CN107502876A - Iron ecology nickel plating water-based process material and its nickel plating process - Google Patents
Iron ecology nickel plating water-based process material and its nickel plating process Download PDFInfo
- Publication number
- CN107502876A CN107502876A CN201710612690.XA CN201710612690A CN107502876A CN 107502876 A CN107502876 A CN 107502876A CN 201710612690 A CN201710612690 A CN 201710612690A CN 107502876 A CN107502876 A CN 107502876A
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- Prior art keywords
- nickel plating
- ecology
- iron
- based process
- nickel
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Classifications
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/31—Coating with metals
- C23C18/32—Coating with nickel, cobalt or mixtures thereof with phosphorus or boron
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/1601—Process or apparatus
- C23C18/1633—Process of electroless plating
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- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electroplating And Plating Baths Therefor (AREA)
Abstract
The invention discloses a kind of iron ecology nickel plating water-based process material, it is made up of the raw material of following mass percent：Wetting agent 0.2~1%, diffusant 0.3~2%, smoothing agent 5~10%, organic acid 5~10%, methenamine 0.2~5%, nickel chloride 5~9%, neutral salt 0.5~6%, organic salt 3~15%, surplus are pure water；The formula of iron ecology nickel plating water-based process material provided by the invention is reasonable, without external dc power supply, without heating source, using plated ironware as negative electrode, different potentials are there are using itself state, by way of ion exchange, so that nickel ion separate out in iron ecology nickel plating water-based process material and being combined with plated ironware, to form one layer of fine and close nickel coating on the surface of plated ironware, nickel plating effect is good, and the thickness of nickel coating is uniform, the effectively combination property and service life of lifting product, cost is low, energy-conserving and environment-protective, beneficial to wide popularization and application.
Description
Technical field
The present invention relates to ironware nickel-plating technology field, and in particular to a kind of iron ecology nickel plating water-based process material and its nickel plating
Method.
Background technology
Nickel plating, referred to as plated in the method for metal or some nonmetal plating last layer nickel by electrolysis or chemical method
Nickel.Nickel plating divides electronickelling and chemical nickel plating.Electronickelling is formed by nickel salt (claiming main salt), conducting salt, pH buffer, wetting agent
Electrolyte in, anode metallic nickel, negative electrode is plating piece, passes to direct current, on negative electrode (plating piece) deposit last layer uniformly, cause
Close nickel coating.What is obtained from the plating solution added with brightener is bright nickel, and is obtained in the electrolyte of no addition brightener
Be dark nickel.But its consuming electric power is more, and the processing of waste water and waste gas is also contemplated that, is unfavorable for energy-conserving and environment-protective.
Chemical plating is also known as electroless plating (Electroless plating), is referred to as self-catalysis plating
(Autocatalytic plating).Detailed process refers to：Under certain condition, the metal ion in the aqueous solution is reduced agent
Reduction, and the process being deposited on solid matrix surface.But it needs heating source, big energy-consuming, is unfavorable for energy-conserving and environment-protective.
The content of the invention
For above-mentioned deficiency, an object of the present invention is, there is provided one kind formula is reasonable, it is easy to accomplish, nickel plating effect
It is good, the iron ecology nickel plating water-based process material of energy-conserving and environment-protective.
The second object of the present invention is, there is provided a kind of energy quick Fabrication goes out above-mentioned iron ecology nickel plating water-based process material
Nickel plating process.The processing step of the nickel plating process is succinct, it is easy to accomplish, nickel plating efficiency high.
To achieve the above object, technical scheme provided by the present invention is：
A kind of iron ecology nickel plating water-based process material, it is made up of the raw material of following mass percent：Wetting agent 0.2~
1%, diffusant 0.3~2%, smoothing agent 5~10%, organic acid 5~10%, methenamine 0.2~5%, nickel chloride 5~9%,
Neutral salt 0.5~6%, organic salt 3~15%, surplus are pure water.
