CN107503163A - A kind of superfine fibre matte dermatine and its manufacture method with water-proof function - Google Patents
A kind of superfine fibre matte dermatine and its manufacture method with water-proof function Download PDFInfo
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- CN107503163A CN107503163A CN201710931947.8A CN201710931947A CN107503163A CN 107503163 A CN107503163 A CN 107503163A CN 201710931947 A CN201710931947 A CN 201710931947A CN 107503163 A CN107503163 A CN 107503163A
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- dermatine
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0004—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using ultra-fine two-component fibres, e.g. island/sea, or ultra-fine one component fibres (< 1 denier)
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0011—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using non-woven fabrics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/007—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by mechanical or physical treatments
- D06N3/0075—Napping, teasing, raising or abrading of the resin coating
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/007—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by mechanical or physical treatments
- D06N3/0077—Embossing; Pressing of the surface; Tumbling and crumbling; Cracking; Cooling; Heating, e.g. mirror finish
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/047—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with fluoropolymers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2201/00—Chemical constitution of the fibres, threads or yarns
- D06N2201/02—Synthetic macromolecular fibres
- D06N2201/0263—Polyamide fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/12—Permeability or impermeability properties
- D06N2209/126—Permeability to liquids, absorption
- D06N2209/128—Non-permeable
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/14—Properties of the materials having chemical properties
- D06N2209/142—Hydrophobic
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/12—Decorative or sun protection articles
- D06N2211/28—Artificial leather
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention discloses a kind of superfine fibre matte dermatine and its manufacture method with water-proof function, belong to the production and processing technical field of superfine fibre matte dermatine, including superfine fibre matte dermatine semi-finished product are carried out into hydrophobicity post processing, the hydrophobicity post processing uses C6 fluoroplasts as waterproofing agent, add blocked isocyanate, the catalyst of watersoluble melamine formaldehyde resin and watersoluble melamine formaldehyde resin is as additive, by being impregnated with and being heat-treated firm waterproof layer is formed in superfine fibre matte dermatine surface of semi-finished.It can be made with good hydrophobicity and water proofing property, and the finished product of the preferable superfine fibre matte dermatine of weatherability by manufacture method of the present invention.
Description
Technical field
The present invention discloses a kind of superfine fibre matte dermatine and its manufacture method with water-proof function, belongs to ultra-fine
The production and processing technical field of copolymer of fiber suede face dermatine.
Background technology
At present, the superfine fibre matte dermatine produced both at home and abroad, is using island superfine fiber as raw material mostly, passes through
Shredding, combing, networking, then consolidated repeatedly by acupuncture (or spun lacing) machine and turn into fabric, then pad, solidify through polyurethane, alkali
Liquid (or solvent) dissolves the part in (or extraction) sea, is most got product afterwards through sanding, dyeing, arrangement.
By above preparation method and the suede-like artificial leather for preparing it is quite varied be applied to clothes, case and bag, ornament materials
With the purposes such as automotive trim.And according to the difference of use, to the various performances of superfine fibre matte dermatine will
Ask and also improving constantly.Clothes are especially applicable to, when case and bag and automotive trim etc., to superfine fibre matte dermatine
Water proofing property have higher requirement.By post processing, preparing has good hydrophobic superfine fibre matte dermatine
There is very big market prospect.
The enterprise and scientific research department of lot of domestic and international have carried out many research to general textile hydrophobic water-proofing treatment, bag
Include and fabric is post-processed using C8 types and C6 type fluororesin, make it have hydrophobic waterproof effect.And use organic silicon
Compound carries out processing to base fabric and makes it have hydrophobicity.The problem of fluororesin of C8 types is due to PFOA, its use range is
Reduce.On the other hand, the principle of the method handled using organosilicon compound base fabric is that scrim surfaces form coating, with base
Do not have strong chemical interactions between cloth, therefore such a processing method is only applicable to require relatively low to durability degree weatherability
Purposes.The fluororesin of C6 types is the hydrophobic treatment resin of present mainstream applications.
But because the carbochain of the fluororesin of C6 types is shorter, the hydrophobic and waterproof of the textile handled using C6 types fluororesin
Effect all decreases compared with C8 type effects.Particularly apply in terms of superfine fibre matte dermatine, due to superfine fibre suede
Polyurethane resin in the dermatine of face has stronger hydrophily, the superfine fibre suede of the fluororesin processing by common C6 types
The hydrophobicity and water proofing property of face dermatine are generally poor, it is impossible to reach requirement.
In order to solve this problem, the present inventor solves by the screening to a variety of crosslinking agents and Integrated comparative
Above mentioned problem.Thus this case produces.
