CN107502092A - A kind of bamboo handicraft product of reversible temperature induced color changing - Google Patents
A kind of bamboo handicraft product of reversible temperature induced color changing Download PDFInfo
- Publication number
- CN107502092A CN107502092A CN201710600396.7A CN201710600396A CN107502092A CN 107502092 A CN107502092 A CN 107502092A CN 201710600396 A CN201710600396 A CN 201710600396A CN 107502092 A CN107502092 A CN 107502092A
- Authority
- CN
- China
- Prior art keywords
- color changing
- reversible temperature
- induced color
- temperature induced
- bamboo handicraft
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/26—Thermosensitive paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/06—Ethers; Acetals; Ketals; Ortho-esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
- C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/10—Encapsulated ingredients
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Dispersion Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of bamboo handicraft product of reversible temperature induced color changing, are made up of the reversible temperature induced color changing coating of bamboo handicraft product and outer surface.By having the coating of reversible temperature induced color changing performance in the coating of traditional bamboo handicraft product surface, the sight of traditional bamboo handicraft product is effectively improved, it is combined with modern science and technology, broken the normal procedure, obtains the higher market competitiveness.
Description
Technical field
The present invention relates to bamboo handicraft product technical field, more particularly to a kind of bamboo handicraft product of reversible temperature induced color changing.
Background technology
Traditional handicraft is a part particularly important in Chinese traditional culture, and bamboo weaving is the Traditional Folk hand of Chinese elite
One of technique.Bamboo silk soft pliable, thickness is well-balanced, color and luster is graceful, by the design of novelty, can be woven into various honesties certainly
So, handsome in appearance, Portable durable practical art product.With the development of the social economy, woven products occupation rate of market progressively carries
Rise, or even find a good sale at home and abroad, the demand in market also promotes traditional bamboo weaving to produce the challenge for facing industrial upgrading, is keeping tradition
The cycle development of industry how is realized on the basis of bamboo handicraft elite, the competitiveness of product is improved, forms a set of fecund
The development model of industry chain is the prerequisite of bamboo weaving techno-globalism and the marketization.
The color and decoration for changing bamboo handicraft product are the important directions that woven products are melted into Times ' Demand, are realized
The color variation of woven products and the important channel of lifting product economy value, it is especially tight in the homogeneity of nowadays woven products
It is the important means for breaking market confinement that under the premise of the market of weight, research and development are characteristic, have the practical product combined with sight concurrently.
Common woven products colouring mode is in its surface spraying colors dyestuff or is impregnated in dye liquor that the product after so handling is in
Existing is a kind of static color character, if product dynamic color feature can be assigned, the market that can effectively improve product is competing
Strive power.
Reversible temperature induced color changing coating is the smart coatings that a kind of temperature change causes color change, it is most common have Ag, Cu,
Hg iodide, complex compound cobalt salt, nickel salt hexamethylenetetramine etc. are the inorganic temperature change material of representative, and this kind of material color is fresh
It is bright, but its discoloring temperature is high, toxicity is big, restorative difference, using being restricted.《Fine chemistry industry》The 9th phase of volume 32 in 2015
On " temperature induced color changing coating preparation and discoloration research " text for publishing describe a kind of organic temperature induced color changing of triarylmethane compound
Coating, its have the advantages that low discoloring temperature, good reversibility, stablize it is safe, but its be suitable for fabric fibre dyeing use,
Difficulty is coated on this kind of material product of bamboo silk, easily causes colouring uneven, influences using effect.
The content of the invention
A kind of the defects of present invention is in order to make up prior art, there is provided bamboo handicraft product of reversible temperature induced color changing.
The present invention is achieved by the following technical solutions：
A kind of bamboo handicraft product of reversible temperature induced color changing, it is the reversible temperature induced color changing coating structure by bamboo handicraft product and outer surface
Into.
Described reversible temperature induced color changing coating color change interval is -5 DEG C -50 DEG C, becomes chromatic sensitivity as 0.5-3 DEG C.
Described reversible temperature induced color changing coating is formed by reversible temperature induced color changing paint solidification, and its thickness is 10-100 μm.
Described reversible temperature induced color changing coating is thermoplastic resin fat liquor, the micro- glue of 10-20% heat discolorations by 60-80%
Capsule, 5-15% heat filling, the coalescents compounding of surplus form.
Described thermoplastic resin fat liquor is emulsion acrylic resin, organosilicon modified crylic acid resin emulsion, water-based poly-
One kind in urethane emulsion, styrene-acrylic emulsion, water-based fluorocarbon resin emulsion, solid content 30-50%.
