CN107513299A - A kind of wall colored drawing acrylic paints and preparation method thereof - Google Patents
A kind of wall colored drawing acrylic paints and preparation method thereof Download PDFInfo
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- CN107513299A CN107513299A CN201710807718.5A CN201710807718A CN107513299A CN 107513299 A CN107513299 A CN 107513299A CN 201710807718 A CN201710807718 A CN 201710807718A CN 107513299 A CN107513299 A CN 107513299A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/06—Artists' paints
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
- C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
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- Chemical & Material Sciences (AREA)
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
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Abstract
It is an object of the invention to disclose a kind of wall colored drawing acrylic paints and preparation method thereof, being calculated according to mass parts mainly includes following component：Modified silicone acrylic emulsion：100 parts；Pigment：15 parts 40 parts；Nano filling：40 70 parts；Dispersion stabilizer：10 20 parts；Coloring agent：22 50 parts；Defoamer：0.3 2 parts；Thickener：0.5 3.5 parts；PH adjusting agent：0.3 2 parts；Modified silicone acrylic emulsion is prepared using emulsion polymerization step by step in the present invention, combines organosilicon fire-resistant, weatherability, chemical-resistant, hydrophobic, the low not v ulnerability of surface energy；High colour retention, pliability, the tack of Organic fluoride high temperature resistant, weatherability, corrosion-resistant, the low free energy in surface and acrylic resin are combined, the acrylic paints are a kind of high durable, high water-fast, resistant to pollution environmental-protection water-based pigment.
Description
Technical field
The invention belongs to wall colored drawing technical field, and in particular to a kind of wall colored drawing acrylic paints and its preparation side
Method.
Background technology
Acrylic paints belong to artificial synthesized polymeric pigment, and in the 50's of 20th century, acrylic paints are pigment powder for invention
Reconcile made of organic polymer new material acrylic based emulsion.Acrylic based emulsion is also known as allyl resin dimerization latex.Allyl resin
There are many kinds, such as methacrylic resin, styrene-acrylate, organosilicon-modified acrylate, fluorine carbon remodeling acrylic acid
Ester etc., therefore, acrylic paints also have many types.
For wall coloured drawing pigment based on acrylic paints, the acrylic paints have advantages below：Dilutable water, beneficial to clear
Wash；Rapid-curing cutback, after pigment is started to write a few minutes can dry；Can lose solubility rapidly after dyed layer is dry, at the same formed it is tough and tensile, have bullet
The impermeable film of property；Full, dense, the fresh profit of color；Persistence is preferable, brittle will not turn yellow；It is nontoxic for aqueous pigment, it is right
Human body will not produce injury.
The content of the invention
It is an object of the invention to provide a kind of wall colored drawing acrylic paints, and being calculated according to mass parts mainly includes being modified
Silicone acrylic emulsion：100 parts；Pigment：15 parts -40 parts；Nano filling：40-70 parts；The present invention prepares propylene using modified silicone acrylic emulsion
Pigment, there is preferable film forming characteristics and preferable waterproof antiwear characteristic, the particle diameter of Nano filling is smaller can be effectively increased third
The film forming compactness of alkene pigment, acrylic paints prepared by the present invention have preferable high colour retention, pliability, tack, film forming
Property, it is a kind of more environmentally friendly water paint.
It is another object of the present invention to provide a kind of preparation method of wall colored drawing acrylic paints, use are newborn step by step
Liquid polymerization is prepared for being modified silicone acrylic emulsion, using coupling agent modified Nano filling, so as to which acrylic paints, this hair be prepared
Bright preparation method is simple, easily realizes.
The present invention is achieved through the following technical solutions：A kind of wall colored drawing acrylic paints, are calculated according to mass parts
Mainly include following component：Modified silicone acrylic emulsion：100 parts；Pigment：15 parts -40 parts；Nano filling：40-70 parts；Stably dispersing
Agent：10-20 parts；Coloring agent：22-50 parts；Defoamer：0.3-2 parts；Thickener：0.5-3.5 parts；PH adjusting agent：0.3-2 parts.
The dispersion stabilizer, coloring agent, defoamer, thickener, pH adjusting agent are prior art and are not of the invention
Improvement, therefore repeat no more.