The content of the invention
To solve the above problems, the present invention provides a kind of superfine fibre matte dermatine and its system with water-proof function
Make method.
To reach above-mentioned purpose, the technical solution adopted in the present invention is：
A kind of manufacture method of the superfine fibre matte dermatine with water-proof function, including by superfine fibre matte people
Make semifinished leather products and carry out hydrophobicity post processing, the hydrophobicity post processing uses C6 fluoroplasts as waterproofing agent, addition envelope
The catalyst of closed form isocyanates, watersoluble melamine formaldehyde resin and watersoluble melamine formaldehyde resin is as addition
Agent, firm waterproof layer is formed in superfine fibre matte dermatine surface of semi-finished by being impregnated with and being heat-treated.That is, it is of the invention
It is prepared for the impregnation processing aqueous solution of C6 fluoroplasts.In the impregnation processing aqueous solution of the C6 fluoroplasts, enclosed type is different
Cyanate is crosslinking agent, and watersoluble melamine formaldehyde resin is weatherability elevator.
As the further setting of above-metioned scheme, the usage amount of the C6 fluoroplasts is 50g/L-200g/L.That is C6 fluorine
In the impregnation processing aqueous solution of plain resin, the content of C6 fluoroplasts is 50g/L-200g/L.
The usage amount of the blocked isocyanate is 5g/L-20g/L.That is the impregnation processing aqueous solution of C6 fluoroplasts
In, the addition of blocked isocyanate is 5g/L-20g/L.
The usage amount of the watersoluble melamine formaldehyde resin is 10g/L-30g/L.I.e. at the impregnation of C6 fluoroplasts
In the reason aqueous solution, the addition of watersoluble melamine formaldehyde resin is 10g/L-30g/L.
The catalyst of the watersoluble melamine formaldehyde resin is acidic catalyst, and pKa scopes are 1-3 phosphoric acid, phosphorus
Any one in hydrochlorate, metal salt, organic acid and acylate, usage amount are the 1/ of watersoluble melamine formaldehyde resin
10-1/2。
The temperature of the heat treatment is more than 130 DEG C, and the time is more than 1 minute.
A kind of superfine fibre matte dermatine with water-proof function of the present invention is a kind of according to any of the above-described
Obtained by the manufacture method of superfine fibre matte dermatine with water-proof function.
In the present invention, superfine fibre matte dermatine semi-finished product are made by following preparation method：
Base fabric is using island or not island fiber with figured sea-island chopped fiber is determined, and by opening bag, lapping, acupuncture (spun lacing) prepares base fabric.
This base fabric carries out the impregnation processing of polyurethane resin after overheat gives contracting to improve apparent density, after impregnation processing, through solidification, alkali lye
(or solvent) dissolves the part in (or extraction) sea, most produces superfine fibre matte dermatine half through sanding, dyeing, arrangement afterwards
Finished product.
Superfine fibre matte dermatine semi-finished product are placed in the impregnation processing aqueous solution of C6 fluoroplasts by the present invention
Dry after impregnation processing, be heat-treated afterwards, the temperature of heat treatment is more than 130 DEG C, and processing time is more than 1 minute.It
After can obtain that there is good hydrophobicity and water proofing property, and the finished product of the preferable superfine fibre matte dermatine of weatherability.
Superfine fibre matte dermatine of the present invention has the characteristics that：
Experimental method JISL1092：2009 spray experiments, Initial Experimental Stage result, more than 4 grades；Weatherability experiment condition：Temperature
70 degree of degree, relative humidity 90%, experimental period 200 hours；Get wet experimental result after weather resistant experiment, more than 3.5 grades.
Embodiment
Below by specific embodiment, the invention will be further described, but the present invention is not limited by following examples
It is fixed.
Embodiment 1
Dacron ultrafine fiber base fabric, the use of fiber is 37 Dao Ding islands, marine origin is divided into terylene, and island component is terylene, and length is
51mm.Above-mentioned fiber passes through lapping, and acupuncture prepares base fabric.This base fabric gives contracting to improve the poly- ammonia of the laggard water-filling of apparent density through overheat
The impregnation processing of ester resin, after impregnation processing, the part in sea is dissolved through solidification, alkali lye, is most produced afterwards through sanding, dyeing, arrangement
Dermatine semi-finished product.Hydrophobicity post processing is carried out to above-mentioned dermatine semi-finished product.
