CN107503125A - A kind of conductive cotton fiber based on nano silver wire nano-Ag particles - Google Patents
A kind of conductive cotton fiber based on nano silver wire nano-Ag particles Download PDFInfo
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- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
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- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
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- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
Abstract
The invention discloses a kind of conductive cotton fiber based on nano silver wire nano-Ag particles, first by bafta anionic, then in anionic surface of cotton fabric LBL self-assembly nano silver wire and nano-Ag particles, the conductive cotton fiber based on nano silver wire nano-Ag particles is finally prepared.Nano silver wire and nano-Ag particles impart the excellent conduction of cotton fiber, antibacterial, uvioresistant, crease-resistant and washing fastness, have important application value in fields such as wearable device, compliant conductive device, functional textiles.
Description
Technical field
The present invention relates to a kind of conductive cotton fiber based on nano silver wire-nano-Ag particles, belongs to textile material field.
Background technology
Cotton fiber is with the performance such as its excellent moisture absorption, ventilative, comfortable, soft, warming, renewable, degradable by vast
Consumer's likes.But compared with synthetic fibers, the feature of cotton fiber still has deficiency.Such as：（1）Cotton fiber have than
The features such as surface area is greatly and wettability power is strong, thus easily adhere to, breed and propagate microorganism during taking, so as to cause
Cotton fiber strength declines, produces stain, colour fading and smell, or even spreads disease, and influences health.（2）Excessive ultraviolet
Irradiation can cause skin injury, aging, or even cause canceration.（3）Conductive spinning product is increasingly becoming the focus of research in recent years, leads
Electric bafta has huge application value in flexible wearable equipment.Therefore in order to fully excavate the potential function of cotton fiber,
The technology content and added value of product of cotton fiber are improved, carrying out functional modification to cotton fiber turns into an important research direction
（The preparation of dissaving polymer and functional modification [D] the University Of Suzhou to cotton fiber, 2009）.
Inorganic nano material refers to that size is in 1-100nm material, relative to other nano materials, inorganic nano material
With preparing simple, the advantage such as cost is cheap, uniform particle diameter, photocatalysis, solar cell, biology, medicine, weaving, printing and dyeing,
There are extensive research and application in the fields such as wearable electronic.In the inorganic nano material of numerous types, Nano Silver accounts for
According to important position, Nano Silver is combined with cotton fiber can be effectively improved cotton fiber inherent shortcoming, expand cotton fiber and be applicable
Scope, improve cotton fiber added value.Lot of documents is reported using after nano-Ag particles modified cotton fiber, and it is excellent can to assign cotton fiber
The performances such as different antibacterial, uvioresistant, conduction, electromagnetic shielding.But above-mentioned document is modified cotton using the silver nano-grain of zero dimension more
Fabric.Such as Zhang carries out antibacterial assembling to bafta using Nano Silver, bafta after assembling to staphylococcus aureus and
The bacteriostasis rate of Escherichia coli is respectively 99.01% and 99.26%, and after 20 washings, bacteriostasis rate is still up to 98.77%（Fibers
and Polymers, 2009, 10(4): 496-501）.
