CN107513904A - Radiation-protection refraction siloxane copolymerization polycarbonate composite wallpaper - Google Patents

Radiation-protection refraction siloxane copolymerization polycarbonate composite wallpaper Download PDF

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Publication number
CN107513904A
CN107513904A CN201610433223.6A CN201610433223A CN107513904A CN 107513904 A CN107513904 A CN 107513904A CN 201610433223 A CN201610433223 A CN 201610433223A CN 107513904 A CN107513904 A CN 107513904A
Authority
CN
China
Prior art keywords
refractive power
copolymeric siloxane
refraction
composite wall
radiation proof
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610433223.6A
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Chinese (zh)
Inventor
季建良
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wuxi Hualian Plastic Products Co ltd
Original Assignee
Wuxi Hualian Plastic Products Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wuxi Hualian Plastic Products Co ltd filed Critical Wuxi Hualian Plastic Products Co ltd
Priority to CN201610433223.6A priority Critical patent/CN107513904A/en
Publication of CN107513904A publication Critical patent/CN107513904A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/10Coatings without pigments
    • D21H19/14Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/10Coatings without pigments
    • D21H19/14Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/16Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising curable or polymerisable compounds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/10Coatings without pigments
    • D21H19/14Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/24Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/80Paper comprising more than one coating
    • D21H19/82Paper comprising more than one coating superposed
    • D21H19/824Paper comprising more than one coating superposed two superposed coatings, both being non-pigmented
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/18Paper- or board-based structures for surface covering
    • D21H27/20Flexible structures being applied by the user, e.g. wallpaper
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/002Coverings or linings, e.g. for walls or ceilings made of webs, e.g. of fabrics, or wallpaper, used as coverings or linings

Landscapes

  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention relates to radiation protection refraction siloxane copolymerization polycarbonate composite wallpaper, which comprises a surface coating, an intermediate refraction siloxane copolymerization polycarbonate layer and bottom layer base paper, wherein the intermediate refraction siloxane copolymerization polycarbonate layer is formed by mixing refraction particles and siloxane copolymerization polycarbonate through thermosetting molding, and the refraction particles are mineral particles or mineral fragments; the surface coating is UV-cured mixed coating which is composed of acrylate, zinc oxide, a silver ion protective agent, a light curing agent, a diluent, a filler and an auxiliary agent. The composite wallpaper with extremely strong decoration performance is provided, and not only has better flexibility, hardness and dimensional stability, but also can play a role in decoration of soft light.

Description

A kind of radiation proof refractive power copolymeric siloxane makrolon composite wall paper
Technical field
The invention belongs to wallpaper technical field, and in particular to a kind of refractive power copolymeric siloxane makrolon composite wall paper.
Background technology
Wallpaper is a kind of using quite extensive house decorative material.Because wallpaper has, color is various, pattern is abundant, person of outstanding talent The characteristics of a variety of other house decorative materials institutes such as magnificent style, safety and environmental protection, easy for construction, affordable are incomparable, therefore The developed countries and regions such as America and Europe, Southeast Asia, Japan obtain considerable degree of popularization.Wallpaper is divided into many classes, such as coating wallpaper, Overlay film wallpaper, embossing wallpaper etc..Body paper, then the working process through different processes generally are produced with bleached wood pulp, be such as coated with, Modeling is covered on printing, embossing or surface, is dispatched from the factory after last cut, packaging.Because with certain intensity, appearance attractive in appearance and good Water repelling property, be widely used in the interior decoration etc. of house, office, hotel.
Makrolon is a kind of new thermoplastic, and transparency firm and flexible, has high impact-resistant up to 90% Property, the very wide temperature in use of the dimensional stability and scope of height, good insulating properties and heat resistance and nontoxicity.Makrolon Polarity is small, and glass temperature is high, and water absorption rate is low, and shrinkage factor is small, and dimensional accuracy is high, stable to light, good weatherability melt viscosities and note Penetrate temperature reduction, thus shaping easy to process.Makrolon is just widely used in all trades and professions.
The content of the invention
It is an object of the invention to provide a kind of radiation proof refractive power copolymeric siloxane makrolon composite wall paper, for room Interior trim wallpaper, by increasing capacitance it is possible to increase the soft degree of indoor light, build the dress environment of warmth.
Technical scheme is used by the present invention solves the above problems:A kind of radiation proof poly- carbon of refractive power copolymeric siloxane Acid esters composite wall paper, including face coat, middle refractive power copolymeric siloxane Polycarbonate Layer and bottom body paper, the middle refractive power Copolymeric siloxane Polycarbonate Layer is molded with by refractive particle and copolymeric siloxane makrolon mixing thermosetting, the refractive power Particle is mineral particle or mineral matter fragment;The face coat is the compo of UV solidifications, and the compo is by propylene Acid esters, zinc oxide, silver ion protective agent, light curing agent, diluent, filler and auxiliary agent are formed.
Preferably, the light curing agent be benzoin isobutyl ether, benzoin isopropyl ether, benzoin dimethylether, diphenylethan, Alpha-hydroxyalkyl benzophenone, α-amine alkyl phenones, aroyl phosphine oxide, bis(benzoylphenyl) phosphine oxide, benzophenone, 2,4- bis- Dihydroxy benaophenonel, thio propoxyl group thioxanthone, one kind in isopropyl thioxanthone or two to three kinds of mixture.
Preferably, the filler is silica, glass fibre or calcium carbonate.
Preferably, the auxiliary agent is the one or more in dispersant, defoamer, preservative.
Preferably, the mineral matter is mica, marble, mineral crystal, spinelle.
Compared with prior art, the advantage of the invention is that:A kind of extremely strong composite wall paper of dicoration is provided, is not only had There are more preferable pliability, hardness and dimensional stability, and the decorative effect of soft light can be played.
Embodiment
The present invention is described in further detail with reference to embodiments.
Embodiment 1
Radiation proof refractive power copolymeric siloxane makrolon composite wall paper, including face coat, middle refractive power copolymeric siloxane Makrolon intermediate layer and bottom body paper, the middle refractive power copolymeric siloxane Polycarbonate Layer is by refractive particle and siloxanes Copolymerization polycarbonate mixing thermosetting is molded with, and the refractive particle is mica flake.
Face coat be UV solidification compo, the compo by acrylate, zinc oxide, silver ion protective agent, Benzoin isobutyl ether, aroyl phosphine oxide, diluent, nano silicon, dispersant, defoamer, preservative.
Embodiment 2
Radiation proof refractive power copolymeric siloxane makrolon composite wall paper, including face coat, middle refractive power copolymeric siloxane Makrolon intermediate layer and bottom body paper, the middle refractive power copolymeric siloxane Polycarbonate Layer is by refractive particle and siloxanes Copolymerization polycarbonate mixing thermosetting is molded with, and the refractive particle is transparent irregular spinelle.
Face coat be UV solidification compo, the compo by acrylate, zinc oxide, silver ion protective agent, Benzoin dimethylether, benzophenone, thio propoxyl group thioxanthone, diluent, calcium carbonate, defoamer, preservative.
Embodiment 3
Radiation proof refractive power copolymeric siloxane makrolon composite wall paper, including face coat, middle refractive power copolymeric siloxane Makrolon intermediate layer and bottom body paper, the middle refractive power copolymeric siloxane Polycarbonate Layer is by refractive particle and siloxanes Copolymerization polycarbonate mixing thermosetting is molded with, and the refractive particle is irregular marble fine particle.
Face coat be UV solidification compo, the compo by acrylate, zinc oxide, silver ion protective agent, Benzophenone, isopropyl thioxanthone, α-amine alkyl phenones, diluent, silica, glass fibre, defoamer, preservative.
In addition to the implementation, it is all to use equivalent transformation or equivalent replacement present invention additionally comprises there is other embodiment The technical scheme that mode is formed, it all should fall within the scope of the hereto appended claims.

