CN107523366A - One kind carries high-octane gasoline environmental-protection additive - Google Patents
One kind carries high-octane gasoline environmental-protection additive Download PDFInfo
- Publication number
- CN107523366A CN107523366A CN201710942002.6A CN201710942002A CN107523366A CN 107523366 A CN107523366 A CN 107523366A CN 201710942002 A CN201710942002 A CN 201710942002A CN 107523366 A CN107523366 A CN 107523366A
- Authority
- CN
- China
- Prior art keywords
- parts
- additive
- gasoline
- dialkyl
- methyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/143—Organic compounds mixtures of organic macromolecular compounds with organic non-macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/10—Use of additives to fuels or fires for particular purposes for improving the octane number
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/16—Hydrocarbons
- C10L1/1608—Well defined compounds, e.g. hexane, benzene
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/16—Hydrocarbons
- C10L1/1616—Hydrocarbons fractions, e.g. lubricants, solvents, naphta, bitumen, tars, terpentine
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
- C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
- C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
- C10L1/1852—Ethers; Acetals; Ketals; Orthoesters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
- C10L1/223—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond having at least one amino group bound to an aromatic carbon atom
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/234—Macromolecular compounds
- C10L1/236—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derivatives thereof
- C10L1/2366—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derivatives thereof homo- or copolymers derived from unsaturated compounds containing amine groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/30—Organic compounds compounds not mentioned before (complexes)
- C10L1/305—Organic compounds compounds not mentioned before (complexes) organo-metallic compounds (containing a metal to carbon bond)
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Liquid Carbonaceous Fuels (AREA)
Abstract
The invention discloses a kind of environmental-protection additive for improving octane number, the additive includes：0.2~0.25 part of methyl cyclopentyl-dialkyl-tricarbon manganium, 10~60 parts of methyl tertiary butyl ether(MTBE), 5~40 parts of absolute ethyl alcohol, 5~30 parts of absolute methanol, 5~15 parts of monomethyl aniline (MMA), 5~15 parts of dimethylbenzene, 5~40 parts of naphtha, 5~20 parts of polyetheramine.The additive can improve octane number 3~5 point, reduce pinking, improve ignition advance angle, so as to improve the power output of engine, gasoline is fully burnt in cylinder body, and oil-saving effect is notable, and can reduce exhaust emissions, have the effect of energy-conserving and environment-protective；The usage amount of methyl cyclopentyl-dialkyl-tricarbon manganium is controlled within 5mg/L simultaneously.
Description
Technical field
The present invention relates to a kind of gasoline additive, and in particular to a kind of environmental-protection additive for improving octane number.
Background technology
With the development of country and the raising of living standards of the people, auto industry develops rapidly, the demand of motor petrol
Also it is increasing.Due to deficiency existing for the existing quality problems of fuel oil itself and the motor vehicle machine-building limit, so as to produce
The sharp effect of raw food, gap effect, pinking, intake valve, electric carbon trumpet easily occurs, waste fuel oil, exhaust emission air etc..
Petrol engine generation pinking is largely relevant with fuel performance and engine structure, if the easy oxygen of gasoline
The peroxide hardly possible change, formed is decomposed, self-ignition point is low, and phenomenon of detonation just easily occurs.Anti-knock characteristic of gasoline is that quality of gasoline is most heavy
One of index wanted, evaluated with octane number.Therefore, the domestic research about clean gasoline is persistently carried out, and it have developed one
Serial high-knock rating gasoline additive, makes the clean gasoline in China be enhanced and develop.Petrol engine compression ratio
Improve, the increase of its thermal efficiency, oil consumption decline, it is desirable to which octane number also increases, and improves the most effective and most economical approach of octane number
It is exactly to add gasoline additive in the oil.
At present, additive methyl cyclopentyl-dialkyl-tricarbon manganium (MMT) is maximally effective anti-when high engine load
Knocker, therefore add a small amount of MMT and very big advantage be present for high engine load operation.Also disclose that in the prior art more
Kind includes methyl cyclopentyl-dialkyl-tricarbon manganium (MMT) gasoline additive, as CN102746919A discloses a kind of gasoline octane
It is worth elevator, the additive is by RONA methyl cyclopentyl-dialkyl-tricarbon manganium (MMT), alcohols octane rating promoter, amine
Class accelerator, amide-type accelerator, induced by alkyl hydroxybenzene octane enhancer, metal draw additive and cosolvent composition；Using
The octane number modifier of the present invention can improve 2.0~10.0 units of octane number of gasoline, while the octane enhancing additive
The characteristics of with engine deposits increase is prevented, automobile engine will not be caused to damage.
CN1536055A discloses a kind of anti-knock, and it is by toluene, methyl tertiary butyl ether, methyl ring penta
Diene manganese tricarbonyl is formulated in proportion, can effectively improve the octane number and gasoline label of gasoline, reduces gasoline knocking,
Have good burning performance.