The nano silver wire of one-dimentional structure has high-specific surface area, heat conduction, conduction, printing opacity, ductility, mechanical strength and flexibility
Etc. performance, there is potential application value in fields such as flexible conductive film, solar cell, touch-screen, display screen, sensors
（Chinese material is in progress, 2016 (07): 545-551）.The existing research on nano silver wire modifying textile fibres on a small quantity at present
Report（Based on the electronic textile of nano silver wire conductive network, chemical progress, 2017,29 (8): 892-901）.Iran she
Si Lan Free University Nateghi uses AgNWs modified cotton fabrics, and have studied the antibacterial, uvioresistant, conduction of modified bafta
And ultra-hydrophobicity（Carbohydrate Polymers, 2015, 117:160）.Canadian University of Waterloo (CA) Waterloo, Ontario, N2L3GI Canada Atwa passes through leaching
Stain-czochralski method coats AgNWs conductive networks on cotton thread surface, then anneals 30 minutes for 150 DEG C, so as to which conductive cotton thread be prepared
（Journal of Materials Chemistry C, 2015, 3(16):3908）.Polish textile science research institute Cies '
Lak uses dipping-oven drying method assembling bafta（Cellulose, 2017, 24(1):409）.University Of Suzhou repaiies A Nan and knits cotton
Thing, which is immersed in AgNWs solution, carries out antibacterial, uvioresistant assembling（Repair the amphiphilic hyper-branched polyglycidyl ethers of A Nan, Yin Na
The preparation of rice noodles and bafta assembling pre-test [D] University Of Suzhou, 2015）.Chinese invention patent CN201610217104.7 is by cotton
Cloth is soaked in nano silver wire/alcohol dispersion liquid, is taken out and is soaked in again in above-mentioned dispersion liquid after drying, repeated multiple times to obtain table
Face is adsorbed with the conductive cotton of nano silver wire.Nanjing Univ. of Posts and Telecommunications Zhang Ziqiang induces the method for self assembly will first with capillary
AgNWs is assembled on nylon yarn, obtains AgNWs conductive yarns, and the AgNWs conductive yarns prepared then are immersed in into fibroin
Secondary assembling is carried out in solution, finally again reduces fibroin, obtains the graphene bag with preferable mechanical performance and adhesion property
The AgNWs conductive yarns wrapped up in（Zhang Ziqiang electrical-conductive nanometers materials are in the capillary self assembly of fiber surface and performance study [D] south
Capital University of Post and Telecommunication, 2016）.But the effect in above-mentioned document between AgNWs and fiber is mainly with Van der Waals force and hydrogen bond formation
Based on existing physical absorption, lack firm active force and combine, its fastness to washing is on the weak side（Based on nano silver wire conductive network
Electronic textile, chemical progress, 2017,29 (8): 892-901）.
The content of the invention
In view of the above problems, the present invention provides a kind of conductive cotton fiber and its system based on nano silver wire-nano-Ag particles
Preparation Method.
The technical scheme is that：
（1）Bafta is placed in the sodium hydroxide solution that mass fraction is 20%, bath raio 1:50,90 DEG C of reaction 120min, are used
Deionized water is washed till neutrality repeatedly, and sodium hydroxide modified cotton fabric is obtained after drying；Then by sodium hydroxide modified cotton fabric weight
Newly it is scattered in deionized water, bath raio 1:50, initiator ammonium ceric nitrate is added, wherein ammonium ceric nitrate is modified cotton with sodium hydroxide and knitted
The mass ratio of thing is 1:10-1:30, nitrogen protection is continually fed into, 120min is mixed, it is pungent to be then slowly added into two butyric acid two
Ester sodium sulfonate, the mass ratio of the sodium hydroxide modified cotton fabric and dioctyl sodium sulfosuccinate is 5:1-1:1, mix
After uniformly, 80-90 DEG C and magnetic agitation 1-12h is to slowly warm up to, room temperature is naturally cooled to, washing, suction filtration, obtains the moon after drying
Ionize bafta.（2）Silver nitrate is configured to the 1-100g/L aqueous solution, is slowly added to vitamin C and dodecyl sulphate
Sodium, wherein the mass ratio of the vitamin C and silver nitrate is 2:1-1:2, the quality of the lauryl sodium sulfate and silver nitrate
Than for 1:5-1:10, after ultrasound is uniform, 80 DEG C of reaction 6h, is cleaned, centrifuged repeatedly with ethanol and deionized water, obtained after drying process
To nano-Ag particles.（3）Nano silver wire is configured to the 1-10g/L aqueous solution, then adds 1-10g/L polyamide-amide tree
The volume ratio of the shape macromolecular PAMAM aqueous solution, the PAMAM aqueous solution and the nano silver wire aqueous solution is 1:1-1:10, under normal temperature
After at the uniform velocity stirring reaction 24h, washed repeatedly with deionized water and ethanol, PAMAM modification nano silver wires are obtained after drying.（4）Will
Above-mentioned PAMAM modifications nano silver wire is configured to the 1-10g/L aqueous solution, is then immersed in above-mentioned anionic bafta
10-60min in the PAMAM modification nano silver wire aqueous solution, bath raio 1:10, rinsed, dried repeatedly with deionized water after taking-up；Then
Above-mentioned bafta is immersed in 10-60min in the 1-10g/L nano-Ag particles aqueous solution, bath raio 1:10, use deionization after taking-up
Water rinses repeatedly, drying, one layer of nano-Ag particles/nano silver wire is so far assembled into the surface of bafta, then existed successively
Aforesaid operations are repeated in nano silver wire and nano-Ag particles dressing liquid, determine surface of cotton fabric nano-Ag particles/silver as needed
The number of plies of nano wire assembling.
