CN107502103A - A kind of high weather resistant water-thinned fluorine silicone mask finish paint of outdoor and preparation method thereof - Google Patents
A kind of high weather resistant water-thinned fluorine silicone mask finish paint of outdoor and preparation method thereof Download PDFInfo
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- CN107502103A CN107502103A CN201710868090.XA CN201710868090A CN107502103A CN 107502103 A CN107502103 A CN 107502103A CN 201710868090 A CN201710868090 A CN 201710868090A CN 107502103 A CN107502103 A CN 107502103A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
- C09D183/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses high weather resistant water-thinned fluorine silicone mask finish paint of a kind of outdoor and preparation method thereof, the fluorine silicone mask finish paint includes the composition of following parts by weight：Fluorinated silicone modified acrylic emulsion：30 ~ 40 parts, hexadecyl trimethoxy silane：5 ~ 10 parts, hydroxymethyl cellulose：5 ~ 10 parts, ethanol：5 ~ 10 parts, oxalic acid：1 ~ 5 part, water-repelling agent：1 ~ 5 part, levelling agent：1 ~ 5 part, mould inhibitor：1 ~ 5 part, coalescents：1 ~ 5 part, defoamer：1 ~ 5 part, wetting agent：1 ~ 5 part, deionized water：40 ~ 50 parts.The finish can effectively improve coating richness, anti-wear performance and water resistance, it is preferred that water-based fluorine silicon resin, has superpower water resistance and washability heart infarction, coating surface hardness is high, pliability is good, film forming compactness is high, resistance to soiling and keeping a public place clean property are good, service life length.
Description
Technical field
The invention belongs to technical field of coatings, and in particular to a kind of high weather resistant water-thinned fluorine silicone mask finish paint of outdoor and its preparation
Method.
Background technology
Finish-all woodworks after mounting, will at once apply and brush one times paint.This layer is referred to as the oil of " finish "
Paint, can not only protect woodwork, and can also play isolation moisture, keep the effect of timber normal moisture content；Finish exists
Constructed behind true mineral varnish, for protecting main coating paint.Morning twilight finish weatherability and dirt-resistant are good, water-fast alkali resistant ability
By force, adhesive force is strong, and fungicidal properties is permanent.After brush finish, the service life of true mineral varnish can be caused to extend, true mineral varnish table
The aesthetic measure in face obtains lasting guarantee.
Present finish has many different calls, and some is crystal paint, and some is dust-proof paint.This product not only with
In woodwork, wallpaper paint is also widely used in, generally, the construction of wallpaper paint applies last layer cover after priming paint has been carried out
Finish paint, dust-proof, scrubbable effect can be played.Finish is liquid-transparent glue thing, need to be diluted with being watered during construction, typically
At least ratio is watered 1：More than 1, the meaning that is, the ratio of water is more than finish at least.As for construction, general facet
Long-pending construction is all painted with wool brush, it is necessary to use undercoat rod if large area.Construct fairly simple.
For finish, the current country is primarily present following patent document：
Publication No. 106634508A Chinese patent discloses a kind of water-based fluorocarbon dumb light finish and preparation method thereof, described
Water-based fluorocarbon dumb light finish is made up of host and curing agent, wherein, the component and content of host are：Water 10-34%, bactericide
0.1-0.3%, mould inhibitor 0.1-0.3%, high hydroxyl water-base fluorocarbon emulsion 40.4-60%, low hydroxyl aqueous acrylic emulsion 25-
35%th, defoamer 0.1-0.3%, thickener 0.3-0.8%, according to host during use：Curing agent is 4-7:1 ratio mixing is equal
It is even；The hydroxy radical content of high hydroxyl water-base fluorocarbon emulsion is between 3.0-3.5%；The hydroxy radical content of low hydroxyl aqueous acrylic emulsion
Between 1.0-2.0%；Curing agent is water-based isocyanate class curing agent.The water-based fluorocarbon dumb light cover that the application provides
Paint, without adding flatting silica, overcomes existing finish between environment and health of human body adverse effect, low production efficiency, batch
Gloss is unstable, easy generation sedimentation, the transparency of paint film, compactness, bad water resistance and levelability the defects of.
