 201710634482 A CN201710634482 A CN 201710634482A CN 107524044 A CN107524044 A CN 107524044A
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China
Prior art keywords
parts
paper
added
wrapping paper
modified
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CN201710634482.XA
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Chinese (zh)
Inventor
李昌斌
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Ma'anshan Kang Hui Carton And Paper Product Co Ltd
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Ma'anshan Kang Hui Carton And Paper Product Co Ltd
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Priority to CN201710634482.XA priority Critical patent/CN107524044A/en
Publication of CN107524044A publication Critical patent/CN107524044A/en
Pending legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/04—Hydrocarbons
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/06—Alcohols; Phenols; Ethers; Aldehydes; Ketones; Acetals; Ketals
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/14—Carboxylic acids; Derivatives thereof
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24—Polysaccharides
    • D21H17/28—Starch
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/675—Oxides, hydroxides or carbonates
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/68—Water-insoluble compounds, e.g. fillers, pigments siliceous, e.g. clays
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Cosmetics (AREA)

Abstract

The invention discloses a kind of damp-prrof packing paper, is related to wrapping paper paper product technical field, has following raw material components to be made：Paper pulp, starch, aloe extract, wool lipoid substance, 3,7,11,15 tetramethyls 1,2,3 trihydroxy C16 alkane, alkalescence purple, titanium dioxide, lanolin, lactic acid tetradecane base ester, antioxidant, beeswax, Aloe Vera Gel, modified propylene acid butyl ester, vaseline, deionized water, modified neopentanoic acid tridecane ester, anti-blushing agent.Damp-prrof packing paper the selection of material prepared by the present invention is environmentally safe by modified safe and non-toxic, packs and uses suitable for moistureproof article, and top layer polyethylene film further strengthens wrapping paper water-proof function；Wrapping paper has bacteriostasis, and wrapping paper also has anti-oxidation function, wrapping paper long-term use ingress of air or sunlight, oxidative phenomena will not occur, therefore wrapping paper will not be oxidized discoloration, colour fading etc..

Description

A kind of damp-prrof packing paper
Technical field：
The present invention relates to wrapping paper paper product technical field, and in particular to a kind of damp-prrof packing paper.
Background technology：
Wrapping paper packaging function is packed for body paper and cardboard, it will usually makes carton, dividing plate, paper bag and carton, ox-hide Paper, unbleached sulphite paper, stripe kraft paper, kraft inner paper, lining paper, boxboard, corrugated paper, honeycomb cardboard etc..
Wrapping paper has in corresponding property wrapping paper, and dosage maximum is that the large granular industrial or agricultural of packaging is former Material, such as sack kraft paper of cement, chemical fertilizer, is generally made of more than 3~4 layers paper, therefore also known as multi-wall paper bag paper, with difference In other bag of paper of the light thin commodity of packaging.This wrapping paper major requirement intensity is high, resistance to heavy duty, shock resistance, and have appropriate saturating Manner.The description of food wrapper is most.And it is divided into inner packing use and two major classes of outer packing.Directly contact the title of food For inner packaging paper, major requirement cleaning, disease carrying germ, does not have the characteristic such as moistureproof, grease proofing, anti-sticking, mould proof.Overwrap is mainly Beautification and protection commodity, in addition to certain physical strength is required, also need clean aesthetic, suitable for printing the commodity pattern and text of polychrome Word.For the wrapping paper of the liquid beverages such as milk, vegetable juice, it is necessary to have fabulous anti-permeability.In order to longer-term preserve, it is fresh-keeping Needs, developed compound paper and metallic film, paper and plastics and the compound extraordinary soft package of beverage paper of metallic film (see food Packing container).To adapt to the antirust needs of metal instrumentation and instrument, anti-tarnish paper is developed.The overwhelming majority is also to supply business in cardboard What product were packed for, mainly for the manufacture of carton, carton and packaging cushion.
For the demand of wrapping paper, occur all kinds in life, the present invention prepares a kind of damp-prrof packing paper.
The content of the invention：
The technical problems to be solved by the invention are to provide a kind of damp-prrof packing paper, safe and non-toxic, be applicable to prevent The packaging of damp article.