Polyol process synthesis of silver nano-wire refers to document：Peng Yongyi, Xu Guojun, Dai Guozhang, Li Hong build nano silver wires
Polyol process preparation process condition research [J] material Leaders, 2015,29 (22):79-81+86；Summer Xingda, Yang Bingchu,
Auspicious, the hot method of Zhou Conghua polyalcohols prepares nano silver wire and its application [J] functional materials in transparent conductive film,
2016,47(05):5091-5095；Li Yiqun liquid phases polyol process controlledly synthesis metal silver nanowires and its in electrically conducting transparent
Application [D] Lanzhou University in film, 2015；Ma Xiao, You Fangfang, Feng Jinyang, Zhao Xiujian polyol process prepare one-dimensional Ag nanometers
Line [J] artificial lens journals, 2014,43 (03):587-591；Guo Ruiping, Zheng Min, Zhang Haixia microwave radiation technology polyol process
Quick research [J] the Institutes Of Technology Of Taiyuan journal for preparing Ag nano wires, 2013,44 (01):76-80；Chinese invention patent
CN201610804238.9；Chinese invention patent CN201710357029.9.
Compared with prior art, the advantage of the invention is that：Using vitamin C as reducing agent, lauryl sodium sulfate
（SDS）Anionic Nano Silver system is prepared as protective agent.It is right when SDS molecules are present between Nano silver grain
Nano silver grain serves electrostatic-space stability ultimate load effect.Nano silver wire and SDS modifications nano-Ag particles, anionic cotton
Fiber imparts the excellent conduction of cotton fiber, antibacterial, anti-purple by electrostatic attraction strong bonded, nano silver wire and nano-Ag particles
Outer and washing fastness.
Embodiment
The invention will be further elucidated with reference to specific embodiments.
Embodiment 1：
（1）Bafta is placed in the sodium hydroxide solution that mass fraction is 20%, bath raio 1:50,90 DEG C of reaction 120min, are used
Deionized water is washed till neutrality repeatedly, and sodium hydroxide modified cotton fabric is obtained after drying；Then by sodium hydroxide modified cotton fabric weight
Newly it is scattered in deionized water, bath raio 1:50, initiator ammonium ceric nitrate is added, wherein ammonium ceric nitrate is modified cotton with sodium hydroxide and knitted
The mass ratio of thing is 1:10, nitrogen protection is continually fed into, 120min is mixed, is then slowly added into two butyric acid dioctyl ester sulfonic acid
Sodium, the mass ratio of the sodium hydroxide modified cotton fabric and dioctyl sodium sulfosuccinate is 5:1, after being mixed evenly, delay
It is slow to be warming up to 80 DEG C and magnetic agitation 1h, room temperature is naturally cooled to, washing, suction filtration, obtains anionic bafta after drying.