CN1544587A discloses a kind of high efficiency fuel combustion adjuvant, and it is by the tertiary butyl ether of low alkyl group, methyl cyclopentadiene
Manganese tricarbonyl, butoxy benzene, carbon number be 3-5 lower alcohol, cetyl benzenesulfonic acid potassium, zinc petroleum sulfonate, petrolic magnesium sulfonate,
No. 200 solvent naphthas of dichloromethane, ferrocene and surplus.The combustion aid of fuel oil that the invention provides, it is possible to increase automobile power, section
Oil cut rate, tail gas clean-up rate, the maintainability of engine and entirety, octane number etc..
However, often there is the problem of methyl cyclopentyl-dialkyl-tricarbon manganium (MMT) is higher, MMT in above-mentioned gasoline additive
Content is higher to cause engine to produce heavy metal manganese residual in operation, and in engine cylinder, ternary catalyzing unit can produce
Raw serious residual, can not only influence engine performance, and can seriously pollute environment；And the vapour improved in CN102746919A
Oil additive can lift 2~10 units, add 18mg/L MMT according to the gasoline standard of state four in theory and can lift 3-5
It is individual, therefore objection be present in the octane number lifting improved in above invention.
The pernicious gas of motor vehicle emission, the health of people is had a strong impact on, it is highly unwanted to human health.Improve gasoline
Cleanliness factor and octane number, which make gasoline fully burn, is current chemical field and the problem of auto industry is extremely paid close attention to, except refining oil
Outside the clean gasoline that olefin(e) centent is reduced in factory's production, it is also to be commonly used in domestic and international chemical industry that additive is added in product oil
Method.Therefore, need that a kind of methyl cyclopentyl-dialkyl-tricarbon manganium (MMT) content is less and can to provide gasoline simultaneously clean badly at present
The environmental-protection additive of cleanliness and octane number.
The content of the invention
According to above-mentioned prior art, for causing that methyl cyclopentyl-dialkyl-tricarbon manganium contains in gasoline after addition gasoline additive
The problems such as amount is higher, the purpose of the present invention be invented it is a kind of it is new carry high-octane gasoline environmental-protection additive, the addition
Agent can significantly improve octane number, by coordinating the use of methyl tertiary butyl ether(MTBE) and naphtha substantially to reduce MMT use
Amount, and residual of the heavy metal manganese in engine interior is reduced by the solvent of no-float.The additive can make gasoline exist
Fully burnt in cylinder body, reduce pinking, improve ignition advance angle, so as to improve the power output of engine, reduce oil consumption；This adds
Add and contain polyetheramine in agent, can effectively remove carbon-deposits the cylinder, safeguard engine performance；The gasoline additive of the present invention passes through
Test of many times, obtain the concentration proportioning of optimum efficiency；In addition, the additive Environmental Safety, it is clean can be effectively improved oil product
Cleanliness, environmental pollution is small, and economic benefit and social benefit are notable.
To achieve the above object, the technical solution adopted by the present invention is as follows：
The first aspect of the invention, improve one kind and carry high-octane gasoline environmental-protection additive, by following parts by weight
Component forms：
The second aspect of the invention, there is provided the above-mentioned preparation method for carrying high-octane gasoline environmental-protection additive, including
Following steps：
(1) absolute ethyl alcohol, absolute methanol are mixed in proportion, and stirred；
(2) monomethyl aniline (MMA), dimethylbenzene are proportionally added into the mixed liquor of step (1), and stirred；
(3) methyl tertiary butyl ether(MTBE), naphtha are proportionally added into the mixed liquor of step (2), and stirred；
(4) polyetheramine is proportionally added into the mixed liquor of step (3), and stirred；
(5) under conditions of strict lucifuge, methyl cyclopentyl-dialkyl-tricarbon manganium is proportionally added to the mixed of step (4)
Close in solution, and stir, that is, be improved the gasoline environmental-protection additive of octane number.
The third aspect of the invention, there is provided application of the above-mentioned additive in octane number is improved.
Compared with prior art, technical scheme has the advantages that：
The gasoline additive of the present invention is added in gasoline according to the amount of one thousandth to 2/1000ths when in use, can be with
Octane number 3~5 point are improved, reduce pinking, ignition advance angle is improved, so as to improve the power output of engine, makes gasoline in cylinder
Fully burning in vivo, oil-saving effect is notable, and can reduce exhaust emissions, has the effect of energy-conserving and environment-protective；The additive is tight
Lattice control the usage amount of methyl cyclopentyl-dialkyl-tricarbon manganium within 5mg/L, and in solvent monomethyl aniline (MMA), dimethylbenzene, first
Burning is completely dissolved and participated in the presence of alcohol and ethanol, so as to smoothly discharge outside engine, present invention lifting octane number
Active ingredient also include methyl tertiary butyl ether(MTBE) and naphtha, the carbonyl of methyl cyclopentadiene three is reduced by the addition of both
The concentration of manganese；Polyetheramine is included in the active ingredient of the additive, gasoline cleanliness factor can be effectively improved, clears up carbon-deposits the cylinder,
Economic benefit and social benefit are notable.