The technical problems to be solved by the invention are realized using following technical scheme：
A kind of damp-prrof packing paper, the raw material components for having following parts by weight are made：
Paper pulp 1-33 parts, starch 6-12 parts, aloe extract 5-10 parts, wool lipoid substance 6-12 parts, 3,7,11, Phytanetriol, 2,3- trihydroxy C16 alkane 6-10 parts, alkaline purple 1 -- 5 parts, titanium dioxide 5-10 parts, lanolin 4-10 parts, breast It is sour tetradecane base ester 5-10 parts, antioxidant 5-15 parts, beeswax 6-10 parts, Aloe Vera Gel 4-8 parts, modified propylene acid butyl ester 4-8 parts, all Intellectual circle 5-10 parts, deionized water 10-20 parts, modified neopentanoic acid tridecane ester 1-19 parts, anti-blushing agent 1-5 parts.
The antioxidant includes following composition：Tricaprylin 2-19 parts, white beeswax 1-10 parts, lecithin coat Talcum powder 1-6 parts, chrysanthemum 2-50 parts, Sculellaria barbata 2-50 parts, bark of eucommia 2-50 parts, coptis 2-50 parts, radix scrophulariae 2-50 parts, bark of official magnolia 2-50 Part, root of herbaceous peony 2-50 parts, root of fangji 2-50 parts, golden cypress 2-50 parts, Buddha's hand 2-50 parts, sweet wormwood 2-50 parts；Its preparation method is：Select excellent The chrysanthemum of matter, Sculellaria barbata, the bark of eucommia, the coptis, radix scrophulariae, the bark of official magnolia, the root of herbaceous peony, the root of fangji, golden cypress, Buddha's hand are shredded to 0.1-0.5cm segments, after Segment is added in 10 times of water big fire heating and boils 10-30min, after switch to small fire and endure 12-24h slowly water is boiled into concentrate, After be cooled to room temperature, after by boil concentrate, tricaprylin, white beeswax, lecithin coating talcum powder place 40-90 In DEG C hot water, stirring and dissolving is uniform, and rear well mixed and room temprature evaporation moisture is until paste mixture produces antioxidant.
The method of modifying of the modified propylene acid butyl ester is：The propylene of 2-20 parts is added in electrical heating stainless steel cauldron Acid butyl ester, 80-100 DEG C of butyl acrylate melting is heated in a kettle uniformly, adds 1-10 part P-hydroxybenzoic acid first Without dialdehyde, 600-5000rpm/min starts stirring for ester and 1-8 parts, and question response kettle is to slowly warm up to 120-160 DEG C, reacts 1-5h, After determining modified propylene acid butyl ester epoxide number, it is cooled to 60-75 DEG C and produces modified propylene acid butyl ester.
The method of modifying of the modified neopentanoic acid tridecane ester is：Uniform neopentanoic acid tridecane ester will be dissolved and add reaction In kettle, stirring is started, is slowly added to 1-5 part formalins, is heated up 40-60 DEG C, is added using SbF5/SiO2-AL2O3 as load Body, the catalyst using platinum, cobalt, chromium or nickel metal as activated centre, 65-80 DEG C is warming up in 30min, is incubated 2h, decompression is de- Water.The boric acid of 0.5-2 parts is added, 120 DEG C are warming up in 20-30min, stirs 30min, when question response thing starts retrogradation, is taken off Water, sampling and measuring gelation time, when 160-180 DEG C of gelation time is 60-90s, thick liquid material is released while hot, after cooling To modified neopentanoic acid tridecane ester.
The anti-blushing agent includes following composition：Cetanol 1-9 parts, sea grass glue 1-6 parts, hydrogenated coco-glyceride 2-9 parts, two Titanium oxide 2-6 parts, methyl glucose ether 2-10 parts.Its preparation method is：By cetanol 1-9 parts, sea grass glue 1-6 parts, hydrogenation coconut palm In oil glyceride 2-9 part mixers, 30-70 DEG C of heating is completely dissolved well mixed, rear to add in grinding mixer, thing to be mixed Mixed grinding, which uniformly adds, is pre-heated to 60-90 DEG C titanium dioxide 2-6 parts, methyl glucose ether 2-10 part, 500- 2000rpm/min stirs 20-40min, stirs while adding mineral water, material to be mixed produces into uniform dope Anti-blushing agent.
