CN107523395A - A kind of energy-saving and emission-reduction steam turbine oil formula and preparation method thereof - Google Patents
A kind of energy-saving and emission-reduction steam turbine oil formula and preparation method thereof Download PDFInfo
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- CN107523395A CN107523395A CN201710867927.9A CN201710867927A CN107523395A CN 107523395 A CN107523395 A CN 107523395A CN 201710867927 A CN201710867927 A CN 201710867927A CN 107523395 A CN107523395 A CN 107523395A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M177/00—Special methods of preparation of lubricating compositions; Chemical modification by after-treatment of components or of the whole of a lubricating composition, not covered by other classes
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/08—Inorganic acids or salts thereof
- C10M2201/081—Inorganic acids or salts thereof containing halogen
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/0206—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers used as base material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/16—Naphthenic acids
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/20—Containing nitrogen-to-oxygen bonds
- C10M2215/202—Containing nitrogen-to-oxygen bonds containing nitro groups
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/02—Groups 1 or 11
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/04—Groups 2 or 12
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/08—Groups 4 or 14
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
- C10N2020/01—Physico-chemical properties
- C10N2020/02—Viscosity; Viscosity index
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/04—Detergent property or dispersant property
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/08—Resistance to extreme temperature
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/72—Extended drain
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/76—Reduction of noise, shudder, or vibrations
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- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
The present invention discloses a kind of energy-saving and emission-reduction steam turbine oil formula and its compound method, belong to formula of oil field, by the PAO4 synthetic base oils of 73 76 parts by weight, the PAO2 synthetic base oils of 46 parts by weight, the pour-point depressant of 0.4 0.6 parts by weight, the tackifier of 10 12 parts by weight, 8 10 parts by weight complexing agent hybrid modulation after, the additive A or additive B of 35 parts by weight are added after 60 70 DEG C, stirs 45 minutes and is made.The present invention is with increase power, energy-saving, reduction noise, cold-starting, reduction pollution, reduction resonance, reduction oil temperature, the function of cleaning, oil product heat endurance itself, inoxidizability can be strengthened, extension device service life, and high efficiency, oil saving, energy-conserving and environment-protective.
Description
Technical field
The present invention relates to a kind of formula of oil, more particularly to a kind of energy-saving and emission-reduction petrol engine oil formula.
Background technology
Ended for the end of the year 2016, national vehicle guaranteeding organic quantity is up to 2.9 hundred million, with the continuous growth of automobile, the waste gas of automobile
Discharge also constantly increase, has a strong impact on health of people, influences the two large divisions of exhaust emissions, and one is that fuel oil one is lubrication
Oil.
Internal lube oil in the market has thousands of kinds of lubricating oil brands at present, and it is limited to be capable of the lubrication technology of energy-saving and emission-reduction, greatly
The replacement cycle of most machine oil is all that the resistance to elevated temperatures and antioxygenic property of many oil products did not reached at 3 months or 5000 kilometers
Mark and itself there is no cleaning capacity, cause the increase of the carbon distribution greasy filth of engine, have a strong impact on service life and the increasing of engine
Add exhaust emissions.
The content of the invention
To solve the deficiencies in the prior art, the present invention is intended to provide a kind of energy-saving and emission-reduction steam turbine oil formula and its preparation side
Method.
To reach above-mentioned purpose, the technical solution adopted by the present invention is as follows：
A kind of energy-saving and emission-reduction steam turbine oil formula disclosed by the invention, including following components：The PAO4 synthesis of 73-76 parts by weight
Base oil, the PAO2 synthetic base oils of 4-6 parts by weight, the pour-point depressant of 0.4-0.6 parts by weight, tackifier, the 8- of 10-12 parts by weight
The complexing agent of 10 parts by weight, the additive A or additive B of 3-5 parts by weight,
The additive A is made by following steps：
(a) 3% sodium hypochlorite of 2 parts by volume is entered into the diesel oil of 45 parts by volume, turns into one kind without sulphur fuel oil；
(b) it is whole water and the debris formed by sodium hypochlorite are cleared；
(c) lead naphthenate, the no sulphur fuel oil and 15 parts by volume of 15 parts by volume of 30 parts by volume lead tolerance 24% are blended
Light mineral oil, form a kind of admixture；
(d) admixture at a slow speed and is heated uniformly to 66.6 DEG C；
The additive B is made by following methods：
3% sodium hypochlorite of 2 parts by volume is added in the carbon-based fuel oil of lightweight of 45 parts by volume, and by it and a kind of cycloalkanes
Sour metallic soap and the light mineral oil blending for being substantially free of zinc, are then heated to 66.6 DEG C by admixture.
