CN107523442A - A kind of stupefied groove cleaning agent of Corrugator roller - Google Patents

A kind of stupefied groove cleaning agent of Corrugator roller Download PDF

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Publication number
CN107523442A
CN107523442A CN201710634548.5A CN201710634548A CN107523442A CN 107523442 A CN107523442 A CN 107523442A CN 201710634548 A CN201710634548 A CN 201710634548A CN 107523442 A CN107523442 A CN 107523442A
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parts
cleaning agent
added
corrugator roller
mixed
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CN201710634548.5A
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李昌斌
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Ma'anshan Kang Hui Carton And Paper Product Co Ltd
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Ma'anshan Kang Hui Carton And Paper Product Co Ltd
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Priority to CN201710634548.5A priority Critical patent/CN107523442A/en
Publication of CN107523442A publication Critical patent/CN107523442A/en
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C11D7/24—Hydrocarbons
    • C11D7/248—Terpenes
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/02—Acyclic compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/02—Amines; Quaternary ammonium compounds
    • A01N33/12—Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/02—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/10—Aromatic or araliphatic carboxylic acids, or thio analogues thereof; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
    • A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
    • A01N37/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system having at least one carboxylic group or a thio analogue, or a derivative thereof, and one oxygen or sulfur atom attached to the same aromatic ring system
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    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/04—Sulfonic acids; Derivatives thereof
    • A01N41/06—Sulfonic acid amides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
    • A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/40—Liliopsida [monocotyledons]
    • A01N65/42—Aloeaceae [Aloe family] or Liliaceae [Lily family], e.g. aloe, veratrum, onion, garlic or chives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C11D7/26—Organic compounds containing oxygen
    • C11D7/265—Carboxylic acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
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    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
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    • C11D7/44—Vegetable products
    • C—CHEMISTRY; METALLURGY
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    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
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Abstract

The invention discloses a kind of stupefied groove cleaning agent of Corrugator roller, it is related to cleaning agent technical field, the raw material components for there are following parts by weight are made：5 60 parts of α firpenes, 4 50 parts of laurene, 2 34 parts of bacteriostatic agent, 3 19 parts of mint extract, 2 59 parts of mineral oil, 2 37 parts of honey, 3 18 parts of hyaluronic acid, 3 30 parts of down alkene, 2 18 parts of Tea Polyphenols, 2 23 parts of resin of modified epoxy phenolic aldehyde compounding, 2 17 parts of Arabic gum, 2 21 parts of natural camphor, 2 23 parts of acetum, 2 16 parts of duck wheat brass, 3 34 parts of peanut oil, 3 16 parts of beta glucan.The stupefied groove cleaning agent of Corrugator roller prepared by the present invention is safe and non-toxic, effectively cleans the stupefied groove dust of Corrugator roller, mushroom, adhesion, the non-sticky stupefied groove of Corrugator roller, does not corrode the stupefied groove of Corrugator roller, and natural camphor has certain inhibitory action to aggregation bacterium class, microbiology class.

Description

A kind of stupefied groove cleaning agent of Corrugator roller
Technical field：
The present invention relates to cleaning agent technical field, and in particular to a kind of stupefied groove cleaning agent of Corrugator roller.
Background technology：
Corrugated paper is to process the plate object being bonded and the corrugated paper of the waveform formed by sheet lining and by corrugated roller, Single wall corrugated board and the class of double-layer corrugated cardboard two are generally divided into, is divided into according to the size of corrugation：A, the type of B, C, E, F five.
Corrugated paper is pressed into corrugated shape in process of production, be made after corrugated board it will provide cardboard elasticity, Flat crushing strength, and influence the performances such as vertical compressive strength.Corrugated paper, paper is smooth, and thickness is consistent, it is impossible to has fold, splits The paper defects such as mouth and hole, otherwise increases the broken end failure of production process, influences product quality.