The modified silicone acrylic emulsion calculates according to mass parts mainly includes following component：Acrylic acid：100 parts；Siliceous propylene
Acid esters：15-20 parts；Fluorinated acrylate：2-8 parts；DAAM：0.2-2 parts；Crosslinking agent：0.3-1.5 parts.
The silicone acrylic emulsion is that the organic silicon monomer containing unsaturated bond and acrylic monomer are added into suitable auxiliary agent,
By emulsion polymerization and the emulsion for preparing；The silicone acrylic emulsion combines organosilicon fire-resistant, weatherability, chemical-resistant,
High colour retention, pliability, the tack of hydrophobic, the low not v ulnerability of surface energy and acrylic resin, the silicone acrylic emulsion are
A kind of high durable, high water-fast, resistant to pollution environmental-friendly type emulsion.
The modified silicone acrylic emulsion is by the organic silicon monomer containing unsaturated bond, acrylic monomer, fluorine-containing
Ester monomer, DAAM class monomer add crosslinking agent and inierpeneirating network structure are prepared；The DAAM
Participate in reacting as sensitization function monomer；The fluorinated acrylate monomer can strengthen silicone acrylic emulsion wash-resistant property and can
Performance is cleaned, while assigns acrylic paints preferable self-cleaning performance.The fluorinated acrylate monomer can be in acrylic paints
Middle introducing fluorine atom, effectively improves the surface hydrophobic after acrylic paints film forming, and surface free energy is relatively low, so as to have automatically cleaning
Performance.
In order to preferably realize the present invention, further, the Nano filling is talcum powder, silica, calcining kaolinite
Soil, any one in titanium dioxide.
In order to preferably realize the present invention, further, the crosslinking agent is N hydroxymethyl acrylamide, methylol propylene
Any one in acid amides, hydroxy propyl methacrylate.
In order to preferably realize the present invention, further, the fluorinated acrylate is Hexafluorobutyl mathacrylate, first
Any one in base dodecafluorhe-ptylacrylate, trifluoroethyl methacrylate.
A kind of preparation method of wall colored drawing acrylic paints, is mainly included the following steps that：
Step A, prepare modified silicone acrylic emulsion；
Step B, modified Nano filling is prepared, it is stand-by after dries pulverizing with coupling agent modified Nano filling；
Step C, dispersion stabilizer, coloring agent, pH adjusting agent and partially modified silicone acrylic emulsion are well mixed；Then with pigment,
Modified Nano filling, remaining modified silicone acrylic emulsion grinding are uniform；Last mixture foam killer, thickener are mixed evenly,
Acrylic paints are prepared
The step A is mainly included the following steps that：
Step A1, acrylic acid, acrylate containing silicone, fluorinated acrylate monomer are mixed to get mix monomer, by emulsifying agent, double
Mixed solution II is obtained after acetone acrylamide, crosslinking agent mixing, initiator is configured to initiator solution；
Step A2, take 1/4 mix monomer, mixed solution II, initiator solution to be well mixed respectively, be placed on heated at constant temperature stirring
Carry out being heated to 70-80 DEG C of reaction on device；When reaction solution turns it is blue when, then be slowly added dropwise by constant pressure funnel remaining mixed
Close monomer, mixed solution II, initiator solution；After being added dropwise to complete, temperature is increased to 75-90 DEG C of reaction 4-8 hour, cool down,
Filtering, discharging, are prepared modified silicone acrylic emulsion
It is further, in the step B to be stirred in a solvent with Nano filling with coupling agent to preferably realize the present invention
Uniformly, temperature is 30-70 DEG C, mixing speed 200-500r/min, and mixing time is 2-5 hours；Then vacuum filtration separation
Modified Nano filling is obtained, is then placed in baking oven and is dried in 40-60 DEG C, attrition grinding is filled out for the nanometer of nano level modification
Material.