Embodiment
It is noted that described further below is all exemplary, it is intended to provides further instruction to the present invention.It is unless another
Indicate, all technologies used herein and scientific terminology are with usual with general technical staff of the technical field of the invention
The identical meanings of understanding.
It should be noted that term used herein above is merely to describe embodiment, and be not intended to restricted root
According to the illustrative embodiments of the present invention.As used herein, unless the context clearly indicates otherwise, otherwise singulative
It is also intended to include plural form, additionally, it should be understood that, when in this manual using term "comprising" and/or " bag
Include " when, it indicates existing characteristics, step, operation and/or combinations thereof.
The molecular weight of the polyetheramine used in the present invention is 230~5000 dalton.
As background technology is introduced, gasoline additive of the prior art, which exists, causes methyl cyclopentadiene in gasoline
The problem of manganese tricarbonyl (MMT) content is higher, MMT contents are higher, and that engine can be caused to produce heavy metal manganese in operation is residual
Stay, in engine cylinder, ternary catalyzing unit can produce serious residual, can not only influence engine performance, and can seriously pollute
Environment, in order to solve technical problem as above, the present invention proposes one kind and carries high-octane gasoline environmental-protection additive, by following
The component composition of parts by weight：
In the gasoline additive of the present invention, most important composition is methyl cyclopentyl-dialkyl-tricarbon manganium, methyl tertbutyl
Ether, naphtha and polyetheramine, methyl cyclopentyl-dialkyl-tricarbon manganium can effectively improve gasoline quality, improve octane number, combustion
Burn property it is good, under appropriate concentration conditions can with fuel together completely burned without produce precipitation or residue, excessive concentration it is then easy
Produce heavy-metal residual；The basic octane number RON of methyl tertiary butyl ether(MTBE) is 118, is excellent gasoline high-octane rating additive, its
Chemical property is stable, and oxygen content is of a relatively high, can significantly improve motor vehicle exhaust emission, reduces containing for carbon monoxide in tail gas
Amount, and high combustion efficiency, can suppress the generation of ozone；Naphtha is the neccessary composition that octane rating gasoline is done in production, at this
Mainly play solvent and higher octane accelerator in the gasoline additive of invention；Polyetheramine is a kind of high polymer material, resistance to height
It is warm, not volatile, strong cleaning can be carried out to in-engine carbon distribution, in the gasoline additive of the present invention and led
Clean the effect of carbon on engine；Absolute ethyl alcohol and absolute methanol are a kind of octane rating promoters, are added in the gasoline of the present invention
Add in agent, it is notable with methyl cyclopentyl-dialkyl-tricarbon manganium, methyl tertiary butyl ether(MTBE) and naphtha synergy, hydro carbons can be greatly reduced
Activation energy, enhance the capability of antidetonance；Effect of the monomethyl aniline (MMA) in the gasoline additive of the present invention is the steady of raising oil product
It is qualitative；Dimethylbenzene is cosolvent, improves the dissolution velocity between reagent.
The present invention uses the mixing conduct of three kinds of methyl cyclopentyl-dialkyl-tricarbon manganium, methyl tertiary butyl ether(MTBE) and naphtha materials
Gasoline antiknock shakes agent, and methyl cyclopentyl-dialkyl-tricarbon manganium is a kind of cheap, positive effect octane number elevator, is being started
Machine is in during high loaded process, and methyl cyclopentyl-dialkyl-tricarbon manganium can effectively reduce combustion knock, lifts engine
Performance, but it is a kind of reagent that dispute be present, is not easy to discharge in engine, easily produces residual, current domestic stone
Oily industry is also gradually reducing its usage amount.It is strict to control making for methyl cyclopentyl-dialkyl-tricarbon manganium in the formula of the present invention
Dosage is completely dissolved and participated in burning under the action of the solvent within 5mg/L, so as to smoothly discharge engine
Outside, in addition the present invention lifting octane number active ingredient also include methyl tertiary butyl ether(MTBE) and naphtha, have been surprisingly found that, by this two
The addition of person can significantly reduce the concentration of methyl cyclopentyl-dialkyl-tricarbon manganium.
Monomethyl aniline (MMA), dimethylbenzene and polyetheramine, monomethyl aniline (MMA) and dimethylbenzene are added in technical scheme
All it is good solvent, can not only lifts the stability of oil product, can also be methyl cyclopentyl-dialkyl-tricarbon manganium in engine
Residual smoothly discharge engine；Polyetheramine can carry out strong cleaning to in-engine carbon distribution, reduce engine and sink
Product thing, improves fuel oil efficiency of combustion.
