CN107523180A - A kind of water-based high rigidity UV optical films coating fluid, Its Preparation Method And Use - Google Patents
A kind of water-based high rigidity UV optical films coating fluid, Its Preparation Method And Use Download PDFInfo
- Publication number
- CN107523180A CN107523180A CN201710671011.6A CN201710671011A CN107523180A CN 107523180 A CN107523180 A CN 107523180A CN 201710671011 A CN201710671011 A CN 201710671011A CN 107523180 A CN107523180 A CN 107523180A
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- water
- weight
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- high rigidity
- based high
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/10—Epoxy resins modified by unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The invention discloses a kind of water-based high rigidity UV optical films coating fluid, Its Preparation Method And Use, the optical film coating fluid includes 0.1 2 parts by weight water nano dispersible pigment color pastes and 98 99.9 water-based high rigidity UV curing systems；Wherein, water nano dispersible pigment color paste includes：The powder pigment of 10 20 parts by weight, the macromolecule dispersing agent of 20 40 parts by weight, the NMF of 5 15 parts by weight, the deionized water of 25 65 parts by weight；Water-based high rigidity UV curing systems include：The water-based high rigidity UV resins of 37 parts by weight, the water-soluble photoinitiator of 12 parts by weight, 16 parts by weight deionizations.The water-based high rigidity UV optical film coating fluids can be applicable to the top layer of vehicle window, lens and building glass, have that weatherability is good, filtering light, and protection is coated the effect of thing.
Description
Technical field
The present invention relates to a kind of water-borne UV-curing system, specifically relate to water-based high rigidity UV optical films coating fluid and
Its preparation method, available for vehicle window, lens and building fenestrated membrane, belong to painting industry.
Background technology
Existing market get on the bus film, lens and the building glass overwhelming majority be all dyestuff coloring, weather resistance is poor, and solidifies
System is not environmentally friendly enough.Patent document such as Publication No. CN102086316A discloses a kind of UV curable resin material compositions
Coating fluid, including：It is dissolved or dispersed in non-polar solven or the UV curable resin material of substantially nonpolar in the mixed solvent
Feed composition.The UV curable resin material compositions include：Monomer and/or its oligomer, there is two or more（Methyl）Third
Enoyl- group and there is affinity to non-polar solven；Modified hollow silica particulate, in aliphatic hydrocarbyl is incorporated into
The surface of empty silica microparticle and being changed to non-polar solven has affinity, and polymerization initiator.But the curable trees of the UV
Fat material compositions contain monomer, and solidification film hardness improves limited.
Publication No. CN102134437B granted patent discloses a kind of UV curing glass plating coating, solves tradition
The problem of glass coating and vacuum coating bottom surface paint and poor glassy bond power, including priming paint and finish paint.In use, need the bottom of
Paint is really plated on pretreated glass baseplate, baking and UV solidifications, vacuum coating, sprays true plating finish paint, secondary baking and UV
Solidification, it is complex using technique.
The content of the invention
It is an object of the invention to provide a kind of water-based high rigidity UV optical film coating fluids, by water nano dispersible pigment color paste with
The water-based UV curing systems of high rigidity are combined, and solve the problem of conventional optical film weatherability is poor, and the feature of environmental protection is not good enough.
It is another object of the present invention to provide a kind of preparation method of water-based high rigidity UV optical film coating fluids, have
Simple production process, cost is cheap, the characteristics of safety and environmental protection.
In order to realize foregoing invention purpose, the present invention uses following scheme：
Water-based high rigidity UV optical film coating fluids, including 0.1-2 parts by weight water nano dispersible pigment color pastes and the water-based height of 98-99.9 are firmly
Spend UV curing systems；
Wherein, water nano dispersible pigment color paste includes：The powder pigment of 10-20 parts by weight, the macromolecule of 20-40 parts by weight disperse
Agent, the NMF of 5-15 parts by weight, the deionized water of 25-65 parts by weight；
Water-based high rigidity UV curing systems include：The water-based high rigidity UV resins of 3-7 parts by weight, 1-2 parts by weight it is water-based light-initiated
Agent, 1-6 parts by weight deionizations.
