CN107521125A - The vacuum of super thick carbon fibre composite plate imports forming method - Google Patents

The vacuum of super thick carbon fibre composite plate imports forming method Download PDF

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Publication number
CN107521125A
CN107521125A CN201710705082.3A CN201710705082A CN107521125A CN 107521125 A CN107521125 A CN 107521125A CN 201710705082 A CN201710705082 A CN 201710705082A CN 107521125 A CN107521125 A CN 107521125A
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China
Prior art keywords
vacuum
carbon fibre
fibre composite
composite plate
steel wire
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CN201710705082.3A
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Chinese (zh)
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CN107521125B (en
Inventor
许少少
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Shaoxing Baojing Composite Material Co ltd
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Jinggong (shaoxing) Composite Materials Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/30Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core
    • B29C70/36Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core and impregnating by casting, e.g. vacuum casting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/54Component parts, details or accessories; Auxiliary operations, e.g. feeding or storage of prepregs or SMC after impregnation or during ageing

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Composite Materials (AREA)
  • Mechanical Engineering (AREA)
  • Moulding By Coating Moulds (AREA)

Abstract

The present invention relates to a kind of vacuum of super thick carbon fibre composite plate to import forming method, using two-step method, the carbon fibre composite prefabricated board prepared upper and lower surface and uniform stria and pore is distributed with first is imported using vacuum using auxiliary materials such as steel wires, then, prefabricated board is positioned over laminboard layer, is imported using vacuum and prepares the carbon fibre composite plate for needing thickness.The scheme for preparing prefabricated board is to lay layer of steel wire net in the upper and lower surface of preform, under negative pressure of vacuum, steel wire " is absorbed in " in preform, and upper and lower surface, which is made, after injecting glue, solidification the prefabricated board of stria, in stria after reasonable layout punching.The present invention not only realizes the cost degradation of super thick carbon fibre composite plate, and provides the thinking that a low-risk prepares super thick carbon fibre composite.