Claims (5)

  1. A kind of 1. radiation proof refractive power copolymeric siloxane makrolon composite wall paper, it is characterised in that:Including face coat, in Between refractive power copolymeric siloxane Polycarbonate Layer and bottom body paper, the middle refractive power copolymeric siloxane Polycarbonate Layer is by refractive power Particle and copolymeric siloxane makrolon mixing thermosetting are molded with, and the refractive particle is that mineral particle or mineral matter are broken Piece;The face coat is the compo of UV solidifications, and the compo is by acrylate, zinc oxide, silver ion protective agent, light Curing agent, diluent, filler and auxiliary agent are formed.
  2. 2. radiation proof refractive power copolymeric siloxane makrolon composite wall paper according to claim 1, it is characterised in that: The light curing agent be benzoin isobutyl ether, benzoin isopropyl ether, benzoin dimethylether, diphenylethan, alpha-hydroxyalkyl benzophenone, α- Amine alkyl phenones, aroyl phosphine oxide, bis(benzoylphenyl) phosphine oxide, benzophenone, 2,4 dihydroxyl benzophenone, sulphur For one kind or two to three kinds of mixture in propoxyl group thioxanthone, isopropyl thioxanthone.
  3. 3. radiation proof refractive power copolymeric siloxane makrolon composite wall paper according to claim 1, it is characterised in that: The filler is silica, glass fibre or calcium carbonate.
  4. 4. radiation proof refractive power copolymeric siloxane makrolon composite wall paper according to claim 1, it is characterised in that: The auxiliary agent is the one or more in dispersant, defoamer, preservative.
  5. 5. radiation proof refractive power copolymeric siloxane makrolon composite wall paper according to claim 1, it is characterised in that: The mineral matter is mica, marble, mineral crystal.
CN201610433223.6A 2016-06-18 2016-06-18 Radiation-protection refraction siloxane copolymerization polycarbonate composite wallpaper Pending CN107513904A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610433223.6A CN107513904A (en) 2016-06-18 2016-06-18 Radiation-protection refraction siloxane copolymerization polycarbonate composite wallpaper

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610433223.6A CN107513904A (en) 2016-06-18 2016-06-18 Radiation-protection refraction siloxane copolymerization polycarbonate composite wallpaper

Publications (1)

Publication Number Publication Date
CN107513904A true CN107513904A (en) 2017-12-26

Family

ID=60721462

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610433223.6A Pending CN107513904A (en) 2016-06-18 2016-06-18 Radiation-protection refraction siloxane copolymerization polycarbonate composite wallpaper

Country Status (1)

Country Link
CN (1) CN107513904A (en)

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Application publication date: 20171226