Beneficial effects of the present invention：
（1）Acrylic paints are prepared using modified silicone acrylic emulsion, there is preferable high colour retention, pliability, tack；
（2）Silicone acrylic emulsion is modified using fluorinated acrylate monomer, the acrylic paints have preferable self-cleaning performance；
（3）Acrylic paints are prepared using Nano filling, there is preferable film forming compactness, the stability enhancing of acrylic paints；
（4）Using coupling agent modified Nano filling, improve compatibility of the Nano filling in acrylic paints, effectively improve propylene face
The stability of material；
（5）Modified silicone acrylic emulsion is prepared using emulsion polymerization step by step in the present invention, and addition crosslinking agent is prepared into interpenetrating networks knot
The modification silicone acrylic emulsion of structure, enhances the mechanical property and hydrophobic performance of acrylic paints, and preparation method is simple.
Embodiment
Embodiment 1：
A kind of wall colored drawing acrylic paints, being calculated according to mass parts mainly includes modified 100 parts of silicone acrylic emulsion, 10 parts of pigment,
55 parts of silica nanometer filler, dispersion stabilizer：12 parts, coloring agent：25 parts, defoamer：0.75 part, thickener：2 parts, pH
Conditioning agent：1.2 part.
The modified silicone acrylic emulsion calculates according to mass parts mainly includes 100 parts of acrylic acid, MTMS 15
Part, 5 parts of Hexafluorobutyl mathacrylate, diacetone propionamide：0.3 part, 0.3 part of N hydroxymethyl acrylamide.
A kind of preparation method of wall colored drawing acrylic paints, is mainly included the following steps that：
Step A, prepare modified silicone acrylic emulsion：Acrylic acid, MTMS, Hexafluorobutyl mathacrylate monomer are mixed
Conjunction obtains mix monomer；Mixed solution II is obtained after emulsifying agent, DAAM, N hydroxymethyl acrylamide are mixed；
Initiator is configured to initiator solution；
Take 1/4 mix monomer, mixed solution II, initiator solution to be well mixed respectively, it is enterprising to be placed on heated at constant temperature agitator
Row is heated to 75 DEG C of reactions；When reaction solution turns it is blue when, then respectively with constant pressure funnel be slowly added dropwise remaining mix monomer,
Mixed solution II, initiator solution；After being added dropwise to complete, temperature is increased to 85 DEG C and reacted 4 hours, mixing speed 300r/
min；Modified silicone acrylic emulsion is prepared after supercooling, filtering, discharging；
Step B, prepare modified silica nanometer filler：KH550 is mixed in methyl alcohol with nano silicon, temperature
Spend for 45 DEG C, mixing speed 400r/min, mixing time is 3.5 hours, is then filtered by vacuum the dioxy of isolated modification
SiClx Nano filling, it is then placed in baking oven and is dried in 40 DEG C, modified silica nanometer is obtained with ball mill attrition grinding
Filler；
Step C, dispersion stabilizer, coloring agent, pH adjusting agent and partially modified silicone acrylic emulsion are well mixed；Then with pigment,
Modified Nano filling, remaining modified silicone acrylic emulsion grinding are uniform；Last mixture foam killer, thickener are mixed evenly,
Acrylic paints are prepared.
The acrylic paints being prepared are more fine and smooth, by acrylic paints natural film forming on a glass, find acrylic paints
Easy film forming, the film forming of acrylic paints is more close, and the surface of acrylic paints film forming has preferable hydrophobicity, and with preferable
Self-cleaning performance, there is preferable film forming；The contact angle that the film formation surface of acrylic paints is found after test is 105 °, surface
For hydrophobicity.The film formation surface hydrophobicity of the acrylic paints is preferable, is primarily due to acrylic paints in film forming procedure, fluorine list
Member has moved to the surface of film.
The modified silicone acrylic emulsion combines organosilicon fire-resistant, weatherability, chemical-resistant, hydrophobic, surface energy is low
Not v ulnerability；Combine the high guarantor of Organic fluoride high temperature resistant, weatherability, corrosion-resistant, the low free energy in surface and acrylic resin
Color, pliability, tack.The acrylic paints are a kind of high durable, high water-fast, resistant to pollution environmental-protection water-based pigment.