Preferably, the formula includes following components：PAO4 synthetic base oils, the PAO2 of 5 parts by weight of 74.5 parts by weight
The addition of synthetic base oil, the pour-point depressant of 0.5 parts by weight, the tackifier of 11 parts by weight, the complexing agent of 9 parts by weight, 3-5 parts by weight
Agent A or additive B.
Further, the addition of the additive A or additive B is 4 parts by weight.
Further, the addition of the additive A or additive B is 3 parts by weight.
Preferably, the tackifier are the tackifier of Lu Borun 7067.
Preferably, the complexing agent is the complexing agent of Chevron Corporation 55501.
Further, the aphthenic acids metallic soap is lead naphthenate, calcium naphthenate, zirconium naphthenate or zinc naphthenate.
Further, the whistle base benzene of 0.5 parts by volume 0.75% is added before (d) step.
A kind of preparation method of energy-saving and emission-reduction steam turbine oil, comprises the following steps：
1) by the PAO4 synthetic base oils of 73-76 parts by weight, the PAO2 synthetic base oils of 4-6 parts by weight, 0.4-0.6 weight
Part pour-point depressant, the tackifier of 10-12 parts by weight, the complexing agent hybrid modulation of 8-10 parts by weight is into intermediate product C；
2) the intermediate product C is heated up to add after 60-70 DEG C to the additive A or additive B of 3-5 parts by weight, stirred
Mix 45 minutes and obtain product.
PAO：Full name Poly Alpha Olefins, it is polyalpha olefin synthetic base oil.Number in PAO4 and PAO2
Value represents the viscosity of the oil product, and PAO4 and PAO2 are low viscosity series.
The invention has the advantages that：
1. the invention enables equipment to have superior abrasion resistance --- enjoy and feel close to " 0 " friction is magical；
2. unique greasy property --- being capable of 2-5 times of prolonged mechanical service life of equipment；
3. increase power --- lifting engine output is up to 30%；
It is 4. energy-saving --- oil consumption is substantially reduced, fuel oil is saved and is up to 35%；
5. noise is reduced --- after engine is run 30 seconds, noise significantly reduces, and improves driving comfort and enjoyment；
6. cold-starting ----in cold snap, it is easy to start, and can reduce by 65% cold start-up friction；
7. reduce pollution ----reduce exhaust emissions；
8. reduce resonance ----greatly reduce engine and produce resonance, improve the stability of vehicle and handling；
9. reduce oil temperature ----heat energy caused by friction is reduced, stable oil temperature is in normal range value；
10. cleaning function ----cleaning engine cylinder-body carbon distribution and greasy filth, improve the greasy property of lubricating oil；
11. the present invention can strengthen oil product heat endurance itself, inoxidizability, extension device service life, and efficiently
Fuel-economizing, energy-conserving and environment-protective.
Embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, the present invention is carried out further detailed
Explanation.
Embodiment one：
The raw material of steam turbine oil formula includes the PAO4 synthetic base oils that mass percent is 74.5%, and mass percent is
5% PAO2 synthetic base oils, mass percent are 0.5% pour-point depressant, and the Lu Borun 7067 that mass percent is 11% increases
Stick, mass percent are 9% complexing agent of Chevron Corporation 55501.Formula is tuned into finished product steam turbine oil up to standard more than.Again
The additive A that addition 4% is heated up to after 60-70 DEG C from product oil is stirred 45 minutes and special formed.
Additive A is made by following steps：
(a) 3% sodium hypochlorite of 2 parts by volume is entered into the diesel oil of 45 parts by volume, turns into one kind without sulphur fuel oil；
(b) it is whole water and the debris formed by sodium hypochlorite are cleared；
(c) blend the lead naphthenates of 30 parts by volume lead tolerance 24%, 15 parts by volume without sulphur fuel oil and 15 parts by volume lightweights
Mineral oil, form a kind of admixture；
(d) admixture at a slow speed and is heated uniformly to 66.6 DEG C.
The additive A of above-mentioned steps production is applied to the product for civilian use；When products application is in industrial goods, (d) step it
The preceding whistle base benzene for adding 0.5 parts by volume 0.75%.
Embodiment two：
The raw material of steam turbine oil formula includes the PAO4 synthetic base oils that mass percent is 74.5%, and mass percent is
5% PAO2 synthetic base oils, mass percent are 0.5% pour-point depressant, and the Lu Borun 7067 that mass percent is 11% increases
Stick, mass percent are 9% complexing agent of Chevron Corporation 55501.Formula is tuned into finished product steam turbine oil up to standard more than.Again
The additive B that addition 5% is heated up to after 60-70 DEG C from product oil is stirred 45 minutes and special formed.