Absolute ethyl alcohol and absolute methanol are added in technical scheme, is used as octane rating promoter, with first
Butylcyclopentadiene manganese tricarbonyl, methyl tertiary butyl ether(MTBE) and naphtha synergy are notable, and methyl ring penta 2 can be greatly lowered
The usage amount of alkene manganese tricarbonyl, enhances the capability of antidetonance.
In a preferred embodiment of the present invention, it is described to carry high-octane gasoline environmental-protection additive, by following parts by weight
Component composition：
It is described to carry high-octane gasoline environmental-protection additive in a currently preferred embodiment, by following heavy
Measure the component composition of part：
0.25 part of methyl cyclopentyl-dialkyl-tricarbon manganium；
44.75 part methyl tertiary butyl ether(MTBE)；
10 parts of absolute ethyl alcohols；
10 parts of absolute methanols；
5 parts of monomethyl aniline (MMA)s；
5 parts of dimethylbenzene；
15 parts of naphthas；
10 parts of polyetheramines.
It is described to carry high-octane gasoline environmental-protection additive in another preferred embodiment of the present invention, by following
The component composition of parts by weight：
0.2 part of methyl cyclopentyl-dialkyl-tricarbon manganium；
39.8 part methyl tertiary butyl ether(MTBE)；
20 parts of absolute ethyl alcohols；
10 parts of absolute methanols；
5 parts of monomethyl aniline (MMA)s；
5 parts of dimethylbenzene；
5 parts of naphthas；
15 parts of polyetheramines.
It is described to carry high-octane gasoline environmental-protection additive in currently preferred further embodiment, by following
The component composition of parts by weight：
0.2 part of methyl cyclopentyl-dialkyl-tricarbon manganium；
49.8 part methyl tertiary butyl ether(MTBE)；
10 parts of absolute ethyl alcohols；
10 parts of absolute methanols；
5 parts of monomethyl aniline (MMA)s；
5 parts of dimethylbenzene；
10 parts of naphthas；
10 parts of polyetheramines.
It is described to carry high-octane gasoline environmental-protection additive in currently preferred further embodiment, by following
The component composition of parts by weight：
0.2 part of methyl cyclopentyl-dialkyl-tricarbon manganium；
59.8 part methyl tertiary butyl ether(MTBE)；
5 parts of absolute ethyl alcohols；
5 parts of absolute methanols；
5 parts of monomethyl aniline (MMA)s；
5 parts of dimethylbenzene；
10 parts of naphthas；
10 parts of polyetheramines.
In a preferred embodiment of the present invention, the above-mentioned preparation for carrying high-octane gasoline environmental-protection additive is additionally provided
Method, comprise the following steps：
(1) absolute ethyl alcohol, absolute methanol are mixed in proportion successively, and stirred；
(2) monomethyl aniline (MMA), dimethylbenzene are proportionally added into the mixed liquor of step (1) successively, and stirred；
(3) methyl tertiary butyl ether(MTBE), naphtha are proportionally added into the mixed liquor of step (2) successively, and stirred equal
It is even；
(4) polyetheramine is proportionally added into the mixed liquor of step (3), and stirred；
(5) under conditions of strict lucifuge, methyl cyclopentyl-dialkyl-tricarbon manganium is proportionally added to the mixed of step (4)
Close in solution, and stir, that is, be improved the gasoline environmental-protection additive of octane number.
According to method made above, reagent mixing can be made more uniform, avoid producing layering, under the conditions of strict lucifuge
The decomposed metamorphic of the gasoline additive can be prevented.
In a preferred embodiment of the present invention, application of the above-mentioned additive in octane number is improved also is provided.
In order that technical scheme can clearly be understood by obtaining those skilled in the art, below with reference to tool
The embodiment and comparative example of body describe technical scheme in detail.
Embodiment 1
It is a kind of to carry high-octane gasoline environmental-protection additive and be made up of the component of following parts by weight：0.25 part of methyl ring penta 2
Alkene manganese tricarbonyl, 44.75 parts of methyl tertiary butyl ether(MTBE)s, 10 parts of absolute ethyl alcohols, 10 parts of absolute methanols, 5 parts of monomethyl aniline (MMA)s, 5 part two
Toluene, 15 parts of naphthas, 10 parts of polyetheramines.
Its preparation method comprises the following steps：
(1) absolute ethyl alcohol, absolute methanol are mixed in proportion successively, and stirred；
(2) monomethyl aniline (MMA), dimethylbenzene are proportionally added into above-mentioned mixed liquor successively, and stirred；
(3) methyl tertiary butyl ether(MTBE), naphtha are proportionally added into above-mentioned mixed liquor successively, and stirred；
(4) polyetheramine is proportionally added into above-mentioned mixed liquor, and stirred；
(5) under conditions of strict lucifuge, proportionally methyl cyclopentyl-dialkyl-tricarbon manganium is added in mixed solution,
And stir.