The content of the invention
To solve above-mentioned problem, it is an object of the invention to provide a kind of high weather resistant water-thinned fluorine silicone mask face of outdoor
Paint and preparation method thereof, the finish can effectively improve coating richness, anti-wear performance and water resistance, preferably water-based fluorine silicon
Resin, has superpower water resistance and a washability heart infarction, and coating surface hardness is high, pliability is good, film forming compactness is high, resistance to soiling and
Keeping a public place clean property is good, service life length.
To reach above-mentioned purpose, the technical scheme is that：
A kind of high weather resistant water-thinned fluorine silicone mask finish paint of outdoor, the fluorine silicone mask finish paint include the composition of following parts by weight：Fluorine silicon changes
Property acrylic emulsion：30 ~ 40 parts, hexadecyl trimethoxy silane：5 ~ 10 parts, hydroxymethyl cellulose：5 ~ 10 parts, ethanol：5~
10 parts, oxalic acid：1 ~ 5 part, water-repelling agent：1 ~ 5 part, levelling agent：1 ~ 5 part, mould inhibitor：1 ~ 5 part, coalescents：1 ~ 5 part, defoamer：
1 ~ 5 part, wetting agent：1 ~ 5 part, deionized water：40 ~ 50 parts.
Further, the fluorine silicone mask finish paint includes the composition of following parts by weight：Fluorinated silicone modified acrylic emulsion：35 ~ 40 parts,
Hexadecyl trimethoxy silane：5 ~ 8 parts, hydroxymethyl cellulose：7 ~ 10 parts, ethanol：6 ~ 10 parts, oxalic acid：1 ~ 3 part, water-repelling agent：
1 ~ 4 part, levelling agent：2 ~ 5 parts, mould inhibitor：3 ~ 5 parts, coalescents：1 ~ 2 part, defoamer：1 ~ 3 part, wetting agent：3 ~ 5 parts, go from
Sub- water：45 ~ 50 parts.
Preferably, the fluorine silicone mask finish paint includes the composition of following parts by weight：Fluorinated silicone modified acrylic emulsion：35 parts, ten
Six alkyl trimethoxysilanes：7 parts, hydroxymethyl cellulose：8 parts, ethanol：6 parts, oxalic acid：3 parts, water-repelling agent：2 parts, levelling agent：4
Part, mould inhibitor：3 parts, coalescents：2 parts, defoamer：1 part, wetting agent：4 parts, deionized water：45 parts.
Preferably, the defoamer is amide-type defoamer, organic silicon defoamer or mineral oil defoaming agent.
Preferably, the coalescents are propandiol butyl ether, alcohol ester 12 or propane diols phenylate.
Preferably, the levelling agent is BYK322.
Preferably, the wetting agent is modified polyorganosiloxane.
Preferably, the water-repelling agent is silanes water-repelling agent.
Preferably, the wetting agent is modified polyorganosiloxane；The mould inhibitor is monoxone or sodium chlorite.
Meanwhile the present invention also provides a kind of preparation method of the high weather resistant water-thinned fluorine silicone mask finish paint of outdoor, it is characterised in that
The preparation method comprises the following steps：1) mixer is taken, by weight by fluorinated silicone modified acrylic emulsion, cetyl front three
TMOS, hydroxymethyl cellulose, ethanol, oxalic acid and 50wt% deionized water are added in mixer, in normal temperature, 600 ~ 700
Rev/min rotating speed under stir 30 ~ 40 minutes；2) water-repelling agent, levelling agent, mould inhibitor, coalescents, defoamer, wetting agent are added
And remaining deionized water, 30 ~ 40 DEG C are warming up to, is stirred 20 ~ 30 minutes under 800 ~ 1000 revs/min of rotating speed, is cooled to room temperature,
Filtering, stand, produce the high weather resistant water-thinned fluorine silicone mask finish paint of the outdoor.