Description

The vacuum of super thick carbon fibre composite plate imports forming method
Technical field
The present invention relates to super thick carbon fibre composite plate technique field, is that a kind of super thick carbon fiber is compound specifically The vacuum of plate of material imports forming method.
Background technology
Carbon fibre composite is widely used in Aero-Space, track traffic, new as a kind of new high performance material The high-tech areas such as energy automobile.At present, prepare the moulding process of carbon fibre composite plate mainly have prepreg-autoclave into Type technique, die press technology for forming, manual pasting forming process, resin transfer molding technique, vacuum guiding and forming technique etc..With it He compares moulding process, and vacuum guiding and forming technique is more suitable for being molded big thickness, large-sized product, is characterized in input cost It is low, production efficiency is high, gained product porosity is low, performance is good, fiber content is high, the method be greatly lowered composite production One of effective way of cost.
Vacuum guiding and forming technique (Vacuum Assisted Resin Infusion) abbreviation VARI moulding process, is one Kind low cost composite large-scale product forming technique, it be under vacuum conditions (atmospheric pressure) exclude fiber in advance into Gas in type body, by the flowing of resin, infiltration, the dipping to preform is realized, and in certain cure profile condition Lower carry out curing molding, form the process of certain resin/fiber ratio.The process of thermoplastic resin-impregnated fibers material is by vacuum What the active force between pressure, self gravitation and resin and fiber drove.Because carbon mono-filaments are superfine, in negative pressure of vacuum Under, the minimum High Pressure Difference caused in aspect in gap between carbon cloth reduces, with continuing for resin impregnated carbon fiber process, Resin flow resistance increases, so, the difficulty using vacuum importing preparation super thick carbon fibre composite product is very big, product Scrappage is high.
Wang Mingjun etc. discloses a kind of new vacuum and imports preparation super thick composite board device and its technique, and this is special The super thick composite board thickness prepared in profit employs two layers of permeable medium up and down and upper and lower two layers of demoulding in more than 8mm The process of cloth realizes that shortening resin imports the time, prepares super thick composite board.The achievable super thick of this method is compound Material thickness is limited, and increased in terms of auxiliary material cost.
Liu Kui etc. discloses a kind of thick size carbon fiber product vacuum infusion molding method, and VAP is used under vacuum slot Film is sealed, and the suction gradient of bottling body is controlled by using VAP films, and realization prepares thick size carbon fiber product.Should The VAP film costs that method uses are higher, and for the larger product of area, its auxiliary material cost is higher.
The carbon fiber board thickness prepared at present using vacuum guiding and forming technique is generally less than 10mm, if but using thick size Large-sized structural component carbon fibre composite plate be difficult to realize low cost vacuum introducing technology shaping.
The content of the invention
It is an object of the invention to overcome the deficiencies of the prior art and provide a kind of vacuum of super thick carbon fibre composite plate Import forming method.The forming method both will not bring influence to the mechanical property and reliability of product, and can realize a variety of Thickness requirement and the preparation of the carbon fibre composite plate of low cost.
The purpose of the present invention is achieved through the following technical solutions:
A kind of vacuum of super thick carbon fibre composite plate imports forming method, and it is concretely comprised the following steps:
Using two-step method, upper and lower surface is first prepared using vacuum importing using auxiliary materials such as steel wires and is distributed with uniformly The carbon fibre composite prefabricated board of stria and pore, then, prefabricated board is positioned over laminboard layer, shaping work is imported using vacuum Skill prepares the carbon fibre composite plate for needing thickness.
The scheme for preparing prefabricated board is to lay layer of steel wire net in the upper and lower surface of preform, and steel wire act as Permeable medium, and " be absorbed in " in preform under negative pressure of vacuum;After injecting glue, solidification, steel wire is shelled from prefabricated component From getting off, the prefabricated board that upper and lower surface stria is evenly distributed then is made, in stria after rationally arrangement punching.
The preparation of prefabricated board uses vacuum guiding and forming technique, and the difference with conventional method is permeable medium being replaced by Steel wire, and the top and bottom of preform lay steel wire;Laying one layer between steel wire and preform has hole to isolate Film;Steel wire specification 10mm*10mm, 20mm*20mm etc., steel wire diameter are 2mm~5mm;Upper and lower two layers of steel wire is before use Rub releasing agent.
It is by the purpose that permeable medium is replaced by steel wire:Arranged using the steel wire lines of steel wire rule, born in vacuum Under the conditions of pressure or simultaneously under malleation and condition of negative pressure, steel wire " is absorbed in " in preform, compared to traditional plastic material water conservancy diversion Medium, the effect that steel wire " is absorbed in " in preform become apparent from, and can adjust preformed member by selecting steel wire diameter Stria depth.Steel wire through rubbing releasing agent can be recycled again, and traditional permeable medium is used only once, this Sample also greatlys save the material cost of product.
Upper and lower two layers of steel wire rubs releasing agent before use, the purpose is to steel wire from prefabricated component it is more easily peelable Get off, steel wire is repeatable to be utilized.
Described super thick carbon fibre composite plate is identical with matrix resin used in prefabricated board.Resin system Main component please state that matrix resin includes epoxy resin, vinyl ester resin etc. and is applied to vacuum guiding and forming technique Resin.
Described has the film that hole barrier film is surface distributed uniform micro, and its effect is by between steel wire and the cloth that strips off the skin Resin-rich layer be easy to strip down from prefabricated component.It is 0.01mm~0.05mm to have hole barrier film pore diameter, and pitch of holes is 1mm~3mm.
A diameter of 1mm~3mm on the resin hole road issued on prefabricated board, adjacent resin hole road spacing are 20mm~50mm, According to the process window of used resin system, the size and thickness of super thick composite panel determine resin hole road diameter and Away from.