Preferably, its preparation method is as follows：
(1) paper pulp 1-33 parts, starch 6-12 parts, aloe extract 5-10 parts, wool lipid are added into deionized water Compound 6-12 parts, 60-90 DEG C of insulation mixing 10-30min is first heated to, reheats 100-120 DEG C of insulation mixing 20min, produce Material I；
(2) 3,7,11,15- tetramethyl -1,2,3- trihydroxy C16 alkane 6-10 parts, alkaline purple 1 are added into deionized water -- 5 parts, titanium dioxide 5-10 parts, lanolin 4-10 parts, soak 30-60min, after under ultrasonic frequency 60khz, power 100W surpass Sonication 15min；Lactic acid tetradecane base ester 5-10 parts are added, continues to be ultrasonically treated, produces material II；
(3) antioxidant 5-15 parts, beeswax 6-10 parts are added into deionized water, anti-blushing agent 1-5 parts, Aloe Vera Gel 4-8 parts, is changed Property butyl acrylate 4-8 parts are sufficiently stirred with mixer 60-200rpm/min, are well mixed mixture and are heated to 50-80 DEG C, treat that material is mixed to soft sticky material III；
(4) material I, material II, material III and vaseline 5-10 parts, modified neopentanoic acid tridecane ester 1-19 parts are added mixed Close in heating grinder, mixed material heating is ground to granularity exquisiteness, and mixture is sticky produces wrapping paper material；
(5) wrapping paper material is put into bag and turns paper producing apparatus one production line, produced wrapping paper, lead to after wrapping paper production Brush film machine is crossed in top layer brush layer of polyethylene film.
The beneficial effects of the invention are as follows：Damp-prrof packing paper the selection of material prepared by the present invention by modified safe and non-toxic, It is environmentally safe, it is more suitable for moistureproof article packaging and uses, wrapping paper does not absorb water, and top layer polyethylene film is further strong Change wrapping paper water-proof function, when water contacts wrapping paper, water will not be immersed in paper；Wrapping paper has bacteriostasis, when packaging paper bag Storage does not have bacteria corrosion article to dress article for a long time, and wrapping paper also has anti-oxidation function, wrapping paper long-term use ingress of air Or sunlight, oxidative phenomena will not occur, therefore wrapping paper will not be oxidized discoloration, colour fading etc..
Embodiment：
In order that the technical method that the present invention realizes, creation characteristic, reached purpose are easy to understand with effect, tied below Specific embodiment is closed, the present invention is expanded on further.
Embodiment 1
A kind of damp-prrof packing paper：
The raw material components for having following parts by weight are made：
21 parts of paper pulp, 6 parts of starch, 5 parts of aloe extract, 6 parts of wool lipoid substance, 3,7,11,15- tetramethyl -1, 6 parts of 2,3- trihydroxy C16 alkane, 2 parts of alkalescence purple, 5 parts of titanium dioxide, 4 parts of lanolin, 5 parts of lactic acid tetradecane base ester, antioxidant 5 Part, 6 parts of beeswax, 4 parts of Aloe Vera Gel, 4 parts of modified propylene acid butyl ester, 5 parts of vaseline, 10 parts of deionized water, modified neopentanoic acid 13 5 parts of alkyl ester, 1 part of anti-blushing agent.
The antioxidant includes following composition：6 parts of tricaprylin, 7 parts of white beeswax, the talcum powder of lecithin coating 2 parts, it is 8 parts of chrysanthemum, 7 parts of Sculellaria barbata, 6 parts of the bark of eucommia, 8.5 parts of the coptis, 8 parts of radix scrophulariae, 10 parts of the bark of official magnolia, 11 parts of the root of herbaceous peony, 12 parts of the root of fangji, yellow 13 parts of cypress, 10.5 parts of Buddha's hand, 8 parts of sweet wormwood；Its preparation method is：Select high-quality chrysanthemum, Sculellaria barbata, the bark of eucommia, the coptis, radix scrophulariae, The bark of official magnolia, the root of herbaceous peony, the root of fangji, golden cypress, Buddha's hand are shredded to 0.1-0.5cm segments, after segment be added in 10 times of water big fire heating boiled Boil 30min, after switch to small fire and endure 12h slowly water is boiled into concentrate, after be cooled to room temperature, after will to boil concentrate, three octanoic acids sweet Grease, white beeswax, the talcum powder of lecithin coating are placed in 40 DEG C of hot water, and stirring and dissolving is uniform, rear well mixed and room temperature Evaporation moisture is until paste mixture produces antioxidant.