The invention has the advantages that：
The finish can effectively improve coating richness, anti-wear performance and water resistance, preferably water-based fluorine silicon resin, have super
Strong water resistance and washability heart infarction, coating surface hardness is high, pliability is good, and film forming compactness is high, resistance to soiling and keeping a public place clean property are good, makes
Use long lifespan；
Application property is tested, and it is accessible to brush two；Low-temperature stability is tested, and is never degenerated；Drying time（Surface drying）, 1 hour；Contrast
Rate（White and light color）, 0.91；96 hours water resistance tests, it is without exception；Alkali resistance test in 48 hours, it is without exception；Abrasion resistance
>=500 times；Stain resistance（5 times）, 13%.
Embodiment
Below by specific embodiment, the present invention is described further, but embodiment is not intended to limit the protection of the present invention
Scope.
The high weather resistant water-thinned fluorine silicone mask finish paint of a kind of outdoor provided by the present invention, the fluorine silicone mask finish paint include following weight
Measure the composition of part：Fluorinated silicone modified acrylic emulsion：30 ~ 40 parts, hexadecyl trimethoxy silane：5 ~ 10 parts, hydroxylmethyl cellulose
Element：5 ~ 10 parts, ethanol：5 ~ 10 parts, oxalic acid：1 ~ 5 part, water-repelling agent：1 ~ 5 part, levelling agent：1 ~ 5 part, mould inhibitor：1 ~ 5 part, film forming
Auxiliary agent：1 ~ 5 part, defoamer：1 ~ 5 part, wetting agent：1 ~ 5 part, deionized water：40 ~ 50 parts.
Further, the fluorine silicone mask finish paint includes the composition of following parts by weight：Fluorinated silicone modified acrylic emulsion：35 ~ 40 parts,
Hexadecyl trimethoxy silane：5 ~ 8 parts, hydroxymethyl cellulose：7 ~ 10 parts, ethanol：6 ~ 10 parts, oxalic acid：1 ~ 3 part, water-repelling agent：
1 ~ 4 part, levelling agent：2 ~ 5 parts, mould inhibitor：3 ~ 5 parts, coalescents：1 ~ 2 part, defoamer：1 ~ 3 part, wetting agent：3 ~ 5 parts, go from
Sub- water：45 ~ 50 parts.
Preferably, the fluorine silicone mask finish paint includes the composition of following parts by weight：Fluorinated silicone modified acrylic emulsion：35 parts, ten
Six alkyl trimethoxysilanes：7 parts, hydroxymethyl cellulose：8 parts, ethanol：6 parts, oxalic acid：3 parts, water-repelling agent：2 parts, levelling agent：4
Part, mould inhibitor：3 parts, coalescents：2 parts, defoamer：1 part, wetting agent：4 parts, deionized water：45 parts.
Preferably, the defoamer is amide-type defoamer, organic silicon defoamer or mineral oil defoaming agent.
Preferably, the coalescents are propandiol butyl ether, alcohol ester 12 or propane diols phenylate.
Preferably, the levelling agent is BYK322.
Preferably, the wetting agent is modified polyorganosiloxane.
Preferably, the water-repelling agent is silanes water-repelling agent.
Preferably, the wetting agent is modified polyorganosiloxane；The mould inhibitor is monoxone or sodium chlorite.
Meanwhile the present invention also provides a kind of preparation method of the high weather resistant water-thinned fluorine silicone mask finish paint of outdoor, it is characterised in that
The preparation method comprises the following steps：1) mixer is taken, by weight by fluorinated silicone modified acrylic emulsion, cetyl front three
TMOS, hydroxymethyl cellulose, ethanol, oxalic acid and 50wt% deionized water are added in mixer, in normal temperature, 600 ~ 700
Rev/min rotating speed under stir 30 ~ 40 minutes；2) water-repelling agent, levelling agent, mould inhibitor, coalescents, defoamer, wetting agent are added
And remaining deionized water, 30 ~ 40 DEG C are warming up to, is stirred 20 ~ 30 minutes under 800 ~ 1000 revs/min of rotating speed, is cooled to room temperature,
Filtering, stand, produce the high weather resistant water-thinned fluorine silicone mask finish paint of the outdoor.