Described heat discoloration microcapsules are made by following methods：
（1）By in the alcohol solution of heat discoloration powder input 90%, 40-50 DEG C is warming up to after ultrasonic disperse processing 30-50min, by
Silane coupler is added dropwise in drop, and is filtered with 300-500 turns/min speed stirring reaction 1-5h, reaction after terminating, and product is through water
Wash, dry after the heat discoloration powder core material that is modified of surface, wherein heat discoloration powder, alcohol solution, silane coupler three
Volume ratio is 1:5-20:0.01-0.1；
（2）Take amphipathic chitose to be dissolved in appropriate 3-5% sodium hydrate aqueous solution, then add the temperature-sensitive that surface is modified
Change colour core, ultrasonic vibration processing 50-60min, epoxychloropropane, stirring reaction is added dropwise after core is dispersed in the solution
5-8h, reaction terminate rear filtration product, and product produces after washing, drying process, and wherein amphipathic chitose, surface are modified sense
Temperature discoloration core, epoxychloropropane three are according to 1g：0.5-1g：0.1ml proportional arrangement.
Described heat filling is one kind in zinc oxide, titanium dioxide, alundum (Al2O3).
Described coalescents be ethylene glycol phenyl ether, dipropylene, one kind in propandiol butyl ether or it is a kind of with
On.
The present invention is using traditional bamboo handicraft product as base material, in painting of its surface coating with reversible temperature induced color changing performance
Layer, effectively improves the sight of traditional bamboo handicraft product, it is combined with modern science and technology, broken the normal procedure, and obtains higher
The market competitiveness.In preparation process, in order to preferably realize the impact of performance, temperature induced color changing powder is subjected to table with silane coupler
Face is modified, and is improved its surface-active, is improved its reactivity with amphipathic chitose, ultimately forms stable amphiphilic chitosan
The temperature induced color changing microencapsulation material of cladding, is finally scattered in water-base resin coating again, is applied with thermally sensitive resin
Layer realizes color changeable effect as carrier, changes toner and bamboo handicraft product are dyed with difficult limitation, the process of this technique is green
Colour circle is protected, and does not destroy the performance characteristics of bamboo plaited article in itself.
Embodiment
A kind of bamboo handicraft product of reversible temperature induced color changing, it is the reversible temperature induced color changing coating by bamboo handicraft product and outer surface
Form.The color change interval of reversible temperature induced color changing coating is -5 DEG C -50 DEG C, becomes chromatic sensitivity as 0.5 DEG C.
Wherein reversible temperature induced color changing coating is formed by reversible temperature induced color changing paint solidification, and its thickness is 10 μm.
Emulsion acrylic resin, 10% heat discoloration that it is 30% by 60% solid content that wherein reversible temperature induced color changing coating, which is,
Microcapsules, 5% zinc oxide, the ethylene glycol phenyl ether compounding of surplus form.
Wherein heat discoloration microcapsules are made by following methods：
（1）By in the alcohol solution of heat discoloration powder input 90%, 40 DEG C are warming up to after ultrasonic disperse processing 30min, is added dropwise dropwise
Silane coupler, and with 300 turns/min speed stirring reaction 1h, reaction is filtered after terminating, product through washing, dry after table
The heat discoloration powder core material that face is modified, wherein heat discoloration powder, alcohol solution, the volume ratio of silane coupler three are 1:5:
0.01；
（2）Take amphipathic chitose to be dissolved in 3% appropriate sodium hydrate aqueous solution, then add the temperature-sensitive that surface is modified and become
Color core, ultrasonic vibration processing 50min, is added dropwise epoxychloropropane after core is dispersed in the solution, stirring reaction 5h, instead
Filtration product after should terminating, product produce after washing, drying process, and wherein amphipathic chitose, surface are modified heat discoloration
Core, epoxychloropropane three are according to 1g：0.5g：0.1ml proportional arrangement.
Claims (8)
1. a kind of bamboo handicraft product of reversible temperature induced color changing, it is characterised in that be the Reversible temperature by bamboo handicraft product and outer surface
Discoloration coating is caused to form.
2. a kind of bamboo handicraft product of reversible temperature induced color changing as claimed in claim 1, it is characterised in that described Reversible temperature causes
Discoloration coating color change interval is -5 DEG C -50 DEG C, becomes chromatic sensitivity as 0.5-3 DEG C.
3. a kind of bamboo handicraft product of reversible temperature induced color changing as claimed in claim 1 or 2, it is characterised in that described is reversible
Temperature induced color changing coating is formed by reversible temperature induced color changing paint solidification, and its thickness is 10-100 μm.
4. a kind of bamboo handicraft product of reversible temperature induced color changing as claimed in claim 3, it is characterised in that described Reversible temperature causes
Allochroic paint is by 60-80% thermoplastic resin fat liquor, 10-20% heat discolorations microcapsules, 5-15% heat filling, surplus
Coalescents compounding form.