The method of modifying of the modified propylene acid butyl ester is：12 parts of acrylic acid is added in electrical heating stainless steel cauldron Butyl ester, 80 DEG C of butyl acrylate meltings are heated in a kettle uniformly, add 4 parts of methyl p-hydroxybenzoates and 1 part of nothing Dialdehyde, 1000rpm/min start stirring, and question response kettle is to slowly warm up to 120 DEG C, reacts 1h, determines modified propylene acid butyl ester ring After oxygen value, it is cooled to 60 DEG C and produces modified propylene acid butyl ester.
The method of modifying of the modified neopentanoic acid tridecane ester is：Uniform neopentanoic acid tridecane ester will be dissolved and add reaction In kettle, stirring is started, is slowly added to 1 part of formalin, heats up 40 DEG C, adds using SbF5/SiO2-AL2O3 as carrier, with Platinum, cobalt, chromium or nickel metal are the catalyst in activated centre, and 65 DEG C are warming up in 30min, are incubated 2h, decompression dehydration, add 0.5 part of boric acid, 120 DEG C are warming up in 20min, stir 30min, when question response thing starts retrogradation, dehydration, sampling and measuring coagulates Gel time, when 160 DEG C of gelation times are 60s, thick liquid material is released while hot, obtains being modified neopentanoic acid tridecane after cooling Ester.
The anti-blushing agent includes following composition：3 parts of cetanol, 6 parts of sea grass glue, 2 parts of hydrogenated coco-glyceride, titanium dioxide 2 parts, 5 parts of methyl glucose ether.Its preparation method is：By 2 parts of 3 parts of cetanol, 6 parts of sea grass glue, hydrogenated coco-glyceride mixing In machine, 30 DEG C of heating is completely dissolved well mixed, and rear to add in grinding mixer, thing mixed grinding to be mixed uniformly adds 70 DEG C of 2 parts of titanium dioxide, 4 parts of methyl glucose ether are preheated to, 1000rpm/min stirring 20min, is stirred while adding Mineral water, material to be mixed produce anti-blushing agent into uniform dope.
Preferably, its preparation method is as follows：
(1) 21 parts of paper pulp, 6 parts of starch, 5 parts of aloe extract, 6 parts of wool lipoid substance are added into deionized water, 60 DEG C of insulation mixing 10min are first heated to, 100 DEG C of insulation mixing 20min is reheated, produces material I；
(2) 6 parts of 3,7,11,15- tetramethyl -1,2,3- trihydroxy C16 alkane, 2 parts of alkalescence purple, two are added into deionized water 5 parts of titanium oxide, 4 parts of lanolin, 30min is soaked, after being ultrasonically treated 15min under ultrasonic frequency 60khz, power 100W；Again 5 parts of lactic acid tetradecane base ester is added, continues to be ultrasonically treated, produces material II；
(3) 5 parts of antioxidant, 6 parts of beeswax, 1 part of anti-blushing agent, 4 parts of Aloe Vera Gel, modified acroleic acid fourth are added into deionized water 4 parts of ester is sufficiently stirred with mixer 200rpm/min, is well mixed mixture and is heated to 80 DEG C, treats that material is mixed to soft It is sticky to obtain material III；
(4) by 5 parts of 5 parts of material I, material II, material III and vaseline, modified neopentanoic acid tridecane ester addition Hybrid Heatings In grinder, mixed material heating is ground to granularity exquisiteness, and mixture is sticky produces wrapping paper material；
(5) wrapping paper material is put into bag and turns paper producing apparatus one production line, produced wrapping paper, lead to after wrapping paper production Brush film machine is crossed in top layer brush layer of polyethylene film.
Embodiment 2
A kind of damp-prrof packing paper：
The raw material components for having following parts by weight are made：
26 parts of paper pulp, 7 parts of starch, 7.5 parts of aloe extract, 6 parts of wool lipoid substance, 3,7,11,15- tetramethyls- 10 parts of 1,2,3- trihydroxy C16 alkane, 2 parts of alkalescence purple, 5.5 parts of titanium dioxide, 4.5 parts of lanolin, 6 parts of lactic acid tetradecane base ester, 6 parts of antioxidant, 7 parts of beeswax, 5 parts of Aloe Vera Gel, 4 parts of modified propylene acid butyl ester, 5.5 parts of vaseline, 10 parts of deionized water, modification are new 8.6 parts of valeric acid tridecane ester, 4 parts of anti-blushing agent.