Corrugated board production process, which is crossed, occurs various kinds problem, therefore prevents the generation of quality of corrugated problem, first Focus on being controlled from the source of quality, i.e., to strengthen the quality inspection and control of body paper, and production equipment is recognized Genuine M R.Quality of production Sources controlling is good, it is also noted that and get hold of operating technology and technology is closed, it is such as different Under the conditions of the body paper of quality, the body paper of different water cut, different production environments, if the speed of production of single-side machine is stepped on the gas without exception, With regard to being easy to produce mass defect problem；Also have the reason for production technology is improper, caused by having machine bad, also with operating technology Assurance degree it is relevant etc..
The present invention is directed to the stupefied groove of Corrugator roller in corrugated paper production equipment and designs cleaning agent, production equipment is cleaned up energy Enough long-time normal operations.
The content of the invention：
The technical problems to be solved by the invention are to provide a kind of Corrugator roller stupefied groove cleaning agent, safe and non-toxic, quality is excellent It is good, using persistence, do not corrode object.
The technical problems to be solved by the invention are realized using following technical scheme：
A kind of stupefied groove cleaning agent of Corrugator roller, the raw material components for having following parts by weight are made：
Australene 5-60 parts, laurene 4-50 parts, bacteriostatic agent 2-34 parts, mint extract 3-19 parts, mineral oil 2-59 parts, Honey 2-37 parts, hyaluronic acid 3-18 parts, down alkene 3-30 parts, Tea Polyphenols 2-18 parts, modified epoxy-phenolic aldehyde compounding resin 2-23 Part, Arabic gum 2-17 parts, natural camphor 2-21 parts, acetum 2-23 parts, duck wheat brass 2-16 parts, peanut oil 3-34 Part, beta glucan 3-16 parts.
The bacteriostatic agent composition includes：Salicylic acid 1-6 parts, sodium formate 2-13 parts, Halazone 2-11 parts, benzoyl peroxide 2-16 parts, dodecyl bromide pyridine 2-17 parts, Sweet Almond Oil 2-16 parts, mint extract 3-19 parts, garlic P.E 2-9 Part, chitosan 1-23 parts, hyperbranched quaternary ammonium salt 1-19 parts, ethanol 2-30 parts.Its preparation method is：Weigh 2-17 parts bromination 12 Alkyl pyridine is placed in 1-6 part absolute ethyl alcohols, distilled water 95:In 5 (V/V) solution, ultrasonic 2h, 2-16 part peroxidating is added Benzoyl, 20-80min is reacted at 40-80 DEG C, with absolute ethyl alcohol centrifuge washing 3-6 times, bromination dodecane must be modified by then drying Yl pyridines；2-13 parts sodium formate, Halazone 2-11 parts, Sweet Almond Oil 2-16 parts, mint extract 3-19 parts are weighed, is placed in and fills In the conical flask of distilled water, the hydrochloric acid that excessive PH is 3-6 is added, through magnetic stirrer untill generating and precipitating；Will be molten Liquid is filtered, and retains sediment therein, and with distilled water washing precipitate repeatedly, into washing lotion in untill neutral, then Precipitation will be obtained it is placed on 30-90 DEG C of drying in vacuum drying oven obtaining sodium formate mixture；Afterwards will modified bromination dodecyl pyrrole Pyridine, sodium formate mixture are added in absolute ethyl alcohol with certain proportion, ultrasonic 1-6h, after by salicylic acid 1-6 parts, garlic P.E 2- 9 parts, chitosan 1-23 parts, hyperbranched quaternary ammonium salt 1-19 parts through melt blending close make the micro-nano grain of rice.