Embodiment 2：
A kind of wall colored drawing acrylic paints, being calculated according to mass parts mainly includes modified 100 parts of silicone acrylic emulsion, 10 parts of pigment,
60 parts of nano titania filler, dispersion stabilizer：12 parts, coloring agent：30 parts, defoamer：1.2 parts, thickener：2 parts, pH is adjusted
Save agent：1.5 part.
The modified silicone acrylic emulsion calculates according to mass parts mainly includes 100 parts of acrylic acid, MTMS 15
Part, 8 parts of dodecafluoroheptyl methacrylate, diacetone propionamide：0.3 part, 0.5 part of N hydroxymethyl acrylamide.
A kind of preparation method of wall colored drawing acrylic paints, is mainly included the following steps that：
Step A, prepare modified silicone acrylic emulsion：By acrylic acid, MTMS, dodecafluoroheptyl methacrylate monomer
It is mixed to get mix monomer；Mixed solution is obtained after emulsifying agent, DAAM, N hydroxymethyl acrylamide are mixed
Ⅱ；Initiator is configured to initiator solution；
Take 1/4 mix monomer, mixed solution II, initiator solution to be well mixed respectively, it is enterprising to be placed on heated at constant temperature agitator
Row is heated to 80 DEG C of reactions；When reaction solution turns it is blue when, then respectively with constant pressure funnel be slowly added dropwise remaining mix monomer,
Mixed solution II, initiator solution；After being added dropwise to complete, temperature is increased to 85 DEG C and reacted 3 hours, and mixing speed is 300 revs/min
Clock；Modified silicone acrylic emulsion is prepared after supercooling, filtering, discharging；
Step B, prepare modified silica nanometer filler：KH550 is mixed in methyl alcohol with nano silicon, temperature
Spend for 55 DEG C, mixing speed 400r/min, mixing time is 3.5 hours, is then filtered by vacuum the dioxy of isolated modification
SiClx Nano filling, it is then placed in baking oven and is dried in 50 DEG C, modified nano titania is obtained with ball mill attrition grinding
Filler；
Step C, dispersion stabilizer, coloring agent, pH adjusting agent, water and partially modified silicone acrylic emulsion are well mixed；Then with face
Material, modified Nano filling, remaining modified silicone acrylic emulsion grinding are uniform；Last mixture foam killer, thickener mix equal
It is even, acrylic paints are prepared.
The acrylic paints being prepared are more fine and smooth, by acrylic paints natural film forming on a glass, find acrylic paints
Easy film forming, the film forming of acrylic paints is more close, and the surface of acrylic paints film forming has preferable hydrophobicity, and with preferable
Self-cleaning performance, there is preferable film forming；The contact angle that the film formation surface of acrylic paints is found after test is 112 °, surface
For hydrophobicity.
The modified silicone acrylic emulsion combines organosilicon fire-resistant, weatherability, chemical-resistant, hydrophobic, surface energy is low
Not v ulnerability；Combine the high guarantor of Organic fluoride high temperature resistant, weatherability, corrosion-resistant, the low free energy in surface and acrylic resin
Color, pliability, tack.The acrylic paints are a kind of high durable, high water-fast, resistant to pollution environmental-protection water-based pigment.
It is described above, be only presently preferred embodiments of the present invention, any formal limitation not done to the present invention, it is every according to
Any simply modification, the equivalent variations made according to the technical spirit of the present invention to above example, each fall within the protection of the present invention
Within the scope of.
Claims (8)
1. a kind of wall colored drawing acrylic paints, it is characterised in that being calculated according to mass parts mainly includes following component：
Modified silicone acrylic emulsion：100 parts；
Pigment：15 parts -40 parts；
Nano filling：40-70 parts；
Dispersion stabilizer：10-20 parts；
Coloring agent：22-50 parts；
Defoamer：0.3-2 parts；
Thickener：0.5-3.5 parts；
PH adjusting agent：0.3-2 parts.
2. a kind of wall colored drawing acrylic paints according to claim 1, it is characterised in that the modified silicone acrylic emulsion is pressed
Being calculated according to mass parts mainly includes following component：
Acrylic acid：100 parts；
Acrylate containing silicone：15-20 parts；
Fluorinated acrylate：2-8 parts；
DAAM：0.2-2 parts；
Crosslinking agent：0.3-1.5 parts.