The powder pigment is inorganic and organic pigment powder；
The macromolecule dispersing agent is water-soluble polymer dispersant；
The NMF is one or more of mixtures in propane diols, ethylene glycol, polyethylene glycol, polypropylene glycol；
The water-based high rigidity UV resins are water-based UV epoxy resin, water-based UV polyester resin, water-based UV epoxy acrylates, water
One or more of mixtures in property UV silane-modified epoxy resins；
Described water-soluble photoinitiator is acyl group phosphorus oxidation species emulsion, benzil derivatives class emulsion, thioxanthones emulsion
In one or more of mixtures, it is preferred that for (2,4,6- trimethylbenzoyl) phenyl aoxidize beautiful jade.
The preparation method of water-based high rigidity UV optical film coating fluids, step are as follows：
(1) by the powder pigment of 10-20 parts by weight, the macromolecule dispersing agent of 20-40 parts by weight, the NMF of 5-15 parts by weight,
The deionized water of 25-65 parts by weight, water nano dispersible pigment color paste of the pigment particle size less than 0.3 μm is obtained through sand mill grinding 1-5h；
(2) the water-based high rigidity UV resins of 3-7 parts by weight, the water-soluble photoinitiator of 1-2 parts by weight, 1-6 parts by weight deionizations are mixed
Close, obtain water-based high rigidity UV curing systems；
(3) dispersible pigment color paste of 0.1-2 parts by weight is added in the water-based high rigidity UV curing systems of 98-99.9 parts by weight, passed through
After high speed dispersor stirring 0.5-2h, water-based high rigidity UV optical film coating fluids are obtained.
Application method is：Water-based high rigidity UV optical film coating fluids are coated on vehicle window, lens, glass surface,
Then solidify by UV：The coating is one kind in spin coating, rolling coating, roller type, and coating thickness is in 1-20 microns
Between.
Beneficial effect：
1. water nano dispersible pigment color paste, which introduces water-borne UV-curing system, has the characteristics of good weatherability, light transmittance is high；
2. water-based high rigidity UV optical film coating fluids are more more environmentally-friendly than UV coating fluid;
3. water-based high rigidity UV optical film coating fluids do not contain monomer, solidification film hardness is higher.
Embodiment
Further detailed description is done to the present invention with reference to embodiment, but the implementation of the present invention is not limited to this.
Raw material is shown in Table 1 used by embodiment 1 to 3：
Table 1（Unit：Parts by weight）
The preparation method of embodiment 1 is as follows：
By the pigment blue 15 of 10 parts by weight:The polyacrylate dispersant of 3,20 parts by weight, the ethylene glycol of 5 parts by weight, 65 weight
The deionized water of part, water nano dispersible pigment color paste of the pigment particle size less than 0.3 μm is obtained through sand mill grinding 5h；
By water-based high rigidity epoxy UV resins, water-soluble photoinitiator (2,4,6- trimethylbenzoyls) phenyl oxidation beautiful jade and deionization
Water is by weight 5:1:4 mixing, obtain water-based high rigidity UV curing systems；
The dispersible pigment color paste of 1 parts by weight is added in the water-based high rigidity UV curing systems of 99 parts by weight, stirred through high speed dispersor
After mixing 1h, water-based high rigidity UV optical film coating fluids are obtained；
Water-based high rigidity UV optical film coating fluids by rotary coating on optical lens, after UV solidifies, color weatherability 8
Level, lens surface hardness 6H.
Claims (5)
1. water-based high rigidity UV optical film coating fluids, it is characterised in that including 0.1-2 parts by weight water nano dispersible pigment color pastes and
The water-based high rigidity UV curing systems of 98-99.9；
Wherein, water nano dispersible pigment color paste includes：The powder pigment of 10-20 parts by weight, the macromolecule of 20-40 parts by weight disperse
Agent, the NMF of 5-15 parts by weight, the deionized water of 25-65 parts by weight；
Water-based high rigidity UV curing systems include：The water-based high rigidity UV resins of 3-7 parts by weight, 1-2 parts by weight it is water-based light-initiated
Agent, 1-6 parts by weight deionizations.
2. water-based high rigidity UV optical film coating fluids according to claim 1, it is characterised in that the water nano pigment
In mill base：Powder pigment is inorganic and organic pigment powder；The macromolecule dispersing agent is water-soluble polymer dispersant；It is described
NMF is one or more of mixtures in propane diols, ethylene glycol, polyethylene glycol, polypropylene glycol.