The antioxidant includes following composition：12 parts of tricaprylin, 4 parts of white beeswax, the talcum of lecithin coating 3 parts of powder, 13 parts of chrysanthemum, 12 parts of Sculellaria barbata, 14 parts of the bark of eucommia, 14 parts of the coptis, 15 parts of radix scrophulariae, 10 parts of the bark of official magnolia, 12 parts of the root of herbaceous peony, the root of fangji 11 Part, 13 parts of golden cypress, 14 parts of Buddha's hand, 13 parts of sweet wormwood；Its preparation method is：Select high-quality chrysanthemum, Sculellaria barbata, the bark of eucommia, the coptis, profound Ginseng, the bark of official magnolia, the root of herbaceous peony, the root of fangji, golden cypress, Buddha's hand are shredded to 0.1-0.5cm segments, after segment be added in 10 times of water big fire heated Boil 25min, after switch to small fire and endure 15h slowly water is boiled into concentrate, after be cooled to room temperature, after will boil concentrate, three octanoic acids Glyceride, white beeswax, the talcum powder of lecithin coating are placed in 80 DEG C of hot water, and stirring and dissolving is uniform, rear well mixed and room Temperature evaporation moisture is until paste mixture produces antioxidant.
The method of modifying of the modified propylene acid butyl ester is：15 parts of acrylic acid is added in electrical heating stainless steel cauldron Butyl ester, 100 DEG C of butyl acrylate meltings are heated in a kettle uniformly, add 4 parts of methyl p-hydroxybenzoates and 2 parts of nothings Dialdehyde, 1000rpm/min start stirring, and question response kettle is to slowly warm up to 120 DEG C, reacts 1h, determines modified propylene acid butyl ester ring After oxygen value, it is cooled to 60 DEG C and produces modified propylene acid butyl ester.
The method of modifying of the modified neopentanoic acid tridecane ester is：Uniform neopentanoic acid tridecane ester will be dissolved and add reaction In kettle, stirring is started, is slowly added to 1 part of formalin, heats up 40 DEG C, adds using SbF5/SiO2-AL2O3 as carrier, with Platinum, cobalt, chromium or nickel metal are the catalyst in activated centre, and 65 DEG C are warming up in 30min, are incubated 2h, decompression dehydration, add 0.5 part of boric acid, 120 DEG C are warming up in 20min, stir 30min, when question response thing starts retrogradation, dehydration, sampling and measuring coagulates Gel time, when 160 DEG C of gelation times are 60s, thick liquid material is released while hot, obtains being modified neopentanoic acid tridecane after cooling Ester.
The anti-blushing agent includes following composition：5 parts of cetanol, 4 parts of sea grass glue, 3 parts of hydrogenated coco-glyceride, titanium dioxide 4 parts, 7 parts of methyl glucose ether.Its preparation method is：By 3 parts of 5 parts of cetanol, 4 parts of sea grass glue, hydrogenated coco-glyceride mixing In machine, 40 DEG C of heating is completely dissolved well mixed, and rear to add in grinding mixer, thing mixed grinding to be mixed uniformly adds 60 DEG C of 3 parts of titanium dioxide, 2 parts of methyl glucose ether are preheated to, 800rpm/min stirring 20min, is stirred while adding Mineral water, material to be mixed produce anti-blushing agent into uniform dope.
Preferably, its preparation method is as follows：
(1) 26 parts of paper pulp, 7 parts of starch, 7.5 parts of aloe extract, wool lipoid substance 6 are added into deionized water Part, 60 DEG C of insulation mixing 15min are first heated to, 100 DEG C of insulation mixing 20min is reheated, produces material I；
(2) added into deionized water 10 parts of 3,7,11,15- tetramethyl -1,2,3- trihydroxy C16 alkane, 2 parts of alkalescence purple, 5.5 parts of titanium dioxide, 4.5 parts of lanolin, 35min is soaked, is ultrasonically treated after under ultrasonic frequency 60khz, power 100W 15min；6 parts of lactic acid tetradecane base ester is added, continues to be ultrasonically treated, produces material II；
(3) 6 parts of antioxidant, 7 parts of beeswax, 4 parts of anti-blushing agent, 5 parts of Aloe Vera Gel, modified acroleic acid fourth are added into deionized water 4 parts of ester is sufficiently stirred with mixer 200rpm/min, is well mixed mixture and is heated to 50 DEG C, treats that material is mixed to soft It is sticky to obtain material III；
(4) 5.5 parts of material I, material II, material III and vaseline, modified 8.6 parts of neopentanoic acid tridecane ester are added into mixing Heat in grinder, mixed material heating is ground to granularity exquisiteness, and mixture is sticky produces wrapping paper material；
(5) wrapping paper material is put into bag and turns paper producing apparatus one production line, produced wrapping paper, lead to after wrapping paper production Brush film machine is crossed in top layer brush layer of polyethylene film.