A kind of 5. bamboo handicraft product of reversible temperature induced color changing as claimed in claim 4, it is characterised in that described thermoplastic resin
Fat liquor is emulsion acrylic resin, organosilicon modified crylic acid resin emulsion, aqueous polyurethane emulsion, styrene-acrylic emulsion, water-based
One kind in fluorocarbon resin emulsion, solid content 30-50%.
A kind of 6. bamboo handicraft product of reversible temperature induced color changing as claimed in claim 4, it is characterised in that described heat discoloration
Microcapsules are made by following methods：
（1）By in the alcohol solution of heat discoloration powder input 90%, 40-50 DEG C is warming up to after ultrasonic disperse processing 30-50min, by
Silane coupler is added dropwise in drop, and is filtered with 300-500 turns/min speed stirring reaction 1-5h, reaction after terminating, and product is through water
Wash, dry after the heat discoloration powder core material that is modified of surface, wherein heat discoloration powder, alcohol solution, silane coupler three
Volume ratio is 1:5-20:0.01-0.1；
（2）Take amphipathic chitose to be dissolved in appropriate 3-5% sodium hydrate aqueous solution, then add the temperature-sensitive that surface is modified
Change colour core, ultrasonic vibration processing 50-60min, epoxychloropropane, stirring reaction is added dropwise after core is dispersed in the solution
5-8h, reaction terminate rear filtration product, and product produces after washing, drying process, and wherein amphipathic chitose, surface are modified sense
Temperature discoloration core, epoxychloropropane three are according to 1g：0.5-1g：0.1ml proportional arrangement.
A kind of 7. bamboo handicraft product of reversible temperature induced color changing as claimed in claim 4, it is characterised in that described heat filling
For one kind in zinc oxide, titanium dioxide, alundum (Al2O3).
A kind of 8. bamboo handicraft product of reversible temperature induced color changing as claimed in claim 4, it is characterised in that described coalescents
For the one or more in ethylene glycol phenyl ether, dipropylene, propandiol butyl ether.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710600396.7A CN107502092A (en) | 2017-07-21 | 2017-07-21 | A kind of bamboo handicraft product of reversible temperature induced color changing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710600396.7A CN107502092A (en) | 2017-07-21 | 2017-07-21 | A kind of bamboo handicraft product of reversible temperature induced color changing |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107502092A true CN107502092A (en) | 2017-12-22 |
Family
ID=60689217
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710600396.7A Pending CN107502092A (en) | 2017-07-21 | 2017-07-21 | A kind of bamboo handicraft product of reversible temperature induced color changing |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107502092A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108624162A (en) * | 2018-05-16 | 2018-10-09 | 奥普家居股份有限公司 | Solvent type oil rub resistance heat discoloration coating and preparation method thereof |
| CN108948927A (en) * | 2018-05-03 | 2018-12-07 | 阜南县铭钰柳木工艺品有限公司 | A kind of preparation method of the bamboo woven flower vase of blooming period prolonging |
| CN109852155A (en) * | 2018-12-04 | 2019-06-07 | 赤水市牵手竹艺发展有限公司 | A kind of self-heating bamboo handicraft product |
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| CN106641830A (en) * | 2015-10-27 | 2017-05-10 | 安徽华宇工艺品集团有限公司 | Novel willow table lamp |
| CN106634313A (en) * | 2016-12-30 | 2017-05-10 | 哈尔滨理工大学 | Low-temperature reversible thermochromic coating and preparation method thereof |
-
2017
- 2017-07-21 CN CN201710600396.7A patent/CN107502092A/en active Pending
Patent Citations (3)
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| CN104086946A (en) * | 2014-07-03 | 2014-10-08 | 合肥杰事杰新材料股份有限公司 | Preparation method of micro-capsule fly ash floating bead toughened and reinforced phenolic foam |
| CN106641830A (en) * | 2015-10-27 | 2017-05-10 | 安徽华宇工艺品集团有限公司 | Novel willow table lamp |
| CN106634313A (en) * | 2016-12-30 | 2017-05-10 | 哈尔滨理工大学 | Low-temperature reversible thermochromic coating and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 张启凤: ""羟丙基壳聚糖及其水凝胶的理化性能和药物缓释应用研究"", 《中国优秀博硕士学位论文全文数据库（硕士） 工程科技Ⅰ辑》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108948927A (en) * | 2018-05-03 | 2018-12-07 | 阜南县铭钰柳木工艺品有限公司 | A kind of preparation method of the bamboo woven flower vase of blooming period prolonging |
| CN108624162A (en) * | 2018-05-16 | 2018-10-09 | 奥普家居股份有限公司 | Solvent type oil rub resistance heat discoloration coating and preparation method thereof |
| CN109852155A (en) * | 2018-12-04 | 2019-06-07 | 赤水市牵手竹艺发展有限公司 | A kind of self-heating bamboo handicraft product |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20171222 |