3. a kind of wall colored drawing acrylic paints according to claim 1, it is characterised in that the Nano filling is talcum
Any one in powder, silica, calcined kaolin, titanium dioxide.
4. a kind of wall colored drawing acrylic paints according to claim 2, it is characterised in that the crosslinking agent is N- hydroxyl first
Any one in base acrylamide, NMA, hydroxy propyl methacrylate.
5. a kind of wall colored drawing acrylic paints according to claim 2, it is characterised in that the fluorinated acrylate is
Any one in Hexafluorobutyl mathacrylate, dodecafluoroheptyl methacrylate, trifluoroethyl methacrylate.
6. a kind of preparation method of wall colored drawing acrylic paints, it is characterised in that mainly include the following steps that：
Step A, prepare modified silicone acrylic emulsion；
Step B, modified Nano filling is prepared, it is stand-by after dries pulverizing with coupling agent modified Nano filling；
Step C, dispersion stabilizer, coloring agent, pH adjusting agent and partially modified silicone acrylic emulsion are well mixed；Then with pigment,
Modified Nano filling, remaining modified silicone acrylic emulsion grinding are uniform；Last mixture foam killer, thickener are mixed evenly,
Acrylic paints are prepared.
A kind of 7. preparation method of wall colored drawing acrylic paints according to claim 6, it is characterised in that the step
A is mainly included the following steps that：
Step A1, acrylic acid, acrylate containing silicone, fluorinated acrylate monomer are mixed to get mix monomer, by emulsifying agent, double
Mixed solution II is obtained after acetone acrylamide, crosslinking agent mixing, initiator is configured to initiator solution；
Step A2, take 1/4 mix monomer, mixed solution II, initiator solution to be well mixed respectively, be placed on heated at constant temperature stirring
Carry out being heated to 70-80 DEG C of reaction on device；When reaction solution turns it is blue when, then be slowly added dropwise by constant pressure funnel remaining mixed
Close monomer, mixed solution II, initiator solution；After being added dropwise to complete, temperature is increased to 75-90 DEG C of reaction 4-8 hour, cool down,
Filtering, discharging, are prepared modified silicone acrylic emulsion.
A kind of 8. preparation method of wall colored drawing acrylic paints according to claim 6, it is characterised in that the step
To be stirred in a solvent with Nano filling with coupling agent in B, temperature is 30-70 DEG C, mixing speed 200-500r/min,
Mixing time is 2-5 hours；Then the Nano filling of isolated modification is filtered by vacuum, is then placed in baking oven in 40-60 DEG C
Drying, attrition grinding are the Nano filling of nano level modification.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710807718.5A CN107513299A (en) | 2017-09-08 | 2017-09-08 | A kind of wall colored drawing acrylic paints and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710807718.5A CN107513299A (en) | 2017-09-08 | 2017-09-08 | A kind of wall colored drawing acrylic paints and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114773930A (en) * | 2022-04-21 | 2022-07-22 | 南阳理工学院 | Method for making hand-painted wall painting |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101348595A (en) * | 2008-07-28 | 2009-01-21 | 北京大学 | Fluorine-silicon modified self-crosslinking acrylic ester emulsion and preparation thereof |
| CN106590288A (en) * | 2016-12-26 | 2017-04-26 | 中冶建筑研究总院有限公司 | Colored drawing coating with penetration dyeing function |
-
2017
- 2017-09-08 CN CN201710807718.5A patent/CN107513299A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101348595A (en) * | 2008-07-28 | 2009-01-21 | 北京大学 | Fluorine-silicon modified self-crosslinking acrylic ester emulsion and preparation thereof |
| CN106590288A (en) * | 2016-12-26 | 2017-04-26 | 中冶建筑研究总院有限公司 | Colored drawing coating with penetration dyeing function |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114773930A (en) * | 2022-04-21 | 2022-07-22 | 南阳理工学院 | Method for making hand-painted wall painting |
| CN114773930B (en) * | 2022-04-21 | 2024-02-27 | 南阳理工学院 | Manufacturing method of hand-painted wall painting |
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Application publication date: 20171226 |
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