It is to carrying out experiment investigation respectively in embodiment provided by the invention, embodiment 1 and embodiment 2 is made a kind of moistureproof Wrapping paper is investigated, as a result as shown in table 1.
The made damp-prrof packing paper of table 1 investigates result
The damp-prrof packing paper of invention preparation is detected with reference to every detection method, it is safe and non-toxic to prepare damp-prrof packing paper, prevents Damp wrapping paper water proofing property is preferable, suitable for papery waterproofing packing, and does not influence papery suppleness and pliability in use, papery bag Dress is not easy to tear, and ftractures, and top layer polyethylene film further strengthens wrapping paper water-proof function, when water contacts wrapping paper, water It will not immerse in paper；Wrapping paper has bacteriostasis, and when wrapping paper packing article, storage does not have bacteria corrosion article for a long time, packs Paper also has anti-oxidation function, wrapping paper long-term use ingress of air or sunlight, oxidative phenomena will not occur, therefore wrapping paper is not Discoloration, colour fading etc. can be oxidized.
The general principle and principal character and advantages of the present invention of the present invention has been shown and described above.The technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the simply explanation described in above-described embodiment and specification is originally The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its Equivalent thereof.

Claims (6)

1. a kind of damp-prrof packing paper, it is characterised in that the raw material for having following parts by weight is made：
The raw material components for having following parts by weight are made：Paper pulp 1-33 parts, starch 6-12 parts, aloe extract 5-10 parts, wool Lipoid substance 6-12 parts, 3,7,11,15- tetramethyl-1,2,3- trihydroxy C16 alkane 6-10 parts, alkaline purple 1 -- 5 parts, titanium dioxide Titanium 5-10 parts, lanolin 4-10 parts, lactic acid tetradecane base ester 5-10 parts, antioxidant 5-15 parts, beeswax 6-10 parts, Aloe Vera Gel 4-8 Part, modified propylene acid butyl ester 4-8 parts, vaseline 5-10 parts, deionized water 10-20 parts, modified neopentanoic acid tridecane ester 1-19 parts, Anti-blushing agent 1-5 parts.
2. damp-prrof packing paper according to claim 1, it is characterised in that the antioxidant includes following composition：Three octanoic acids Glyceride 2-19 parts, white beeswax 1-10 parts, lecithin coating talcum powder 1-6 parts, chrysanthemum 2-50 parts, Sculellaria barbata 2-50 parts, Bark of eucommia 2-50 parts, coptis 2-50 parts, radix scrophulariae 2-50 parts, bark of official magnolia 2-50 parts, root of herbaceous peony 2-50 parts, root of fangji 2-50 parts, golden cypress 2-50 parts, Buddha's hand 2-50 parts, sweet wormwood 2-50 parts；Its preparation method is：Select high-quality chrysanthemum, Sculellaria barbata, the bark of eucommia, the coptis, radix scrophulariae, the bark of official magnolia, The root of herbaceous peony, the root of fangji, golden cypress, Buddha's hand are shredded to 0.1-0.5cm segments, after segment be added in 10 times of water big fire heating boil 10- 30min, after switch to small fire and endure 12-24h slowly water is boiled into concentrate, after be cooled to room temperature, after will to boil concentrate, three octanoic acids sweet Grease, white beeswax, the talcum powder of lecithin coating are placed in 40-90 DEG C of hot water, and stirring and dissolving is uniform, rear well mixed and room Temperature evaporation moisture is until paste mixture produces antioxidant.
3. damp-prrof packing paper according to claim 2, it is characterised in that：The method of modifying of the modified propylene acid butyl ester For：The butyl acrylate of 2-20 parts is added in electrical heating stainless steel cauldron, is heated to 80-100 DEG C of propylene in a kettle Acid butyl ester melting is uniform, adds 1-10 parts methyl p-hydroxybenzoate and 1-8 parts are started without dialdehyde, 600-5000rpm/min Stirring, question response kettle are to slowly warm up to 120-160 DEG C, react 1-5h, after determining modified propylene acid butyl ester epoxide number, are cooled to 60-75 DEG C produces modified propylene acid butyl ester.