Compared with prior art, the positive effect of the present invention is:
A kind of vacuum guiding and forming technique for preparing super thick carbon fibre composite plate provided by the invention, is more suitable for being molded Big thickness, large-sized carbon fibre composite product, are characterized in that input cost is low, production efficiency is high, gained product hole Rate is low, performance is good, fiber content is high and stably;Main is that can be changed according to the thickness and size of carbon fibre composite product Process window prepares the wind of big thickness, large-sized carbon fibre composite product to reduce using vacuum guiding and forming technique Danger.
Brief description of the drawings
Fig. 1 is super thick composite plys schematic diagram of the present invention;
Fig. 2 is prefabricated board laying schematic diagram of the present invention;
Fig. 3 is prefabricated board schematic diagram of the present invention;
Fig. 4 is super thick composite vacuum guiding and forming technique schematic diagram of the present invention;
Mark in accompanying drawing for:1- moulds;2- strips off the skin cloth one;3- carbon fibre fabrics;4- prefabricated boards;5- strips off the skin cloth two;6- Have on the barrier film of hole;7- flow-guiding screens;8- vacuum bags;9- sealing joint strips;Under 10- steel wires;11- has under the barrier film of hole;12- steel wires On the net;13- injecting glue buckets;14- glue inlet tubes;15- preforms;16- Ω are managed;17- glue-feeders;18-1# helix tubes;19-1# vacuum Pipe;20-2# helix tubes;21-2# vacuum tubes;22- resin traps.
Embodiment
A kind of vacuum of super thick carbon fibre composite plate of the present invention presented below imports the specific embodiment party of forming method Formula.
Embodiment 1
Below in conjunction with the accompanying drawings 1, accompanying drawing 2, accompanying drawing 3, the present invention is further described for accompanying drawing 4.The present embodiment is for length 1000mm, wide 1000mm, thickness 30mm carbon fibre composite plate vacuum import shaping example.
A kind of vacuum guiding and forming technique for preparing super thick carbon fibre composite plate, its first step are to prepare prefabricated board. As shown in figure accompanying drawing two, layer of steel wire off the net 10 is first laid in the die surface for rubbing releasing agent, then laying has hole isolation 11 under film, then the cloth 1 that strips off the skin is laid, lay 40 layers of carbon fibre fabric 3 (individual layer carbon fibre fabric thickness 0.6mm) successively, afterwards Lay strips off the skin cloth 25, has 6 on the barrier film of hole, 12 on steel wire.Used steel wire specification is 10mm*10mm, steel wire diameter For 3mm, and surface erasing releasing agent;Lay carbon fibre fabric, which must be rolled, overlays reality, avoids interlayer from " bridge formation " occur.
Similar, refer to the attached drawing four, glue inlet tube road and vacuum-pumping pipeline are laid out, is laid under 1# helix tubes and 2# helix tubes Strip is breathed freely cotton;The ventilative cotton of strip is laid in the surrounding of preform 15, but middle position disconnects.
In the position adhesive seal adhesive tape 9 apart from each 30~40mm of side of preform 15, vacuum bag 8 is then pasted.Arrange After good vacuum bag, start slowly to vacuumize, when vacuum is less than -97.5KPa, stuck 1# vacuum tubes and 2# vacuum tubes, Vacuum change is that pressurize is qualified less than 2KPa after 5min.
After pressurize is qualified can will be deployed, resin through deaeration carries out injecting glue, the observation resin dipping feelings of preform 15 Condition, after resin thorough impregnation preform 15, stuck glue inlet tube 14, then stuck 1# vacuum tubes and 2# vacuum tubes.Solidification, molding The auxiliary material of carbon fibre composite plate surface is cleaned out afterwards.
Through range estimation, phenomena such as surface of prefabricated board is not noted, dry spot, using lossless detection method-ultrasound examination, The defects of prefabricated board pore-free, layering;Thickness is uniform, and quality is good.
The a diameter of 2mm in resin hole road issued on prefabricated board, adjacent resin hole road spacing are 30mm.
A kind of vacuum guiding and forming technique for preparing super thick carbon fibre composite plate, its second step are to prepare super thick carbon fibre Tie up composite panel.As shown in figure accompanying drawing one, the one layer of cloth 1 that strips off the skin first is laid in the die surface for rubbing releasing agent, then 5 layers of carbon fibre fabric 3 are laid successively, lay prefabricated board 4 afterwards, then lay 5 layers of carbon fibre fabric 3 successively, and strip off the skin cloth 25, has 6 on the barrier film of hole, flow-guiding screen 7.Lay carbon fibre fabric, which must be rolled, overlays reality, avoids interlayer from " bridge formation " occur.
Refer to the attached drawing four, follow-up operational sequence are identical with preparing prefabricated board.
Through range estimation, phenomena such as surface of super thick carbon fibre composite plate is not noted, dry spot, using Non-Destructive Testing side Method-ultrasound examination, super thick carbon fibre composite plate pore-free, layering the defects of;Thickness is uniform, and quality is good.
Present application addresses the high technology of the super thick carbon fibre composite plate scrappage prepared using vacuum introducing technology Problem.The thickness of the super thick composite panel prepared in the present invention is more than 25mm.The present invention uses two-step method, first using steel wire Etc. auxiliary material using vacuum import prepare upper and lower surface be distributed with uniform stria and pore carbon fibre composite it is prefabricated Plate, then, prefabricated board is positioned over laminboard layer, is imported using vacuum and prepare the carbon fibre composite plate for needing thickness.System The scheme of standby prefabricated board is to lay layer of steel wire net in the upper and lower surface of preform, and under negative pressure of vacuum, steel wire " is fallen into Enter " in preform, after injecting glue, solidification upper and lower surface is made has the prefabricated board of stria, and reasonable layout punches in stria Afterwards.The present invention not only realizes the cost degradation of super thick carbon fibre composite plate, and provides a low-risk system The thinking of standby super thick carbon fibre composite.
Described above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art Member, without departing from the inventive concept of the premise, can also make some improvements and modifications, these improvements and modifications also should be regarded as In protection scope of the present invention.