Using the gasoline additive described in embodiment 1, it is added in No. 92 gasoline, leads to according to 2/1000ths volume ratio
Organon measure gasoline octane value changes are crossed, research finds the octane number lifting of No. 92 gasoline after addition additive of the invention
To No. 95；The moment of torsion enhancing that 2000~3000 turns of engine, engine power output are stronger more linear；Travel 100km and save vapour
Oil 10%；Changed by cylinder endoscopic observation carbon-deposits the cylinder, it is found that carbon-deposits the cylinder significantly reduces.
Embodiment 2
It is composed of the following components that one kind carries high-octane gasoline environmental-protection additive：0.2 part of carbonyl of methyl cyclopentadiene three
Manganese, 39.8 parts of methyl tertiary butyl ether(MTBE)s, 20 parts of absolute ethyl alcohols, 10 parts of absolute methanols, 5 parts of monomethyl aniline (MMA)s, 5 parts of dimethylbenzene, 5 parts of stones
Cerebrol, 15 parts of polyetheramines.
Its preparation method comprises the following steps：
(1) absolute ethyl alcohol, absolute methanol are mixed in proportion successively, and stirred；
(2) monomethyl aniline (MMA), dimethylbenzene are proportionally added into above-mentioned mixed liquor successively, and stirred；
(3) methyl tertiary butyl ether(MTBE), naphtha are proportionally added into above-mentioned mixed liquor successively, and stirred；
(4) polyetheramine is proportionally added into above-mentioned mixed liquor, and stirred；
(5) under conditions of strict lucifuge, proportionally methyl cyclopentyl-dialkyl-tricarbon manganium is added in mixed solution,
And stir.
Using the gasoline additive described in embodiment 2, it is added in No. 92 gasoline, leads to according to 2/1000ths volume ratio
Organon measure gasoline octane value changes are crossed, research finds the octane number lifting of No. 92 gasoline after addition additive of the invention
To No. 95；The moment of torsion enhancing that 2000~3000 turns of engine, engine power output are stronger more linear；Travel 100km and save vapour
Oil 10%；Changed by cylinder endoscopic observation carbon-deposits the cylinder, it is found that carbon-deposits the cylinder significantly reduces.
Embodiment 3
It is composed of the following components that one kind carries high-octane gasoline environmental-protection additive：0.2 part of carbonyl of methyl cyclopentadiene three
Manganese, 49.8 parts of methyl tertiary butyl ether(MTBE)s, 10 parts of absolute ethyl alcohols, 10 parts of absolute methanols, 5 parts of monomethyl aniline (MMA)s, 5 parts of dimethylbenzene, 10 parts
Naphtha, 10 parts of polyetheramines.
Its preparation method comprises the following steps：
(1) absolute ethyl alcohol, absolute methanol are mixed in proportion successively, and stirred；
(2) monomethyl aniline (MMA), dimethylbenzene are proportionally added into above-mentioned mixed liquor successively, and stirred；
(3) methyl tertiary butyl ether(MTBE), naphtha are proportionally added into above-mentioned mixed liquor successively, and stirred；
(4) polyetheramine is proportionally added into above-mentioned mixed liquor, and stirred；
(5) under conditions of strict lucifuge, proportionally methyl cyclopentyl-dialkyl-tricarbon manganium is added in mixed solution,
And stir.
Using the gasoline additive described in embodiment 3, it is added in No. 92 gasoline, leads to according to 2/1000ths volume ratio
Organon measure gasoline octane value changes are crossed, research finds the octane number lifting of No. 92 gasoline after addition additive of the invention
To No. 95.5；The moment of torsion enhancing that 2000~3000 turns of engine, engine power output are stronger more linear；100km is travelled to save
Gasoline 10%；Changed by cylinder endoscopic observation carbon-deposits the cylinder, it is found that carbon-deposits the cylinder significantly reduces.
Embodiment 4
It is composed of the following components that one kind carries high-octane gasoline environmental-protection additive：0.2 part of carbonyl of methyl cyclopentadiene three
Manganese, 59.8 parts of methyl tertiary butyl ether(MTBE)s, 5 parts of absolute ethyl alcohols, 5 parts of absolute methanols, 5 parts of monomethyl aniline (MMA)s, 5 parts of dimethylbenzene, 10 parts of stones
Cerebrol, 10 parts of polyetheramines.
Preparation method：
(1) absolute ethyl alcohol, absolute methanol are mixed in proportion successively, and stirred；
(2) monomethyl aniline (MMA), dimethylbenzene are proportionally added into above-mentioned mixed liquor successively, and stirred；
(3) methyl tertiary butyl ether(MTBE), naphtha are proportionally added into above-mentioned mixed liquor successively, and stirred；
(4) polyetheramine is proportionally added into above-mentioned mixed liquor, and stirred；
(5) under conditions of strict lucifuge, proportionally methyl cyclopentyl-dialkyl-tricarbon manganium is added in mixed solution,
And stir.