One kind as invention is improved, and the wetting agent includes but are not limited to paregal O -15 or peregal O-25.
One kind as invention is improved, and the diffusant includes but are not limited to calcium sulfate, magnesium carbonate or sulfate.
One kind as invention is improved, and the smoothing agent includes but are not limited to smoothing agent LS-2 or smoothing agent DXS-2.
One kind as invention is improved, and the organic acid includes but are not limited to malic acid or ethylenediamine tetra-acetic acid.
One kind as invention is improved, and the neutral salt includes but are not limited to sodium chloride, sodium sulphate or sodium nitrate.
One kind as invention is improved, and the organic salt includes but are not limited to disodium EDTA or ethylenediamine
Tetraacethyl tetrasodium salt.
A kind of nickel plating process of above-mentioned iron ecology nickel plating water-based process material, it comprises the following steps：
(1) preparation one uses liner magnesium drum made of magnesium material, and honeycomb hole is evenly distributed with the liner magnesium drum；
(2) the plated ironware for needing nickel plating is put into liner magnesium drum；
(3) the liner magnesium drum equipped with plated ironware is put into described iron ecology nickel plating water-based process material and soaked
Bubble, and constantly rotate liner magnesium drum so that plated ironware is constantly in contact with liner magnesium drum；And at this moment, plated ironware is
Negative electrode, itself state there are different potentials, by way of ion exchange so that in iron ecology nickel plating water-based process material
Nickel ion be combined with plated ironware, to form one layer of nickel coating fine and close, in uniform thickness on the surface of plated ironware.
Beneficial effects of the present invention are：The formula of iron ecology nickel plating water-based process material provided by the invention is reasonable, does not have to
External dc power supply, without heating source, using plated ironware as negative electrode, different potentials are there are using itself state, by from
The mode that son exchanges so that nickel ion separate out in iron ecology nickel plating water-based process material is simultaneously combined with plated ironware,
To form one layer of fine and close nickel coating on the surface of plated ironware, nickel plating effect is good, and the thickness of nickel coating is uniform, effectively lifting
The combination property and service life of product；The processing step of other nickel plating process is succinct, it is easy to accomplish, nickel plating efficiency high, cost
It is low, energy-conserving and environment-protective, beneficial to wide popularization and application.
With reference to embodiment, the present invention is further described.
Embodiment
Embodiment 1, a kind of iron ecology nickel plating water-based process material that the present embodiment provides, it is by following mass percent
Raw material forms：Wetting agent 0.2%, diffusant 1%, smoothing agent 10%, organic acid 5%, methenamine 4%, nickel chloride 9%, in
Property salt 0.5%, organic salt 15%, pure water 57.3%.
In the present embodiment, preferably, the wetting agent is preferably paregal O -15 or peregal O-25.The diffusant is excellent
Elect calcium sulfate, magnesium carbonate or sulfate as.The smoothing agent is preferably smoothing agent LS-2 or smoothing agent DXS-2.The organic acid
Preferably malic acid or ethylenediamine tetra-acetic acid.The neutral salt is preferably sodium chloride, sodium sulphate or sodium nitrate.The organic salt is excellent
Elect disodium EDTA or tetrasodium salt of EDTA as.
A kind of nickel plating process of above-mentioned iron ecology nickel plating water-based process material, it comprises the following steps：
(1) preparation one uses liner magnesium drum made of magnesium material, and honeycomb hole is evenly distributed with the liner magnesium drum；
(2) the plated ironware for needing nickel plating is put into liner magnesium drum；
(3) the liner magnesium drum equipped with plated ironware is put into described iron ecology nickel plating water-based process material and soaked
Bubble, and constantly rotate liner magnesium drum so that plated ironware is constantly in contact with liner magnesium drum；And at this moment, plated ironware is
Negative electrode, itself state there are different potentials, by way of ion exchange so that in iron ecology nickel plating water-based process material
Nickel ion be combined with plated ironware, to form one layer of nickel coating fine and close, in uniform thickness on the surface of plated ironware.