（2）Silver nitrate is configured to the 1g/L aqueous solution, is slowly added to vitamin C and lauryl sodium sulfate, wherein the vitamin C
Mass ratio with silver nitrate is 2:1, the mass ratio of the lauryl sodium sulfate and silver nitrate is 1:5, after ultrasound is uniform, 80 DEG C
6h is reacted, cleaned repeatedly with ethanol and deionized water, centrifuge, nano-Ag particles is obtained after drying process.（3）Nano silver wire is matched somebody with somebody
The 1g/L aqueous solution is made, then adds the 1g/L Polyamidoamine Dendrimers PAMAM aqueous solution, the PAMAM aqueous solution
Volume ratio with the nano silver wire aqueous solution is 1:1, under normal temperature after at the uniform velocity stirring reaction 24h, washed repeatedly with deionized water and ethanol
Wash, PAMAM modification nano silver wires are obtained after drying.（4）Above-mentioned PAMAM modification nano silver wires are configured to the 1g/L aqueous solution,
Then above-mentioned anionic bafta is immersed in 10min in the PAMAM modification nano silver wire aqueous solution, bath raio 1:10, after taking-up
Rinsed, dried repeatedly with deionized water；Then above-mentioned bafta is immersed in 10min in the 1g/L nano-Ag particles aqueous solution,
Bath raio 1:10, rinsed repeatedly with deionized water after taking-up, dry, obtain conductive cotton.
Embodiment 2：
（1）Bafta is placed in the sodium hydroxide solution that mass fraction is 20%, bath raio 1:50,90 DEG C of reaction 120min, are used
Deionized water is washed till neutrality repeatedly, and sodium hydroxide modified cotton fabric is obtained after drying；Then by sodium hydroxide modified cotton fabric weight
Newly it is scattered in deionized water, bath raio 1:50, initiator ammonium ceric nitrate is added, wherein ammonium ceric nitrate is modified cotton with sodium hydroxide and knitted
The mass ratio of thing is 1:20, nitrogen protection is continually fed into, 120min is mixed, is then slowly added into two butyric acid dioctyl ester sulfonic acid
Sodium, the mass ratio of the sodium hydroxide modified cotton fabric and dioctyl sodium sulfosuccinate is 2:1, after being mixed evenly, delay
It is slow to be warming up to 85 DEG C and magnetic agitation 6h, room temperature is naturally cooled to, washing, suction filtration, obtains anionic bafta after drying.
（2）Silver nitrate is configured to the 10g/L aqueous solution, is slowly added to vitamin C and lauryl sodium sulfate, wherein the vitamin
The mass ratio of C and silver nitrate is 1:1, the mass ratio of the lauryl sodium sulfate and silver nitrate is 1:6, after ultrasound is uniform, 80
DEG C reaction 6h, cleaned repeatedly with ethanol and deionized water, centrifuge, nano-Ag particles obtained after drying process.（3）By nano silver wire
The 5g/L aqueous solution is configured to, then adds the 5g/L Polyamidoamine Dendrimers PAMAM aqueous solution, the PAMAM is water-soluble
The volume ratio of liquid and the nano silver wire aqueous solution is 1:5, under normal temperature after at the uniform velocity stirring reaction 24h, with deionized water and ethanol repeatedly
Washing, PAMAM modification nano silver wires are obtained after drying.（4）Above-mentioned PAMAM modification nano silver wires are configured to the water-soluble of 5g/L
Liquid, above-mentioned anionic bafta is then immersed in 30min in the PAMAM modification nano silver wire aqueous solution, bath raio 1:10, take out
Rinsed, dried repeatedly with deionized water afterwards；Then above-mentioned bafta is immersed in the 5g/L nano-Ag particles aqueous solution
30min, bath raio 1:10, rinsed, dried, so far by one layer of nano-Ag particles/nano silver wire repeatedly with deionized water after taking-up
The surface of bafta is assembled into, then aforesaid operations is repeated once in nano silver wire and nano-Ag particles dressing liquid successively, obtains
To conductive cotton.