It should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted.Although with reference to compared with
The present invention is described in detail good embodiment, it will be understood by those within the art that, can be to the technology of invention
Scheme is modified or equivalent substitution, and without departing from the scope of technical solution of the present invention, it all should cover the power in the present invention
In sharp claimed range.
Claims (10)
1. a kind of high weather resistant water-thinned fluorine silicone mask finish paint of outdoor, it is characterised in that the fluorine silicone mask finish paint includes following parts by weight
Composition：Fluorinated silicone modified acrylic emulsion：30 ~ 40 parts, hexadecyl trimethoxy silane：5 ~ 10 parts, hydroxymethyl cellulose：5~
10 parts, ethanol：5 ~ 10 parts, oxalic acid：1 ~ 5 part, water-repelling agent：1 ~ 5 part, levelling agent：1 ~ 5 part, mould inhibitor：1 ~ 5 part, coalescents：1
~ 5 parts, defoamer：1 ~ 5 part, wetting agent：1 ~ 5 part, deionized water：40 ~ 50 parts.
2. the high weather resistant water-thinned fluorine silicone mask finish paint of outdoor according to claim 1, it is characterised in that the fluorine silicone mask finish paint
Include the composition of following parts by weight：Fluorinated silicone modified acrylic emulsion：35 ~ 40 parts, hexadecyl trimethoxy silane：5 ~ 8 parts, hydroxyl
Methylcellulose：7 ~ 10 parts, ethanol：6 ~ 10 parts, oxalic acid：1 ~ 3 part, water-repelling agent：1 ~ 4 part, levelling agent：2 ~ 5 parts, mould inhibitor：3~5
Part, coalescents：1 ~ 2 part, defoamer：1 ~ 3 part, wetting agent：3 ~ 5 parts, deionized water：45 ~ 50 parts.
3. the high weather resistant water-thinned fluorine silicone mask finish paint of outdoor according to claim 1, it is characterised in that the fluorine silicone mask finish paint
Include the composition of following parts by weight：Fluorinated silicone modified acrylic emulsion：35 parts, hexadecyl trimethoxy silane：7 parts, methylol
Cellulose：8 parts, ethanol：6 parts, oxalic acid：3 parts, water-repelling agent：2 parts, levelling agent：4 parts, mould inhibitor：3 parts, coalescents：2 parts, disappear
Infusion：1 part, wetting agent：4 parts, deionized water：45 parts.
4. the high weather resistant water-thinned fluorine silicone mask finish paint of outdoor according to claim 1, it is characterised in that the defoamer is acyl
Amine defoamer, organic silicon defoamer or mineral oil defoaming agent.
5. the high weather resistant water-thinned fluorine silicone mask finish paint of outdoor according to claim 1, it is characterised in that the coalescents are
Propandiol butyl ether, alcohol ester 12 or propane diols phenylate.
6. the high weather resistant water-thinned fluorine silicone mask finish paint of outdoor according to claim 1, it is characterised in that the levelling agent is
BYK322。
7. the high weather resistant water-thinned fluorine silicone mask finish paint of outdoor according to claim 1, it is characterised in that the wetting agent is to change
Property polysiloxanes.
8. the high weather resistant water-thinned fluorine silicone mask finish paint of outdoor according to claim 1, it is characterised in that the water-repelling agent is silicon
Alkanes water-repelling agent.
9. the high weather resistant water-thinned fluorine silicone mask finish paint of outdoor according to claim 1, it is characterised in that the wetting agent is to change
Property polysiloxanes；The mould inhibitor is monoxone or sodium chlorite.