The modified epoxy-phenolic aldehyde compounding process for preparing resins：Fusing epoxy-phenolic aldehyde compounding resin is added into reactor In, stirring is started, is slowly added to Quant Formaldehyde solution, heated up 40-80 DEG C of addition catalyst, and 60- is warming up in 20-60min 160 DEG C, it is incubated 1-5h, decompression dehydration.Quantitative boric acid is added, 200 DEG C is warming up in 20-50min, stirs 20-40min, treat When reactant starts retrogradation, dehydration, 180 DEG C of gelation times release green-yellow thick liquid while hot when being 60-90s, after cooling Epoxy after to denaturation-phenolic aldehyde compounding resin, after montmorillonite is added to progress intercalation synthesis processing in resin, make resin inserted with The interlayer of machine montmorillonite, 30-60min is stirred under conditions of 75 DEG C, so that peeling off filler into receiving after curing of coatings Rice lamella, obtain modified epoxy-phenolic aldehyde compounding resin.
Preferably, its preparation method is as follows：
(1) australene 5-60 parts, laurene 4-50 parts are first added into 40-80 DEG C of heating of heating fully dissolving in deionized water Uniformly, mint extract 3-19 parts, mineral oil 2-59 parts, honey 2-37 parts, hyaluronic acid 3-18 parts are added in backward solution, first 80-180 DEG C is heated to, thing to be mixed dissolves and is cooled to room temperature in the heating grinder that rotating speed is 1000-5000rpm/min Grinding stirs, and takes out the mixture I that 1-12h is dried in 50-120 DEG C of baking oven afterwards；
(2) step 1 gained mixture I and bacteriostatic agent 2-34 parts, down alkene 3-30 parts, Tea Polyphenols 2-18 parts are added and added at a high speed In hot mixing mill, 1000-3000rpm/min is uniformly mixed；
(3) material, which is added in fluid-flywheel clutch, after being well mixed in step 2 is mixed, rear to add in refiner, Refine repeatedly refines material, so as to obtain cleaning agent matrix；
(4) the cleaning agent matrix obtained in step 3 and modified epoxy-phenolic aldehyde are compounded into resin 2-23 parts, Arabic gum 2- 17 parts, natural camphor 2-21 parts be heated at high temperature at 30-90 DEG C and homogenizer and be well mixed, in microwave frequency be 2450MHz, power Microwave treatment 10-30min under 800w, material I is produced after well mixed；
(5) acetum 2-23 parts, duck wheat brass 2-16 parts, peanut oil 3-34 parts, beta glucan 3-16 parts are added Into 5 times of 0.1-0.5% mineral oil solutions, being stored at room temperature 1-24h is uniformly dissolved it, is mixed in 30-50 DEG C of condition high-speed stirred Close uniformly, be microwave treatment 10-30min under 2450MHz, power 800w in microwave frequency, material II is produced after well mixed；
(6) material I and material II are mixed, is warming up to 40-60 DEG C and is sufficiently stirred 15-60min, it is rear to stand room temperature again 1000-5000rpm/min 20-40 DEG C insulated and stirred 20-40min, it is rear to stand room temperature cooling, obtain mixed emulsion material；Will be mixed Compound material is added in mulser, is acted on by mulser and is produced cleaning agent, and cleaning agent packing loads packing box.
Cleaning agent infiltrates 2-5min in use, cleaning agent is applied into the stupefied groove of Corrugator roller, is subsequently poured into warm water and with scrubbing Instrument cleans, and is rinsed after cleaning with clear water；Or cleaning agent use before by the pre- heat soaking 2-10min of cleaning agent warm water, Cleaning agent is put into the stupefied groove of Corrugator roller afterwards, then pours into appropriate hot water and is cleaned with cleaning means, after rinsed well with clear water.
The beneficial effects of the invention are as follows：The stupefied groove cleaning agent the selection of material of Corrugator roller prepared by the present invention is safe and non-toxic, to ring Border is pollution-free, effectively cleans the stupefied groove dust of Corrugator roller, mushroom, adhesion, the non-sticky stupefied groove of Corrugator roller, does not corrode the stupefied groove of Corrugator roller, And natural camphor has certain inhibitory action to aggregation bacterium class, microbiology class, can also be sterilized simultaneously in the cleaning stupefied groove of Corrugator roller The stupefied groove of Corrugator roller, the stupefied groove of high-efficiency washing Corrugator roller remove pollutant, therefore also reduce the corrugated paper caused by machine is bad and produce Caused quality problems.