Specific prescription is as follows：
1. great Jin TG-5601 50g/L (great Jin)
2. blocked isocyanate 5g/L (solar corona chemistry)
3. watersoluble melamine formaldehyde resin 30g/L (solar corona chemistry)
4. catalyst 10g/L (solar corona chemistry)
Dermatine semi-finished product are dried in the above-mentioned aqueous solution after impregnation processing, are heat-treated afterwards, heat treatment
Temperature is 130 degree, and processing time is 2 minutes.
Embodiment 2
Nylon ultrafine fiber base fabric, the use of fiber is 37 Dao Ding islands, marine origin is divided into terylene, and island component is nylon, and length is
51mm.Subsequent treatment is same as Example 1.
Embodiment 3
Use base fabric same as Example 1.
The prescription of hydrophobicity post processing is as follows：
1. great Jin TG-5601 80g/L (great Jin)
2. blocked isocyanate 8g/L (solar corona chemistry)
3. watersoluble melamine formaldehyde resin 20g/L (solar corona chemistry)
4. catalyst 10g/L (solar corona chemistry)
Dermatine semi-finished product are dried in the above-mentioned aqueous solution after impregnation processing, are heat-treated afterwards, heat treatment
Temperature is 130 degree, and processing time is 2 minutes.
Embodiment 4
Use base fabric same as Example 1.
The prescription of hydrophobicity post processing is as follows：
1. great Jin TG-5601 100g/L (great Jin)
2. blocked isocyanate 10g/L (solar corona chemistry)
3. watersoluble melamine formaldehyde resin 10g/L (solar corona chemistry)
4. catalyst 5g/L (solar corona chemistry)
Dermatine semi-finished product are dried in the above-mentioned aqueous solution after impregnation processing, are heat-treated afterwards, heat treatment
Temperature is 130 degree, and processing time is 2 minutes.
Embodiment 5
Use base fabric same as Example 1.
The prescription of hydrophobicity post processing is as follows：
1. great Jin TG-5601 200g/L (great Jin)
2. blocked isocyanate 10g/L (solar corona chemistry)
3. watersoluble melamine formaldehyde resin 10g/L (solar corona chemistry)
4. catalyst 5g/L (solar corona chemistry)
Dermatine semi-finished product are dried in the above-mentioned aqueous solution after impregnation processing, are heat-treated afterwards, heat treatment
Temperature is 130 degree, and processing time is 2 minutes.
In above-mentioned all embodiments, great Jin TG-5601 are the specifications and models of C6 fluoroplasts, and catalyst is pKa scopes
For any one in 1-3 phosphoric acid, phosphate, metal salt, organic acid and acylate.
Comparative example 1
It is same as Example 1 using base fabric.
Specific prescription when hydrophobicity post-processes is as follows：
1. great Jin TG-5601 40g/L (great Jin)
Dermatine semi-finished product are dried in the above-mentioned aqueous solution after impregnation processing, are heat-treated afterwards, heat treatment
Temperature is 130 degree, and processing time is 2 minutes.
Comparative example 2
It is same as Example 1 using base fabric.
Specific prescription when hydrophobicity post-processes is as follows：
1. great Jin TG-5601 40g/L (great Jin)
2. blocked isocyanate 4g/L (solar corona chemistry)
Dermatine semi-finished product are dried in the above-mentioned aqueous solution after impregnation processing, are heat-treated afterwards, heat treatment
Temperature is 130 degree, and processing time is 2 minutes.
Comparative example 3
It is same as Example 1 using base fabric.
Specific prescription when hydrophobicity post-processes is as follows：
1. great Jin TG-5601 80g/L (great Jin)
2. blocked isocyanate 8g/L (solar corona chemistry)
Dermatine semi-finished product are dried in the above-mentioned aqueous solution after impregnation processing, are heat-treated afterwards, heat treatment
Temperature is 100 degree, and processing time is 2 minutes
Comparative example 4
It is same as Example 1 using base fabric.
Specific prescription when hydrophobicity post-processes is as follows：
1. great Jin TG-5601 80g/L
2. blocked isocyanate 8g/L
Dermatine semi-finished product are dried in the above-mentioned aqueous solution after impregnation processing, are heat-treated afterwards, heat treatment
Temperature is 150 degree, and processing time is 30 seconds.
The treatment conditions of embodiment and comparative example, see the table below 1
Performance test：
In order to evaluate the hydrophobic weatherability of above-mentioned sample, weatherability evaluation method is JIS D0205Test
Method of Weatherability for Automotive Parts test species WAL-1S (H) experimental period 50,100,
150,200 hours.
Hydrophobicity evaluation method is JIS L 1092：2009Testing methods for water resistance
Of textiles hydrophobicitys are tested, spray process.