Using the gasoline additive described in embodiment 4, it is added in No. 92 gasoline, leads to according to 2/1000ths volume ratio
Organon measure gasoline octane value changes are crossed, research finds the octane number lifting of No. 92 gasoline after addition additive of the invention
To No. 96.5；The moment of torsion enhancing that 2000~3000 turns of engine, engine power output are stronger more linear；100km is travelled to save
Gasoline 10%；Changed by cylinder endoscopic observation carbon-deposits the cylinder, it is found that carbon-deposits the cylinder significantly reduces.
Above example proves that the gasoline additive of the present invention adds according to the amount of one thousandth to 2/1000ths when in use
Enter into gasoline, octane number 3~5 point can be improved in theory, reduce pinking, ignition advance angle is improved, so as to improve engine
Power output, gasoline is fully burnt in cylinder body, oil-saving effect is notable, and can reduce exhaust emissions, have energy-conservation
The effect of environmental protection；The additive strictly controls the usage amount of methyl cyclopentyl-dialkyl-tricarbon manganium within 5mg/L, and in solvent
Burning is completely dissolved and participated in the presence of monomethyl aniline (MMA), dimethylbenzene, methanol and ethanol, so as to smoothly discharge engine
Outside, the active ingredient of present invention lifting octane number also includes methyl tertiary butyl ether(MTBE) and naphtha, is shown by the supplement of both
Writing reduces the concentration of methyl cyclopentyl-dialkyl-tricarbon manganium；Polyetheramine is included in the active ingredient of the additive, can be effectively improved
Gasoline cleanliness factor, carbon-deposits the cylinder is cleared up, economic benefit and social benefit are notable.
Inventor employs different raw materials and different raw material proportioning contents is tried during experimental study
Test, the best results of some solution ratios and the easy caused bad problem of some proportionings found in the process tested,
It is comparing result example below：
The present embodiment 1 contrasts with embodiment in CN201210053039 4：MMT in CN201210053039 in embodiment 4
Content is 60mg/l, seriously more than national standard, generates serious heavy metal manganese residual, cylinder in engine in experimentation
Substantial amounts of pale brown color substance is adsorbed in interior and exhaust ternary, three-element catalytic fails after a period of time is run, engine exhaust
It is exceeded.And the present embodiment 1 does not produce any residue, the carbon distribution in engine cylinder is cleaned, three-element catalytic normal work, and
Possess and CN201210053039 identical anti-knocks.
Contrast the present embodiment 4 contrasts with embodiment in CN201210053039 6：In CN201210053039 in embodiment 4
MMT contents be 70.4mg/l, seriously more than national standard, serious heavy metal manganese is generated in engine in experimentation
Residual, cylinder is interior and is vented the substantial amounts of pale brown color substance of absorption in ternary, and three-element catalytic fails after a period of time is run, and starts
Machine exhaust is exceeded.And the present embodiment 4 does not produce any residue, the carbon distribution in engine cylinder is cleaned, the normal work of three-element catalytic
Make, and possess and CN201210053039 identical anti-knocks.
When carrying out contrast test, methyl cyclopentyl-dialkyl-tricarbon manganium, methyl tertiary butyl ether(MTBE) and naphtha three are found not
The octane number of increase gasoline can be only cooperateed with, and may also reach up and resist with high content methyl cyclopentyl-dialkyl-tricarbon manganium identical
Pinking ability.Meanwhile the polyetheramine in the present patent application can cooperate with and remove caused carbon distribution in engine, have well clear
Clean effect.
Above-described embodiment is the preferable embodiment of the present invention, but embodiments of the present invention are not by above-described embodiment
Limitation, other any Spirit Essences without departing from the present invention with made under principle change, modification, replacement, combine, simplification,
Equivalent substitute mode is should be, is included within protection scope of the present invention.
Claims (10)
1. one kind carries high-octane gasoline environmental-protection additive, it is characterized in that, it is made up of the component of following parts by weight：
0.2~0.25 part of methyl cyclopentyl-dialkyl-tricarbon manganium；
10~60 parts of methyl tertiary butyl ether(MTBE)；
5~40 parts of absolute ethyl alcohol；
5~30 parts of absolute methanol；
5~15 parts of monomethyl aniline (MMA)；
5~15 parts of dimethylbenzene；
5~40 parts of naphtha；
5~20 parts of polyetheramine.
2. additive as claimed in claim 1, it is characterized in that, it is made up of the component of following parts by weight：
0.2~0.25 part of methyl cyclopentyl-dialkyl-tricarbon manganium；
35~60 parts of methyl tertiary butyl ether(MTBE)；
5~20 parts of absolute ethyl alcohol；
5~10 parts of absolute methanol；
5~10 parts of monomethyl aniline (MMA)；
5~10 parts of dimethylbenzene；
5~15 parts of naphtha；
10~15 parts of polyetheramine.