Embodiment：
In order that the technical method that the present invention realizes, creation characteristic, reached purpose are easy to understand with effect, tied below Specific embodiment is closed, the present invention is expanded on further.
Embodiment 1
A kind of stupefied groove cleaning agent of Corrugator roller, the raw material components for having following parts by weight are made：
19 parts of australene, 12 parts of laurene, 4 parts of bacteriostatic agent, 11 parts of mint extract, 29 parts of mineral oil, 7 parts of honey, thoroughly Bright 8 parts of matter acid, 10 parts of down alkene, 12 parts of Tea Polyphenols, modified epoxy -23 parts of resin of phenolic aldehyde compounding, 4 parts of Arabic gum, natural camphor 5 Part, 3 parts of acetum, 11 parts of duck wheat brass, 4 parts of peanut oil, 6 parts of beta glucan.
The bacteriostatic agent composition includes：5 parts of salicylic acid, 3 parts of sodium formate, 6 parts of Halazone, 5.5 parts of benzoyl peroxide, bromine Change 7 parts of dococylpyridinium, 6 parts of Sweet Almond Oil, 3.5 parts of mint extract, 4.5 parts of garlic P.E, 3 parts of chitosan, over-expense Change 4 parts of quaternary ammonium salt, 3.6 parts of ethanol.Its preparation method is：7 parts of dodecyl bromide pyridines are weighed to be placed in 2 parts of absolute ethyl alcohols, Distilled water is 95:In 5 (V/V) solution, ultrasonic 2h, 5.5 parts of benzoyl peroxides are added, react 20min at 40 DEG C, use is anhydrous Ethanol centrifuge washing 3 times, dodecyl bromide pyridine must be modified by then drying；Weigh 3 parts of sodium formates, 6 parts of Halazone, dessert almond Oily 6 parts, 3.5 parts of mint extract, are placed in the conical flask for filling distilled water, add the hydrochloric acid that excessive PH is 6, are stirred through magnetic force Device is mixed to stir untill generating and precipitating；Solution is filtered, retains sediment therein, and wash precipitation repeatedly with distilled water Thing, sodium formate mixture is obtained in untill neutral, then obtaining precipitation and be placed on 50 DEG C of drying in vacuum drying oven into washing lotion； Modified dodecyl bromide pyridine, sodium formate mixture are added in absolute ethyl alcohol with certain proportion afterwards, ultrasonic 1h, after by bigcatkin willow 5 parts of acid, 4.5 parts of garlic P.E, 3 parts of chitosan, 4 parts of hyperbranched quaternary ammonium salt close through melt blending and make the micro-nano grain of rice.
The modified epoxy-phenolic aldehyde compounding process for preparing resins：Fusing epoxy-phenolic aldehyde compounding resin is added into reactor In, stirring is started, is slowly added to Quant Formaldehyde solution, heat up 40 DEG C of addition catalyst, 60 DEG C is warming up in 20min, insulation 1h, decompression dehydration.Quantitative boric acid is added, 200 DEG C is warming up in 20min, stirs 20min, when question response thing starts retrogradation, is taken off Water, 180 DEG C of gelation times release green-yellow thick liquid while hot when being 60s, epoxy-phenolic aldehyde compounding tree after being denatured after cooling Fat, after montmorillonite is added in resin progress intercalation synthesis processing, make the interlayer of resin insertion organo montmorillonite, at 75 DEG C Under the conditions of be stirred 40min so that after curing of coatings by filler peel off into nanoscale twins, it is multiple to obtain modified epoxy-phenolic aldehyde With resin.