Performance test result, see the table below 2
Above-described embodiment is only used for illustrating the inventive concept of the present invention, rather than the restriction to rights protection of the present invention,
All changes for carrying out unsubstantiality to the present invention using this design, all should fall into protection scope of the present invention.
Claims (7)
1. a kind of manufacture method of the superfine fibre matte dermatine with water-proof function, including superfine fibre matte is artificial
Semifinished leather products carry out hydrophobicity post processing, it is characterised in that：The hydrophobicity post processing uses C6 fluoroplasts as waterproof
Agent, the catalysis of addition blocked isocyanate, watersoluble melamine formaldehyde resin and watersoluble melamine formaldehyde resin
Agent forms firm waterproof by being impregnated with and being heat-treated as additive in superfine fibre matte dermatine surface of semi-finished
Layer.
2. a kind of manufacture method of the superfine fibre matte dermatine with water-proof function as claimed in claim 1, it is special
Sign is：The usage amount of the C6 fluoroplasts is 50g/L-200g/L.
3. a kind of manufacture method of the superfine fibre matte dermatine with water-proof function as claimed in claim 1, it is special
Sign is：The usage amount of the blocked isocyanate is 5g/L-20g/L.
4. a kind of manufacture method of the superfine fibre matte dermatine with water-proof function as claimed in claim 1, it is special
Sign is：The usage amount of the watersoluble melamine formaldehyde resin is 10g/L-30g/L.
5. a kind of manufacture method of the superfine fibre matte dermatine with water-proof function as claimed in claim 1, it is special
Sign is：The catalyst of the watersoluble melamine formaldehyde resin is acidic catalyst, and pKa scopes are 1-3 phosphoric acid, phosphoric acid
Any one in salt, metal salt, organic acid and acylate, usage amount are the 1/10- of watersoluble melamine formaldehyde resin
1/2。
6. a kind of manufacture method of the superfine fibre matte dermatine with water-proof function as claimed in claim 1, it is special
Sign is：The temperature of the heat treatment is more than 130 DEG C, and the time is more than 1 minute.
A kind of 7. superfine fibre matte dermatine with water-proof function, it is characterised in that：According to any one of claim 1-6
Obtained by a kind of manufacture method of superfine fibre matte dermatine with water-proof function.
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| CN201710931947.8A CN107503163B (en) | 2017-10-10 | 2017-10-10 | Superfine fiber suede artificial leather with waterproof function and manufacturing method thereof |
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| CN201710931947.8A CN107503163B (en) | 2017-10-10 | 2017-10-10 | Superfine fiber suede artificial leather with waterproof function and manufacturing method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109082895A (en) * | 2018-05-02 | 2018-12-25 | 浙江梅盛实业股份有限公司 | A kind of superfine fibre flannelette rtificial leather and preparation method |
| CN109537305A (en) * | 2018-11-20 | 2019-03-29 | 浙江梅盛实业股份有限公司 | A kind of superfine fibre flannelette artificial leather and preparation method thereof with bacteria resistance function |
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| CN101424043B (en) * | 2007-10-30 | 2011-05-11 | 欧诺法装饰材料（上海）有限公司 | PVC chemical leather treating agent, PVC chemical leather and method for producing the same |
| JP5596081B2 (en) * | 2012-06-11 | 2014-09-24 | セーレン株式会社 | Stretch coated fabric and method for producing the same |
| CN104151953B (en) * | 2014-08-20 | 2016-06-01 | 杭州福斯特光伏材料股份有限公司 | A kind of weather resistance fluorocarbon coating and its preparation method |
| CN104562710B (en) * | 2015-01-27 | 2016-08-17 | 张家港市德宝化工有限公司 | A kind of high-durability ultra-fine polyester fiber fabric surface treating method |
| CN106592254B (en) * | 2016-11-21 | 2018-10-26 | 上海华峰超纤材料股份有限公司 | Outdoor water-proof antibiotic superfine fiber chemical leather and its method for sorting |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109082895A (en) * | 2018-05-02 | 2018-12-25 | 浙江梅盛实业股份有限公司 | A kind of superfine fibre flannelette rtificial leather and preparation method |
| CN109082895B (en) * | 2018-05-02 | 2021-04-06 | 浙江梅盛实业股份有限公司 | Superfine fiber suede artificial leather and preparation method thereof |
| CN109537305A (en) * | 2018-11-20 | 2019-03-29 | 浙江梅盛实业股份有限公司 | A kind of superfine fibre flannelette artificial leather and preparation method thereof with bacteria resistance function |
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