Additive B is made by following methods：
3% sodium hypochlorite of 2 parts by volume is added in the carbon-based fuel oil of lightweight of 45 parts by volume, and by it and a kind of cycloalkanes
Sour metallic soap and the light mineral oil blending for being substantially free of zinc, are then heated to 66.6 DEG C by admixture.
Specifically, lead naphthenate, calcium naphthenate, zirconium naphthenate or zinc naphthenate can be selected in aphthenic acids metallic soap.
The advantage of the invention is that：Conventional lubrication oil can be one layer of oil of holding on two surfaces to be contacted with each other in motion
Film, the surface of two contacts is separated, and resist slip, caused friction in rolling or shearing motion.In fact, fluid
Dynamic lubrication, hydrostatic lubrication and boundary lubrication occur in the plant equipment for needing to lubricate simultaneously.Overwhelming majority lubrication production
Product also can solve the problem that these lubrication problems.The present invention walks more advanced more environmentally friendly than plain oil in greasy property this step
It is more energy efficient, not only help to provide splendid lubricating oil film, moreover it is possible to form full oil film protective layer in metal friction surface.Specifically from
Under several aspects illustrate：
1. types of lubrication
Most lubricating oil is divided into following species：Mineral (paraffin, cycloalkanes, pitch), synthetic (ester, polymerization
Thing), solid (graphite, curing group, Teflon), or grease (oil containing various organic or inorganic thickening agents).
Contain multiple additives in lubricating oil product：Preservative, antirust agent etc..Such as in Modern motor oils, usually contain 8-10
The different additive of kind, the 15-20% of machine oil total amount is accounted for, balanced with the petroleum base of refinement or the crude oil of synthesis base.Some lubrications
In product containing particulate additive (such as：Graphite, molybdenum disulfide, Teflon) improve the anti-extreme pressure energy of lubricating oil.The present invention
It is made up of pure oil and pure petroleum additive, therefore any side effect related to particulate additive will not be brought.
2. lubrication mechanism of the present invention
The energy of friction consumption is directly changed into heat.When countless miniature prominent surface (mat surface) motions on metal surface
When, mat surface wears out lubricating oil film, collides, thus produces heat.During using plain oil, we generally can be in oil
Middle range estimation is arrived：When these coarse points mutually hit, meeting is broken at once, is caused " galling ".But it is different from conventional lubrication oil, this
Invention has extremely strong lubricating oil film, and rough surface is adjusted in terms of heat, so as to along the direction of mechanical shock, help to permeate
These mat surfaces mutually impacted are wrapped up, keep oil film continuous.
The oil film protection of formation becomes flat pattern, into cylindrical or flat shearing vertical plane.Tend to be flat
Mat surface greatly expand the gross area of two potential contact surfaces, therefore bigger area is provided for bearing load.It is latent
It can strengthen load capacity in the increase of contact area, or extend abrasion timeliness, or both and get both.
In addition, in the case where running at high speed, when occurring face to face with the shock in face, although this shock is very faint, it is enough
Destroy the molecular pattern and crystal structure of oil film.When trellis or crystal structure are destroyed inside steel, while produce micro-
See the lower substantial amounts of heat of local generation.When heat reaches Isosorbide-5-Nitrae 00-1, during 800 degrees Fahrenheit, usual crystal pattern because heat at once
Austenite crystal bulk-mode is expanded into, can allow of the invention free enter and permanent in this loose austenite crystal bulk-mode
Stop wherein to property.This metal surface that is entrapped in forms one layer of tempered oil film, a thin layer of similar to having been plated on surface
Alloy strengthens resistance friction and hardening capacity.
Plain oil often departs from these regions of lubrication at these temperatures, and they cannot propagate into austenite matrix
Pattern, and then oil film can not be hardened and reduced and worn.However, the lubricating oil film of the present invention carries strong positive electricity, can be tight
Tightly it is adhered to metal surface.Remain to keep tightly adhering at the abovementioned high temperatures, the present invention can enter crystal pattern, according to metallurgy
Learn principle to decompose at once, change oil film Surface hardened layer and frictional behavior.