Preferably, its preparation method is as follows：
(1) 19 parts of australene, 12 parts of laurene first are added into 50 DEG C of heating of heating in deionized water to be sufficiently uniformly dissolved, after 11 parts of mint extract, 29 parts of mineral oil, 7 parts of honey, 8 parts of hyaluronic acid are added into solution, is first heated to 80 DEG C, it is to be mixed Thing, which dissolves and is cooled to room temperature, to be ground and stirs in the heating grinder that rotating speed is 1000rpm/min, is taken out afterwards at 50 DEG C 1h mixture I is dried in baking oven；
(2) step 1 gained mixture I is added heated at high speed and mixed with 4 parts of bacteriostatic agent, 10 parts of down alkene, 12 parts of Tea Polyphenols In mill, 1000rpm/min is uniformly mixed；
(3) material, which is added in fluid-flywheel clutch, after being well mixed in step 2 is mixed, rear to add in refiner, Refine repeatedly refines material, so as to obtain cleaning agent matrix；
(4) by the cleaning agent matrix obtained in step 3 and modified epoxy-phenolic aldehyde compound 23 parts of resin, 4 parts of Arabic gum, 5 parts of natural camphor is heated at high temperature homogenizers at 40 DEG C and is well mixed, in microwave frequency be microwave under 2450MHz, power 800w 10min is handled, material I is produced after well mixed；
(5) 3 parts of acetum, 11 parts of duck wheat brass, 4 parts of peanut oil, 6 parts of beta glucan are added to 5 times of 0.1- In 0.5% mineral oil solution, being stored at room temperature 1h is uniformly dissolved it, is well mixed in 30 DEG C of condition high-speed stirreds, in Microwave Frequency Rate is microwave treatment 15min under 2450MHz, power 800w, and material II is produced after well mixed；
(6) material I and material II are mixed, is warming up to 40 DEG C and is sufficiently stirred 15min, it is rear to stand room temperature 1000rpm/ again 30 DEG C of insulated and stirred 20min of min, it is rear to stand room temperature cooling, obtain mixed emulsion material；Mixed material is added in mulser, Acted on by mulser and produce cleaning agent, cleaning agent packing loads packing box.
Cleaning agent in use, cleaning agent use before by the pre- heat soaking 10min of cleaning agent warm water, after cleaning agent is put into watt In the stupefied stupefied groove of roller, then pour into 40 DEG C of hot water and cleaned with cleaning means, after rinsed well with clear water.
Embodiment 2
A kind of stupefied groove cleaning agent of Corrugator roller, the raw material components for having following parts by weight are made：
It is 26 parts of australene, 15 parts of laurene, 4 parts of bacteriostatic agent, 9 parts of mint extract, 29 parts of mineral oil, 7 parts of honey, transparent 8 parts of matter acid, 10 parts of down alkene, 8 parts of Tea Polyphenols, 13 parts of resin of modified epoxy-phenolic aldehyde compounding, 7 parts of Arabic gum, 2 parts of natural camphor, 3 parts of acetum, 6 parts of duck wheat brass, 14 parts of peanut oil, 6 parts of beta glucan.
The bacteriostatic agent composition includes：4 parts of salicylic acid, 3 parts of sodium formate, 5 parts of Halazone, 6 parts of benzoyl peroxide, bromination 7 parts of dococylpyridinium, 4 parts of Sweet Almond Oil, 4 parts of mint extract, 2 parts of garlic P.E, 13 parts of chitosan, hyperbranched quaternary ammonium 9 parts of salt, 10 parts of ethanol.Its preparation method is：Weigh 7 parts of dodecyl bromide pyridines to be placed in 6 parts of absolute ethyl alcohols, distilled water is 95:In 5 (V/V) solution, ultrasonic 2h, 6 parts of benzoyl peroxides are added, react 20min at 50 DEG C, washed with absolute ethyl alcohol centrifugation Wash 3 times, dodecyl bromide pyridine must be modified by then drying；Weigh 3 parts of sodium formates, 5 parts of Halazone, 4 parts of Sweet Almond Oil, peppermint 4 parts of extract, is placed in the conical flask for filling distilled water, the hydrochloric acid solution that excessive PH is 5 is added, through magnetic stirrer Untill generating and precipitating；Solution is filtered, retains sediment therein, and with distilled water washing precipitate repeatedly, to washing Sodium formate mixture is obtained in untill neutral, then obtaining precipitation and be placed on 60 DEG C of drying in vacuum drying oven in liquid；After will change Property dodecyl bromide pyridine, sodium formate mixture with certain proportion add absolute ethyl alcohol in, ultrasonic 1h, after by 4 parts of salicylic acid, 2 parts of garlic P.E, 13 parts of chitosan, 9 parts of hyperbranched quaternary ammonium salt close through melt blending and make micro-nano grain of rice bacteriostatic agent.