Embodiment 3：
（1）Bafta is placed in the sodium hydroxide solution that mass fraction is 20%, bath raio 1:50,90 DEG C of reaction 120min, are used
Deionized water is washed till neutrality repeatedly, and sodium hydroxide modified cotton fabric is obtained after drying；Then by sodium hydroxide modified cotton fabric weight
Newly it is scattered in deionized water, bath raio 1:50, initiator ammonium ceric nitrate is added, wherein ammonium ceric nitrate is modified cotton with sodium hydroxide and knitted
The mass ratio of thing is 1:30, nitrogen protection is continually fed into, 120min is mixed, is then slowly added into two butyric acid dioctyl ester sulfonic acid
Sodium, the mass ratio of the sodium hydroxide modified cotton fabric and dioctyl sodium sulfosuccinate is 1:1, after being mixed evenly, delay
It is slow to be warming up to 90 DEG C and magnetic agitation 12h, room temperature is naturally cooled to, washing, suction filtration, obtains anionic bafta after drying.
（2）Silver nitrate is configured to the 100g/L aqueous solution, is slowly added to vitamin C and lauryl sodium sulfate, wherein the dimension life
Plain C and silver nitrate mass ratio are 1:2, the mass ratio of the lauryl sodium sulfate and silver nitrate is 1:10, after ultrasound is uniform,
80 DEG C of reaction 6h, are cleaned, centrifuge, nano-Ag particles are obtained after drying process repeatedly with ethanol and deionized water.（3）By silver nanoparticle
Line is configured to the 10g/L aqueous solution, then adds the 10g/L Polyamidoamine Dendrimers PAMAM aqueous solution, the PAMAM
The volume ratio of the aqueous solution and the nano silver wire aqueous solution is 1:10, under normal temperature after at the uniform velocity stirring reaction 24h, with deionized water and ethanol
Wash repeatedly, PAMAM modification nano silver wires are obtained after drying.（4）Above-mentioned PAMAM modification nano silver wires are configured to 10g/L's
The aqueous solution, above-mentioned anionic bafta is then immersed in 60min in the PAMAM modification nano silver wire aqueous solution, bath raio 1:10,
Rinsed, dried repeatedly with deionized water after taking-up；Then above-mentioned bafta is immersed in the 10g/L nano-Ag particles aqueous solution
60min, bath raio 1:10, rinsed, dried, so far by one layer of nano-Ag particles/nano silver wire repeatedly with deionized water after taking-up
The surface of bafta is assembled into, then aforesaid operations in triplicate in nano silver wire and nano-Ag particles dressing liquid successively, obtained
To conductive cotton.
Obviously, the above embodiment of the present invention is only intended to clearly illustrate example of the present invention, and is not pair
The restriction of embodiments of the present invention.For those of ordinary skill in the field, may be used also on the basis of the above description
To make other changes in different forms.Here all embodiments can not be exhaustive.It is every to belong to this hair
Row of the obvious changes or variations that bright technical scheme is amplified out still in protection scope of the present invention.