Only because the infiltration oil film time is inadequate, these oil films for being changed characteristic only only have the thickness of crystal pattern
Degree, or it is more slightly thicker than crystal pattern.It is this circulating when friction occurs due to the self-regeneration characteristic of the present invention
Invade bubble constantly to repeat to be located at below oil film, in outside not wrapped crystal pattern into next, automatically form guarantor
Shield reduces abrasion.
Evidence show：Abrasion or seizing surface can form polishing and polishing effect suddenly, and polishing and polishing are corresponding again
The abrasion bump of smooth lengthening can be made substantially to harden.The outstanding value of the present invention is that it can be repaired to seizing surface through row.
This reparation means that former abrasion can provide a volume by Slow Down or stopping to mechanical last failure now
Outer buffer time.
If seizing, reparation leaching of the present invention with constantly circulation repeatedly because bearing load is very big, then occurs for machinery
It is this seizing that bubble parcel can compensate reparation automatically.When area of localised wear amplifies, load, which is worn, is dispersed in larger region, thus single
First stress reduces.Shown according to the evidence of the test machine measured equipped with electronic monitoring ampere meter：This polishing effect often reduces
Coefficient of friction.Impaired region, by repair process, it can almost be used with before, and with a surprising low friction resistance
Power.
Surface hardened layer phenomenon may have two reasons：A part is due to located immediately at a large amount of of very weak friction surface
Quenching is produced under cooling steel to be influenceed, and another part reason is to produce ion implanting in austenite phase.
3. unique operation principle
All materials in universe are all made up of molecule, their either positively charged or negative electrical charges.Traditional lubrication
Oil and bearing metal are made up of negatively charged molecule.Due to " identical charges repel each other " between molecule, therefore lubricate oil molecule and bearing
There is no that van der Waals' force between metal.When lubricating oil bears extreme pressure, oil molecule can be walked by " crowded ".This conventional profit
Why so important oil viscosity is.Due to oxonium ion positively charged, when oxonium ion is attracted by the anion of bearing,
Corrosion process is begun to.After preparation method processing of the lubricating oil by the present invention, chemical change, negative electricity originally can be produced
Lotus becomes positive charge.At this moment, lubricate oil molecule and produce attraction between each other with bearing metal molecule.This attraction makes axle
Hold the lubricating oil film that metal surface adhering to one layer of flexible adhesive force extra-heavy, the thickness of a molecule.In this case, glue
Spend just becomes less important for providing appropriate lubrication.Because electric charge has certain intensity, sediment and pollutant
All it is rejected as an outsider.And the positive charge of institute's band can repel positively charged oxonium ion in lubricating oil, make the corrosion of metal surface
Chance is reduced.Metal is protect by one layer of superpower lubricating oil film of adhesive force, and corrosion also will not be there occurs.Friction and wear also will
Substantially reduce.
4. summarize
Other benefits of the present invention are as follows：
1. due to its ionic charge feature, excellent adsorption capacity is made it have.This means when engine or other machines
When tool equipment shuts down, oil molecule of the invention " will not be squeezed away " easily, but tightly be adsorbed in metal surface, significantly
Reduce the wear phenomenon occurred when " dry to start ".
2. tough and tensile metal surface crystal structure ability.
3. surprising reduction coefficient of friction, long-effective protection oil film is formed in metal surface.
4. reproducing repeatedly, there are hardening and repair to Worn metal surface.
Using small day qin machine, the performance of the senior lubricant of in the market two and the steam turbine oil of embodiment two is contrasted, tied
Fruit such as table one：
A1：Mobil 5W40 oil-bath lubrications, 7 counterweights；
A2：Castrol 5W40 oil-bath lubrications, 6 counterweights；
A3：The oil-bath lubrication of embodiment two, 13 counterweights；
A4：The infiltration recession oil removing groove of embodiment two, 13 counterweights；
A5：The infiltration recession oil removing groove of embodiment two, installs tank, 13 counterweights；
The experimental condition of 1. each test example of table and wear-resistant effect
This experiment is the data that simulated automotive engine is obtained under extreme operating condition, as shown in Table 1, embodiment two
The more existing senior lubricant of film strength greatly improve, in the severe working environment such as high temperature, high pressure, oil starvation, infiltration
Under, remain to keep mechanical normal operation, and its wear-resistant more existing senior lubricant of effect improves more than 80%.
Certainly, the present invention can also have other various embodiments, ripe in the case of without departing substantially from spirit of the invention and its essence
Various corresponding changes and deformation, but these corresponding changes and deformation can be made according to the present invention by knowing those skilled in the art
The protection domain of appended claims of the invention should all be belonged to.