The modified epoxy-phenolic aldehyde compounding process for preparing resins：Fusing epoxy-phenolic aldehyde compounding resin is added into reactor In, stirring is started, is slowly added to Quant Formaldehyde solution, heat up 40 DEG C of addition catalyst, 80 DEG C is warming up in 20min, insulation 1h, decompression dehydration.Quantitative boric acid is added, 200 DEG C is warming up in 20min, stirs 20min, when question response thing starts retrogradation, is taken off Water, 180 DEG C of gelation times release green-yellow thick liquid while hot when being 60s, epoxy-phenolic aldehyde compounding tree after being denatured after cooling Fat, after montmorillonite is added in resin progress intercalation synthesis processing, make the interlayer of resin insertion organo montmorillonite, at 75 DEG C Under the conditions of be stirred 30min so that after curing of coatings by filler peel off into nanoscale twins, it is multiple to obtain modified epoxy-phenolic aldehyde With resin.
Preferably, its preparation method is as follows：
(1) 26 parts of australene, 15 parts of laurene first are added into 40 DEG C of heating of heating in deionized water to be sufficiently uniformly dissolved, after 9 parts of mint extract, 29 parts of mineral oil, 7 parts of honey, 8 parts of hyaluronic acid are added into solution, is first heated to 80 DEG C, it is to be mixed Thing, which dissolves and is cooled to room temperature, to be ground and stirs in the heating grinder that rotating speed is 1000rpm/min, is taken out afterwards at 50 DEG C 1h mixture I is dried in baking oven；
(2) step 1 gained mixture I is added heated at high speed and mixed out with 4 parts of bacteriostatic agent, 10 parts of down alkene, 8 parts of Tea Polyphenols In mill, 1000rpm/min is uniformly mixed；
(3) material, which is added in fluid-flywheel clutch, after being well mixed in step 2 is mixed, rear to add in refiner, Refine repeatedly refines material, so as to obtain cleaning agent matrix；
(4) by the cleaning agent matrix obtained in step 3 and modified epoxy-phenolic aldehyde compound 13 parts of resin, 7 parts of Arabic gum, 2 parts of natural camphor is heated at high temperature homogenizers at 60 DEG C and is well mixed, in microwave frequency be microwave under 2450MHz, power 800w 10min is handled, material I is produced after well mixed；
(5) 3 parts of acetum, 6 parts of duck wheat brass, 14 parts of peanut oil, 6 parts of beta glucan are added to 5 times of 0.1- In 0.5% mineral oil solution, being stored at room temperature 1h is uniformly dissolved it, is well mixed in 30 DEG C of condition high-speed stirreds, in Microwave Frequency Rate is microwave treatment 10min under 2450MHz, power 800w, and material II is produced after well mixed；
(6) material I and material II are mixed, is warming up to 50 DEG C and is sufficiently stirred 20min, it is rear to stand room temperature 1000rpm/ again 30 DEG C of insulated and stirred 20min of min, it is rear to stand room temperature cooling, obtain mixed emulsion material；Mixed material is added in mulser, Acted on by mulser and produce cleaning agent, cleaning agent packing loads packing box.
Cleaning agent infiltrates 2min, is subsequently poured into 40 DEG C of immersions of warm water in use, cleaning agent is applied into the stupefied groove of Corrugator roller 2min, after cleaned with Cleaning tool, then rinsed with clear water.