4. damp-prrof packing paper according to claim 3, it is characterised in that：The modification side of the modified neopentanoic acid tridecane ester Method is：Uniform neopentanoic acid tridecane ester will be dissolved to add in reactor, stirring is started, be slowly added to 1-5 part formalins, 40-60 DEG C of heating, is added using SbF5/SiO2-AL2O3 as carrier, the catalyst using platinum, cobalt, chromium or nickel metal as activated centre, 65-80 DEG C is warming up in 30min, 2h is incubated, decompression dehydration, adds the boric acid of 0.5-2 parts, be warming up in 20-30min 120 DEG C, 30min is stirred, when question response thing starts retrogradation, dehydration, sampling and measuring gelation time, during 160-180 DEG C of gelation Between when being 60-90s, release thick liquid material while hot, obtain being modified neopentanoic acid tridecane ester after cooling.
5. damp-prrof packing paper according to claim 4, it is characterised in that：The anti-blushing agent includes following composition：Cetanol 1-9 parts, sea grass glue 1-6 parts, hydrogenated coco-glyceride 2-9 parts, titanium dioxide 2-6 parts, methyl glucose ether 2-10 parts, it is prepared Method is：In cetanol 1-9 parts, sea grass glue 1-6 parts, hydrogenated coco-glyceride 2-9 part mixers, 30-70 DEG C will be heated completely Dissolving is well mixed, rear to add in grinding mixer, thing mixed grinding to be mixed uniformly add be pre-heated to 60-90 DEG C two Titanium oxide 2-6 parts, methyl glucose ether 2-10 parts, 500-2000rpm/min stirring 20-40min, stir while adding ore deposit Material water, material to be mixed produce anti-blushing agent into uniform dope.
6. damp-prrof packing paper according to claim 5, it is characterised in that：Preferably, its preparation method is as follows：
(1) paper pulp 1-33 parts, starch 6-12 parts, aloe extract 5-10 parts, wool lipoid substance are added into deionized water 6-12 parts, 60-90 DEG C of insulation mixing 10-30min is first heated to, reheats 100-120 DEG C of insulation mixing 20min, produce material Ⅰ；
(2) 3,7,11,15- tetramethyl -1,2,3- trihydroxy C16 alkane 6-10 parts, alkaline purple 1 are added into deionized water -- 5 parts, Titanium dioxide 5-10 parts, lanolin 4-10 parts, 30-60min is soaked, at ultrasonic under ultrasonic frequency 60khz, power 100W Manage 15min；Lactic acid tetradecane base ester 5-10 parts are added, continues to be ultrasonically treated, produces material II；
(3) antioxidant 5-15 parts, beeswax 6-10 parts, anti-blushing agent 1-5 parts, Aloe Vera Gel 4-8 parts, modified third are added into deionized water Olefin(e) acid butyl ester 4-8 parts are sufficiently stirred with mixer 60-200rpm/min, are well mixed mixture and are heated to 50-80 DEG C, treat Material is mixed to soft sticky material III；
(4) material I, material II, material III and vaseline 5-10 parts, modified neopentanoic acid tridecane ester 1-19 parts are added mixing and added In hot grinder, mixed material heating is ground to granularity exquisiteness, and mixture is sticky produces wrapping paper material；
(5) wrapping paper material is put into bag and turns paper producing apparatus one production line, produced wrapping paper, pass through brush after wrapping paper production Film machine is in top layer brush layer of polyethylene film.
CN201710634482.XA 2017-07-29 2017-07-29 A kind of damp-prrof packing paper Pending CN107524044A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109629341A (en) * 2019-01-24 2019-04-16 苏州冠威热敏纸有限公司 Sun-proof antibacterial heat-sensitive paper of one kind and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109629341A (en) * 2019-01-24 2019-04-16 苏州冠威热敏纸有限公司 Sun-proof antibacterial heat-sensitive paper of one kind and preparation method thereof
CN109629341B (en) * 2019-01-24 2020-12-29 苏州冠威热敏纸有限公司 Sun-proof antibacterial thermosensitive paper and preparation method thereof

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