Claims (10)

1. a kind of vacuum of super thick carbon fibre composite plate imports forming method, it is characterised in that it is concretely comprised the following steps:Using Two-step method, first using steel wire using vacuum import prepare upper and lower surface be distributed with uniform stria and pore carbon fiber it is compound Prefabricated plate, then, prefabricated board is positioned over laminboard layer, is imported using vacuum and prepare the carbon fiber composite for needing thickness Flitch.
2. a kind of vacuum of super thick carbon fibre composite plate as claimed in claim 1 imports forming method, it is characterised in that The scheme for preparing prefabricated board is to lay layer of steel wire net in the upper and lower surface of preform, and steel wire act as water conservancy diversion Jie Matter, and " be absorbed in " in preform under negative pressure of vacuum;After injecting glue, solidification, steel wire is stripped down from prefabricated component, Then the prefabricated board that upper and lower surface stria is evenly distributed is made, in stria after rationally arrangement punching.
3. a kind of vacuum of super thick carbon fibre composite plate as claimed in claim 2 imports forming method, it is characterised in that The preparation of prefabricated board uses vacuum guiding and forming technique, and permeable medium is replaced by into steel wire, and the top and bottom of preform Lay steel wire;Laying one layer between steel wire and preform has hole barrier film.
4. a kind of vacuum of super thick carbon fibre composite plate as claimed in claim 3 imports forming method, it is characterised in that Steel wire specification 10mm*10mm, 20mm*20mm.
5. a kind of vacuum of super thick carbon fibre composite plate as claimed in claim 3 imports forming method, it is characterised in that Steel wire diameter is 2mm~5mm.
6. a kind of vacuum of super thick carbon fibre composite plate as claimed in claim 3 imports forming method, it is characterised in that Upper and lower two layers of steel wire rubs releasing agent before use.
7. a kind of vacuum of super thick carbon fibre composite plate as claimed in claim 3 imports forming method, it is characterised in that Described has the film that hole barrier film is the uniform pore of surface distributed.
8. a kind of vacuum of super thick carbon fibre composite plate as claimed in claim 1 imports forming method, it is characterised in that Upper and lower two layers of steel wire rubs releasing agent before use.
9. a kind of vacuum of super thick carbon fibre composite plate as claimed in claim 1 imports forming method, it is characterised in that Described super thick carbon fibre composite plate is identical with resin system used in prefabricated board.
10. a kind of vacuum of super thick carbon fibre composite plate as claimed in claim 1 imports forming method, its feature exists In a diameter of 1mm~3mm on the resin hole road issued on prefabricated board, adjacent resin hole road spacing is 20mm~50mm.
CN201710705082.3A 2017-08-17 2017-08-17 The vacuum of super thick carbon fibre composite plate imports forming method Active CN107521125B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111941876A (en) * 2020-08-12 2020-11-17 山东英特力新材料有限公司 Process for solving problem of dry cloth on surface of embedded part in vacuum infusion molding
CN112743873A (en) * 2020-12-17 2021-05-04 东方电气(天津)风电叶片工程有限公司 Manufacturing method of carbon pultrusion plate single lap joint tensile shear sample