It is to carrying out experiment investigation respectively in embodiment provided by the invention, embodiment 1 and 2 made Corrugator roller of embodiment is stupefied Groove cleaning agent is investigated, and is investigated as shown in table 1.
The stupefied groove cleaning agent of the Corrugator roller of table 1 investigates result
From above detection method and testing result：It is safe and non-toxic to prepare Corrugator roller bearing cleaning agent material, to environment It is pollution-free, and the effectively stupefied groove dust of cleaning Corrugator roller, mushroom, adhesion, the non-sticky stupefied groove of Corrugator roller, do not corrode the stupefied groove of Corrugator roller, And natural camphor has certain inhibitory action to aggregation bacterium class, microbiology class, can also be sterilized simultaneously in the cleaning stupefied groove of Corrugator roller The stupefied groove of Corrugator roller, the stupefied groove of high-efficiency washing Corrugator roller remove pollutant, therefore also reduce the corrugated paper caused by machine is bad and produce Caused quality problems
The general principle and principal character and advantages of the present invention of the present invention has been shown and described above.The technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the simply explanation described in above-described embodiment and specification is originally The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its Equivalent thereof.

Claims (4)

1. a kind of stupefied groove cleaning agent of Corrugator roller, it is characterised in that the raw material for having following parts by weight is made：
Australene 5-60 parts, laurene 4-50 parts, bacteriostatic agent 2-34 parts, mint extract 3-19 parts, mineral oil 2-59 parts, honey 2-37 parts, hyaluronic acid 3-18 parts, down alkene 3-30 parts, Tea Polyphenols 2-18 parts, modified epoxy-phenolic aldehyde compounding resin 2-23 parts, Ah Draw primary glue 2-17 parts, natural camphor 2-21 parts, acetum 2-23 parts, duck wheat brass 2-16 parts, peanut oil 3-34 parts, β-Portugal Glycan 3-16 parts.
2. the stupefied groove cleaning agent of Corrugator roller according to claim 1, it is characterised in that：The bacteriostatic agent composition includes：Bigcatkin willow Sour 1-6 parts, sodium formate 2-13 parts, Halazone 2-11 parts, benzoyl peroxide 2-16 parts, dodecyl bromide pyridine 2-17 parts, Sweet Almond Oil 2-16 parts, mint extract 3-19 parts, garlic P.E 2-9 parts, chitosan 1-23 parts, hyperbranched quaternary ammonium salt 1-19 Part, ethanol 2-30 parts.Its preparation method is：Weigh 2-17 part dodecyl bromide pyridines to be placed in 1-6 part absolute ethyl alcohols, distill Water is 95:In 5 (V/V) solution, ultrasonic 2h, 2-16 part benzoyl peroxides are added, react 20-80min at 40-80 DEG C, are used Absolute ethyl alcohol centrifuge washing 3-6 times, dodecyl bromide pyridine must be modified by then drying；Weigh 2-13 parts sodium formate, Halazone 2-11 parts, Sweet Almond Oil 2-16 parts, mint extract 3-19 parts, are placed in the conical flask for filling distilled water, add excessive PH For 3-6 hydrochloric acid, through magnetic stirrer untill generating and precipitating；Solution is filtered, retains sediment therein, and With distilled water washing precipitate repeatedly, into washing lotion in untill neutral, it then will obtain precipitation and be placed on 30-90 in vacuum drying oven DEG C drying obtains sodium formate mixture；Dodecyl bromide pyridine will be modified afterwards, sodium formate mixture adds nothing with certain proportion In water-ethanol, ultrasonic 1-6h, after by salicylic acid 1-6 parts, garlic P.E 2-9 parts, chitosan 1-23 parts, hyperbranched quaternary ammonium salt 1- 19 parts are made the micro-nano grain of rice through melt blending conjunction.