10. a kind of preparation method of high weather resistant water-thinned fluorine silicone mask finish paint of outdoor as any one of claim 1 ~ 9, its
It is characterised by, the preparation method comprises the following steps：1) mixer is taken, by weight by fluorinated silicone modified acrylic emulsion, ten
Six alkyl trimethoxysilanes, hydroxymethyl cellulose, ethanol, oxalic acid and 50wt% deionized water are added in mixer, normal
Stirred 30 ~ 40 minutes under temperature, 600 ~ 700 revs/min of rotating speed；2) water-repelling agent, levelling agent, mould inhibitor, coalescents, defoaming are added
Agent, wetting agent and remaining deionized water, are warming up to 30 ~ 40 DEG C, are stirred 20 ~ 30 minutes under 800 ~ 1000 revs/min of rotating speed, cold
But to room temperature, filter, stand, produce the high weather resistant water-thinned fluorine silicone mask finish paint of the outdoor.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710868090.XA CN107502103A (en) | 2017-09-22 | 2017-09-22 | A kind of high weather resistant water-thinned fluorine silicone mask finish paint of outdoor and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710868090.XA CN107502103A (en) | 2017-09-22 | 2017-09-22 | A kind of high weather resistant water-thinned fluorine silicone mask finish paint of outdoor and preparation method thereof |
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| Publication Number | Publication Date |
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| CN107502103A true CN107502103A (en) | 2017-12-22 |
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| CN201710868090.XA Pending CN107502103A (en) | 2017-09-22 | 2017-09-22 | A kind of high weather resistant water-thinned fluorine silicone mask finish paint of outdoor and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108587130A (en) * | 2018-04-27 | 2018-09-28 | 天长市协正塑业有限公司 | A kind of clean surfaces type outdoor plastics |
| CN108975785A (en) * | 2018-08-27 | 2018-12-11 | 盐城市荣立新型建材有限公司 | The cement process for producing bricks of natural-like stone |
| CN111471367A (en) * | 2020-04-10 | 2020-07-31 | 湖南化工职业技术学院（湖南工业高级技工学校） | High-transparency hydrophobic water-based paint and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104277652A (en) * | 2014-10-20 | 2015-01-14 | 芜湖县双宝建材有限公司 | Water-based anticorrosive paint |
| CN105295632A (en) * | 2015-12-07 | 2016-02-03 | 佛山市高明福隆斯新材料科技有限公司 | Environment-friendly furniture coating and preparation method thereof |
| CN105619558A (en) * | 2016-03-01 | 2016-06-01 | 山东农业大学 | Preparation method of organic-inorganic hybrid super-hydrophobic and oleophobic wood modifier with mold-proof, sterilization, anti-flaming and weather-proof properties |
-
2017
- 2017-09-22 CN CN201710868090.XA patent/CN107502103A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104277652A (en) * | 2014-10-20 | 2015-01-14 | 芜湖县双宝建材有限公司 | Water-based anticorrosive paint |
| CN105295632A (en) * | 2015-12-07 | 2016-02-03 | 佛山市高明福隆斯新材料科技有限公司 | Environment-friendly furniture coating and preparation method thereof |
| CN105619558A (en) * | 2016-03-01 | 2016-06-01 | 山东农业大学 | Preparation method of organic-inorganic hybrid super-hydrophobic and oleophobic wood modifier with mold-proof, sterilization, anti-flaming and weather-proof properties |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108587130A (en) * | 2018-04-27 | 2018-09-28 | 天长市协正塑业有限公司 | A kind of clean surfaces type outdoor plastics |
| CN108975785A (en) * | 2018-08-27 | 2018-12-11 | 盐城市荣立新型建材有限公司 | The cement process for producing bricks of natural-like stone |
| CN111471367A (en) * | 2020-04-10 | 2020-07-31 | 湖南化工职业技术学院（湖南工业高级技工学校） | High-transparency hydrophobic water-based paint and preparation method thereof |
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Application publication date: 20171222 |