Claims (9)
1. a kind of energy-saving and emission-reduction steam turbine oil formula, it is characterised in that including following components：The PAO4 synthesis bases of 73-76 parts by weight
Plinth oil, the PAO2 synthetic base oils of 4-6 parts by weight, the pour-point depressant of 0.4-0.6 parts by weight, tackifier, the 8-10 of 10-12 parts by weight
The complexing agent of parts by weight, the additive A or additive B of 3-5 parts by weight,
The additive A is made by following steps：
(a) 3% sodium hypochlorite of 2 parts by volume is entered into the diesel oil of 45 parts by volume, turns into one kind without sulphur fuel oil；
(b) it is whole water and the debris formed by sodium hypochlorite are cleared；
(c) lead naphthenate, the no sulphur fuel oil and 15 parts by volume lightweights of 15 parts by volume of 30 parts by volume lead tolerance 24% are blended
Mineral oil, form a kind of admixture；
(d) admixture at a slow speed and is heated uniformly to 66.6 DEG C；
The additive B is made by following methods：
3% sodium hypochlorite of 2 parts by volume is added in the carbon-based fuel oil of lightweight of 45 parts by volume, and it and a kind of aphthenic acids is golden
Category soap and the light mineral oil blending for being substantially free of zinc, are then heated to 66.6 DEG C by admixture.
2. a kind of energy-saving and emission-reduction steam turbine oil formula according to claim 1, it is characterised in that including following components：74.5
The PAO4 synthetic base oils of parts by weight, the PAO2 synthetic base oils of 5 parts by weight, 0.5 parts by weight pour-point depressant, 11 parts by weight increasing
Stick, the complexing agent of 9 parts by weight, the additive A of 3-5 parts by weight or additive B.
3. a kind of energy-saving and emission-reduction steam turbine oil formula according to claim 2, it is characterised in that the additive A adds
The addition for adding agent B is 4 parts by weight.
4. a kind of energy-saving and emission-reduction steam turbine oil formula according to claim 2, it is characterised in that the additive A adds
The addition for adding agent B is 3 parts by weight.
A kind of 5. energy-saving and emission-reduction steam turbine oil formula according to claim 1-4 any one, it is characterised in that the thickening
Agent is the tackifier of Lu Borun 7067.
6. a kind of energy-saving and emission-reduction steam turbine oil formula according to claim 1-4 any one, it is characterised in that described compound
Agent is the complexing agent of Chevron Corporation 55501.
A kind of 7. energy-saving and emission-reduction steam turbine oil formula according to claim 1-4 any one, it is characterised in that the cycloalkanes
Sour metallic soap is lead naphthenate, calcium naphthenate, zirconium naphthenate or zinc naphthenate.
8. a kind of energy-saving and emission-reduction steam turbine oil formula according to claim 1-4 any one, it is characterised in that (d)
The whistle base benzene of 0.5 parts by volume 0.75% is added before step.
A kind of 9. preparation method of energy-saving and emission-reduction steam turbine oil according to claim 1-8 any one, it is characterised in that bag
Include following steps：
1) by the PAO4 synthetic base oils of 73-76 parts by weight, the PAO2 synthetic base oils of 4-6 parts by weight, 0.4-0.6 parts by weight
Pour-point depressant, the tackifier of 10-12 parts by weight, the complexing agent hybrid modulation of 8-10 parts by weight are into intermediate product C；
2) the intermediate product C is heated up to add after 60-70 DEG C to the additive A or additive B of 3-5 parts by weight, stirring 45
Minute obtains product.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN112210424A (en) * | 2019-07-11 | 2021-01-12 | 广州市万灵霸环保产品有限公司 | Preparation method of lubricating oil for large heavy-load mobile equipment |
| CN112210419A (en) * | 2019-07-11 | 2021-01-12 | 广州市万灵霸环保产品有限公司 | Strong anti-wear energy-saving lubricating oil additive and lubricating oil preparation method |
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| WO2015092736A1 (en) * | 2013-12-20 | 2015-06-25 | Organización Terpel S.A | Lubricating composition with a synthetic base |
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| CN1041969A (en) * | 1985-05-02 | 1990-05-09 | 赫伯特·毕晓普 | Lubricating oil additive |
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| CN112210424A (en) * | 2019-07-11 | 2021-01-12 | 广州市万灵霸环保产品有限公司 | Preparation method of lubricating oil for large heavy-load mobile equipment |
| CN112210419A (en) * | 2019-07-11 | 2021-01-12 | 广州市万灵霸环保产品有限公司 | Strong anti-wear energy-saving lubricating oil additive and lubricating oil preparation method |
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