3. the stupefied groove cleaning agent of Corrugator roller according to claim 2, it is characterised in that：The modified epoxy-phenolic aldehyde compounding tree Fat preparation method：Fusing epoxy-phenolic aldehyde compounding resin is added in reactor, stirring is started, is slowly added to Quant Formaldehyde solution, 40-80 DEG C of addition catalyst of heating, 60-160 DEG C is warming up in 20-60min, is incubated 1-5h, decompression dehydration.Add quantitative Boric acid, it is warming up to 200 DEG C in 20-50min, stirs 20-40min, when question response thing starts retrogradation, dehydration, during 180 DEG C of gelations Between release green-yellow thick liquid while hot when being 60-90s, epoxy-phenolic aldehyde compounding resin after being denatured after cooling, after by montmorillonite Progress intercalation synthesis processing in resin is added to, makes the interlayer of resin insertion organo montmorillonite, is stirred under conditions of 75 DEG C mixed 30-60min is closed, so that peeling off filler into nanoscale twins after curing of coatings, obtains modified epoxy-phenolic aldehyde compounding resin.
4. the stupefied groove cleaning agent of Corrugator roller according to claim 3, it is characterised in that：Preferably, its preparation method is as follows：
(1) first 40-80 DEG C of heating of heating in australene 5-60 parts, laurene 4-50 parts addition deionized water is fully dissolved It is even, mint extract 3-19 parts, mineral oil 2-59 parts, honey 2-37 parts, hyaluronic acid 3-18 parts are added in backward solution, is first added To 80-180 DEG C, thing to be mixed dissolves and is cooled to room temperature to be ground heat in the heating grinder that rotating speed is 1000-5000rpm/min Mill stirs, and takes out the mixture I that 1-12h is dried in 50-120 DEG C of baking oven afterwards；
(2) step 1 gained mixture I and bacteriostatic agent 2-34 parts, down alkene 3-30 parts, Tea Polyphenols 2-18 parts are added heated at high speed and mixed Run jointly in mill, 1000-3000rpm/min is uniformly mixed；
(3) material, which is added in fluid-flywheel clutch, after being well mixed in step 2 is mixed, rear to add in refiner, is carried out Refining repeatedly refines material, so as to obtain cleaning agent matrix；
(4) by the cleaning agent matrix obtained in step 3 and modified epoxy-phenolic aldehyde compound resin 2-23 parts, Arabic gum 2-17 parts, Natural camphor 2-21 parts are heated at high temperature at 30-90 DEG C homogenizer and to be well mixed, in microwave frequency be 2450MHz, power 800w Lower microwave treatment 10-30min, material I is produced after well mixed；
(5) acetum 2-23 parts, duck wheat brass 2-16 parts, peanut oil 3-34 parts, beta glucan 3-16 parts are added to 5 times In 0.1-0.5% mineral oil solutions, being stored at room temperature 1-24h is uniformly dissolved it, equal in 30-50 DEG C of condition high-speed stirred mixing It is even, it is microwave treatment 10-30min under 2450MHz, power 800w in microwave frequency, material II is produced after well mixed；
(6) material I and material II are mixed, is warming up to 40-60 DEG C and is sufficiently stirred 15-60min, it is rear to stand room temperature 1000- again 5000rpm/min 20-40 DEG C insulated and stirred 20-40min, it is rear to stand room temperature cooling, obtain mixed emulsion material；By mixture Material is added in mulser, is acted on by mulser and is produced cleaning agent, and cleaning agent packing loads packing box.
CN201710634548.5A 2017-07-29 2017-07-29 A kind of stupefied groove cleaning agent of Corrugator roller Pending CN107523442A (en)

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1948447A (en) * 2005-10-14 2007-04-18 花王株式会社 Detersive for hard surface
CN102906237A (en) * 2010-05-31 2013-01-30 荷兰联合利华有限公司 Hard surface treatment composition

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1948447A (en) * 2005-10-14 2007-04-18 花王株式会社 Detersive for hard surface
CN102906237A (en) * 2010-05-31 2013-01-30 荷兰联合利华有限公司 Hard surface treatment composition

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Application publication date: 20171229