Embodiment 2, a kind of the iron ecology nickel plating water-based process material and its nickel plating process that the present embodiment provides, itself and implementation
Example 1 is essentially identical, and distinctive points are, it is made up of the raw material of following mass percent：Wetting agent 0.8%, diffusant 2%, put down
Whole dose 5%, organic acid 10%, methenamine 5%, nickel chloride 7%, neutral salt 3%, organic salt 3%, pure water 57.3%.
Embodiment 3, a kind of the iron ecology nickel plating water-based process material and its nickel plating process that the present embodiment provides, itself and implementation
Example 1 is essentially identical, and distinctive points are, it is made up of the raw material of following mass percent：Wetting agent 1%, diffusant 0.3%, put down
Whole dose 8%, organic acid 7%, methenamine 0.2%, nickel chloride 5%, neutral salt 6%, organic salt 15%, pure water 57.5%.
Embodiment 4, a kind of the iron ecology nickel plating water-based process material and its nickel plating process that the present embodiment provides, itself and implementation
Example 1 is essentially identical, and distinctive points are, it is made up of the raw material of following mass percent：Wetting agent 0.6%, diffusant 1.5%,
Smoothing agent 7%, organic acid 8%, methenamine 3%, nickel chloride 8%, neutral salt 4%, organic salt 14%, pure water 53.9%.
Embodiment 5, a kind of the iron ecology nickel plating water-based process material and its nickel plating process that the present embodiment provides, itself and implementation
Example 1 is essentially identical, and distinctive points are, it is made up of the raw material of following mass percent：Wetting agent 0.5%, diffusant 1.6%,
Smoothing agent 6%, organic acid 9%, methenamine 3.4%, nickel chloride 6%, neutral salt 2.5%, organic salt 6%, pure water 65%.
Above-described embodiment is only the preferable embodiment of the present invention, and the present invention can not enumerate out whole embodiment party
Formula, all technical schemes using one of above-described embodiment, or the equivalent variations done according to above-described embodiment, protected in the present invention
In the range of shield.
The formula of iron ecology nickel plating water-based process material provided by the invention is reasonable, without external dc power supply, without adding
Thermal source, using plated ironware as negative electrode, different potentials are there are using itself state, by way of ion exchange so that iron
Nickel ion separate out in ecological nickel plating water-based process material is simultaneously combined with plated ironware, with the surface shape of plated ironware
The nickel coating fine and close into one layer, nickel plating effect is good, and the thickness of nickel coating is uniform, effectively lifts combination property and the use of product
In the life-span, nickel plating efficiency high, cost is low, energy-conserving and environment-protective.
The announcement and teaching of book according to the above description, those skilled in the art in the invention can also be to above-mentioned embodiment party
Formula is changed and changed.Therefore, the invention is not limited in embodiment disclosed and described above, to the present invention's
Some modifications and changes should also be as falling into the scope of the claims of the present invention.In addition, although used in this specification
Some specific terms, but these terms are merely for convenience of description, do not form any restrictions to the present invention.Such as the present invention
Described in above-described embodiment, using other materials obtained from same or similarity method and component and its nickel plating process at this
In invention protection domain.
Claims (8)
1. a kind of iron ecology nickel plating water-based process material, it is characterised in that it is made up of the raw material of following mass percent：Wetting
Agent 0.2~1%, diffusant 0.3~2%, smoothing agent 5~10%, organic acid 5~10%, methenamine 0.2~5%, nickel chloride
5~9%, neutral salt 0.5~6%, organic salt 3~15%, surplus is pure water.
2. iron ecology nickel plating water-based process material according to claim 1, it is characterised in that：The wetting agent is included but not
It is only limitted to paregal O -15 or peregal O-25.