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JP2012196969A (en) * 2002-05-29 2012-10-18 Boeing Co:The Controlled atmospheric pressure resin infusion process
CN105034408A (en) * 2015-07-14 2015-11-11 江苏九鼎新材料股份有限公司 Method for manufacturing fiber reinforced composite product through resin pocket pressing
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CN205651673U (en) * 2016-01-27 2016-10-19 江苏恒神股份有限公司 Novel super thick combined material panel of leading -in preparation in vacuum device
CN106239935A (en) * 2016-09-30 2016-12-21 咸宁海威复合材料制品有限公司 The double membrane forming device of vacuum aided
CN206154744U (en) * 2016-09-30 2017-05-10 咸宁海威复合材料制品有限公司 Supplementary two membrane forming device in vacuum
CN106945308A (en) * 2017-04-21 2017-07-14 陕西飞机工业(集团)有限公司 A kind of vacuum aided infiltration molding process method of insert-molded article
CN207711416U (en) * 2018-01-16 2018-08-10 东北林业大学 A kind of process equipment for plant fiber vacuum compression molding

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20020006081A (en) * 2000-07-11 2002-01-19 이성우 Rehabilitation of Concrete Structures with Composites by Vacuum Bag Method
JP2012196969A (en) * 2002-05-29 2012-10-18 Boeing Co:The Controlled atmospheric pressure resin infusion process
CN105034408A (en) * 2015-07-14 2015-11-11 江苏九鼎新材料股份有限公司 Method for manufacturing fiber reinforced composite product through resin pocket pressing
CN105563855A (en) * 2016-01-27 2016-05-11 江苏恒神股份有限公司 Novel device and technology for manufacturing ultra-thick composite plate by means of vacuum infusion
CN205651673U (en) * 2016-01-27 2016-10-19 江苏恒神股份有限公司 Novel super thick combined material panel of leading -in preparation in vacuum device
CN106239935A (en) * 2016-09-30 2016-12-21 咸宁海威复合材料制品有限公司 The double membrane forming device of vacuum aided
CN206154744U (en) * 2016-09-30 2017-05-10 咸宁海威复合材料制品有限公司 Supplementary two membrane forming device in vacuum
CN106945308A (en) * 2017-04-21 2017-07-14 陕西飞机工业(集团)有限公司 A kind of vacuum aided infiltration molding process method of insert-molded article
CN207711416U (en) * 2018-01-16 2018-08-10 东北林业大学 A kind of process equipment for plant fiber vacuum compression molding

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111941876A (en) * 2020-08-12 2020-11-17 山东英特力新材料有限公司 Process for solving problem of dry cloth on surface of embedded part in vacuum infusion molding
CN112743873A (en) * 2020-12-17 2021-05-04 东方电气(天津)风电叶片工程有限公司 Manufacturing method of carbon pultrusion plate single lap joint tensile shear sample

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