3. additive as claimed in claim 2, it is characterized in that, it is made up of the component of following parts by weight：
0.25 part of methyl cyclopentyl-dialkyl-tricarbon manganium；
44.75 part methyl tertiary butyl ether(MTBE)；
10 parts of absolute ethyl alcohols；
10 parts of absolute methanols；
5 parts of monomethyl aniline (MMA)s；
5 parts of dimethylbenzene；
15 parts of naphthas；
10 parts of polyetheramines.
4. additive as claimed in claim 2, it is characterized in that, it is made up of the component of following parts by weight：
0.2 part of methyl cyclopentyl-dialkyl-tricarbon manganium；
39.8 part methyl tertiary butyl ether(MTBE)；
20 parts of absolute ethyl alcohols；
10 parts of absolute methanols；
5 parts of monomethyl aniline (MMA)s；
5 parts of dimethylbenzene；
5 parts of naphthas；
15 parts of polyetheramines.
5. additive as claimed in claim 2, it is characterized in that, it is made up of the component of following parts by weight：
0.2 part of methyl cyclopentyl-dialkyl-tricarbon manganium；
49.8 part methyl tertiary butyl ether(MTBE)；
10 parts of absolute ethyl alcohols；
10 parts of absolute methanols；
5 parts of monomethyl aniline (MMA)s；
5 parts of dimethylbenzene；
10 parts of naphthas；
10 parts of polyetheramines.
6. additive as claimed in claim 2, it is characterized in that, it is made up of the component of following parts by weight：
0.2 part of methyl cyclopentyl-dialkyl-tricarbon manganium；
59.8 part methyl tertiary butyl ether(MTBE)；
5 parts of absolute ethyl alcohols；
5 parts of absolute methanols；
5 parts of monomethyl aniline (MMA)s；
5 parts of dimethylbenzene；
10 parts of naphthas；
10 parts of polyetheramines.
7. the additive as any one of claim 1 ~ 6, it is characterized in that the molecular weight of the polyetheramine is 230 ~ 5000
Dalton.
8. the preparation method for carrying high-octane gasoline environmental-protection additive any one of claim 1 ~ 7, it is characterized in that,
Comprise the following steps：
（1）Absolute ethyl alcohol, absolute methanol are mixed in proportion, and stirred；
（2）Monomethyl aniline (MMA), dimethylbenzene are proportionally added into step（1）Mixed liquor in, and stir；
（3）Methyl tertiary butyl ether(MTBE), naphtha are proportionally added into step（2）Mixed liquor in, and stir；
（4）Polyetheramine is proportionally added into step（3）Mixed liquor in, and stir；
（5）Under conditions of strict lucifuge, methyl cyclopentyl-dialkyl-tricarbon manganium is proportionally added to step（4）Mixing it is molten
In liquid, and stir, that is, be improved the gasoline environmental-protection additive of octane number.
9. application of the additive in octane number is improved any one of claim 1 ~ 7.
10. application as claimed in claim 9, it is characterized in that：Volume by the additive according to one thousandth ~ thousand/bis-
Ratio is added in gasoline.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710942002.6A CN107523366A (en) | 2017-10-11 | 2017-10-11 | One kind carries high-octane gasoline environmental-protection additive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710942002.6A CN107523366A (en) | 2017-10-11 | 2017-10-11 | One kind carries high-octane gasoline environmental-protection additive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107523366A true CN107523366A (en) | 2017-12-29 |
Family
ID=60684898
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710942002.6A Pending CN107523366A (en) | 2017-10-11 | 2017-10-11 | One kind carries high-octane gasoline environmental-protection additive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107523366A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109294639A (en) * | 2018-11-23 | 2019-02-01 | 广东月福汽车用品有限公司 | A kind of fuel power elevator and preparation method thereof |
| CN109370668A (en) * | 2018-10-17 | 2019-02-22 | 湖南普瑞飞新能源科技有限公司 | A kind of energy-saving emission-reduction type gasoline additive and preparation method thereof |
| CN111996044A (en) * | 2020-09-04 | 2020-11-27 | 北京中燕恒成能源有限公司 | Primary oil for compound oxygen-containing compound vehicle and preparation method thereof |
| CN112574790A (en) * | 2020-11-23 | 2021-03-30 | 邵占林 | Gasoline cleaning synergist and preparation method thereof |
| CN115895743A (en) * | 2022-11-25 | 2023-04-04 | 山东京博新能源控股发展有限公司 | Power improver suitable for refitted vehicle fuel and fuel |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1526798A (en) * | 2003-09-23 | 2004-09-08 | 林金池 | Lead-less clean environment protection gasoline additive |
| CN101225332A (en) * | 2007-12-13 | 2008-07-23 | 南京石油化工股份有限公司 | Polyethenoxyamines used as main agent of gasoline detergent and preparation method thereof |