3. water-based high rigidity UV optical film coating fluids according to claim 1, it is characterised in that water-based high rigidity UV solidifications
In system：The water-based high rigidity UV resins are water-based UV epoxy resin, water-based UV polyester resin, water-based UV epoxy acrylics
One or more of mixtures in ester, water-based UV silane-modified epoxy resins；Described water-soluble photoinitiator is acyl group phosphorus oxidation
One or more of mixtures in species emulsion, benzil derivatives class emulsion, thioxanthones emulsion.
4. the preparation method of the water-based high rigidity UV optical film coating fluids described in claim 1, it is characterised in that step is as follows：
(1) by the powder pigment of 10-20 parts by weight, the macromolecule dispersing agent of 20-40 parts by weight, the NMF of 5-15 parts by weight,
The deionized water of 25-65 parts by weight, water nano dispersible pigment color paste of the pigment particle size less than 0.3 μm is obtained through sand mill grinding 1-5h；
(2) the water-based high rigidity UV resins of 3-7 parts by weight, the water-soluble photoinitiator of 1-2 parts by weight, 1-6 parts by weight deionizations are mixed
Close, obtain water-based high rigidity UV curing systems；
(3) dispersible pigment color paste of 0.1-2 parts by weight is added in the water-based high rigidity UV curing systems of 98-99.9 parts by weight, passed through
After high speed dispersor stirring 0.5-2h, water-based high rigidity UV optical film coating fluids are obtained.
5. the purposes of the water-based high rigidity UV optical film coating fluids described in claim 1, it is to apply water-based high rigidity UV optical films
Cloth liquid is coated on vehicle window, lens, glass surface, then solidifies by UV：It is described coating be spin coating, rolling coating,
One kind in roller type, coating thickness is between 1-20 microns.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710671011.6A CN107523180A (en) | 2017-08-08 | 2017-08-08 | A kind of water-based high rigidity UV optical films coating fluid, Its Preparation Method And Use |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710671011.6A CN107523180A (en) | 2017-08-08 | 2017-08-08 | A kind of water-based high rigidity UV optical films coating fluid, Its Preparation Method And Use |
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| CN107523180A true CN107523180A (en) | 2017-12-29 |
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| CN201710671011.6A Pending CN107523180A (en) | 2017-08-08 | 2017-08-08 | A kind of water-based high rigidity UV optical films coating fluid, Its Preparation Method And Use |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109337447A (en) * | 2018-09-30 | 2019-02-15 | 合肥微晶材料科技有限公司 | A kind of graphene quantum dot/nano-silver thread composite water soluble conductive ink and the flexible transparent conducting film based on it |
Citations (3)
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| CN102585691A (en) * | 2012-02-13 | 2012-07-18 | 长沙市原鹏化工科技有限公司 | Ultraviolet-cured hydrophilic coating composition and preparation method thereof |
| CN104231685A (en) * | 2013-06-09 | 2014-12-24 | 展辰涂料集团股份有限公司 | Water-based UV paint used on organic glass, and preparation method thereof |
| CN106147357A (en) * | 2015-06-02 | 2016-11-23 | 湖北航天化学技术研究所 | A kind of light absorptive anti-glare hard coating film and its preparation method and application |
-
2017
- 2017-08-08 CN CN201710671011.6A patent/CN107523180A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102585691A (en) * | 2012-02-13 | 2012-07-18 | 长沙市原鹏化工科技有限公司 | Ultraviolet-cured hydrophilic coating composition and preparation method thereof |
| CN104231685A (en) * | 2013-06-09 | 2014-12-24 | 展辰涂料集团股份有限公司 | Water-based UV paint used on organic glass, and preparation method thereof |
| CN106147357A (en) * | 2015-06-02 | 2016-11-23 | 湖北航天化学技术研究所 | A kind of light absorptive anti-glare hard coating film and its preparation method and application |
Non-Patent Citations (1)
| Title |
|---|
| 朱棉霞: "《综合 设计 研究性化学实验》", 31 August 2008, 江西高校出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109337447A (en) * | 2018-09-30 | 2019-02-15 | 合肥微晶材料科技有限公司 | A kind of graphene quantum dot/nano-silver thread composite water soluble conductive ink and the flexible transparent conducting film based on it |
| CN109337447B (en) * | 2018-09-30 | 2021-09-24 | 合肥微晶材料科技有限公司 | Graphene quantum dot/nano silver wire composite water-based conductive ink and flexible transparent conductive film based on same |
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