3. iron ecology nickel plating water-based process material according to claim 1, it is characterised in that：The diffusant is included but not
It is only limitted to calcium sulfate, magnesium carbonate or sulfate.
4. iron ecology nickel plating water-based process material according to claim 1, it is characterised in that：The smoothing agent is included but not
It is only limitted to smoothing agent LS-2 or smoothing agent DXS-2.
5. iron ecology nickel plating water-based process material according to claim 1, it is characterised in that：The organic acid is included but not
It is only limitted to malic acid or ethylenediamine tetra-acetic acid.
6. iron ecology nickel plating water-based process material according to claim 1, it is characterised in that：The neutral salt is included but not
It is only limitted to sodium chloride, sodium sulphate or sodium nitrate.
7. iron ecology nickel plating water-based process material according to claim 1, it is characterised in that：The organic salt is included but not
It is only limitted to disodium EDTA or tetrasodium salt of EDTA.
8. the nickel plating process of any described iron ecology nickel plating water-based process material, its feature exist in a kind of claim 1~7
In：It comprises the following steps：
(1) preparation one uses liner magnesium drum made of magnesium material, and honeycomb hole is evenly distributed with the liner magnesium drum；
(2) the plated ironware for needing nickel plating is put into liner magnesium drum；
(3) the liner magnesium drum equipped with plated ironware is put into described iron ecology nickel plating water-based process material and soaked,
And constantly rotate liner magnesium drum so that plated ironware is constantly in contact with liner magnesium drum；And at this moment, ironware is plated as the moon
Pole, itself state there are different potentials, by way of ion exchange so that in iron ecology nickel plating water-based process material
Nickel ion is combined with plated ironware, to form one layer of nickel coating fine and close, in uniform thickness on the surface of plated ironware.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710612690.XA CN107502876A (en) | 2017-07-25 | 2017-07-25 | Iron ecology nickel plating water-based process material and its nickel plating process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710612690.XA CN107502876A (en) | 2017-07-25 | 2017-07-25 | Iron ecology nickel plating water-based process material and its nickel plating process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107502876A true CN107502876A (en) | 2017-12-22 |
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ID=60689398
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710612690.XA Pending CN107502876A (en) | 2017-07-25 | 2017-07-25 | Iron ecology nickel plating water-based process material and its nickel plating process |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201834999U (en) * | 2010-10-20 | 2011-05-18 | 北京中科三环高技术股份有限公司 | Rotary drum for surface treatment |
| CN102732862A (en) * | 2012-07-18 | 2012-10-17 | 哈尔滨工业大学 | Method for displacement plating of Ni-S alloy barrier layer on copper foil, and chemical passivation method of barrier layer |
| CN106191824A (en) * | 2015-05-28 | 2016-12-07 | 石原化学株式会社 | Copper surface process displacement nickel plating bath, the manufacture method using the copper part of this plating bath and this copper part |
-
2017
- 2017-07-25 CN CN201710612690.XA patent/CN107502876A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201834999U (en) * | 2010-10-20 | 2011-05-18 | 北京中科三环高技术股份有限公司 | Rotary drum for surface treatment |
| CN102732862A (en) * | 2012-07-18 | 2012-10-17 | 哈尔滨工业大学 | Method for displacement plating of Ni-S alloy barrier layer on copper foil, and chemical passivation method of barrier layer |
| CN106191824A (en) * | 2015-05-28 | 2016-12-07 | 石原化学株式会社 | Copper surface process displacement nickel plating bath, the manufacture method using the copper part of this plating bath and this copper part |
Non-Patent Citations (3)
| Title |
|---|
| 刘智颖等: "还原性铁粉置换法处理化学镀低浓度含镍漂洗水", 《电镀与涂饰》 * |
| 张允诚等: "《电镀手册》", 31 January 2007 * |
| 田栋: "铜表面置换镀镍及镀层性能研究", 《中国博士学位论文全文数据库》 * |
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Application publication date: 20171222 |
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