| CN103160344A (en) * | 2011-12-12 | 2013-06-19 | 杨军 | Large-proportion methanol gasoline catalyst and preparation method |
| CN107118816A (en) * | 2017-07-08 | 2017-09-01 | 湖北文理学院 | A kind of composite gasoline additive |
-
2017
- 2017-10-11 CN CN201710942002.6A patent/CN107523366A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1526798A (en) * | 2003-09-23 | 2004-09-08 | 林金池 | Lead-less clean environment protection gasoline additive |
| CN101225332A (en) * | 2007-12-13 | 2008-07-23 | 南京石油化工股份有限公司 | Polyethenoxyamines used as main agent of gasoline detergent and preparation method thereof |
| CN103160344A (en) * | 2011-12-12 | 2013-06-19 | 杨军 | Large-proportion methanol gasoline catalyst and preparation method |
| CN107118816A (en) * | 2017-07-08 | 2017-09-01 | 湖北文理学院 | A kind of composite gasoline additive |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109370668A (en) * | 2018-10-17 | 2019-02-22 | 湖南普瑞飞新能源科技有限公司 | A kind of energy-saving emission-reduction type gasoline additive and preparation method thereof |
| CN109294639A (en) * | 2018-11-23 | 2019-02-01 | 广东月福汽车用品有限公司 | A kind of fuel power elevator and preparation method thereof |
| CN111996044A (en) * | 2020-09-04 | 2020-11-27 | 北京中燕恒成能源有限公司 | Primary oil for compound oxygen-containing compound vehicle and preparation method thereof |
| CN112574790A (en) * | 2020-11-23 | 2021-03-30 | 邵占林 | Gasoline cleaning synergist and preparation method thereof |
| CN115895743A (en) * | 2022-11-25 | 2023-04-04 | 山东京博新能源控股发展有限公司 | Power improver suitable for refitted vehicle fuel and fuel |
| CN115895743B (en) * | 2022-11-25 | 2024-08-13 | 山东京博新能源控股发展有限公司 | Power lifting agent suitable for refitting vehicle fuel oil and fuel oil |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107523366A (en) | One kind carries high-octane gasoline environmental-protection additive | |
| CN104212500B (en) | A kind of fuel oil fume-eliminating energy-saving additive, preparation method and its application method | |
| CN109207212A (en) | A kind of diesel fuel additives and preparation method thereof of environment friendly combustion-supporting type | |
| CN103642541B (en) | A kind of environment protection gasoline additive and preparation method thereof | |
| CN114907891B (en) | Clean fuel and preparation method thereof | |
| CN106947553A (en) | One kind administers haze environment friendly energy-saving gasoline | |
| CN106947552A (en) | One kind administers haze environmental protection and energy saving premium gas | |
| CN106978222A (en) | One kind administers haze environment-protecting energy-saving gasoline | |
| CN107916147A (en) | A kind of nonmetallic gasoline additive and preparation method thereof | |
| CN105907432B (en) | A kind of environmental protection and energy saving super-gasoline accelerator | |
| CN107312579A (en) | A kind of energy-efficient fuel oil additive for improving power and preparation method thereof | |
| CN1277908C (en) | Additive for environmental protection and saving petrol of fuel, and preparation method thereof | |
| CN1236023C (en) | Cleaning gasoline with alcohol ether base | |
| CN106811242A (en) | A kind of environmentally friendly low-carbon (LC) high heating value New Marine fuel oil | |
| CN108463541A (en) | Fuel additive | |
| CN1281724C (en) | Highly efficient fuel accelerant and method for preparing the same | |
| CN105331404B (en) | A kind of environment protection type gasoline additive and preparation method thereof | |
| CN100519709C (en) | Fluorocarbon surfactant modified fuel oil synergic masterbatch composition | |
| CN101760261A (en) | Gasoline environmental-protection additive | |
| CN101314740B (en) | High-efficiency environment friendly energy-conservation gasoline additive | |
| CN1526798A (en) | Lead-less clean environment protection gasoline additive | |
| CN106987286B (en) | A kind of ether-base gasoline of clean and environmental protection and preparation method thereof | |
| CN101497830A (en) | Efficient environment-friendly energy-saving diesel fuel additive | |
| CN1247750C (en) | Alcohol diesel and its preparing method | |
| CN110713854A (en) | Polyether oxygen-containing cleaning synergist composition for cleaning gasoline |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20190612 Address after: 266034 Unit 3105, Building 2, 138 Shandong Road, North District, Qingdao City, Shandong Province Applicant after: Qingdao Boting Transportation Co., Ltd. Address before: 266061 Hongkong East Road, Laoshan District, Qingdao, Shandong Province, No. 7 Applicant before: Qingdao University |
|
| TA01 | Transfer of patent application right | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20171229 |
|
| RJ01 | Rejection of invention patent application after publication |