Claims (5)
- A kind of 1. preparation method of the conductive cotton fiber based on nano silver wire-nano-Ag particles, it is characterised in that：Step 1：Bafta is placed in the sodium hydroxide solution that mass fraction is 20%, bath raio 1:50,90 DEG C of reactions 120min, neutrality is washed till repeatedly with deionized water, sodium hydroxide modified cotton fabric is obtained after drying；Then sodium hydroxide is modified Bafta is scattered in deionized water again, bath raio 1:50, add initiator ammonium ceric nitrate, wherein ammonium ceric nitrate and sodium hydroxide The mass ratio of modified cotton fabric is 1:10-1:30, nitrogen protection is continually fed into, 120min is mixed, is then slowly added into two Fourth sodium dioctyl sulfo, the mass ratio of the sodium hydroxide modified cotton fabric and dioctyl sodium sulfosuccinate is 5:1-1:1, After being mixed evenly, 80-90 DEG C and magnetic agitation 1-12h is to slowly warm up to, room temperature is naturally cooled to, washing, filters, dries After obtain anionic bafta；Step 2：Silver nitrate is configured to the 1-100g/L aqueous solution, is slowly added to vitamin C and lauryl sodium sulfate, is surpassed After sound is uniform, 80 DEG C of reaction 6h, is cleaned repeatedly with ethanol and deionized water, centrifuge, nano-Ag particles are obtained after drying process；Step 3：Nano silver wire is configured to the 1-10g/L aqueous solution, then adds 1-10g/L tree-shaped big point of polyamide-amide The volume ratio of the sub- PAMAM aqueous solution, the PAMAM aqueous solution and the nano silver wire aqueous solution is 1:1-1:10, at the uniform velocity stir under normal temperature After mixing reaction 24h, washed repeatedly with deionized water and ethanol, PAMAM modification nano silver wires are obtained after drying；Step 4：Above-mentioned PAMAM modification nano silver wires are configured to the 1-10g/L aqueous solution, then by above-mentioned anionic cotton Fabric is immersed in 10-60min in the PAMAM modification nano silver wire aqueous solution, bath raio 1:10, rushed repeatedly with deionized water after taking-up Wash, dry；Then above-mentioned bafta is immersed in 10-60min in the 1-10g/L nano-Ag particles aqueous solution, bath raio 1:10, take Rinsed, dried repeatedly with deionized water after going out, one layer of nano-Ag particles/nano silver wire is so far assembled into the table of bafta Face, aforesaid operations are then repeated in nano silver wire and nano-Ag particles dressing liquid successively, determine surface of cotton fabric as needed The number of plies of nano-Ag particles/nano silver wire assembling.
- 2. a kind of preparation method of conductive cotton fiber based on nano silver wire-nano-Ag particles according to claim 1, its It is characterised by, the mass ratio of the vitamin C and silver nitrate is 2:1-1:2.
- 3. a kind of preparation method of conductive cotton fiber based on nano silver wire-nano-Ag particles according to claim 1, its It is characterised by, the mass ratio of the lauryl sodium sulfate and silver nitrate is 1:5-1:10.
- 4. a kind of preparation method of conductive cotton fiber based on nano silver wire-nano-Ag particles according to claim 1, its It is characterised by, the nano silver wire is synthesized using polyol process.
- A kind of 5. conductive cotton fiber based on nano silver wire-nano-Ag particles obtained by claim 1 preparation method.
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| CN108867060A (en) * | 2018-07-17 | 2018-11-23 | 澳洋集团有限公司 | A kind of preparation method of conduction cotton fabric |
| CN111335026A (en) * | 2020-05-06 | 2020-06-26 | 电子科技大学中山学院 | Super-hydrophobic antibacterial conductive fabric and preparation method thereof |
| CN112210870A (en) * | 2020-10-09 | 2021-01-12 | 大连尚捷科技有限公司 | Preparation method of antibacterial anti-static fabric |
| CN112941899A (en) * | 2021-03-05 | 2021-06-11 | 苏州经贸职业技术学院 | MXenes-AgNPs synergistic antibacterial cotton fabric and preparation method thereof |
| CN114671711A (en) * | 2022-04-19 | 2022-06-28 | 新明珠集团股份有限公司 | Antibacterial rock plate and manufacturing method thereof |
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| CN114671711A (en) * | 2022-04-19 | 2022-06-28 | 新明珠集团股份有限公司 | Antibacterial rock plate and manufacturing method thereof |
| CN114892396A (en) * | 2022-06-20 | 2022-08-12 | 深圳市乐清合兴电子有限公司 | Conductive cloth with good conductivity and manufacturing method thereof |
| CN114892396B (en) * | 2022-06-20 | 2024-01-19 | 深圳市乐清合兴电子有限公司 | Conductive cloth with good conductivity and manufacturing method thereof |
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